KR920000805A - 에틸렌의 삼원공중합체, 그의 제조방법 및 광유 증류물용 첨가제로서의 그의 용도 - Google Patents
에틸렌의 삼원공중합체, 그의 제조방법 및 광유 증류물용 첨가제로서의 그의 용도 Download PDFInfo
- Publication number
- KR920000805A KR920000805A KR1019910009838A KR910009838A KR920000805A KR 920000805 A KR920000805 A KR 920000805A KR 1019910009838 A KR1019910009838 A KR 1019910009838A KR 910009838 A KR910009838 A KR 910009838A KR 920000805 A KR920000805 A KR 920000805A
- Authority
- KR
- South Korea
- Prior art keywords
- terpolymer
- mol
- mineral oil
- molecular weight
- mpa
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/197—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid
- C10L1/1973—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid mono-carboxylic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Emergency Medicine (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polymerisation Methods In General (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 에틸렌 단위이외에 5∼20몰%의 비닐 아세테이트 단위 및 0.2∼5몰%의 이소부틸 비닐 에테르 단위를 함유하고 평균 분자량()이 500∼5,000g,·mol-1임을 특징으로 하는 삼원공중합체.
- 단량체들의 혼합물을 개시 제의 존재하에 분자량 조절제를 첨가하여, 50∼700MPa, 바람직하게는 약 150∼300MPa의 압력 및 100∼350℃. 바람직하게는 120∼325℃의 온도에서 중합시킴을 특징으로 하는 제1항에 청구된 삼원공중합체의 제조방법.
- 제2항에 있어서, 분자량 조절제가 단량체 혼합물을 기준으로 0.05∼10중량%의 양으로 사용됨을 특징으로 하는 삼원공중합체의 제조방법.
- 제2항 또는 제3항에 있어서, 분자량 조절제가 프로피온알데히드 임을 특징으로 하는 삼원공중합체의 제조방법.
- 광유증류물, 특히 중간 증류물의 유동성을 개선하는데 사용되는 제1항에 청구된 삼원공중합체의 용도.
- 제5항에 있어서, 에틸렌 단위 이외에 7∼15몰%의 비닐 아세테이트 단위 및 0.5∼2몰%의 부틸 비닐 에테르 단위를 함유함을 특징으로 하는 삼원공중합체의 용도.
- 제5항 또는 제6항에 있어서, 삼원공중합체의 평균 분자량이 1,000∼3,000g/mol임을 특징으로 하는 삼원 공중합체의 용도.
- 제5항∼제7항중 어느 한 항에 있어서, 140℃에서 측정한 용유 점도가 25∼500mPa.s, 바람직하게는 50∼300mPa.s임을 특징으로 하는 삼원공중합체의 용도.
- 제5항∼제7항중 어느 한 항에 있어서, 증류물을 기준으로 하여 0.001∼2중량%, 바람직하게는 0.005∼0.5중량%의 양으로 광유 증류물에 가해짐을 특징으로 하는 삼원공중합체의 용도.
