KR910016855A - 엘라스토머-개질 에폭시 수지 조성물의 제조방법 및 그로써 얻어질 수 있는 코우팅 조성물 - Google Patents

엘라스토머-개질 에폭시 수지 조성물의 제조방법 및 그로써 얻어질 수 있는 코우팅 조성물 Download PDF

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KR910016855A
KR910016855A KR1019910004708A KR910004708A KR910016855A KR 910016855 A KR910016855 A KR 910016855A KR 1019910004708 A KR1019910004708 A KR 1019910004708A KR 910004708 A KR910004708 A KR 910004708A KR 910016855 A KR910016855 A KR 910016855A
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epoxy resin
block
monomer units
conjugated diolefin
elastomer
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KR1019910004708A
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KR0177167B1 (ko
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존 막스 에드워드
제임스 웬킨즈 마이클
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오노 알버어스
셀 인터나쵸 나아레 레사아치 마아츠 샤피 비이부이
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/066—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with chain extension or advancing agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/934—Powdered coating composition

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Epoxy Resins (AREA)
  • Paints Or Removers (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

내용 없음

Description

엘라스토머-개질 에폭시 수지 조성물의 제조방법 및 그로써 얻어질수 있는 코우팅 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. (a)액체 에폭시 수지내에, 개질되지 않은 에폭시 수지를 기준으로 5-30중량%의 카르복시-관능화되고 수소화된 공역 디올레핀/모노알케닐아렌 블록 공중합체를 분산시켜서 엘라스토머-분산 에폭시 수지 조성물을 생성시키고, (b)엘라스토머-분산 에폭시 수지 조성물과, 최종 엘라스토머-개질 에폭시 수지 조성물 중량 기준으로 15-30%의 다가(多價)페놀화합물을, 40-200℃ 범위내 온도로 진보 촉매의 존재하에서, 500-1,500 범위인 에폭시 당량을 갖는 고체 엘라스토머-개질 에폭시 수지를 생산하는데 효과적인 시간 동안 접촉시키고, (c) 상기 고체 엘라스토머-개질 에폭시 수지를 회수하는 단계들로 구성되는, 엘라스토머-개질 에폭시 수지 조성물의 제조 방법.
  2. 제1항에 있어서, 에폭시 수지가 2가 페놀의 글리시딜 에테르인 방법.
  3. 제1항 또는 제2항에 있어서, 카르복시-관능화되고 수소화된 공역 디올레핀/모노알케닐아렌 블록 공중합체가 하기 일반식의 카르복실화된 베이스 블록 공중합체로 구성되는 방법 :
    AZ-(B-A)y-Bx
    상기식에서, A는 모노알케닐 방향족 탄화수소 단량체 단위들로 우세하게 구성되는 선형 또는 분지된 중합체 블록이고, B는 공역 디올레핀 단량체 단위들을 우세하게 함유하는 선형 또는 분지된 중합체 블록이며, x 및 z는 독립적으로 0 또는 1이고, y는 1-20의 범위인 총 수이다.
  4. 제1항 또는 제2항에 있어서, 카르복시-관능화되고 수소화된 공역 디올레핀/모노알케닐아렌 블록 공중합체가 하기 일반식의 카르복실화된 베이스 블록 공중합체로 구성되는 방법 :
    [Bx-(A-B)y-Az]n-C-Pn'
    상기식에서, A는 모노알케닐 방향족 탄화수소 단량체 단위들로 우세하게 구성되는 선형 또는 분지된 중합체 블록이고, B는 공역 디올레핀 단량체 단위들을 우세하게 함유하는 선형 또는 분지된 중합체 블록이며, x 및 z는 독립적으로 0 또는 1이고, y는 1-20의 범위인 총수이며, n 및 n'는 0-100인 수인데 n+n3이고, C는 다관능성 커플링제로 형성된 결합형 또는 방사형 중합체의 코어이며, P 각각은 하기 일반식을 갖는 같거나 다른 중합체 블록 또는 중합체 세그먼트이다.
    B'x'-(A'-B")y'-A"z'
    상기식에서, A"는 A와 같거나 다를 수 있는 모노알케닐 방향족 탄화수소 단량체 단위들을 우세하게 함유하는 중합체 블록이고, B'는 B와 같거나 다를 수 있는 공역 디올레핀 단량체 단위들을 우세하게 함유하는 중합체 블록이며, A'-B"는 모노알케닐 방향족 탄화수소 단량체 단위들 A' 및 공역 디올레핀 단량체 단위들 B"을 함유하는 중합체 블록인데, A'-B" 단량체 단위들은 랜덤하고, 테이퍼되거나 블록 일 수 있고, 각각의 A' 및 B"가 블록인 경우, A' 블록은 A"와 같거나 다를 수 있고 B"는 B'와 같거나 다를 수 있으며, x' 및 z'는 독립적으로 0 또는 1이고, y'는 0-20의 수이며, x'+y'+z'의 합은 1보다 크거나 같다.
  5. 제1항 내지 제4항중 어느 한 항에서 청구된 바와같은 방법으로 얻을 수 있는 조성물로 구성되는 코우팅 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910004708A 1990-03-30 1991-03-25 엘라스토머-개질 에폭시 수지 조성물의 제조방법 및 그로써 얻어질 수 있는 코우팅 조성물 KR0177167B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/503,343 US5115019A (en) 1990-03-30 1990-03-30 Carboxy-functional hydrogenated block copolymer dispersed in epoxy resin
US07/503,343 1990-03-30
US7/503343 1990-03-30

