KR930012896A - 술폰화 아닐린형 코폴리머 및 그의 제조방법 - Google Patents

술폰화 아닐린형 코폴리머 및 그의 제조방법 Download PDF

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KR930012896A
KR930012896A KR1019920025672A KR920025672A KR930012896A KR 930012896 A KR930012896 A KR 930012896A KR 1019920025672 A KR1019920025672 A KR 1019920025672A KR 920025672 A KR920025672 A KR 920025672A KR 930012896 A KR930012896 A KR 930012896A
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South Korea
Prior art keywords
copolymer
sulfonated
aniline
compound
alkylaniline
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KR1019920025672A
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KR100256217B1 (ko
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시미즈 시게루
사이또 다까시
나까무라 도미오
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이찌로 우에다께
니또 케미칼 인더스트리 컴퍼니, 리미티드
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/026—Wholly aromatic polyamines
    • C08G73/0266—Polyanilines or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/16—Anti-static materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/128—Intrinsically conductive polymers comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Paints Or Removers (AREA)

Abstract

술폰화 아닐린형 코폴리머 및 그들의 제조방법이 개시된다.
이들 생성물은 아닐린, N－알킬아닐린 및 페닐렌디아민중에서 선택된 화합물(A), 및 아미노벤젠 술폰산(B)의 수용성 및 알코올 가용성 코폴리머로 이루어지며; 그 술폰화 생성물은 명세서에서 언급된 일반식(Ⅰ－Ⅴ)의 화합물, 또는 그의 혼합물이다.
또한, 술폰산 아닐린형 코폴리머의 제조방법은 아닐린, N－알킬아닐린 및 페닐렌디아민중에서 선택된 화합물(A), 및 아미노벤젠술폰산(B)을 공중합시켜 코폴리머를 얻고; 얻어진 코폴리머를 술폰화제로서 술폰화시키는 단계로 이루어진다.

Description

술폰화 아닐린형 코폴리머 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 실시예 2에서 얻어진 본 발명의 코폴리머의 FT－IR 스펙트럼(KBr법)을 도시한 그래프,
제2도는 실시예 8에서 얻어진 본 발명의 코폴리머의 FT－IR 스펙트럼(KBr법)을 도시한 그래프.

Claims (4)

  1. 아닐린, N－알킬아닐린 및 페닐렌디아민중에서 선택된 화합물(A), 및 아미노벤젠 술폰산(B)의 수용성 및 알코올 가용성 코폴리머로 이루어지고; 술폰화 코폴리머가 다음 일반식(Ⅰ－Ⅴ)의 화합물, 또는 그의 혼합물인 것이 특징인 술폰화 아닐린형 코폴리머.
    상기에서, R1, R2, R3및 R4은 각각 수소, 메톡시, C1－C2알킬 및 히드록실 중에서 선택되며; R´은 수소 또는 C1－C2알킬, 및 바람직하게는 메틸이고; x는 0－1의 임의의 수이다.
  2. 제1항에 있어서, 술폰산을 40－80퍼센트의 비율로 방향족 링에 도입하는 것이 특징인 술폰화 아닐린형 코폴리머.
  3. 제1항에 있어서, 코폴리머의 분자량이 300－500,000인 것이 특징인 술폰화 아닐린형 코폴리머.
  4. 아닐린, N－알킬아닐린 및 페닐렌디아민중에서 선택된 화합물(A), 및 아미노벤젠술폰산(B)을 공중합시켜 코폴리머를 얻고; 얻어진 코폴리머를 술폰화제로서 술폰화시키는 단계로 이루어진 제1항의 술폰화 아닐린형 코폴리머의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920025672A 1991-12-27 1992-12-26 술폰화 아닐린형 코폴리머 및 그의 제조방법 KR100256217B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP360226/1991 1991-12-27
JP3360226A JP3051244B2 (ja) 1991-12-27 1991-12-27 アニリン系共重合体スルホン化物とその製法

Publications (2)

Publication Number Publication Date
KR930012896A true KR930012896A (ko) 1993-07-21
KR100256217B1 KR100256217B1 (ko) 2000-05-15

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KR1019920025672A KR100256217B1 (ko) 1991-12-27 1992-12-26 술폰화 아닐린형 코폴리머 및 그의 제조방법

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US (1) US5354816A (ko)
JP (1) JP3051244B2 (ko)
KR (1) KR100256217B1 (ko)
DE (1) DE4244360A1 (ko)