- 제1항에 청구된 삼원공중합체를 용해된 형태로서 증류물을 기준으로 하여 0.001∼2중량% 함유함을 특징으로 하는 광유 증류물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4020640.8 | 1990-06-29 | ||
DE4020640A DE4020640A1 (de) | 1990-06-29 | 1990-06-29 | Terpolymerisate des ethylens, ihre herstellung und ihre verwendung als additive fuer mineraloeldestillate |
Publications (2)
Publication Number | Publication Date |
---|---|
KR920000805A true KR920000805A (ko) | 1992-01-29 |
KR940006450B1 KR940006450B1 (ko) | 1994-07-20 |
Family
ID=6409276
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019910009838A KR940006450B1 (ko) | 1990-06-29 | 1991-06-14 | 에틸렌의 삼원공중합체, 그의 제조방법 및 광유 증류물용 첨가제로서의 그의 용도 |
Country Status (9)
Country | Link |
---|---|
US (1) | US5200484A (ko) |
EP (1) | EP0463518B1 (ko) |
JP (1) | JPH04226514A (ko) |
KR (1) | KR940006450B1 (ko) |
AT (1) | ATE116342T1 (ko) |
CA (1) | CA2045155A1 (ko) |
DE (2) | DE4020640A1 (ko) |
ES (1) | ES2069123T3 (ko) |
ZA (1) | ZA914805B (ko) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3499244B2 (ja) * | 1993-10-02 | 2004-02-23 | ビーエーエスエフ アクチェンゲゼルシャフト | エチレンを基礎とする共重合体及びその鉱油中間留分における流動性改善剤としての使用 |
DE19620119C1 (de) * | 1996-05-18 | 1997-10-23 | Hoechst Ag | Terpolymerisate des Ethylens, ihre Herstellung und ihre Verwendung als Additive für Mineralöldestillate |
DE19620118C1 (de) * | 1996-05-18 | 1997-10-23 | Hoechst Ag | Terpolymerisate des Ethylens, ihre Herstellung und ihre Verwendung als Additive für Mineralöldestillate |
EP0857776B2 (de) * | 1997-01-07 | 2007-05-02 | Clariant Produkte (Deutschland) GmbH | Verbesserung der Fliessfähigkeit von Mineralölen und Mineralöldestillaten unter Verwendung von Alkylphenol-Aldehydharzen |
US6846338B2 (en) | 1997-07-08 | 2005-01-25 | Clariant Gmbh | Fuel oils based on middle distillates and copolymers of ethylene and unsaturated carboxylic esters |
DE19729055C2 (de) * | 1997-07-08 | 2000-07-27 | Clariant Gmbh | Brennstofföle auf Basis von Mitteldestillaten und Copolymeren aus Ethylen und ungesättigten Carbonsäureestern |
DE19739271A1 (de) * | 1997-09-08 | 1999-03-11 | Clariant Gmbh | Additiv zur Verbesserung der Fließfähigkeit von Mineralölen und Mineralöldestillaten |
DE19754555A1 (de) * | 1997-12-09 | 1999-06-24 | Clariant Gmbh | Verfahren zur Herstellung von Ethylen-Mischpolymerisaten und deren Verwendung als Zusatz zu Mineralöl und Mineralöldestillaten |
DE19823565A1 (de) | 1998-05-27 | 1999-12-02 | Clariant Gmbh | Mischungen von Copolymeren mit verbesserter Schmierwirkung |
EP1294832B1 (de) | 2000-06-15 | 2004-09-08 | Clariant International Ltd. | Additive zur verbesserung von kaltfliesseigenschaften und lagerstabilität von rohölen |
DE10102019A1 (de) * | 2001-01-18 | 2002-07-25 | Clariant Gmbh | Pulverförmige Pigmentpräparationen zur Einfärbung von Folien |
FR2827608B1 (fr) * | 2001-07-17 | 2004-01-16 | Elf Antar France | Polymeres a base d'olefine et d'alkylate d'alkenyle et leur utilisation comme additif multifonctionnel dans les carburants et les combustiles |
DE10155748B4 (de) * | 2001-11-14 | 2009-04-23 | Clariant Produkte (Deutschland) Gmbh | Schwefelarme Mineralöldestillate mit verbesserten Kälteeigenschaften, umfassend einen Ester eines alkoxylierten Polyols und ein Copolymer aus Ethylen und ungesättigten Estern |
