KR930021735A - 수용성 모노아조염료 - Google Patents

수용성 모노아조염료 Download PDF

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KR930021735A
KR930021735A KR1019930006574A KR930006574A KR930021735A KR 930021735 A KR930021735 A KR 930021735A KR 1019930006574 A KR1019930006574 A KR 1019930006574A KR 930006574 A KR930006574 A KR 930006574A KR 930021735 A KR930021735 A KR 930021735A
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group
halogen
compound
substituted
monoazo dyes
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KR1019930006574A
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KR100255686B1 (ko
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요오스께 다까하시
유끼하루 시미즈
도시오 히하라
기요시 히메노
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와따나베 히로시
미쓰비시가세이훽스트 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/02—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
    • C09B62/20—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a pyrimidine ring
    • C09B62/24—Azo dyes
    • C09B62/245—Monoazo dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/4401—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system
    • C09B62/4403—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system the heterocyclic system being a triazine ring
    • C09B62/4411—Azo dyes
    • C09B62/4413—Non-metallized monoazo dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/02—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
    • C09B62/04—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a triazine ring
    • C09B62/08—Azo dyes
    • C09B62/085—Monoazo dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/4401—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system
    • C09B62/4424—Azo dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/503—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl or mercaptoalkyl sulfonyl group, a quaternised or non-quaternised aminoalkyl sulfonyl group, a heterylmercapto alkyl sulfonyl group, a vinyl sulfonyl or a substituted vinyl sulfonyl group, or a thiophene-dioxide group
    • C09B62/507—Azo dyes
    • C09B62/51—Monoazo dyes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

유리 산 형태의 하기 식(Ⅰ)을 갖는 수용성 모노아조염료:
[상기식에서, X는 -CH=CH2또는 -CH2CH2W (여기에서, W는 알칼리에 의해 제거가능한 이탈기임)이고, R1은 메틸, -NHCONH2또는 -NHCOT1(여기에서, T1은 메틸, 에틸, -CH2CH2COOH 또는 -CH=CHCOOH임)이고, R2는 수소, 저급알킬 또는 저급 알콕시이며,
(여기에서, P는 시아노 또는 할로겐이고, Q 및 U는 각각 서로 독립적으로 할로겐이고, V는 할로겐 또는이며, Y는 할로겐 또는 하기식(1) 또는 (2)의 기이고,
R3는 수소 또는 저급 알킬이고, A는 술폰산기 및 카르복실산기로 구성된 군에서 선택되는 적어도 하나로 치환된 C1∼C4알킬 또는 나프탈렌기, 또는 술폰산기 및 카르복실산기로 구성된 군에서 선택되는 적어도 하나로 치환된 페닐기이고, 이는 히드록실, 할로겐, C1∼C2알킬 및 C1∼C2알콕시기로 구성된 군에서 선택된 적어도 하나로 치환될 수도 있고, R4는 수소 또는 C1∼C4알킬이고, E는 비치환되거나 저급 알킬, 저급 알콕시, 할로겐 또는 술폰산기로 치환된 페닐렌, 비치환되거나 술폰산기, C1∼C4알킬렌 또는 C1∼C4알킬렌옥시 C1∼C4알킬렌으로 치환된 나프탈렌기이며, X는 상기 정의된 바와 같다.

Description

수용성 모노아조염료
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. 유리 산 형태의 하기 식(Ⅰ)을 갖는 수용성 모노아조염료:
    [상기식에서, X는 -CH=CH2또는 -CH2CH2W (여기에서, W는 알칼리에 의해 제거가능한 이탈기임)이고, R1은 메틸, -NHCONH2또는 -NHCOT1(여기에서, T1은 메틸, 에틸, -CH2CH2COOH 또는 -CH=CHCOOH임)이고, R2는 수소, 저급알킬 또는 저급 알콕시이며,
    (여기에서, P는 시아노 또는 할로겐이고, Q 및 U는 각각 서로 독립적으로 할로겐이고, V는 할로겐 또는이며, Y는 할로겐 또는 하기식(1) 또는 (2)의 기이고,
    R3는 수소 또는 저급 알킬이고, A는 술폰산기 및 카르복실산기로 구성된 군에서 선택되는 적어도 하나로 치환된 C1∼C4알킬 또는 나프탈렌기, 또는 술폰산기 및 카르복실산기로 구성된 군에서 선택되는 적어도 하나로 치환된 페닐기이고, 이는 히드록실, 할로겐, C1∼C2알킬 및 C1∼C2알콕시기로 구성된 군에서 선택된 적어도 하나로 치환될 수도 있고, R4는 수소 또는 C1∼C4알킬이고, E는 비치환되거나 저급 알킬, 저급 알콕시, 할로겐 또는 술폰산기로 치환된 페닐렌, 비치환되거나 술폰산기, C1∼C4알킬렌 또는 C1∼C4알킬렌옥시C1∼C4알킬렌으로 치환된 나프탈렌기이며, X는 상기 정의된 바와 같다.]
  2. 제1항에 있어서, 하기 식(Ⅰ')을 갖는 모노아조염료:
  3. 제1항에 있어서,인 모노아조염료.
  4. 제3항에 있어서,인 모노아조염료.
  5. 제3항에 있어서, V가
    인 모노아조 염료.
  6. 제3항에 있어서, Y가 불소 또는 염소이고,V가
    인 모노아조염료.
  7. 제3항에 있어서, R1이 -NHCONH2인 모노아조염료.
  8. 제3항에 있어서, Y가인 모노아조염료.
  9. 제8항에 있어서, E가또는인 모노아조염료.
  10. 제3항에 있어서, Y가인 모노아조염료.
  11. 제3항에 있어서, Y가이고, V가 불소 또는 염소인 모노아조염료.
  12. 제3항에 있어서, Y가이고, V가 불소 또는 염소이고, R1이 -NHCOCH3, -NHCH2CH2COOH 또는 -NHCH=CH-COOH인 모노아조염료.
  13. 제12항에 있어서, R1이 -NHCH2CH2COOH 도는 -NHCH=CH-COOH인 모노아조염료.
  14. 제1항에 있어서, Z이인 모노아조염료.
  15. 제1항에 있어서, Z이또는인 모노아조염료.
  16. 제14항에 있어서, R1이 -NHCH2CH2COOH 또는 -NHCH=CHCOOH인 모노아조염료.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930006574A 1992-04-20 1993-04-19 수용성모노아조염료 KR100255686B1 (ko)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
JP92-125380 1992-04-20
JP12538092 1992-04-20
JP92-134426 1992-04-28
JP13442692 1992-04-28
JP92-216242 1992-08-14
JP92-307867 1992-10-23
JP30786792 1992-10-23

