KR930701505A - 미세한 비닐클로리드 그라프트코폴리머의 제조방법 및 점도환원제와 광택제로서의 사용 - Google Patents

미세한 비닐클로리드 그라프트코폴리머의 제조방법 및 점도환원제와 광택제로서의 사용

Info

Publication number
KR930701505A
KR930701505A KR1019930700548A KR930700548A KR930701505A KR 930701505 A KR930701505 A KR 930701505A KR 1019930700548 A KR1019930700548 A KR 1019930700548A KR 930700548 A KR930700548 A KR 930700548A KR 930701505 A KR930701505 A KR 930701505A
Authority
KR
South Korea
Prior art keywords
vinyl chloride
monomer
alkyl acrylate
graft
content
Prior art date
Application number
KR1019930700548A
Other languages
English (en)
Inventor
그라우에르 페터
오버 루드비그
Original Assignee
에리히 프랑크,칼 하인즈 림빅
와커-헤미 게엠베하
칼 하인즈 림빅
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 에리히 프랑크,칼 하인즈 림빅, 와커-헤미 게엠베하, 칼 하인즈 림빅 filed Critical 에리히 프랑크,칼 하인즈 림빅
Publication of KR930701505A publication Critical patent/KR930701505A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02—Monomers containing chlorine
    • C08F214/04—Monomers containing two carbon atoms
    • C08F214/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Color Printing (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

이 발명은 현탁중합에 의해 평균입자크기 20∼30㎛의 미세한 비늘플로리드 그라프트 코폴리머의 제조방법에 있어서, 그 그라프트모너머상을 미가교 또는 가로알킬아크릴레이트폴리머 0. 1∼5.0wt%의 존재하에서 메톡시함량 15∼25% 히드록시프로필함량 3∼10%, ASTM D 2363에 의한 점도 30∼150mpa·s를 가진 셀룰로오스에테르를 사용하여 중합하는 제조방법에 그 특징이 있다.

Description

미세한 비닐클로리드 그라프트코폴리며의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 모노머-가용성 프리래디컬개시제와, 버퍼물질(buffersubstances) 또는 유화제등의 또다른 통상의 첨가제의 존재하에서 현탁중합에 의해 평균입자크기 20∼30㎛의 미세한 비닐클로리드 그라프트코폴리머의 제조방법에 있어서, 그라프트모노머(graft monomer), 비닐플로리드 또는 C2- 내지 C12-알킬래디컬을 가진 (메타)아크릴레이트 또는 탄소원자 2-12의 지방족모노카르확실산의 비닐에스테르등 비닐클로리드와 공중합할 수 있는 20wt% 이내의 모노머와 비닐클로리드의 혼합물이 그 그라프트모노머의 함량에 대하여, 고형분함량 30-60wt%의 수용성에멀죤에 초기 도입시킨 C2-C8-알킬래디컬을 가진 알킬아크릴레이트의 가교코폴리머 또는 미가교호모폴리머의 그룹에서의 알킬아크릴레이트 폴리머 1.0∼5.0wt%와, 그라프트모노머의 함량에 대하여, 메톡시함량 15∼25%, 히드록시프로필함량 3∼10% ASTM D2363에 의한 점도 30∼150mpa·s를 가지며 초기 도입시키거나 그 그라프트모노머의 첨가후에 계량할 셀룰로오스에테르 0.1∼1.0wt%의 존재하에 중합시킴을 특징으로 하는 위 제조방법.
  2. 제1항에 있어서, 그 그라프트모노머는 비닐플로리드임을 특징으로 하는 위 제조방법.
  3. 제1항에 있어서, 그 알킬아크릴레이트 폴리머는 폴리부틸 아크릴레이트임을 특징으로 하는 위 제조방법.
  4. 제3항에 있어서, 그 알킬아크릴레이트 폴리머는 그 알킬아크릴레이트 부분에 대하여 가교작용을 가진 에틸렌기 폴리불포화모노머 (ethylenically polyunsaturated comonomers) 0.1∼1.0wt%를 포함함을 특징으로 하는 위 제조방법.
  5. 제3항에 있어서, 알릴메타크릴레이트 0.1∼1.0wt%로 가교시킨 폴리부틸아크릴레이트를 사용함을 특징으로 하는 위 제조방법.
  6. 제1항에 있어서, 비닐클로리드 그라프트모노머상에는 가교작용을 가진 에틸렌기 폴리불포화코모노머 0.1∼5.0wt%를 포함함을 특징으로 하는 위 제조방법.
  7. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930700548A 1990-09-17 1991-09-12 미세한 비닐클로리드 그라프트코폴리머의 제조방법 및 점도환원제와 광택제로서의 사용 KR930701505A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4029471A DE4029471A1 (de) 1990-09-17 1990-09-17 Verfahren zur herstellung eines feinteiligen vinylchlorid-pfropfcopolymerisats und verwendung fuer den einsatz als viskositaetserniedriger und mattierungsmittel
DEP4029471.4 1990-09-17
PCT/EP1991/001740 WO1992005210A1 (de) 1990-09-17 1991-09-12 Verfahren zur herstellung eines feinteiligen vinylchlorid-pfropfcopolymerisats und verwendung für den einsatz als viskositätserniedriger und mattierungsmittel

Publications (1)

Publication Number Publication Date
KR930701505A true KR930701505A (ko) 1993-06-11

Family

ID=6414422

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019930700548A KR930701505A (ko) 1990-09-17 1991-09-12 미세한 비닐클로리드 그라프트코폴리머의 제조방법 및 점도환원제와 광택제로서의 사용

Country Status (11)

