KR950000844A - 탄화수소의 촉매 부분 산화 방법 - Google Patents

탄화수소의 촉매 부분 산화 방법 Download PDF

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KR950000844A
KR950000844A KR1019940013621A KR19940013621A KR950000844A KR 950000844 A KR950000844 A KR 950000844A KR 1019940013621 A KR1019940013621 A KR 1019940013621A KR 19940013621 A KR19940013621 A KR 19940013621A KR 950000844 A KR950000844 A KR 950000844A
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catalyst
feed
oxygen
hydrocarbon feedstock
process according
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KR1019940013621A
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레오나르두스 게라르두스 야곱스 루도비쿠스
윌리엄 레드너 피이터
알렉산더 본 케만 코에르트
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알베르투스 빌헬무스, 요아네스 쩨스트 라텐
셀 인터나쵸 나아레 레사아치 마아츠샤피 비이부이
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Publication of KR950000844A publication Critical patent/KR950000844A/ko

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1023—Catalysts in the form of a monolith or honeycomb
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1029—Catalysts in the form of a foam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C01B2203/107—Platinum catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

탄화수소 공급 재료의 촉매 부분 산화 방법은 탄화수소 공급 재료 및 산소-함유 가스로 구성되는 공급물을 승압 및 적어도 950℃ 온에서 촉매적 활성 금속으로서 로듐, 이리듐 또는 루테늄으로 구성된 촉매와 접촉시키는 것으로 구성된다.

Description

탄화수소의 촉매 부분 산화 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 탄화수소 공급재료 및 산소-함유 가스로 구성된 공급물을 승압 및 적어도 950℃ 온도에서 촉매적 활성 금속으로서 로듐, 이리듐 또는 루테늄으로 구성된 촉매와 접촉시키는 것으로 구성된 탄화수소 공급 재료의 촉매 부분 산화 방법.
  2. 제1항에 있어서, 탄화수소 공급 재료가 메탄, 천연 가스, 혼합 가스 또는 저급 탄화수소 원료로 구성되는 것을 특징으로 하는 방법.
  3. 제1 또는 2항에 있어서, 산소-함유 가스가 실질적으로 순수한 산소인 것을 특징으로 하는 방법.
  4. 제1-3항중 임의의 한 항에 있어서, 공급물이 산소-대-탄소 비가 0.3-0.8 바람직하게는 0.45-0.75, 보다 바람직하게 0.45-0.65이도록하는 양으로 탄화수소 공급재료 및 산소-함유 가스로 구성되는 것을 특징으로 하는 방법.
  5. 제1-4항중 임의의 한 항에 있어서, 공급물을 촉매와 150바아까지, 바람직하게 3-100바아, 보다 바람직하게 10-75바아 범위내 압력에서 접촉시키는 것을 특징으로 하는 방법.
  6. 제1-5항중 임의의 한 항에 있어서, 공급물을 촉매와 950-1300℃, 바람직하게 950-1200℃ 범위내 온도에서 접촉시키는 것을 특징으로 하는 방법.
  7. 제1-6항중 임의의 한 항에 있어서, 공급물을 촉매와 20,000-50,000,000N1/1시, 바람직하게는 50,000-20,000,000N1/1시, 보다 바람직하게 500,000-10,000,000N1/1시 범위내 시간당 가스의 공간 속도에서 접촉시키는 것을 특징으로 하는 방법.
  8. 제1-7항중 임의의 한 항에 있어서, 촉매가 로듐으로 구성되는 것을 특징으로 하는 방법.
  9. 제1-8항중 임의의 한 항에 있어서, 촉매가 고정 베드 배열, 바람직하게 높은 사행 보다 바람직하게 1.1-5.0 범위내 시행을 갖는 고정 베드 배열에 보유되는 것을 특징으로 하는 방법.
  10. 제9항에 있어서, 촉매가 촉매적 활성 금속으로 함침된 세라믹 기포 형태인 것을 특징으로 하는 방법.
  11. 제1-10항중 임의의 한 항에 있어서, 공급물을 촉매와 실질적으로 단열 조건하에 접촉시키는 것을 특징으로 하는 방법.
  12. 제1-11 항중 임의의 한 항에 따른 방법에 의해 제조되는 모든 일산화탄소 또는 수소.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940013621A 1993-06-18 1994-06-16 탄화수소의 촉매 부분 산화 방법 KR950000844A (ko)

