KR940019810A - 실온경화성 오가노폴리실록산 조성물 - Google Patents

실온경화성 오가노폴리실록산 조성물 Download PDF

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KR940019810A
KR940019810A KR1019940003316A KR19940003316A KR940019810A KR 940019810 A KR940019810 A KR 940019810A KR 1019940003316 A KR1019940003316 A KR 1019940003316A KR 19940003316 A KR19940003316 A KR 19940003316A KR 940019810 A KR940019810 A KR 940019810A
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KR100311849B1 (ko
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히사유키 나가오카
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이치세 야요이
도시바실리콘 가부시키가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/04—Polysiloxanes
    • C08J2483/06—Polysiloxanes containing silicon bound to oxygen-containing groups

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

본 발명은 실란올 그룹 또는 알콕시 그룹으로 말단화된 오가노폴리실록산 (A) 100중량부, 규소원자에 결합된 가수분해 가능한 그룹을 분자당 평균 2개 이상 함유하는 오가노실리콘 화합물 (B) 0.1 내지 30중량부, 폴리올레핀 수지를 팽윤시킬 수 있는 하이드록실 함유 유기 화합물(C) 0.5 내지 50중량부 및, 경우에 따라, 필수량의 경화 촉매(D)를 포함하는 실온경화성 오가노폴리실록산 조성물에 관한 것이다. 당해 조성물은 처리되지 않은 폴리올레핀 수지에 대한 만족할 만한 접착력을 나타내어 실제적인 사용시 오래 견디어내기에 충분한 접착 강도를 제공해준다.

Description

실온경화성 오가노폴리실록산 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 전단 접착 시험용으로 실시예에서 사용된 표본의 투시도이다.

Claims (11)

  1. 실란올 그룹 또는 알콕시 그룹으로 말단화된 오가노폴리실록산(A) 100중량부, 규소원자에 결합된 가수분해 가능한 그룹을 분자당 평균 2개 이상 함유하는 오가노실리콘 화합물(B) 0.1 내지 30중량부 및 폴리올레핀 수지를 팽윤시킬 수 있는 하이드록실 함유 유기 화합물(C) 0.5 내지 50중량부를 포함하는 실온경화성 오가노폴리실록산 조성물.
  2. 제1항에 있어서, 필수량의 경화 촉매(D)를 추가로 포함하는 실온경화성 오가노폴리실록산 조성물.
  3. 제1항에 있어서, 오가노폴리실록산의 점도가 25℃에서 100 내지 500,000cSt인 실온경화성 오가노폴리실록산 조성물.
  4. 제1항에 있어서, 오가노폴리실록산의 점도가 25℃에서 2,000 내지 100,000cSt인 실온경화성 오가노폴리실록산 조성물.
  5. 제1항에 있어서, 알콕시 그룹이 메톡시, 에톡시 또는 이소프로폭시인 실온경화성 오가노폴리실록산 조성물.
  6. 제1항에 있어서, 오가노실리콘 화합물(B)의 양이 성분(A) 100중량부당 0.5 내지 15중량부인 실온경화성 오가노폴리실록산 조성물.
  7. 제1항에 있어서, 가수분해 가능한 그룹이 알콕시 그룹, 엔옥시 그룹, 이소시아네이토 그룹, 옥심 그룹, 유기 아미노 그룹 또는 아미도 그룹인 실온경화성 오가노폴리실록산 조성물.
  8. 제1항에 있어서, 하이드록실 함유 유기 화합물(C)의 양이 성분(A) 100중량부당 1 내지 35중량부인 실온경화성 오가노폴리실록산 조성물.
  9. 제1항에 있어서, 하이드록실 함유 유기 화합물이 탄소수 4 내지 16의 환식, 직쇄 또는 측쇄 탄화수소 그룹을 갖는 지방족 알콜 ; 방향족 탄화수소 그룹, 할로겐 원자 또는 벤질아미노 그룹에 의해 치환된 탄소수 2 내지 8의 지방족 알콜 ; 탄소수 6 내지 18의 지방족 디옥 ; 페놀 ; 및 방향족 탄화수소 그룹 및 탄소수 2 내지 8의 환식, 직쇄 또는 측새 지방족 탄화수소 그룹 중의 하나 이상을 갖는 옥심 중에서 선택되는 실온경화성 오가노폴리실록산 조성물.
  10. 제1항에 있어서, 하이드록실 함유 유기 화합물이 탄소수 4 내지 16의 환식 또는 직쇄 탄화수소 그룹을 갖는 지방족 알콜 ; 할로겐 원자 또는 벤질아미노 그룹에 의해 치환된 탄소수 2 내지 8의 지방족 알콜 ; 및 방향족탄화수소 그룹 및 탄소수 2 내지 8의 환식 또는 직쇄 지방족 탄화수소 그룹 중의 하나 이상을 갖는 옥심 중에서 선택되는 실온경화성 오가노폴리실록산 조성물.
  11. 제 1 항에 있어서, 하이드록실 함유 유기 화합물이 탄소수 4 내지 16의 환식 탄화수소 그룹을 갖는 지방족 알콜; 할로겐 원자 또는 벤질아미노 그룹에 의해 치환된 탄소수2 내지 8의 지방족 알콜; 및 방향족탄화수소 그룹 및 탄소수 2 내지 8의 환식 또는 직쇄 지방족 탄화수소 그룹 중의 하나 이상을 갖는 옥심 중에서 선택되는 실온경화성 오가노폴리실록산 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940003316A 1993-02-24 1994-02-24 실온경화성오가노폴리실록산조성물 KR100311849B1 (ko)

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Application Number Priority Date Filing Date Title
JP93-035354 1993-02-24
JP5035354A JPH06248185A (ja) 1993-02-24 1993-02-24 室温硬化性ポリオルガノシロキサン組成物

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KR100311849B1 KR100311849B1 (ko) 2001-12-15

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6013752A (en) * 1997-06-04 2000-01-11 Ameron International Corporation Halogenated resin compositions
JP5241613B2 (ja) * 2009-06-02 2013-07-17 信越化学工業株式会社 アクリル樹脂用接着剤

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5790045A (en) * 1980-10-29 1982-06-04 Toshiba Silicone Co Ltd Adherent polyorganosiloxane composition
GB2233251B (en) * 1989-06-20 1993-03-10 Courtaulds Films & Packaging Production of polymeric films

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JPH06248185A (ja) 1994-09-06
EP0612810A2 (en) 1994-08-31
KR100311849B1 (ko) 2001-12-15

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