KR950008459A - 1,3-부타디엔의 하이드로포밀화 방법 - Google Patents

1,3-부타디엔의 하이드로포밀화 방법 Download PDF

Info

Publication number
KR950008459A
KR950008459A KR1019940022057A KR19940022057A KR950008459A KR 950008459 A KR950008459 A KR 950008459A KR 1019940022057 A KR1019940022057 A KR 1019940022057A KR 19940022057 A KR19940022057 A KR 19940022057A KR 950008459 A KR950008459 A KR 950008459A
Authority
KR
South Korea
Prior art keywords
process according
aqueous
aqueous solution
butadiene
water soluble
Prior art date
Application number
KR1019940022057A
Other languages
English (en)
Other versions
KR100335516B1 (ko
Inventor
펠 베른하르트
헤르만스 페터
Original Assignee
페터스, 라이헬트
훽스트 아크티엔게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 페터스, 라이헬트, 훽스트 아크티엔게젤샤프트 filed Critical 페터스, 라이헬트
Publication of KR950008459A publication Critical patent/KR950008459A/ko
Application granted granted Critical
Publication of KR100335516B1 publication Critical patent/KR100335516B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1,3-부타디엔을 촉매로서 하나 이상의 수용성 로듐 화합물 및 하나 이상의 수용성 유기 포스핀을 함유하는 수용액의 존재하에서 60 내지 150℃ 및 1 내지 20MPa에서 하이드로포밀화시킨다. n-C5알데히드 및 n-C5알데히드의 2차 생성물의 생성에 대한 반응 선택성을 증가시키기 위해 촉매 수용액의 pH를 8 내지 11로 유지시킨다.

Description

1,3-부타디엔의 하이드로포밀화 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하나 이상의 수용성 모듐 화합물과 하나 이상의 수용성 유기 포스핀을 함유하는 pH 8.0 내지 11.0의 수용액속에서 부타디엔을 반응시킴을 포함하여, 1,3-부타디엔을 촉매로서의 당해 수용액의 존재하에 60 내지 150℃의 온도 및 1 내지 20MPa의 압력에서 하이드로포밀화시키는 방법.
  2. 제1항에 있어서, 수용액의 pH 8.5 내지 9.5인 방법.
  3. 제1항 또는 제2항에 있어서, pH가 완충 혼합물을 사용하여 조절되는 방법.
  4. 제1항 내지 제3항 중의 어느 한 항에 있어서, 반응이 90 내지 120℃에서 수행되는 방법.
  5. 제1항 내지 제4항 중의 어느 한 항에 있어서, 반응이 1 내지 10MPa의 압력하에서 수행되는 방법.
  6. 제1항 내지 제5항 중의 어느 한 항에 있어서, 촉매 수용액의 로듐 농도가 촉매 수용액을 기준으로 하여 20 내지 2000중량ppm, 바람직하게는 50 내지 700중량ppm인 방법.
  7. 제1항 내지 제6항 중의 어느 한 항에 있어서, 로듐 1mol당 4 내지 100mol, 바람직하게는 10 내지 60mol의 인이 수용액에 존재하는 방법.
  8. 제1항 내지 제7항 중의 어느 한 항에 있어서, 사용되는 수용성 포스핀이 하나 이상의 설폰산 그룹 또는 하나 이상의 카복실 그룹을 함유하는 트리아릴포스핀, 트리알킬포스핀, 트리(알킬아릴)포스핀, 알킬렌디포스핀 또는 아릴디포스핀인 방법.
  9. 제1항 내지 제8항 중의 어느 한 항에 있어서, 촉매 수용액이 가용화제를 함유하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940022057A 1993-09-09 1994-09-02 1,3-부타디엔의하이드로포밀화방법 KR100335516B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4330489A DE4330489A1 (de) 1993-09-09 1993-09-09 Verfahren zur Hydroformylierung von Butadien-1,3
DEP4330489.3 1993-09-09

Publications (2)

Publication Number Publication Date
KR950008459A true KR950008459A (ko) 1995-04-17
KR100335516B1 KR100335516B1 (ko) 2002-11-13

