KR930000543A - 다중 부위의 올레핀 중합촉매 및 중합방법 - Google Patents
다중 부위의 올레핀 중합촉매 및 중합방법 Download PDFInfo
- Publication number
- KR930000543A KR930000543A KR1019920009893A KR920009893A KR930000543A KR 930000543 A KR930000543 A KR 930000543A KR 1019920009893 A KR1019920009893 A KR 1019920009893A KR 920009893 A KR920009893 A KR 920009893A KR 930000543 A KR930000543 A KR 930000543A
- Authority
- KR
- South Korea
- Prior art keywords
- compound
- catalyst component
- zirconium
- catalyst
- titanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims 4
- 150000001336 alkenes Chemical class 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 239000002685 polymerization catalyst Substances 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
- 239000003054 catalyst Substances 0.000 claims 22
- 239000010936 titanium Substances 0.000 claims 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 8
- -1 organometallic halide Chemical class 0.000 claims 8
- 229910052719 titanium Inorganic materials 0.000 claims 8
- 150000003755 zirconium compounds Chemical class 0.000 claims 8
- 239000000463 material Substances 0.000 claims 7
- 150000003682 vanadium compounds Chemical class 0.000 claims 7
- 125000000217 alkyl group Chemical group 0.000 claims 6
- 229910052736 halogen Inorganic materials 0.000 claims 6
- 239000002841 Lewis acid Substances 0.000 claims 5
- 125000004432 carbon atom Chemical group C* 0.000 claims 5
- 125000005843 halogen group Chemical group 0.000 claims 5
- 150000007517 lewis acids Chemical class 0.000 claims 5
- 239000003607 modifier Substances 0.000 claims 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 4
- 239000007795 chemical reaction product Substances 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 229910052726 zirconium Inorganic materials 0.000 claims 4
- 229940100198 alkylating agent Drugs 0.000 claims 3
- 239000002168 alkylating agent Substances 0.000 claims 3
- 239000007787 solid Substances 0.000 claims 3
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052749 magnesium Inorganic materials 0.000 claims 2
- 239000011777 magnesium Substances 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 230000000379 polymerizing effect Effects 0.000 claims 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 2
- 229910052720 vanadium Inorganic materials 0.000 claims 2
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims 1
- 241000207961 Sesamum Species 0.000 claims 1
- 235000003434 Sesamum indicum Nutrition 0.000 claims 1
- 229910003902 SiCl 4 Inorganic materials 0.000 claims 1
- 229910004298 SiO 2 Inorganic materials 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 150000007942 carboxylates Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 230000009977 dual effect Effects 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- 230000002140 halogenating effect Effects 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 239000013067 intermediate product Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 229910001507 metal halide Inorganic materials 0.000 claims 1
- 150000005309 metal halides Chemical class 0.000 claims 1
- 238000001465 metallisation Methods 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- QSLMQGXOMLSFAW-UHFFFAOYSA-N methanidylbenzene;zirconium(4+) Chemical compound [Zr+4].[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1 QSLMQGXOMLSFAW-UHFFFAOYSA-N 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 229930195734 saturated hydrocarbon Natural products 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical group CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 150000003752 zinc compounds Chemical class 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US712206 | 1991-06-07 | ||
| US07/712,206 US5155079A (en) | 1991-06-07 | 1991-06-07 | Multiple site olefin polymerization catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR930000543A true KR930000543A (ko) | 1993-01-15 |
Family
ID=24861176
