KR920004393A - 고리형 아세탈 화합물 - Google Patents

고리형 아세탈 화합물 Download PDF

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KR920004393A
KR920004393A KR1019900012652A KR900012652A KR920004393A KR 920004393 A KR920004393 A KR 920004393A KR 1019900012652 A KR1019900012652 A KR 1019900012652A KR 900012652 A KR900012652 A KR 900012652A KR 920004393 A KR920004393 A KR 920004393A
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group
methyl
glucopyranoside
enylidene
methoxy
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KR1019900012652A
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KR0164848B1 (ko
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지.에일러만 로버트
에이.크리스텐슨 필립
엠.유레코 존
마일드 프랭크
이.쿠차르스키 패터
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원본미기재
바스프 케이 앤드 에프 코포레이션
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    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00—Chewing gum
    • A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/20—Synthetic spices, flavouring agents or condiments
    • A23L27/205—Heterocyclic compounds
    • A23L27/2052—Heterocyclic compounds having oxygen or sulfur as the only hetero atoms
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/36—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring
    • A24B15/40—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring having only oxygen or sulfur as hetero atoms
    • A24B15/403—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring having only oxygen or sulfur as hetero atoms having only oxygen as hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes
    • C11B9/0069—Heterocyclic compounds
    • C11B9/0073—Heterocyclic compounds containing only O or S as heteroatoms
    • C11B9/008—Heterocyclic compounds containing only O or S as heteroatoms the hetero rings containing six atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Food Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Nutrition Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture Of Tobacco Products (AREA)
  • Saccharide Compounds (AREA)
  • Fats And Perfumes (AREA)
  • Wrappers (AREA)
  • Confectionery (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)

Abstract

내용 없음

Description

고리형 아세탈 화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 다음 일반식(I)의 화합물들 :
    상기식에서, R1은 H또는 C1-C6-알킬기이고 ; R은 Ar또는 Arl이며, Ar은 3-에톡시-4-히드록시페닐기 또는 5-메틸티오펜-2-일기이고, Ar은
    이고, 여기에서, A는 페닐기, 4-페톡시페닐기 또는 3-메톡시-4-히드록시 페닐기이고, 그래서 A가 페닐기일 경우, R2는 C1-C6-알킬기이고 ; A가 4-메톡시페닐기일 경우, R2는 H또는 C1-C6-알킬기이고 ; A가 3-메톡시-4-히드록시페닐기일 경우, R2는 H이다.
  2. 제1항에 있어서, 다음 그룹들로부터 선택됨을 특징으로 하는 화합물 : 메틸4,6-0-(4-히드록시-3-에톡시벤질리덴)글루코피라 노시드 ; 메틸 4,6-0-(3-메톡시-4-히드록시페닐)프로프-2-엔일리덴 글루코피라노시드;메틸 4,6-0-(5-메틸티오펜-2-메틸리덴)글루코피라노시드;메틸 4,6-0-[3-(4-메톡시페닐)프로프-2-엔일리덴]글루코피리노시드;메틸 4,6-0-(3-페닐-2-펜틸프로프-2-엔일리덴) 글루코피라노시드 및 메틸 4,6-0-(3-페닐-2-헥실프로프-2-엔일리덴)글루코피라 노시드.
  3. 관능검사적으로 유효량의 다음 일반식(Ib)의 화합물과의 결합으로 천연 담배또는 담배 대체물로 이루어진 흡연 조성물:
    상기식에서, R1b는 H 또는 C1-C6-알킬기이고 ; Rb는 Arb 또는 Arlb이며,Arb는 3-에톡시-4-히드록시페닐기, 3-메톡시-4-히드록시페닐기, 4-메톡시페닐기,3,4-메틸렌디옥시페닐기 또는 헤테로 아릴기이고, Arlb는
    이며, 여기에서 Ab는 페닐기, 4-메톡시페닐기, 3-메톡시-4-히드록시페닐기, 3,4-메틸렌디옥시페닐기 또는 헤테로아릴기 이고, R2b는 H또는 C1-C6-알킬기이다.
  4. 제3항에 있어서, 화합물이 하기의 것들로 이루어진 그룹으로부터 선택됨을 특징으로 하는 흡연 조성물 : 메틸 4,6-0-(4-히드록시-3-에톡시벤질리덴)글루코피라노시드 ; 메틸 4,6-0-(3-메톡시-4-히드록시페닐)프로프-2-엔일리덴글루코피라노시드 ; 메틸 4,6-0-(5-메틸티오펜-2-메틸리덴)글루코피라노시드; 메틸 4,6-0-[3-(4-메톡시페닐)프로프-2-엔일리덴]글루코피라노시드 ; 메틸4,6-0-(3-페닐-2-펜틸프로프-2-엔일리덴)글루코피라노시드;메틸 4,6-0-(3-페닐-2-헥실프로프-2-엔일리덴)글루코피라노시드;메틸 4,6-0-(3-메톡시-4-히드록시벤질리덴)글루코피라노시드;메틸 4,6-0-(4-메톡시벤질리덴)글루코피라노시드;메틸 4,6-0-(3-페닐프로프-2-엔일리덴)글루코피라노시드;메틸 4,6-0-(3-푸란일프로프-2-엔일리덴)글루코피라노시드;메틸 4,6-0-(3,4-메틸렌디옥시벤질리덴)글루코피라노시드 및 메틸 4,6-0-(3-(3,4-메틸렌디옥시페닐)프로프-2-엔일리덴)글루코피라노시드.
  5. 제4항에 있어서, 화합물의 농도가 담배 또는 담배 대체물의 약 5중량 ppm내지 약 50,000중량 ppm임을 특징으로 하는 흡연 조성물.
  6. 하기의 것들로 이루어진 그룹에서 선택된 약 5ppm 내지 약 50,000ppm의 화합물을 포함하는, 담배 또는 담배 대체물을 말기에 적합한 매체 : 메틸 4,6-0-(4-히드록시-3-에톡시벤질리덴)글루코피라노시드; 메틸 4,6-0-(3-메톡시-4-히드록시페닐)프로프-2-엔일리덴글루코피라노시드;메틸 4,6-0-(5-메틸티오펜메틸리덴)글루코피라노시드;메틸 4,6-0-[3-(4-메톡시페닐)프로프-2-엔일리덴]글루코피라노시드; 메틸 4,6-0-(3-페닐-2-펜틸프로프-2-엔일리덴)글루코피라노시드;메틸 4,6-0-(3-페닐-2-헥실프로프-2-엔일리덴)글로코피라노시드;메틸4,6-0-(3-메톡시-4-히드록시벤질리덴)글루코피라노시드; 메틸 4,6-0-(4-메톡시벤질리덴)글루코피라노시드;메틸 4,6-0-(3-페닐프로프-2-엔일리덴)글루코피라노시드;메틸 4,6-0-(3-푸란일프로필-2-엔일리덴)글루코피라노시드;메틸4,6-0-(3,4-메틸렌디옥시벤질리덴)글루코피라노시드 및 메틸 4,6-0-(3-(3,4-메틸렌디옥시페닐)프로프-2-엔일리덴)글루코피라노시드.
  7. 관능검사적으로 유효량의 다음 일반식(Ia)의 화합물과의 조합으로서 식품재료로 포함하는 식품 ;
    상기식에서, Rla는 H또는 C1-C6-알킬기이고 ;Ra는 Ara또는 Arla이며, Ara는3-에톡시-4-히드록시페닐기, 3-메톡시-4-히드록시페닐기, 4-메톡시페닐기 또는 헤테로아릴기이고, Arla는
    이며, 여기에서 Aa는 페닐기, 4-메톡시페닐기, 3-메톡시-4-히드록시페닐기 또는 헤테로아릴기이고, R2a는 H또는 C1-C6-알킬기이다.
  8. 제7항에 있어서, 화합물이 약 0.05중량% 내지 5.00중량 %의 양으로 존재함을 특징으로 하는 식품.
  9. 제7항에 있어서, 베이킹시에 식품재료에 풍미를 전달하기에 효과적인 양의 화합물과 조합하는 베이킹된 식품재료로 이루어지는 것을 특징으로 하는 식품.
  10. 저작시에 껌 베이스에 향을 전달하기에 효과적인 양으로 존재하는 다음 일반식(Ia)의 화합물과 조합하는 껌 베이스로 이루어진 츄잉껌 베이스 조성물 :
    상기식에서, Rla는 H또는 C1-C6-알킬기이고 ;Ra는 Ara 또는 Arla이며, Ara는3-에톡시-4-히드록시페닐기, 3-메톡시-4-히드록시페닐기, 4-메톡시페닐기 또는 헤테로아릴기 이고 Arla는
    이며, 여기에서 Aa는 페닐기, 4-메톡시페닐기, 3-메톡시-4-히드록시페닐기 또는 헤테로아릴기이고, R2a는 H또는 C1-C6-알킬기이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019900012652A 1989-08-18 1990-08-17 고리형 아세탈 화합물 KR0164848B1 (ko)