Family

ID=6497218

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940022057A KR100335516B1 (ko) 1993-09-09 1994-09-02 1,3-부타디엔의하이드로포밀화방법

Country Status (14)

Country Link
US (1) US5434312A (ko)
EP (1) EP0643031B1 (ko)
JP (1) JP2609429B2 (ko)
KR (1) KR100335516B1 (ko)
CN (1) CN1106374A (ko)
AU (1) AU671763B2 (ko)
BR (1) BR9403438A (ko)
CA (1) CA2131337A1 (ko)
DE (2) DE4330489A1 (ko)
ES (1) ES2112457T3 (ko)
PL (1) PL177092B1 (ko)
SG (1) SG44824A1 (ko)
TW (1) TW289017B (ko)
ZA (1) ZA946773B (ko)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19532394A1 (de) * 1995-09-02 1997-03-06 Hoechst Ag Verfahren zur Herstellung von Pentenalen
US6187970B1 (en) * 1996-04-24 2001-02-13 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing 1,6-hexanediols
US5886237A (en) * 1996-04-24 1999-03-23 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing alkenals and alkenols
US6172269B1 (en) * 1996-04-24 2001-01-09 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing 1,6-hexanediols
US5821389A (en) * 1996-04-24 1998-10-13 Union Carbide Chemicals & Technology Corporation Processes for producing hydroxyaldehydes
US5817883A (en) * 1996-04-24 1998-10-06 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing hydroxyaldehydes
US5962680A (en) * 1997-04-15 1999-10-05 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing epsilon caprolactams
US5925754A (en) * 1997-04-15 1999-07-20 Union Carbide Chemicals & Plastics Technology Corporation Epsilon caprolactam compositions
US5886236A (en) * 1997-04-15 1999-03-23 Union Carbide Chemicals & Plastics Technology Corporation Process for producing aldehyde acid salts
DE102004029732A1 (de) 2004-06-21 2006-01-19 Basf Ag Hilfsmittel enthaltend Cyclohexanpolycarbonsäurederivate
CN100496736C (zh) * 2007-05-31 2009-06-10 南京大学 一种用于双环戊二烯氢甲酰化制醛的水溶性配体铑配合物催化剂
BRPI0922742A2 (pt) * 2008-12-05 2016-01-05 Basf Se adesivo ou selante, processo para preparar um adesivo ou selante, e, uso do adesivo ou selante.
US20120220678A1 (en) 2009-11-03 2012-08-30 Christof Mehler Thermoplastic compositions having improved flowability
PL2576674T3 (pl) 2010-06-01 2015-02-27 Basf Se Sposób wytwarzania spienialnych kompozycji polimerów styrenowych
EP2716623A1 (de) 2012-10-05 2014-04-09 Basf Se Verfahren zur Herstellung von Cyclohexanpolycarbonsäure-Derivaten mit geringem Nebenproduktanteil
US20220177405A1 (en) 2019-02-25 2022-06-09 Basf Se Method for processing benzene polycarboxylic acid esters and use of same to produce cyclohexane polycarboxylic acid esters

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
EP0033554B1 (en) * 1980-02-04 1983-11-09 Shell Internationale Researchmaatschappij B.V. A process for the hydroformylation of conjugated dienes
US4426542A (en) * 1981-04-22 1984-01-17 Monsanto Company Synthesis of plasticizer and detergent alcohols
DE3412335A1 (de) * 1984-04-03 1985-10-10 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
FR2571725B1 (fr) * 1984-10-16 1987-09-18 Rhone Poulenc Chim Base Complexes rhodies, dinucleaires et hydrosolubles et leur utilisation comme catalyseur d'hydroformylation
DE3534314A1 (de) * 1985-09-26 1987-04-02 Ruhrchemie Ag Verfahren zur herstellung von aldehyden
US4969953A (en) * 1988-10-25 1990-11-13 Mitsubishi Kasei Corporation Alcohol mixture for plasticizer and method for producing the same
IT1229512B (it) * 1989-01-27 1991-09-03 Eniricerche Spa Procedimento per la idroformilazione catalitica di.olefine
DE4210028A1 (de) * 1992-03-27 1993-09-30 Hoechst Ag Decyclalkoholgemische, daraus erhältliche Phthalsäureester und ihre Verwendung als Weichmacher
US5312996A (en) * 1992-06-29 1994-05-17 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process for producing 1,6-hexanedials