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019920009893A Withdrawn KR930000543A (ko) | 1991-06-07 | 1992-06-08 | 다중 부위의 올레핀 중합촉매 및 중합방법 |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US5155079A (enExample) |
| EP (1) | EP0538554A1 (enExample) |
| JP (1) | JPH05239141A (enExample) |
| KR (1) | KR930000543A (enExample) |
| CN (1) | CN1069033A (enExample) |
| AU (1) | AU650344B2 (enExample) |
| BR (1) | BR9202181A (enExample) |
| CA (1) | CA2070496A1 (enExample) |
| FI (1) | FI922616L (enExample) |
| NO (1) | NO922231L (enExample) |
| TW (1) | TW238313B (enExample) |
| ZA (1) | ZA924073B (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5399540A (en) * | 1993-02-12 | 1995-03-21 | Quantum Chemical Corporation | ZR/V multi-site olefin polymerization catalyst |
| FI96611C (fi) * | 1993-09-10 | 1996-07-25 | Neste Oy | Heterogeeninen polymerointikatalyytti ja menetelmä sen valmistamiseksi |
| EP0692498A1 (en) * | 1994-07-13 | 1996-01-17 | Quantum Chemical Corporation | Vanadium-containing polymerization catalyst |
| US5661097A (en) * | 1994-08-12 | 1997-08-26 | The Dow Chemical Company | Supported olefin polymerization catalyst |
| JPH10505622A (ja) | 1994-09-08 | 1998-06-02 | モービル・オイル・コーポレーション | 単一の反応器内での広い／２モードのｍｗｄの樹脂の触媒制御 |
| US5895770A (en) * | 1995-02-28 | 1999-04-20 | Pq Corporation | Olefin polymerization catalysts with specific silica supports |
| US5723402A (en) * | 1996-05-30 | 1998-03-03 | Pq Corporation | Silicas with specific contents of cations as supports for olefin polymerization catalysts |
| TW421663B (en) | 1996-09-04 | 2001-02-11 | Dow Chemical Co | Blends of <alpha>-olefin/vinyl or vinylidene aromatic monomer and/or aliphatic or cycloaliphatic vinyl or vinylidene monomer interpolymers |
| US6268447B1 (en) | 1998-12-18 | 2001-07-31 | Univation Technologies, L.L.C. | Olefin polymerization catalyst |
| US6103657A (en) | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
| US6177375B1 (en) | 1998-03-09 | 2001-01-23 | Pq Corporation | High activity olefin polymerization catalysts |
| US6001764A (en) * | 1998-05-08 | 1999-12-14 | Pq Corporation | Olefin polymerization catalysts with specific silica supports |
| US6303719B1 (en) | 1998-12-18 | 2001-10-16 | Univation Technologies | Olefin polymerization catalyst system |
| KR20020019476A (ko) * | 1999-06-30 | 2002-03-12 | 조셉 에스. 바이크 | 마그네슘-지르코늄 알콕사이드 착물 및 이로부터 제조된중합 촉매 |
| US6479598B1 (en) | 1999-07-20 | 2002-11-12 | Exxonmobil Chemical Patents Inc. | Petroleum resins and their production with BF3 catalyst |
| US20090048402A1 (en) * | 2007-08-17 | 2009-02-19 | Lynch Michael W | Preparing multimodal polyethylene having controlled long chain branching distribution |
| US8012900B2 (en) * | 2007-12-28 | 2011-09-06 | Chevron Phillips Chemical Company, L.P. | Nano-linked metallocene catalyst compositions and their polymer products |
| US7863210B2 (en) | 2007-12-28 | 2011-01-04 | Chevron Phillips Chemical Company Lp | Nano-linked metallocene catalyst compositions and their polymer products |
| US8080681B2 (en) * | 2007-12-28 | 2011-12-20 | Chevron Phillips Chemical Company Lp | Nano-linked metallocene catalyst compositions and their polymer products |
| CN101745422B (zh) * | 2008-11-28 | 2013-06-05 | 中国石油化工股份有限公司 | 一种烯烃齐聚催化剂及制备方法与应用 |
| CN101816951B (zh) * | 2009-02-27 | 2013-01-09 | 中国石油化工股份有限公司 | 一种乙烯齐聚催化剂及制备方法 |
| US7919639B2 (en) * | 2009-06-23 | 2011-04-05 | Chevron Phillips Chemical Company Lp | Nano-linked heteronuclear metallocene catalyst compositions and their polymer products |
| EP3749707A1 (en) | 2018-02-05 | 2020-12-16 | ExxonMobil Chemical Patents Inc. | Enhanced processability of lldpe by addition of ultra-high molecular weight high density polyethylene |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE543941A (enExample) * | 1954-12-24 | |||
| JPS55151009A (en) * | 1979-05-16 | 1980-11-25 | Mitsui Petrochem Ind Ltd | Preparation of olefin polymer or copolymer |
| US4325835A (en) * | 1980-01-10 | 1982-04-20 | Imperial Chemical Industries Limited | Catalyst component |