DE10155774B4 (de) | 2001-11-14 | 2020-07-02 | Clariant Produkte (Deutschland) Gmbh | Additive für schwefelarme Mineralöldestillate, umfassend einen Ester alkoxylierten Glycerins und einen polaren stickstoffhaltigen Paraffindispergator |
EP1380635B1 (de) | 2002-07-09 | 2013-01-23 | Clariant Produkte (Deutschland) GmbH | Kaltfliessverbesserer für Brennstofföle pflanzlichen oder tierischen Ursprungs |
ATE370214T1 (de) * | 2002-07-09 | 2007-09-15 | Clariant Produkte Deutschland | Oxidationsstabilisierte schmieradditive für hochentschwefelte brennstofföle |
CA2431748C (en) * | 2002-07-09 | 2010-11-09 | Clariant Gmbh | Oxidation-stabilized oily liquids based on vegetable or animal oils |
DE10349851B4 (de) * | 2003-10-25 | 2008-06-19 | Clariant Produkte (Deutschland) Gmbh | Kaltfließverbesserer für Brennstofföle pflanzlichen oder tierischen Ursprungs |
DE10349850C5 (de) * | 2003-10-25 | 2011-12-08 | Clariant Produkte (Deutschland) Gmbh | Kaltfließverbesserer für Brennstofföle pflanzlichen oder tierischen Ursprungs |
DE10357878C5 (de) * | 2003-12-11 | 2013-07-25 | Clariant Produkte (Deutschland) Gmbh | Brennstofföle aus Mitteldestillaten und Ölen pflanzlichen oder tierischen Ursprungs mit verbesserten Kälteeigenschaften |
DE10357880B4 (de) * | 2003-12-11 | 2008-05-29 | Clariant Produkte (Deutschland) Gmbh | Brennstofföle aus Mitteldestillaten und Ölen pflanzlichen oder tierischen Ursprungs mit verbesserten Kälteeigenschaften |
DE10357877B4 (de) * | 2003-12-11 | 2008-05-29 | Clariant Produkte (Deutschland) Gmbh | Brennstofföle aus Mitteldestillaten und Ölen pflanzlichen oder tierischen Ursprungs mit verbesserten Kälteeigenschaften |
DE102006022719B4 (de) * | 2006-05-16 | 2008-10-02 | Clariant International Limited | Kaltfließverbesserer für pflanzliche oder tierische Brennstofföle |
DE102006022718B4 (de) * | 2006-05-16 | 2008-10-02 | Clariant International Limited | Zusammensetzung von Brennstoffölen |
DE102006022720B4 (de) * | 2006-05-16 | 2008-10-02 | Clariant International Limited | Kaltfließverbesserer für pflanzliche oder tierische Brennstofföle |
DE102006022698B4 (de) * | 2006-05-16 | 2008-10-02 | Clariant International Limited | Zusammensetzung von Brennstoffölen |
US20110296743A1 (en) | 2009-01-13 | 2011-12-08 | Evonik Rohmax Additives Gmbh | Fuel compositions having improved cloud point and improved storage properties |
US20110192076A1 (en) | 2010-02-05 | 2011-08-11 | Evonik Rohmax Additives Gmbh | Composition having improved filterability |
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GB715913A (en) * | 1951-03-09 | 1954-09-22 | Rohm & Haas | Improvements in or relating to esters of vinyloxyalkoxy compounds and unsaturated carboxylic acids |
DE1495660B2 (de) * | 1957-01-02 | 1972-04-13 | Farbenfabriken Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von mischpolymerisaten aus aethylen und vinylestern |
NL130129C (ko) * | 1960-01-05 | |||
US3159608A (en) * | 1963-01-08 | 1964-12-01 | Exxon Research Engineering Co | Copolymerization of ethylene and vinyl acetate |
DE1267429B (de) * | 1964-07-18 | 1968-05-02 | Hoechst Ag | Verfahren zur Herstellung waessriger stabiler Dispersionen von Mischpolymerisaten aus Vinylestern und AEthylen |
