KR920018196A - 자동열 증기 개질방법 - Google Patents

자동열 증기 개질방법 Download PDF

Info

Publication number
KR920018196A
KR920018196A KR1019920004225A KR920004225A KR920018196A KR 920018196 A KR920018196 A KR 920018196A KR 1019920004225 A KR1019920004225 A KR 1019920004225A KR 920004225 A KR920004225 A KR 920004225A KR 920018196 A KR920018196 A KR 920018196A
Authority
KR
South Korea
Prior art keywords
feed stream
mixed feed
stream
volume percent
steam
Prior art date
Application number
KR1019920004225A
Other languages
English (en)
Other versions
KR100201886B1 (ko
Inventor
알. 르블랑 조셉
Original Assignee
크레이그 더블유. 왈포드
더 엠. 더블유. 켈로그 컴페니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=24641931&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR920018196(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 크레이그 더블유. 왈포드, 더 엠. 더블유. 켈로그 컴페니 filed Critical 크레이그 더블유. 왈포드
Publication of KR920018196A publication Critical patent/KR920018196A/ko
Application granted granted Critical
Publication of KR100201886B1 publication Critical patent/KR100201886B1/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/0257—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical annular shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0476—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds
    • B01J8/0488—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds the beds being placed in separate reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/025—Preparation or purification of gas mixtures for ammonia synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19—Details relating to the geometry of the reactor
    • B01J2219/194—Details relating to the geometry of the reactor round
    • B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
    • B01J2219/1946—Details relating to the geometry of the reactor round circular or disk-shaped conical
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/061—Methanol production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/068—Ammonia synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

자동열 증기 개질방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명 방법의 순서적인 공정의 흐름도를 나타낸다.

Claims (7)

  1. 새로운 탄화수소 성분 스트림으로부터 암모니아 및 메탄올의 제조에 쓰이는 합성가스 제조방법으로서, a)증기, 상기 새로운 탄화수소 성분 스트림의 대부분, 및 공기, 산소 다량 공기 및 산소로 이루어지는 군에서 선택된 산화제로 이루어지는 제1혼합 공급 스트림을 형성하고 상기 제1혼합 공급 스트림을 건조기준 2.0 용적 퍼센트 보다 적은 잔류 탄화수소를 함유하는 제1개질된 가스가 제조되는 발열 촉매 증기 개질 영역으로 도입하며 그곳으로부터 상기 제1개질된 가스를 회수하는 단계; b)상기 새로운 탄화수소 성분 스트림의 나머지 적은 부분과 증기로 구성되는 제2혼합 공급 스트림을 형성하고 상기 제2혼합 공급 스트림을 건조기준 10.0 용적 퍼센트 보다 적은 잔류 탄화수소를 함유하는 제2개질된 가스가 제조되는 흡열 촉매 증기 개질 영역으로 도입하며 그곳으로부터 상기 제2개질된 가스를 회수하는 단계; c)상기 제1및 제2개질된 가스를 합치고 상기 합친 제1및 제2개질된 가스를 상기 제2혼합 공급 스트림과 간접 열 교환하에 상기 흡열 촉매 증기 개질영역내를 통과시키는 것에 의해 상기 합친 제1및 제2개질된 가스를 냉각시켜 상기 제2공급 스트림의 흡열촉매 증기 개질에 필요한 모든 열을 제공받는 단계; 및 d)상기 냉각된 합쳐진 가스를 합성 가스물로 배출시켜 회수하는 단계로 이루어지는 합성가스의 제조방법.
  2. 제1항에 있어서, 상기 새로운 탄화수소 성분 스트림의 대부분은 상기 새로운 탄화수소공급의 55와 85용적 퍼센트사이에 있는 합성가스 제조방법.
  3. 제2항에 있어서, 상기 새로운 탄화수소 성분 스트림은 450℃와 650℃사이의 온도로 예열되는 합성가스 제조방법.
  4. 제3항에 있어서, 상기 새로운 탄화수소 성분 스트림은 상기 합성가스물과의 간접 열교환에 의해 예열되는 합성가스 제조방법.
  5. 제3항에 있어서, 산화제는 480°와 720℃사이의 온도로 예열된 공기이고, 상기 제1공급 스트림의 증기 대 C1는 1.5와 3.5사이이며, 상기 제2혼합공급스트림의 증기 대 C1비는 4.0과 5.0사이이고, 상기 발열촉매 증기 재질영역으로부터 배출된 제1개질된 가스는 건조기준으로 1.0 용적 퍼센트보다 작은 잔류 탄화수소를 함유하며 상기 흡열 촉매 증기 개질영역으로부터 배출된 상기 제2개질된 가스는 건조기준으로 4.0 용적 퍼센트보다 적은 잔류 탄화수소를 함유하는 합성 가스 제조방법.
  6. 제3항에 있어서, 산화제는 480°와 720℃사이의 온도로 예열된 산소다량 공기이고, 상기 제1혼합공급 스트림의 증기 대 C1는 비는 2.5와 4.5사이이며, 상기 제2혼합공급스트림의 증기 대 C1비는 4.0과 5.0사이이고, 상기 발열촉매 증기 재질영역으로부터 배출된 제1개질된 가스는 건조기준으로 1.0 용적 퍼센트보다 작은 잔류 탄화수소를 함유하며 상기 흡열 촉매 증기 개질영역으로부터 배출된 상기 제2개질된 가스는 건조기준으로 4.0 용적 퍼센트보다 적은 잔류 탄화수소를 함유하는 합성 가스 제조방법.
  7. 제1항에 있어서, 산화제는 90°와 450℃사이의 온도로 예열된 산소이고 제1혼합 공급 스트림 및 제2혼합공급 스트림 각각의 증기 대 C1비는 2.5와 4.5사이인 합성 가스 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019920004225A 1991-03-14 1992-03-14 자동열 증기 개질방법 KR100201886B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US7/658,604 1991-03-14
US07/658,604 US5122299A (en) 1989-12-11 1991-03-14 Autothermal steam reforming process
US07/658,604 1991-03-14