Country Link
US (1) US5314966A (ko)
EP (1) EP0549631B1 (ko)
JP (1) JPH0747610B2 (ko)
KR (1) KR930701505A (ko)
AT (1) ATE106413T1 (ko)
CA (1) CA2091880A1 (ko)
DE (2) DE4029471A1 (ko)
ES (1) ES2054506T3 (ko)
NO (1) NO930927D0 (ko)
TW (1) TW200496B (ko)
WO (1) WO1992005210A1 (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4334727A1 (de) * 1993-10-12 1995-04-13 Vinnolit Kunststoff Gmbh Thermoplastische Elastomere auf der Basis von Vinylchlorid-Pfropfcopolymerisaten
TW200526737A (en) * 2003-12-22 2005-08-16 Kaneka Corp Method for producing vinyl chloride copolymer resin
KR20070006858A (ko) * 2004-03-30 2007-01-11 카네카 코포레이션 염화비닐계 수지 조성물
WO2007032630A1 (en) * 2005-09-13 2007-03-22 Lg Chem, Ltd. Method of preparing vinylchloride-based copolymer and vinylchloride plastisol composition including vinylchloride-based copolymer prepared using the method

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH566354A5 (ko) * 1972-06-08 1975-09-15 Lonza Ag
CH616168A5 (en) * 1974-11-14 1980-03-14 Lonza Ag Process for the preparation of transparent, impact-resistant polymers of vinyl chloride
US4162239A (en) * 1974-11-14 1979-07-24 Lonza Ltd. Process for the production of transparent polymers of vinyl chloride with very high impact strength
DE3132890A1 (de) * 1981-08-20 1983-03-03 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von polymeren und copolymeren des vinylchlorids durch suspensionspolymerisation und verwendung fuer den einsatz als viskositaetserniedriger in der plastisolverarbeitung
DE3510899A1 (de) * 1985-03-26 1986-10-02 Hüls AG, 4370 Marl Verfahren zur herstellung eines rieselfaehigen polyvinylchlorids mit hohen anteilen an acrylatelastomeren
DE3544235C2 (de) * 1985-12-14 1993-10-07 Hoechst Ag Formmasse zur Verarbeitung als Plastisol
DE3700973A1 (de) * 1987-01-15 1988-07-28 Wacker Chemie Gmbh Zusatzstoffe fuer lackmischungen
DE3803036A1 (de) * 1988-02-02 1989-08-10 Wacker Chemie Gmbh Verfahren zur herstellung eines elastomerhaltigen vinylchloridpfropfcopolymerisats
US4939212A (en) * 1989-03-31 1990-07-03 The B. F. Goodrich Company Elasticized vinyl dispersion resins having outstanding stability

Also Published As

Publication number Publication date
EP0549631A1 (de) 1993-07-07
DE4029471A1 (de) 1992-03-19
ES2054506T3 (es) 1994-08-01
NO930927L (no) 1993-03-15
TW200496B (ko) 1993-02-21
WO1992005210A1 (de) 1992-04-02
EP0549631B1 (de) 1994-06-01
ATE106413T1 (de) 1994-06-15
US5314966A (en) 1994-05-24
JPH0747610B2 (ja) 1995-05-24
NO930927D0 (no) 1993-03-15
JPH05507309A (ja) 1993-10-21
CA2091880A1 (en) 1992-03-18
DE59101813D1 (de) 1994-07-07

Similar Documents

Publication Publication Date Title
FI95585C (fi) Polymeeripartikkelit ja niiden valmistaminen
ATE262557T1 (de) Zelluloseether in durch emulsionspolymerisation hergestellten dispersionen
NZ221423A (en) Paper sizing composition based on aqueous dispersion of a copolymer
GB1272171A (en) Process for the preparation of an aqueous dispersion of a copolymer
KR960701909A (ko) 수성 중합체 분산액, 그의 제조방법 및 그의 페인트 조성물에의 응용(aqueous polymer dispersion, method for making same and use thereof for preparing paints)
KR950014843B1 (ko) 내충격성 열가소성 수지의 제조방법
KR980002070A (ko) 충분히 가수분해된 폴리(비닐 알코올) 존재하에 제조되는 아크릴계 에멀션
GB1291327A (en) Processing aid for polyvinyl chloride
KR930701505A (ko) 미세한 비닐클로리드 그라프트코폴리머의 제조방법 및 점도환원제와 광택제로서의 사용
KR970074807A (ko) 염화 비닐 공중합체의 2원 입자 라텍스 및 그것에 관한 제조 방법과 적용
KR840008658A (ko) 고분자량 아크릴로 니트릴계 중합체의 제조법
ES471638A1 (es) Procedimiento de fabricacion de copolimeros injertados
ATE166897T1 (de) Wässrige dispersion aus vinylpolymeren
ES8305015A1 (es) "procedimiento para la preparacion de una dispersion acuosa de material sintetico".
EP0468433A2 (en) Polyvinyl chloride resin composition
GB1475552A (en) Emulsion copolymers
JPS57125238A (en) Vinyl chloride resin composition with improved antiblocking property
JPS5667320A (en) Production of graftcopolymer
MX9703243A (es) Esteres de celulosa en dispersiones de polimerizacion por emulsion.
JPS564618A (en) Preparation of thermoplastic resin
KR960033151A (ko) 겉보기 비중이 높은 폴리염화비닐수지의 제조방법
JPH11152316A (ja) アルキル化ポリビニルアルコール及びその製造方法
RU93047161A (ru) Способ получения модификатора перерабатываемости поливинилхлоридной композиции
KR870004089A (ko) 공중합체 라텍스 코팅제의 제조방법
MX9705755A (es) Polimeros de latex (met)acrilico transportadores de agua para liberacion.

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E601 Decision to refuse application