DE1914756C3 (de) * | 1968-04-01 | 1985-05-15 | Exxon Research and Engineering Co., Linden, N.J. | Verwendung von Ethylen-Vinylacetat- Mischpolymerisaten für Erdöl-Destillate |
GB1217449A (en) * | 1969-04-10 | 1970-12-31 | Leuna Werke Veb | Process for initiating polymerization and co-polymerization of ethylene by means of radicals |
GB1233837A (ko) * | 1969-08-29 | 1971-06-03 | ||
US3640836A (en) * | 1970-10-19 | 1972-02-08 | Hoechst Ag | Vibration damped sandwich systems having interlayers of vinyl acetate-ethylene copolymers |
NL7305415A (ko) * | 1973-04-18 | 1974-10-22 | ||
DE2437490A1 (de) * | 1974-08-03 | 1976-02-12 | Bayer Ag | Verfahren zur herstellung von niedermolekularen aethylen/vinylacetat-copolymerisaten |
DE2456576C3 (de) * | 1974-11-29 | 1983-03-10 | Wacker-Chemie GmbH, 8000 München | Verfahren zur kontinuierlichen Herstellung von Äthylen-Vinylacetat-Copolymerdispersionen |
US4164489A (en) * | 1978-04-24 | 1979-08-14 | Air Products And Chemicals, Inc. | Continuous emulsion polymerization of vinyl acetate and ethylene |
JPS55129469A (en) * | 1979-03-29 | 1980-10-07 | Toyo Soda Mfg Co Ltd | Method of adhesion |
JPH0710900B2 (ja) * | 1982-06-18 | 1995-02-08 | エクソン リサーチ アンド エンヂニアリング コムパニー | 中級蒸留物燃料油用流動性改良剤 |
DE3247753A1 (de) * | 1982-12-23 | 1984-06-28 | Ruhrchemie Ag, 4200 Oberhausen | Verwendung von ethylencopolymerisaten als mineraloeladditive |
DE3443475A1 (de) * | 1984-11-29 | 1986-05-28 | Amoco Corp., Chicago, Ill. | Terpolymerisate des ethylens, verfahren zu ihrer herstellung und ihre verwendung |
CA1263663C (en) * | 1984-12-06 | 1989-12-05 | ETHYLENE, VINYL ACETATE AND ISOBUTYLENE TERPOLYMERS, ADDITIVES FOR DEPRESSING THE POUR POINT IN DISTILLED HYDROCARBONS | |
DE3640613A1 (de) * | 1986-11-27 | 1988-06-09 | Ruhrchemie Ag | Verfahren zur herstellung von ethylen-mischpolymerisaten und deren verwendung als zusatz zu mineraloel und mineraloelfraktionen |
GB8820071D0 (en) * | 1988-08-24 | 1988-09-28 | Exxon Chemical Patents Inc | Fuel compositions |
-
1990
- 1990-06-29 DE DE4020640A patent/DE4020640A1/de not_active Withdrawn
-
1991
- 1991-06-14 KR KR1019910009838A patent/KR940006450B1/ko active IP Right Grant
- 1991-06-15 AT AT91109829T patent/ATE116342T1/de not_active IP Right Cessation
- 1991-06-15 EP EP91109829A patent/EP0463518B1/de not_active Expired - Lifetime
- 1991-06-15 DE DE59104024T patent/DE59104024D1/de not_active Expired - Fee Related
- 1991-06-15 ES ES91109829T patent/ES2069123T3/es not_active Expired - Lifetime
- 1991-06-18 US US07/716,949 patent/US5200484A/en not_active Expired - Fee Related
- 1991-06-21 ZA ZA914805A patent/ZA914805B/xx unknown
- 1991-06-21 JP JP3150299A patent/JPH04226514A/ja active Pending
- 1991-06-21 CA CA002045155A patent/CA2045155A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
CA2045155A1 (en) | 1991-12-30 |
ZA914805B (en) | 1992-04-29 |
KR940006450B1 (ko) | 1994-07-20 |
EP0463518A1 (de) | 1992-01-02 |
ES2069123T3 (es) | 1995-05-01 |
JPH04226514A (ja) | 1992-08-17 |
US5200484A (en) | 1993-04-06 |
ATE116342T1 (de) | 1995-01-15 |
DE4020640A1 (de) | 1992-01-02 |
EP0463518B1 (de) | 1994-12-28 |
DE59104024D1 (de) | 1995-02-09 |
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