Also Published As

Publication number Publication date
KR100335516B1 (ko) 2002-11-13
JPH07173094A (ja) 1995-07-11
EP0643031B1 (de) 1997-11-05
CA2131337A1 (en) 1995-03-10
SG44824A1 (en) 1997-12-19
JP2609429B2 (ja) 1997-05-14
PL304861A1 (en) 1995-03-20
BR9403438A (pt) 1995-05-09
ES2112457T3 (es) 1998-04-01
US5434312A (en) 1995-07-18
ZA946773B (en) 1995-04-03
PL177092B1 (pl) 1999-09-30
EP0643031A1 (de) 1995-03-15
AU7166094A (en) 1995-03-23
CN1106374A (zh) 1995-08-09
TW289017B (ko) 1996-10-21
DE59404520D1 (de) 1997-12-11
DE4330489A1 (de) 1995-03-16
AU671763B2 (en) 1996-09-05

Similar Documents

Publication Publication Date Title
KR950008459A (ko) 1,3-부타디엔의 하이드로포밀화 방법
KR930019606A (ko) 데실 알콜 혼합물, 이로부터 수득가능한 프탈산 에스테르 및 가소제로서의 이의 용도
KR950008456A (ko) 데실 알콜 혼합물, 이로부터 수득가능한 프탈산 에스테르 및 가소제로서의 이의 용도
DE3771686D1 (de) Selektives herstellungsverfahren von alkencarbonsaeurederivaten.
KR850008479A (ko) 알데히드의 제조방법
SA93130348B1 (ar) إعادة تنشيط حفازات ادماج هيدروفورميل hydroformylation
GB1526245A (en) Manufacture of concentrated aqueous solutions of formaldehyde
DE69607937T2 (de) Hydroformylierungsverfahren
Jardine et al. Homogeneous catalytic hydrogenation of unsaturated aldehydes to form saturated aldehydes
ATE147382T1 (de) Verfahren zur herstellung von sclareolid
SE8603007L (sv) Sett att framstella 5-aminosalicylsyra
KR910011764A (ko) α-히드록시이소부티르산아미드의 제조방법
GB1319473A (en) Process for the preparation of 1,1-dihydroperfluoroalkanols
ATE51217T1 (de) Verfahren zur herstellung von nonadecandiolen.
RU94037588A (ru) Способ оксикарбонилирования бутадиена
KR940011422A (ko) 방향족 알데하이드의 제조방법
KR910007807A (ko) 옥소합성(oxo synthesis)후 증류 잔존물로 부터의 로듐 회수 공법
ATE180245T1 (de) Verfahren zur herstellung von propionaldehyd
KR880006153A (ko) 알데히드의 제조 방법
GB1514836A (en) Production of 2-hydroxynaphthalene-3-carboxylic acid
ATE2332T1 (de) Verfahren zur herstellung bekannter und neuer 6- amino-6-desoxy-2,3-0-isopropyliden-alpha-lsorbofuranose-derivate sowie neue zwischenprodukte des verfahrens.
SU461921A1 (ru) Способ получени -ацетопрорилового спирта
JPS56135482A (en) Production of 5-methyl-2-frufural
ATE228495T1 (de) Verfahren zur herstellung von 3-hydroxy-2- methylbenzoesäure
DE58901819D1 (de) Verfahren zur herstellung von 3-methyl-2-pentyl-cyclopent-2-en-1-on.

Legal Events

Date Code Title Description
N231 Notification of change of applicant
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20060330

Year of fee payment: 5

LAPS Lapse due to unpaid annual fee