Publications (2)

Publication Number Publication Date
KR920018196A true KR920018196A (ko) 1992-10-21
KR100201886B1 KR100201886B1 (ko) 1999-06-15

Family

ID=24641931

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920004225A KR100201886B1 (ko) 1991-03-14 1992-03-14 자동열 증기 개질방법

Country Status (11)

Country Link
US (1) US5122299A (ko)
EP (1) EP0503482B1 (ko)
JP (1) JPH0585701A (ko)
KR (1) KR100201886B1 (ko)
AU (1) AU640599B2 (ko)
BR (1) BR9200858A (ko)
CA (1) CA2061977A1 (ko)
DE (1) DE69200267T2 (ko)
ES (1) ES2057936T3 (ko)
MX (1) MX9201101A (ko)
NO (1) NO311019B1 (ko)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9709857A (pt) * 1996-06-21 2002-05-21 Syntroleum Corp processo e sistema de produção de gás de sìntese
MY118075A (en) 1996-07-09 2004-08-30 Syntroleum Corp Process for converting gas to liquids
ATE194816T1 (de) * 1996-10-04 2000-08-15 Haldor Topsoe As Dampfreformierungsverfahren
KR100454641B1 (ko) * 1997-05-16 2004-12-17 앵스띠뛰 프랑세 뒤 뻬뜨롤 오염성폐기물을탈취및탈질소처리하기위한자열식촉매방법
AU9690298A (en) 1997-10-10 1999-05-03 Syntroleum Corporation System and method for converting light hydrocarbons to heavier hydrocarbons withseparation of water into oxygen and hydrogen
EP0936182A3 (en) * 1998-02-13 2000-02-23 Haldor Topsoe A/S Method of soot-free start-up of autothermal reformers
GB0025150D0 (en) † 2000-10-13 2000-11-29 Air Prod & Chem A process and apparatus for the production of synthesis gas
DK173742B1 (da) * 1998-09-01 2001-08-27 Topsoe Haldor As Fremgangsmåde og reaktorsystem til fremstilling af syntesegas
US6641625B1 (en) 1999-05-03 2003-11-04 Nuvera Fuel Cells, Inc. Integrated hydrocarbon reforming system and controls
ATE556987T1 (de) * 2000-03-22 2012-05-15 Ammonia Casale Sa Verfahren zur kohlenwasserstoffreformierung
FR2811976A1 (fr) * 2000-07-19 2002-01-25 Air Liquide Procede et dispositif de production d'un melange gazeux contenant de l'hydrogene et du co par oxydation etagee d'un hydrocarbure
US6544494B2 (en) * 2001-05-14 2003-04-08 General Motors Corporation Reformate preheat of ATR reactants
US20030162846A1 (en) * 2002-02-25 2003-08-28 Wang Shoou-L Process and apparatus for the production of synthesis gas
US6794417B2 (en) 2002-06-19 2004-09-21 Syntroleum Corporation System and method for treatment of water and disposal of contaminants produced by converting lighter hydrocarbons into heavier hydrocarbon
US7102048B2 (en) 2002-12-17 2006-09-05 Exxonmobil Chemical Patents Inc. Methanol feed for producing olefin streams
US7932296B2 (en) * 2003-03-16 2011-04-26 Kellogg Brown & Root Llc Catalytic partial oxidation reforming for syngas processing and products made therefrom
US7138001B2 (en) * 2003-03-16 2006-11-21 Kellogg Brown & Root Llc Partial oxidation reformer-reforming exchanger arrangement for hydrogen production