| US4381253A (en) * | 1981-10-22 | 1983-04-26 | The Dow Chemical Company | Ultra high efficiency catalyst for polymerizing olefins |
| US4435518A (en) * | 1982-11-24 | 1984-03-06 | Cities Service Co. | Polymerization catalyst |
| FR2541683B1 (fr) * | 1983-02-28 | 1986-05-09 | Ato Chimie | Procede pour la preparation d'un solide hydrocarbone actif utilisable pour polymeriser des olefines, et procede de synthese d'un polymere ou copolymere olefinique faisant appel audit solide hydrocarbone actif comme systeme |
| US4672096A (en) * | 1984-04-04 | 1987-06-09 | Mobil Oil Corporation | Catalyst composition for polymerizing alpha-olefins |
| DE3417238A1 (de) * | 1984-05-10 | 1985-11-14 | Basf Ag, 6700 Ludwigshafen | Verfahren zum herstellen von homopolymerisaten des ethens sowie copolymerisaten des ethens mit hoeheren -monoolefinen mittels eines ziegler-katalysatorsystems |
| US4554265A (en) * | 1984-06-29 | 1985-11-19 | Exxon Research & Engineering Co. | Polymerization catalyst |
| US4578373A (en) * | 1984-09-04 | 1986-03-25 | Exxon Research & Engineering Co. | Polymerization catalyst system |
| US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4659685A (en) * | 1986-03-17 | 1987-04-21 | The Dow Chemical Company | Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound |
| DE3635028A1 (de) * | 1986-10-15 | 1988-04-21 | Basf Ag | Verfahren zum herstellen von homopolymerisaten des ethens sowie copolymerisaten des ethens mit hoeheren (alpha)-monoolefinen mittels eines ziegler-katalysatorsystems |
| SE458612B (sv) * | 1987-08-19 | 1989-04-17 | Neste Oy | Katalysatorkomposition baserad paa aktiverad silika och en reaktionsprodukt av vanadinpentoxid och ett kloreringsmedel samt saett att framstaella en olefinpolymer haermed |
| US4918038A (en) * | 1987-10-29 | 1990-04-17 | Union Carbide Chemicals And Plastics Company Inc. | Process for the production of polyethylene with a broad and/or bimodal molecular weight distribution |
| US4866021A (en) * | 1988-01-15 | 1989-09-12 | Mobil Oil Corp. | Catalyst composition for preparing high density, broad molecular weight distribution alpha-olefin polymers |
| US5070055A (en) * | 1990-06-29 | 1991-12-03 | Union Carbide Chemicals And Plastics Technology Corporation | Novel coimpregnated vanadium-zirconium catalyst for making polyethylene with broad or bimodal MW distribution |
-
1991
- 1991-06-07 US US07/712,206 patent/US5155079A/en not_active Expired - Fee Related
-
1992
- 1992-06-04 ZA ZA924073A patent/ZA924073B/xx unknown
- 1992-06-04 AU AU18022/92A patent/AU650344B2/en not_active Ceased
- 1992-06-04 CA CA002070496A patent/CA2070496A1/en not_active Abandoned
- 1992-06-05 JP JP4187286A patent/JPH05239141A/ja active Pending
- 1992-06-05 FI FI922616A patent/FI922616L/fi not_active Application Discontinuation
- 1992-06-05 NO NO92922231A patent/NO922231L/no unknown
- 1992-06-05 EP EP92109559A patent/EP0538554A1/en not_active Withdrawn
- 1992-06-06 CN CN92105100A patent/CN1069033A/zh active Pending
- 1992-06-08 BR BR929202181A patent/BR9202181A/pt not_active Application Discontinuation
- 1992-06-08 KR KR1019920009893A patent/KR930000543A/ko not_active Withdrawn
- 1992-07-20 TW TW081105713A patent/TW238313B/zh active
-
1993
- 1993-02-24 US US08/023,135 patent/US5369194A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| NO922231L (no) | 1992-12-08 |
| NO922231D0 (no) | 1992-06-05 |
| FI922616A7 (fi) | 1992-12-08 |
| CA2070496A1 (en) | 1992-12-08 |
| TW238313B (enExample) | 1995-01-11 |
| CN1069033A (zh) | 1993-02-17 |
| EP0538554A1 (en) | 1993-04-28 |
| FI922616L (fi) | 1992-12-08 |
| US5369194A (en) | 1994-11-29 |
| US5155079A (en) | 1992-10-13 |
| AU650344B2 (en) | 1994-06-16 |
| BR9202181A (pt) | 1993-02-02 |
| FI922616A0 (fi) | 1992-06-05 |
| JPH05239141A (ja) | 1993-09-17 |
| ZA924073B (en) | 1993-04-28 |
| AU1802292A (en) | 1992-12-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19920608 |
|
| PG1501 | Laying open of application | ||
| PC1203 | Withdrawal of no request for examination | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |