ES2196489T3 - Procedimiento para la fabricacion de 2,6-naftalendicarboxilato de dimetilo de elevada pureza y acido naftalendicarboxilico. - Google Patents

Procedimiento para la fabricacion de 2,6-naftalendicarboxilato de dimetilo de elevada pureza y acido naftalendicarboxilico.

Info

Publication number
ES2196489T3
ES2196489T3 ES98303601T ES98303601T ES2196489T3 ES 2196489 T3 ES2196489 T3 ES 2196489T3 ES 98303601 T ES98303601 T ES 98303601T ES 98303601 T ES98303601 T ES 98303601T ES 2196489 T3 ES2196489 T3 ES 2196489T3
Authority
ES
Spain
Prior art keywords
oxidation
procedure
acid
naftalendicarboxylate
naftalendicarboxilic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98303601T
Other languages
English (en)
Inventor
Hiroshi Machida
Fumiya Zaima
Kengi Nakaya
Kazuo Tanaka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Gas Chemical Co Inc
Original Assignee
Mitsubishi Gas Chemical Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP11816397A external-priority patent/JP4032186B2/ja
Priority claimed from JP9186882A external-priority patent/JPH1129521A/ja
Application filed by Mitsubishi Gas Chemical Co Inc filed Critical Mitsubishi Gas Chemical Co Inc
Application granted granted Critical
Publication of ES2196489T3 publication Critical patent/ES2196489T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCEDIMIENTO DE PRODUCCION DE DIMETIL 2,6 - NAFTALENDICARBOXILATO, EL CUAL COMPRENDE ESTERIFICAR CON METANOL ACIDO 2,6 - NAFTALENDICARBOXILICO OBTENIDO MEDIANTE OXIDACION EN FASE LIQUIDA DE 2,6 DIALQUILNAFTALENO CON OXIGENO MOLECULAR, EN PRESENCIA DE UN CATALIZADOR DE OXIDACION Y, A CONTINUACION, PURIFICAR EL ESTER BRUTO ASI OBTENIDO, EN PRESENCIA DE UN DISOLVENTE HIDROCARBONADO AROMATICO. EN DICHO PROCEDIMIENTO, LAS IMPUREZAS CONTENIDAS EN EL PRODUCTO DE REACCION SE PUEDEN ELIMINAR DE FORMA EFECTIVA MEDIANTE PROCEDIMIENTOS SIMPLES. SE PRESENTA ASIMISMO UN PROCEDIMIENTO DE PRODUCCION DE ACIDO NAFTALEDICARBOXILICO, EL CUAL COMPRENDE LA OXIDACION DE DIALQUILNAFTALENO Y/O UN OXIDO DEL MISMO, CON UN GAS QUE CONTENGA OXIGENO, EN UN DISOLVENTE QUE CONTENGA UN ACIDO CARBOXILICO ALIFATICO INFERIOR, Y EN PRESENCIA DE UN CATALIZADOR DE OXIDACION, QUE COMPRENDE AL MENOS COBALTO, MANGANESO Y BROMO, REALIZANDOSE DICHA OXIDACION EN PRESENCIA DE UN COMPONENTE CATALIZADOR DE UNA SAL METALICA DE ACIDO NAFTALENDICARBOXILICO.
ES98303601T 1997-05-08 1998-05-07 Procedimiento para la fabricacion de 2,6-naftalendicarboxilato de dimetilo de elevada pureza y acido naftalendicarboxilico. Expired - Lifetime ES2196489T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP11816397A JP4032186B2 (ja) 1997-05-08 1997-05-08 高純度２，６−ナフタレンジカルボン酸ジメチルの製造法
JP9186882A JPH1129521A (ja) 1997-07-11 1997-07-11 ナフタレンジカルボン酸の製造法

Publications (1)

Publication Number Publication Date
ES2196489T3 true ES2196489T3 (es) 2003-12-16

Family

ID=26456147

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98303601T Expired - Lifetime ES2196489T3 (es) 1997-05-08 1998-05-07 Procedimiento para la fabricacion de 2,6-naftalendicarboxilato de dimetilo de elevada pureza y acido naftalendicarboxilico.

Country Status (6)

Country Link
US (1) US6013831A (es)
EP (1) EP0877012B1 (es)
KR (1) KR100562436B1 (es)
DE (1) DE69813361T2 (es)
ES (1) ES2196489T3 (es)
TW (1) TW421642B (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6211398B1 (en) * 1997-10-03 2001-04-03 Eastman Chemical Company Process for the preparation of dialkyl esters of naphthalenedicarboxylic acids
KR20020001687A (ko) * 2001-11-23 2002-01-09 주식회사 브레인체인 딜스-알더 반응을 이용한 피이엔 원료의 제조방법
GB0504079D0 (en) * 2005-02-28 2005-04-06 Davy Process Techn Ltd Process
KR100721439B1 (ko) * 2006-06-01 2007-05-23 주식회사 효성 나프탈렌디카르복실산의 정제 공정
CN112441918A (zh) * 2019-09-04 2021-03-05 中国石油化工股份有限公司 合成2,6-萘二甲酸二甲酯的方法
CN112694397B (zh) * 2019-10-23 2023-03-03 中国石油化工股份有限公司 2,6-萘二甲酸的提纯方法
CN114832738A (zh) * 2021-08-30 2022-08-02 煤炭科学技术研究院有限公司 反应器
CN114805071A (zh) * 2022-05-23 2022-07-29 煤炭科学技术研究院有限公司 一种连续精制2,6-萘二甲酸二甲酯的方法
CN114773192B (zh) * 2022-05-23 2023-09-26 煤炭科学技术研究院有限公司 一种连续制备2,6-萘二甲酸二甲酯切片的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4886901A (en) * 1988-11-21 1989-12-12 Amoco Corporation Method for purifying a crude dimethyl naphthalene dicarboxylate
US5095135A (en) * 1990-04-05 1992-03-10 Sumikin Chemical Co., Ltd. Process for the preparation of high-purity naphthalenecarboxylic acid esters
US5262560A (en) * 1991-05-31 1993-11-16 Amoco Corporation Process for preparing purified dimethyl naphthalenedicarboxylate
JPH04364152A (ja) * 1991-06-10 1992-12-16 Teijin Ltd 触媒の回収方法
US5183933A (en) * 1991-10-15 1993-02-02 Amoco Corporation Process for preparing 2,6-naphthalene-dicarboxylic acid
JP3199104B2 (ja) * 1995-01-11 2001-08-13 三菱瓦斯化学株式会社 ２，６−ナフタレンジカルボン酸及びそのエステルの製造法

Also Published As

Publication number Publication date
DE69813361T2 (de) 2003-10-16
EP0877012B1 (en) 2003-04-16
DE69813361D1 (de) 2003-05-22
EP0877012A3 (en) 1999-01-07
KR19980086891A (ko) 1998-12-05
EP0877012A2 (en) 1998-11-11
US6013831A (en) 2000-01-11
KR100562436B1 (ko) 2006-12-05
TW421642B (en) 2001-02-11

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