KR930006181A - 알루미늄을 보호하기 위한 크롬-배제 방법 및 조성물 - Google Patents
알루미늄을 보호하기 위한 크롬-배제 방법 및 조성물 Download PDFInfo
- Publication number
- KR930006181A KR930006181A KR1019920017512A KR920017512A KR930006181A KR 930006181 A KR930006181 A KR 930006181A KR 1019920017512 A KR1019920017512 A KR 1019920017512A KR 920017512 A KR920017512 A KR 920017512A KR 930006181 A KR930006181 A KR 930006181A
- Authority
- KR
- South Korea
- Prior art keywords
- nitrate
- cerium
- aluminum
- exposing
- aqueous solution
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Ceramic Products (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Basic Packing Technique (AREA)
- Glass Compositions (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
본 발명은 불순물들을 알루미늄 또는 알루미늄 합금의 표면으로부터 제거하고; 상기 표면을 50 내지 100℃에서 물에 노출시켜 상기 표면상에 다공성 베마이트 코팅을 형성시키고; 상기 베마이트-코팅된 표면을 70 내지 100℃의 온도에서 새륨염 및 금속 질산염을 포함하는 수용액에 노출시킴을 포함하는, 상기 표면상에 보호 코팅을 제공하는 개선된 방법을 제공한다. 세륨의 산화물 및 수산화물이 상기 베마이트의 기공내에 형성되어 보호 코팅을 제공하며, 상기는 내식성 및 개선된 도료 접착성을 제공한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- (a) 알루미늄 또는 알루미늄 합금의 표면으로부터 불순물을 제거하여 세척된 표면을 수득하고; (b) 상기 세척된 표면을 50 내지 100℃ 범위의 온도에서 탈이온수에 노출시켜 상기 표면상에 다공성 베마이트 코팅을 형성 시키고; (c) 상기 베마이트 코팅을 갖는 표면을 세륨염 및 금속 질산염을 포함하는 수용액에 70 내지 100℃범위의 온도에서 상기 다공성 베마이트 코팅의 기공내에 상기 세륨의 산화물 및 수산화물이 형성되기에 충분한 시간동안 노출시키므로써 보호코팅을 제공함을 포함하는, 알루미늄 또는 알루미늄 합금의 표면에 상기 보호 코팅을 제공하는 방법.
- 제1항에 있어서, 상기 세륨염이 염화 세륨, 질산 세륨 및 황산 세륨으로 이루어진 그룹으로부터 선택되는 방법.
- 제1항에 있어서, 상기 세륨염이 염화세륨을 포함하고 상기 세륨 염의 농도가 약 0. 0l중량% 내지 약 1중량%인 방법.
- 제1항에 있어서. 상기 세륨 염의 농도가 약 0.1중량%인 방법.
- 제1항에 있어서, 상기 금속질산염이 질산 리튬, 질산알루미늄, 질산암모늄, 질산나트륨 및 이들의 혼합물로 이루어진 그룹중에서 선택되는 방법.
- 제5항에 있어서, 상기 수용액이 약 0.1 내지 약5중량%의 질산 리튬 및 약 0.1 내지 약5중량%의 질산 알루미늄을 포함하는 방법.
- 제1항에 있어서, 상기 불순물 제거 단계가 상기 표면을 알칼리 세척 조성물 또는 탈산제에 노출시킴을 포함하는 방법.
- 제1항에 있어서, 상기 수용액의 pH가 약 3.5 내지 약 4의 범위인 방법.
- 제1항에 있어서, (c)단계 후에, 상기 보호 코팅을 갖는 상기 표면을 최종 밀봉제 층이 형성되기에 충분한 시간동안 약 90 내지 95℃의 온도에서 금속 규산염 용액에 노출시킴을 또한 포함하는 방법.
