KR920021486A - 비닐 유도체의 제조 방법 - Google Patents

비닐 유도체의 제조 방법 Download PDF

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Publication number
KR920021486A
KR920021486A KR1019920007730A KR920007730A KR920021486A KR 920021486 A KR920021486 A KR 920021486A KR 1019920007730 A KR1019920007730 A KR 1019920007730A KR 920007730 A KR920007730 A KR 920007730A KR 920021486 A KR920021486 A KR 920021486A
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KR
South Korea
Prior art keywords
acid
porous support
carboxylic acid
inert porous
alumina
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Application number
KR1019920007730A
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English (en)
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KR100209276B1 (ko
Inventor
드렌트 아이트
Original Assignee
알베르투스 빌헬무스 요아네스, 쩨스트 라텐
셀 인터나쵸 나아레 레사아치 마아츠 샤피 비이부이
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Application filed by 알베르투스 빌헬무스 요아네스, 쩨스트 라텐, 셀 인터나쵸 나아레 레사아치 마아츠 샤피 비이부이 filed Critical 알베르투스 빌헬무스 요아네스, 쩨스트 라텐
Publication of KR920021486A publication Critical patent/KR920021486A/ko
Application granted granted Critical
Publication of KR100209276B1 publication Critical patent/KR100209276B1/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/24—Oxygen or sulfur atoms
    • C07D207/26—2-Pyrrolidones
    • C07D207/263—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms
    • C07D207/267—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
    • C07C69/01—Vinyl esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyrrole Compounds (AREA)

Abstract

내용 없음

Description

비닐 유도체의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 불활성 다공성 지지체상에 지지된 루테늄으로 구성되는 불균질 촉매의 존재하에서 승온에서 아세틸렌형으로 불포화된 화합물과 브뢴스테드산을 접촉시킴으로 브뢴스테드산의 비닐 유도체를 제조하는 방법.
  2. 제1항에 있어서, 아세틸형으로 불포화된 화합물은 에틴인 방법.
  3. 제1-2항중 어느 한 항 이상에 있어서, 브뢴스테드산은 카르복실산, 시클릭 아미드 및 방향족 히드록시 화합물로부터 선택되는 방법.
  4. 제3항에 있어서, 카르복실산은 C1-C30을 갖는 지방족 카르복실산인 방법.
  5. 제4항에 있어서, 지방족 카르복실산은 트리알킬아세트산인 방법.
  6. 제1-5항중 어느 한 항 이상에 있어서, 온도는 40-250℃ 범위내, 바람직하게 80-175℃ 범위 내인 방법.
  7. 제1-6항중 어느 한 항 이상에 있어서, 불균질 촉매는 O 가루테늄으로 구성되는 방법.
  8. 제1-7항중 어느 한 항 이상에 있어서, 불활성 다공성 지지체는 내화성 산화물 및 탄소의 군으로부터 선택되는 방법.
  9. 제8항에 있어서, 내화성 산화물은 알루미나, 실리카, 실리카-알루미나, 티타니아, 지르코니아, 마그네시아 및 이의 혼합물의 군으로부터 선택되는 방법.
  10. 제8항에 있어서, 불활성 다공성 지지체는 탄소인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920007730A 1991-05-10 1992-05-07 비닐 유도체의 제조 방법 KR100209276B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB919110110A GB9110110D0 (en) 1991-05-10 1991-05-10 Process for the preparation of vinyl derivatives
GB9110110.5 1991-05-10

Publications (2)

Publication Number Publication Date
KR920021486A true KR920021486A (ko) 1992-12-18
KR100209276B1 KR100209276B1 (ko) 1999-07-15

Family

ID=10694751

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920007730A KR100209276B1 (ko) 1991-05-10 1992-05-07 비닐 유도체의 제조 방법

Country Status (7)

Country Link
EP (1) EP0512656B1 (ko)
JP (1) JPH05170700A (ko)
KR (1) KR100209276B1 (ko)
CA (1) CA2068291A1 (ko)
DE (1) DE69209713T2 (ko)
ES (1) ES2086635T3 (ko)
GB (1) GB9110110D0 (ko)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4313922A1 (de) * 1993-04-28 1994-11-03 Basf Ag Verfahren zur Herstellung von Carbonsäurevinylestern
DE4333237A1 (de) * 1993-09-30 1995-04-06 Basf Ag Verfahren zur Herstellung von N-Vinylverbindungen
JPH09505070A (ja) * 1993-11-17 1997-05-20 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ エチレン性不飽和化合物の製造方法
US5430179A (en) * 1994-07-28 1995-07-04 Union Carbide Chemicals & Plastics Technology Homogeneous process for the ruthenium catalyzed addition of carboxylic acids to alkynes
DE19509362A1 (de) * 1995-03-15 1996-09-19 Basf Ag Verfahren zur Herstellung von N-Vinyllactamen
DE19816479B4 (de) * 1998-04-14 2005-02-03 Müller, Thomas, Dr. Verfahren zur Herstellung von Enaminen, Iminen, Indolen und Diaminen aus Alkinen und deren Weiterverarbeitung durch katalytische Hydrierung
DE19836814A1 (de) * 1998-08-14 2000-02-17 Basf Ag Verfahren zur Herstellung von Iminen und Enaminen und gegebenenfalls deren Weiterhydrierung zu Aminen
DE10001208B4 (de) * 2000-01-14 2005-02-03 Müller, Thomas, Dr. Verfahren zur homogen-katalytischen Hydroaminierung von Alkinen für die Herstellung von Enaminen, Iminen, Indolen und Diaminen und deren Weiterverarbeitung durch katalytische Hydrierung
EP1281700A1 (en) 2001-07-31 2003-02-05 Resolution Research Nederland B.V. Manufacturing process for the preparation of alpha, alpha-branched alkane carboxylic acids providing esters with an improved softness
KR101374505B1 (ko) 2005-11-23 2014-03-13 바스프 에스이 비닐 카르복실레이트의 제조 방법
KR101529337B1 (ko) 2007-05-16 2015-06-16 바스프 에스이 카르복실산의 비닐 에스테르의 제조 방법
US7982065B2 (en) * 2009-05-07 2011-07-19 Celanese International Corporation Vinyl ester production from acetylene and carboxylic acid utilizing heterogeneous catalyst
US8173830B2 (en) * 2009-05-07 2012-05-08 Celanese International Corporation Vinyl ester production from acetylene and carboxylic acid utilizing homogeneous catalyst
CN114829339A (zh) 2019-12-20 2022-07-29 巴斯夫欧洲公司 通过使环状nh-化合物与乙炔在均相催化剂存在下反应而合成n-乙烯基化合物
US20240270690A1 (en) 2021-05-19 2024-08-15 Basf Se Synthesis of n-vinyl compounds by reacting nh-compounds with acetylene in presence of homogeneous phosphine catalyst

Also Published As

Publication number Publication date
DE69209713T2 (de) 1996-10-31
CA2068291A1 (en) 1992-11-11
GB9110110D0 (en) 1991-07-03
EP0512656B1 (en) 1996-04-10
ES2086635T3 (es) 1996-07-01
EP0512656A3 (en) 1993-05-05
EP0512656A2 (en) 1992-11-11
DE69209713D1 (de) 1996-05-15
KR100209276B1 (ko) 1999-07-15
JPH05170700A (ja) 1993-07-09

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