US8273139B2 (en) * 2003-03-16 2012-09-25 Kellogg Brown & Root Llc Catalytic partial oxidation reforming
US7220505B2 (en) * 2003-03-18 2007-05-22 Kellogg Brown & Root Llc Autothermal reformer-reforming exchanger arrangement for hydrogen production
US7892511B2 (en) * 2004-07-02 2011-02-22 Kellogg Brown & Root Llc Pseudoisothermal ammonia process
AU2005291226B2 (en) * 2004-10-04 2009-04-02 Shell Internationale Research Maatschappij B.V. Integrated process for hydrocarbon synthesis
DE102004049076A1 (de) * 2004-10-08 2006-04-13 Uhde Gmbh Verfahren zur Erzeugung von Synthesegas für eine Ammoniakanlage
AU2005321933B2 (en) * 2004-12-23 2011-09-08 King Fahd University Of Petroleum And Minerals Thermo-neutral reforming of petroleum-based liquid hydrocarbons
US20080016768A1 (en) 2006-07-18 2008-01-24 Togna Keith A Chemically-modified mixed fuels, methods of production and used thereof
US7700005B2 (en) 2006-12-26 2010-04-20 Saudi Arabian Oil Company Oil-based thermo-neutral reforming with a multi-component catalyst
EP2065337A1 (en) * 2007-11-27 2009-06-03 Ammonia Casale S.A. Process for producing ammonia synthesis gas
US8617270B2 (en) * 2008-12-03 2013-12-31 Kellogg Brown & Root Llc Systems and methods for improving ammonia synthesis efficiency
US9321655B2 (en) * 2009-08-20 2016-04-26 Kellogg Brown & Root Llc Systems and methods for producing syngas and products therefrom
US8287763B2 (en) 2010-10-28 2012-10-16 Air Products And Chemicals, Inc. Steam-hydrocarbon reforming with limited steam export
US8545775B2 (en) 2011-10-20 2013-10-01 Kellogg Brown & Root Llc Reforming exchanger system with intermediate shift conversion
US9101899B2 (en) 2011-10-20 2015-08-11 Kellogg Brown & Root Llc Reforming exchanger with integrated shift conversion
GB201219960D0 (en) 2012-11-06 2012-12-19 Johnson Matthey Plc Process
US9561968B2 (en) 2013-08-07 2017-02-07 Kellogg Brown & Root Llc Methods and systems for producing and processing syngas in a pressure swing adsorption unit and making ammonia therefrom
CA2939769C (en) 2014-02-28 2021-06-22 Haldor Topsoe A/S Process for the production of synthesis gas
US10384993B2 (en) 2015-05-08 2019-08-20 Sabic Global Technologies B.V. Method for producing hydrocarbons and alcohols
US10745624B2 (en) 2015-05-08 2020-08-18 Sabic Global Technologies B.V. Systems and methods related to syngas to olefin production
US20220127209A1 (en) * 2019-01-15 2022-04-28 Sabic Global Technologies B.V. Use of renewable energy in olefin synthesis
GB202117591D0 (en) 2021-12-06 2022-01-19 Johnson Matthey Plc Method for retrofitting a hydrogen production unit
CA3230466A1 (en) 2021-11-17 2023-05-25 Kendra BRIGGS Method for retrofitting a hydrogen production unit