- 약 0.01 내지 약 1중량%의 세륨염 및 약 0.2 내지 약 10중량%의 금속 질산염을 포함하는 수용액을 포함하는, 제1항의 방법에 따라 보호 코팅을 알루미늄 또는 알루미늄 합금의 표면에 제공하기 위한 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/766,319 US5192374A (en) | 1991-09-27 | 1991-09-27 | Chromium-free method and composition to protect aluminum |
US766,319 | 1991-09-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR930006181A true KR930006181A (ko) | 1993-04-21 |
KR950001218B1 KR950001218B1 (ko) | 1995-02-14 |
Family
ID=25076084
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019920017512A KR950001218B1 (ko) | 1991-09-27 | 1992-09-25 | 알루미늄을 보호하기 위한 크롬-배제 방법 및 조성물 |
Country Status (8)
Country | Link |
---|---|
US (1) | US5192374A (ko) |
EP (1) | EP0534120B1 (ko) |
JP (1) | JP2716328B2 (ko) |
KR (1) | KR950001218B1 (ko) |
AT (1) | ATE119949T1 (ko) |
CA (1) | CA2075118C (ko) |
DE (1) | DE69201707T2 (ko) |
MX (1) | MX9205471A (ko) |
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US6123782A (en) * | 1994-05-27 | 2000-09-26 | Raytheon Company | Nonchromated, primer-free, surface preparation for painting, powder coating and adhesive bonding |
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US6068711A (en) | 1994-10-07 | 2000-05-30 | Mcmaster University | Method of increasing corrosion resistance of metals and alloys by treatment with rare earth elements |
GB9420295D0 (en) * | 1994-10-07 | 1994-11-23 | Lu Yucheng | Method of increasing corrosion resistance of steels by treatment with cerium |
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DE19548740A1 (de) * | 1995-12-23 | 1997-06-26 | Abb Research Ltd | Verfahren zur Oberflächenbehandlung von Aluminium und Aluminiumlegierungen |
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US6190780B1 (en) * | 1996-02-05 | 2001-02-20 | Nippon Steel Corporation | Surface treated metal material and surface treating agent |
US5866652A (en) * | 1996-02-27 | 1999-02-02 | The Boeing Company | Chromate-free protective coatings |
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US6248184B1 (en) | 1997-05-12 | 2001-06-19 | The Boeing Company | Use of rare earth metal salt solutions for sealing or anodized aluminum for corosion protection and paint adhesion |
US6248183B1 (en) * | 1997-06-27 | 2001-06-19 | Concurrent Technologies Corporation | Non-chromate conversion coatings for aluminum and aluminum alloys |
US6669786B2 (en) * | 1997-06-27 | 2003-12-30 | Concurrent Technologies Corporation | Self-healing non-chromate coatings for aluminum and aluminum alloys |
US5964928A (en) * | 1998-03-12 | 1999-10-12 | Natural Coating Systems, Llc | Protective coatings for metals and other surfaces |
EP1144707B1 (en) | 1998-12-15 | 2006-03-01 | Lynntech, Inc. | Polymetalate and heteropolymetalate conversion coatings for metal substrates |
AUPQ633300A0 (en) | 2000-03-20 | 2000-04-15 | Commonwealth Scientific And Industrial Research Organisation | Process and solution for providing a conversion coating on a metallic surface ii |
AUPQ633200A0 (en) | 2000-03-20 | 2000-04-15 | Commonwealth Scientific And Industrial Research Organisation | Process and solution for providing a conversion coating on a metallic surface I |
US7241371B2 (en) * | 2000-08-17 | 2007-07-10 | The Curators Of University Of Missouri | Additive-assisted, cerium-based, corrosion-resistant e-coating |
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US7235142B2 (en) * | 2002-01-04 | 2007-06-26 | University Of Dayton | Non-toxic corrosion-protection rinses and seals based on cobalt |
US7294211B2 (en) * | 2002-01-04 | 2007-11-13 | University Of Dayton | Non-toxic corrosion-protection conversion coats based on cobalt |
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-
1991
- 1991-09-27 US US07/766,319 patent/US5192374A/en not_active Expired - Fee Related
-
1992
- 1992-07-31 CA CA002075118A patent/CA2075118C/en not_active Expired - Fee Related
- 1992-08-15 EP EP92113941A patent/EP0534120B1/en not_active Expired - Lifetime
- 1992-08-15 AT AT92113941T patent/ATE119949T1/de not_active IP Right Cessation
- 1992-08-15 DE DE69201707T patent/DE69201707T2/de not_active Expired - Fee Related
- 1992-09-25 MX MX9205471A patent/MX9205471A/es unknown
- 1992-09-25 KR KR1019920017512A patent/KR950001218B1/ko active IP Right Grant
- 1992-09-28 JP JP4258161A patent/JP2716328B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP2716328B2 (ja) | 1998-02-18 |
EP0534120A1 (en) | 1993-03-31 |
KR950001218B1 (ko) | 1995-02-14 |
DE69201707T2 (de) | 1995-09-07 |
US5192374A (en) | 1993-03-09 |
ATE119949T1 (de) | 1995-04-15 |
MX9205471A (es) | 1993-03-01 |
DE69201707D1 (de) | 1995-04-20 |
CA2075118A1 (en) | 1993-03-28 |
CA2075118C (en) | 1997-03-04 |
JPH05195247A (ja) | 1993-08-03 |
EP0534120B1 (en) | 1995-03-15 |
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