KR920021486A - 비닐 유도체의 제조 방법 - Google Patents
비닐 유도체의 제조 방법 Download PDFInfo
- Publication number
- KR920021486A KR920021486A KR1019920007730A KR920007730A KR920021486A KR 920021486 A KR920021486 A KR 920021486A KR 1019920007730 A KR1019920007730 A KR 1019920007730A KR 920007730 A KR920007730 A KR 920007730A KR 920021486 A KR920021486 A KR 920021486A
- Authority
- KR
- South Korea
- Prior art keywords
- acid
- porous support
- carboxylic acid
- inert porous
- alumina
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/24—Oxygen or sulfur atoms
- C07D207/26—2-Pyrrolidones
- C07D207/263—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms
- C07D207/267—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to the ring nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
- C07C69/01—Vinyl esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Pyrrole Compounds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 불활성 다공성 지지체상에 지지된 루테늄으로 구성되는 불균질 촉매의 존재하에서 승온에서 아세틸렌형으로 불포화된 화합물과 브뢴스테드산을 접촉시킴으로 브뢴스테드산의 비닐 유도체를 제조하는 방법.
- 제1항에 있어서, 아세틸형으로 불포화된 화합물은 에틴인 방법.
- 제1-2항중 어느 한 항 이상에 있어서, 브뢴스테드산은 카르복실산, 시클릭 아미드 및 방향족 히드록시 화합물로부터 선택되는 방법.
- 제3항에 있어서, 카르복실산은 C1-C30을 갖는 지방족 카르복실산인 방법.
- 제4항에 있어서, 지방족 카르복실산은 트리알킬아세트산인 방법.
- 제1-5항중 어느 한 항 이상에 있어서, 온도는 40-250℃ 범위내, 바람직하게 80-175℃ 범위 내인 방법.
- 제1-6항중 어느 한 항 이상에 있어서, 불균질 촉매는 O 가루테늄으로 구성되는 방법.
- 제1-7항중 어느 한 항 이상에 있어서, 불활성 다공성 지지체는 내화성 산화물 및 탄소의 군으로부터 선택되는 방법.
- 제8항에 있어서, 내화성 산화물은 알루미나, 실리카, 실리카-알루미나, 티타니아, 지르코니아, 마그네시아 및 이의 혼합물의 군으로부터 선택되는 방법.
- 제8항에 있어서, 불활성 다공성 지지체는 탄소인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB919110110A GB9110110D0 (en) | 1991-05-10 | 1991-05-10 | Process for the preparation of vinyl derivatives |
GB9110110.5 | 1991-05-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR920021486A true KR920021486A (ko) | 1992-12-18 |
KR100209276B1 KR100209276B1 (ko) | 1999-07-15 |
Family
ID=10694751
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019920007730A KR100209276B1 (ko) | 1991-05-10 | 1992-05-07 | 비닐 유도체의 제조 방법 |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0512656B1 (ko) |
JP (1) | JPH05170700A (ko) |
KR (1) | KR100209276B1 (ko) |
CA (1) | CA2068291A1 (ko) |
DE (1) | DE69209713T2 (ko) |
ES (1) | ES2086635T3 (ko) |
GB (1) | GB9110110D0 (ko) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4313922A1 (de) * | 1993-04-28 | 1994-11-03 | Basf Ag | Verfahren zur Herstellung von Carbonsäurevinylestern |
DE4333237A1 (de) * | 1993-09-30 | 1995-04-06 | Basf Ag | Verfahren zur Herstellung von N-Vinylverbindungen |
JPH09505070A (ja) * | 1993-11-17 | 1997-05-20 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | エチレン性不飽和化合物の製造方法 |
US5430179A (en) * | 1994-07-28 | 1995-07-04 | Union Carbide Chemicals & Plastics Technology | Homogeneous process for the ruthenium catalyzed addition of carboxylic acids to alkynes |
DE19509362A1 (de) * | 1995-03-15 | 1996-09-19 | Basf Ag | Verfahren zur Herstellung von N-Vinyllactamen |
DE19816479B4 (de) * | 1998-04-14 | 2005-02-03 | Müller, Thomas, Dr. | Verfahren zur Herstellung von Enaminen, Iminen, Indolen und Diaminen aus Alkinen und deren Weiterverarbeitung durch katalytische Hydrierung |
DE19836814A1 (de) * | 1998-08-14 | 2000-02-17 | Basf Ag | Verfahren zur Herstellung von Iminen und Enaminen und gegebenenfalls deren Weiterhydrierung zu Aminen |
DE10001208B4 (de) * | 2000-01-14 | 2005-02-03 | Müller, Thomas, Dr. | Verfahren zur homogen-katalytischen Hydroaminierung von Alkinen für die Herstellung von Enaminen, Iminen, Indolen und Diaminen und deren Weiterverarbeitung durch katalytische Hydrierung |
EP1281700A1 (en) | 2001-07-31 | 2003-02-05 | Resolution Research Nederland B.V. | Manufacturing process for the preparation of alpha, alpha-branched alkane carboxylic acids providing esters with an improved softness |
KR101374505B1 (ko) | 2005-11-23 | 2014-03-13 | 바스프 에스이 | 비닐 카르복실레이트의 제조 방법 |
KR101529337B1 (ko) | 2007-05-16 | 2015-06-16 | 바스프 에스이 | 카르복실산의 비닐 에스테르의 제조 방법 |
US7982065B2 (en) * | 2009-05-07 | 2011-07-19 | Celanese International Corporation | Vinyl ester production from acetylene and carboxylic acid utilizing heterogeneous catalyst |
US8173830B2 (en) * | 2009-05-07 | 2012-05-08 | Celanese International Corporation | Vinyl ester production from acetylene and carboxylic acid utilizing homogeneous catalyst |
CN114829339A (zh) | 2019-12-20 | 2022-07-29 | 巴斯夫欧洲公司 | 通过使环状nh-化合物与乙炔在均相催化剂存在下反应而合成n-乙烯基化合物 |
US20240270690A1 (en) | 2021-05-19 | 2024-08-15 | Basf Se | Synthesis of n-vinyl compounds by reacting nh-compounds with acetylene in presence of homogeneous phosphine catalyst |
-
1991
- 1991-05-10 GB GB919110110A patent/GB9110110D0/en active Pending
-
1992
- 1992-05-07 KR KR1019920007730A patent/KR100209276B1/ko not_active IP Right Cessation
- 1992-05-08 ES ES92201337T patent/ES2086635T3/es not_active Expired - Lifetime
- 1992-05-08 CA CA002068291A patent/CA2068291A1/en not_active Abandoned
- 1992-05-08 JP JP4142020A patent/JPH05170700A/ja active Pending
- 1992-05-08 DE DE69209713T patent/DE69209713T2/de not_active Expired - Fee Related
- 1992-05-08 EP EP92201337A patent/EP0512656B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69209713T2 (de) | 1996-10-31 |
CA2068291A1 (en) | 1992-11-11 |
GB9110110D0 (en) | 1991-07-03 |
EP0512656B1 (en) | 1996-04-10 |
ES2086635T3 (es) | 1996-07-01 |
EP0512656A3 (en) | 1993-05-05 |
EP0512656A2 (en) | 1992-11-11 |
DE69209713D1 (de) | 1996-05-15 |
KR100209276B1 (ko) | 1999-07-15 |
JPH05170700A (ja) | 1993-07-09 |
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