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4337170A (en) * 1980-01-23 1982-06-29 Union Carbide Corporation Catalytic steam reforming of hydrocarbons
US4479925A (en) * 1982-09-13 1984-10-30 The M. W. Kellogg Company Preparation of ammonia synthesis gas
GB8308343D0 (en) * 1983-03-25 1983-05-05 Ici Plc Steam reforming
US4666680A (en) * 1984-01-30 1987-05-19 Fluor Corporation Autothermal production of synthesis gas
DE3663652D1 (en) * 1985-03-05 1989-07-06 Ici Plc Steam reforming hydrocarbons
US5011625A (en) * 1989-12-11 1991-04-30 The M. W. Kellogg Company Autothermal steam reforming process

Also Published As

Publication number Publication date
KR100201886B1 (ko) 1999-06-15
US5122299A (en) 1992-06-16
NO921001D0 (no) 1992-03-13
EP0503482A1 (en) 1992-09-16
JPH0585701A (ja) 1993-04-06
AU1147992A (en) 1992-09-17
EP0503482B1 (en) 1994-07-27
AU640599B2 (en) 1993-08-26
CA2061977A1 (en) 1992-09-15
DE69200267D1 (de) 1994-09-01
DE69200267T2 (de) 1994-11-03
NO311019B1 (no) 2001-10-01
NO921001L (no) 1992-09-15
MX9201101A (es) 1992-09-01
BR9200858A (pt) 1992-11-17
ES2057936T3 (es) 1994-10-16

Similar Documents

Publication Publication Date Title
KR920018196A (ko) 자동열 증기 개질방법
US4409196A (en) Synthesis gas for ammonia production
US4618451A (en) Synthesis gas
US5030661A (en) Hydrogen production
CA2163615A1 (en) Gasification process combined with steam methane reforming to produce syngas suitable for methanol production
US20100098601A1 (en) System for extracting hydrogen from a gas containing methane
EA006869B1 (ru) Получение углеводородов
CA2038995A1 (en) Autothermal steam reforming process
GB798741A (en) Process for the production of combustible gas enriched with methane
GB1448562A (en) Process for the production of methane containing gases
KR940002345A (ko) 플레이트-핀 열교환기를 이용한 개질 공정법
CA2337937A1 (en) Synthesis gas production by steam reforming
KR19980086722A (ko) 암모니아합성가스의 제조를 위한 방법 및 공정장치
CA1160020A (en) Process for synthetising ammonia from hydro carbons
GB2139644A (en) Synthesis gas
US3418082A (en) Process for the preparation of a hydrogen-containing gas mixture
KR880013816A (ko) 일산화탄소의 제조방법
JPS5938161B2 (ja) アンモニア製造用の合成ガスの製造方法
CA1050052A (en) Method of transporting heat energy
KR100313460B1 (ko) 암모니아 합성가스 및 동력을 복합 생성하기 위한 방법 및 장치
JPS6039050B2 (ja) メタノ−ルの製造方法
JPH04331705A (ja) アンモニア合成ガスの調製方法
JPH04130001A (ja) 製品フラッシュガスの物質利用の方法
SU798031A1 (ru) Способ получени аммиака и метанола
JPH03115117A (ja) 稀ガス装置の残ガスを物質利用する方法

Legal Events

Date Code Title Description
A201 Request for examination
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20030130

Year of fee payment: 5

LAPS Lapse due to unpaid annual fee