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Publication number Priority date Publication date Assignee Title
US5589108A (en) * 1993-12-29 1996-12-31 Nitto Chemical Industry Co., Ltd. Soluble alkoxy-group substituted aminobenzenesulfonic acid aniline conducting polymers
JP3349843B2 (ja) * 1994-10-12 2002-11-25 富士通株式会社 電離放射線照射用組成物及び電離放射線照射方法
US6024895A (en) * 1995-08-11 2000-02-15 Mitsubishi Rayon Co., Ltd. Cross-linkable, electrically conductive composition, electric conductor and process for forming the same
TW464661B (en) * 1996-06-10 2001-11-21 Nippon Catalytic Chem Ind Water-soluble electrically-conductive polyaniline and method for production thereof and antistatic agent using water-soluble electrically-conductive polymer
DE19654965A1 (de) * 1996-07-26 1998-05-28 Frank Dr Ing Lux Dispergierbare Partikel, die supermagnetische/ferromagnetische Kristalle und/oder maßgeschneiderte di-, tri- oder mehr Blockcopolymere enthalten
US6241913B1 (en) * 1996-09-27 2001-06-05 International Business Machines Corporation Branched electrically conductive polymers and precursors and applications thereof
US5958301A (en) * 1996-09-27 1999-09-28 International Business Machines Corporation Methods of fabricating branched electrially conductive polymers and precursors thereof
US5980784A (en) * 1996-10-02 1999-11-09 Mitsubishi Rayon Co., Ltd. Method for producing soluble conductive polymer having acidic group
JPH10217623A (ja) * 1997-01-31 1998-08-18 Dainippon Printing Co Ltd 熱転写受像シート
TW502046B (en) * 1998-10-22 2002-09-11 Nippon Catalytic Chem Ind Method for production of water-soluble conducting polyaniline
KR100704795B1 (ko) 2002-11-01 2007-04-09 미츠비시 레이온 가부시키가이샤 탄소 나노튜브 함유 조성물, 이를 포함하는 도막을 갖는복합체, 및 이들의 제조 방법
WO2009041837A1 (en) * 2007-09-28 2009-04-02 Auckland Uniservices Limited Bioactive aniline copolymers
JP5712633B2 (ja) 2011-01-21 2015-05-07 戸田工業株式会社 アニリンブラック及び該アニリンブラックを用いた樹脂組成物ならびに水系、溶剤系分散体
JP2012246427A (ja) * 2011-05-30 2012-12-13 Nec Tokin Corp 導電性高分子、導電性高分子水溶液、導電性高分子膜、固体電解コンデンサ及びその製造方法
JP6094030B2 (ja) 2011-08-17 2017-03-15 三菱レイヨン株式会社 固体電解コンデンサ、およびその製造方法
KR20220136489A (ko) 2012-07-24 2022-10-07 미쯔비시 케미컬 주식회사 도전체, 도전성 조성물, 및 적층체
US9952173B2 (en) * 2013-09-30 2018-04-24 Tongji University Lead ion sensors, methods of making and uses thereof
JP6742723B2 (ja) * 2015-01-16 2020-08-19 日東電工株式会社 表面保護フィルム、及び、光学部材
KR102211565B1 (ko) 2017-02-10 2021-02-03 미쯔비시 케미컬 주식회사 도전성 조성물, 도전성 조성물의 제조 방법 및 도전체의 제조 방법
WO2019146715A1 (ja) 2018-01-26 2019-08-01 三菱ケミカル株式会社 導電性組成物とその製造方法及び水溶性ポリマーとその製造方法
TW202344565A (zh) 2018-03-15 2023-11-16 日商三菱化學股份有限公司 導電膜及其製造方法、導電體、抗蝕劑圖案的形成方法及積層體
WO2019198749A1 (ja) 2018-04-10 2019-10-17 三菱ケミカル株式会社 導電性組成物、導電膜及び積層体
WO2020100791A1 (ja) 2018-11-15 2020-05-22 三菱ケミカル株式会社 導電性組成物及びその製造方法と、導電体及びその製造方法
WO2021153678A1 (ja) 2020-01-29 2021-08-05 三菱ケミカル株式会社 導電性組成物、レジスト被覆材料、レジスト、及びレジストパターンの形成方法

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JPH05178989A (ja) 1993-07-20
KR100256217B1 (ko) 2000-05-15
JP3051244B2 (ja) 2000-06-12
US5354816A (en) 1994-10-11
DE4244360A1 (en) 1993-07-01

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