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KR930021735A true KR930021735A (ko) 1993-11-22
KR100255686B1 KR100255686B1 (ko) 2000-05-01

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US (2) US5380827A (ko)
EP (1) EP0567036B1 (ko)
JP (2) JP3649749B2 (ko)
KR (1) KR100255686B1 (ko)
DE (1) DE69319649T2 (ko)
ES (1) ES2120457T3 (ko)
TW (1) TW224984B (ko)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0559617B1 (de) * 1992-03-05 1998-01-07 Ciba SC Holding AG Reaktivfarbstoffe, Verfahren zu deren Herstellung und deren Verwendung
JP3649749B2 (ja) * 1992-04-20 2005-05-18 ダイスタージャパン株式会社 水溶性モノアゾ色素
DE4423650A1 (de) 1994-07-06 1996-01-11 Bayer Ag Azofarbstoffe mit einer faserreaktiven Gruppe
JP3829992B2 (ja) * 1994-07-16 2006-10-04 クラリアント ファイナンス （ビーブイアイ） リミティド 反応性モノアゾ染料
DE4425618A1 (de) 1994-07-20 1996-01-25 Bayer Ag Azofarbstoffe mit einer Chlortriazingruppe
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CN103030990A (zh) * 2011-06-30 2013-04-10 上海安诺其纺织化工股份有限公司 一种偶氮化合物的应用
CN102898867B (zh) * 2012-10-31 2014-07-30 无锡润新染料有限公司 一种复合活性黄染料及其制备方法
CN104231666B (zh) * 2014-09-03 2015-08-12 蓬莱嘉信染料化工股份有限公司 常-中温下染色的黄色活性染料及其复配混合物
CN106893352B (zh) * 2015-12-17 2018-10-09 上海安诺其集团股份有限公司 一种单偶氮类化合物
CN106892874B (zh) * 2015-12-17 2019-06-25 江苏安诺其化工有限公司 单偶氮类化合物的制备方法
CN106893361B (zh) * 2015-12-17 2018-10-09 上海安诺其集团股份有限公司 一种染料组合物及其制备方法
CN106893353B (zh) * 2015-12-17 2018-10-09 上海安诺其集团股份有限公司 一种单偶氮类化合物的应用
WO2023144005A1 (en) 2022-01-25 2023-08-03 Huntsman Advanced Materials (Switzerland) Gmbh Isomeric mixture of reactive dyes and their use for the dyeing or printing of textile fibre materials
WO2024133576A1 (en) 2022-12-23 2024-06-27 Archroma (Switzerland) Gmbh Fibre-reactive isomeric yellow dye mixtures, their preparation and their use

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JP3649749B2 (ja) * 1992-04-20 2005-05-18 ダイスタージャパン株式会社 水溶性モノアゾ色素
JP3829992B2 (ja) * 1994-07-16 2006-10-04 クラリアント ファイナンス （ビーブイアイ） リミティド 反応性モノアゾ染料

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JP4040011B2 (ja) 2008-01-30
DE69319649T2 (de) 1999-01-21
JPH06184456A (ja) 1994-07-05
USRE37004E (en) 2000-12-26
EP0567036B1 (en) 1998-07-15
DE69319649D1 (de) 1998-08-20
JP2004131737A (ja) 2004-04-30
KR100255686B1 (ko) 2000-05-01
TW224984B (ko) 1994-06-11
JP3649749B2 (ja) 2005-05-18
US5380827A (en) 1995-01-10
ES2120457T3 (es) 1998-11-01
EP0567036A1 (en) 1993-10-27

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