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EP93201768 1993-06-18
EP93201768.4 1996-06-18

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EP (1) EP0629578B1 (ko)
JP (1) JP3514826B2 (ko)
KR (1) KR950000844A (ko)
CN (1) CN1039698C (ko)
AT (1) ATE195922T1 (ko)
AU (1) AU672901B2 (ko)
BR (1) BR9402445A (ko)
CA (1) CA2126036C (ko)
CO (1) CO4370113A1 (ko)
DE (1) DE69425692T2 (ko)
DZ (1) DZ1789A1 (ko)
ES (1) ES2152965T3 (ko)
MY (1) MY110723A (ko)
NO (1) NO942284L (ko)
NZ (1) NZ260621A (ko)
RU (1) RU2123471C1 (ko)
SG (1) SG97732A1 (ko)
ZA (1) ZA944286B (ko)

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EP1004561A1 (en) * 1998-11-27 2000-05-31 Shell Internationale Researchmaatschappij B.V. Process for the production of liquid hydrocarbons
ATE327964T1 (de) 1999-08-31 2006-06-15 Shell Int Research Katalytisches oxidationsverfahren mit durchflussregelsystem
EP1095903A1 (en) * 1999-10-28 2001-05-02 Shell Internationale Researchmaatschappij B.V. Process for the oxidation of a hydrocarbonaceous feedstock
EP1274650A1 (en) 2000-04-17 2003-01-15 Shell Internationale Researchmaatschappij B.V. Fuel processor
US6746658B2 (en) * 2000-04-20 2004-06-08 Conocophillips Company Rhodium cloth catalyst for partial oxidation of hydrocarbons
EP1156026A1 (en) 2000-05-19 2001-11-21 Shell Internationale Researchmaatschappij B.V. Process for the production of liquid hydrocarbons
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EP1569869A4 (en) 2002-11-11 2008-11-19 Conocophillips Co STABILIZED ALUMINUM OXIDE SUPPLEMENTS, Catalysts Produced Therefrom, and Their Use in Partial Oxidation
JP2007108046A (ja) * 2005-10-14 2007-04-26 Idemitsu Kosan Co Ltd 二層分離温度測定装置およびその測定方法
BRPI0817652A2 (pt) * 2007-10-11 2015-09-29 Japan Petroleum Exploration Co catalizador de reforma de hidrocarboneto e processo para produção de gás de síntese usando o mesmo
JP4639247B2 (ja) 2008-07-23 2011-02-23 石油資源開発株式会社 炭化水素リフォーミング用触媒およびその製造方法ならびにこれを用いた合成ガスの製法
DE102014007001B4 (de) * 2014-05-13 2020-08-06 Caphenia Gmbh Verfahren und Anlage zur Herstellung von H2-reichem Synthesegas
RU2571147C1 (ru) * 2014-06-09 2015-12-20 Федеральное государственное бюджетное учреждение Национальный исследовательский центр "Курчатовский институт" Способ конверсии метана
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CN116272968B (zh) * 2022-09-07 2024-01-30 中山大学 一种碳载Ir催化剂及其制备方法和应用

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BR9402445A (pt) 1995-01-24
EP0629578B1 (en) 2000-08-30
CO4370113A1 (es) 1996-10-07
ES2152965T3 (es) 2001-02-16
CA2126036C (en) 2005-06-14
DZ1789A1 (fr) 2002-02-17
AU672901B2 (en) 1996-10-17
MY110723A (en) 1999-01-30
ZA944286B (en) 1995-02-10
EP0629578A1 (en) 1994-12-21
JPH0710503A (ja) 1995-01-13
JP3514826B2 (ja) 2004-03-31
DE69425692T2 (de) 2001-04-19
NO942284L (no) 1994-12-19
RU94021643A (ru) 1996-04-27
CN1039698C (zh) 1998-09-09
NZ260621A (en) 1996-03-26
CA2126036A1 (en) 1994-12-19
AU6478694A (en) 1994-12-22
ATE195922T1 (de) 2000-09-15
CN1101891A (zh) 1995-04-26
NO942284D0 (no) 1994-06-16
RU2123471C1 (ru) 1998-12-20
DE69425692D1 (de) 2000-10-05
SG97732A1 (en) 2003-08-20

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