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Application Number Priority Date Filing Date Title
US395628 1989-08-18
US395,628 1989-08-18
US07/395,628 US5147463A (en) 1989-08-18 1989-08-18 Cyclic acetals

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KR920004393A true KR920004393A (ko) 1992-03-27
KR0164848B1 KR0164848B1 (ko) 1999-01-15

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US (1) US5147463A (ko)
EP (1) EP0413162B1 (ko)
JP (1) JP3080973B2 (ko)
KR (1) KR0164848B1 (ko)
CA (1) CA2012826C (ko)
DE (1) DE69030470T2 (ko)
SG (1) SG48363A1 (ko)

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US4538627A (en) 1984-10-25 1985-09-03 Philip Morris Incorporated Smoking compositions containing a β-hydroxy-γ-ketoester flavorant-release additive
US4701282A (en) 1984-10-25 1987-10-20 Philip Morris Incorporated β-hydroxy-γ-ketoester flavorant-release additives
EP0186502A3 (en) 1984-12-25 1986-12-10 Jano Tyroler Flavor capsule and method of preparing same
JPS62109281A (ja) * 1985-11-08 1987-05-20 Matsushita Electric Ind Co Ltd 光学式デイスク再生装置
US4690157A (en) 1986-03-21 1987-09-01 Philip Morris Incorporated Smoking compositions containing a flavorant-release additive
JPS63211391A (ja) * 1987-02-23 1988-09-02 日立電線株式会社 送電線用絶縁ロ−プ
US4857964A (en) 1987-08-14 1989-08-15 Eastman Kodak Company Apparatus for printing customized photographic prints

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JPH03218390A (ja) 1991-09-25
KR0164848B1 (ko) 1999-01-15
CA2012826C (en) 2000-05-30
JP3080973B2 (ja) 2000-08-28
CA2012826A1 (en) 1991-02-18
EP0413162A3 (en) 1991-07-03
DE69030470D1 (de) 1997-05-22
SG48363A1 (en) 1998-04-17
EP0413162B1 (en) 1997-04-16
US5147463A (en) 1992-09-15
DE69030470T2 (de) 1997-11-06
EP0413162A2 (en) 1991-02-20

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