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Publication Number Publication Date
KR910016855A true KR910016855A (ko) 1991-11-05
KR0177167B1 KR0177167B1 (ko) 1999-05-15

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US (1) US5115019A (ko)
EP (1) EP0449359B1 (ko)
JP (1) JP3023515B2 (ko)
KR (1) KR0177167B1 (ko)
CA (1) CA2039273A1 (ko)
DE (1) DE69129476T2 (ko)
DK (1) DK0449359T3 (ko)
ES (1) ES2116274T3 (ko)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5248400A (en) * 1992-03-27 1993-09-28 Ppg Industries, Inc. Thermosetting powder coating compositions based on polyepoxides and elastomer-modified phenolics
USH1405H (en) * 1992-04-09 1995-01-03 Shell Oil Company Epoxy resin composition
DE4313762C1 (de) * 1993-04-27 1994-04-28 Ppg Ind Deutschland Gmbh Verfahren zur Beschichtung eines metallischen Trägermaterials, um dessen Steinschlagbeständigkeit zu verbessern
US5332783A (en) * 1993-07-12 1994-07-26 Shell Oil Company Compatible blends of epoxy resins and epoxidized polydienes
US5478885A (en) * 1994-04-15 1995-12-26 Shell Oil Company Composition of epoxy resin, epoxidized block polydiene and curing agent
US5420202A (en) * 1994-04-15 1995-05-30 Shell Oil Company Epoxidized low viscosity rubber toughening modifiers for cycloaliphatic epoxy resins
US5499409A (en) * 1994-07-18 1996-03-19 Shell Oil Company Epoxidized polydiene block polymer with epoxy resins
US5500481A (en) * 1995-05-17 1996-03-19 Shell Oil Company Compositions containing epoxidized monohydroxylated diene polymers, amino resins, and reactive reinforcement agents
US5461112A (en) * 1994-10-11 1995-10-24 Shell Oil Company Epoxidized monohydroxylated block polymer, epoxy resin, curing agent and epoxy diluent
US5459200A (en) * 1994-10-11 1995-10-17 Shell Oil Company Polyurethane coatings and adhesives containing monohydroxylated diene polymers and epoxidized derivatives thereof
US6525142B1 (en) 1994-10-11 2003-02-25 Kraton Polymers U.S. Llc Monohydroxylated diene polymers and epoxidized derivatives thereof
US5576388A (en) * 1994-10-11 1996-11-19 Shell Oil Company Telechelic polymers and heterotelechelic polydiene block polymers with dual cure systems
US5721316A (en) * 1995-07-12 1998-02-24 Shell Oil Company Process for incorporation of expoxidized polydienes into epoxy resins
BR9611434A (pt) * 1995-11-16 2000-10-24 Shell Int Research Composições de revestimento de polìmero polidieno com funcionalidade hidróxi reticulável e um processo para prepará-las
US5922467A (en) * 1996-10-15 1999-07-13 Shell Oil Company Method for coating crosslinkable epoxidized monohydroxylated diene polymer coating compositions on primed substrates
US6043316A (en) * 1996-11-13 2000-03-28 Shell Oil Company Crosslinkable hydroxy terminated polydiene polymer coating compositions for use on substrates and a process for preparing them
US6309502B1 (en) 1997-08-19 2001-10-30 3M Innovative Properties Company Conductive epoxy resin compositions, anisotropically conductive adhesive films and electrical connecting methods
EP1005509B1 (en) * 1997-08-19 2002-01-16 Minnesota Mining And Manufacturing Company Conductive epoxy resin compositions, anisotropically conductive adhesive films and electrical connecting methods
US6486256B1 (en) * 1998-10-13 2002-11-26 3M Innovative Properties Company Composition of epoxy resin, chain extender and polymeric toughener with separate base catalyst
US6924328B2 (en) 2001-09-06 2005-08-02 Valspar Sourcing, Inc. Stabilized coating compositions
ATE291069T1 (de) * 2001-09-06 2005-04-15 Valspar Sourcing Inc Stabilisierte beschichtungszusammensetzungen
US6916874B2 (en) 2001-09-06 2005-07-12 Valspar Sourcing, Inc. Coating compositions having epoxy functional stabilizer
CN101023144B (zh) * 2004-07-14 2010-09-22 澳大利亚澳瑞凯有限公司 粉末涂料组合物
EP2036950B1 (en) * 2006-06-30 2017-05-31 Toray Industries, Inc. Epoxy resin composition, prepreg, and fiber-reinforced composite material
DE102007052069A1 (de) * 2007-07-20 2009-01-22 Tesa Ag Verfahren zur Korrosionsschutzbehandlung von Metalloberflächen
JP5420212B2 (ja) * 2007-10-31 2014-02-19 アクゾ ノーベル コーティングス インターナショナル ビー ヴィ スチール用耐薄チップパウダートップコート
MX2010008104A (es) * 2008-01-25 2010-09-09 Akzo Nobel Coatings Int Bv Composiciones de revestimiento en polvo que tienen una base que sustancialmente no conntiene zinc.
US9321856B2 (en) 2013-12-19 2016-04-26 Exxonmobil Chemical Patents Inc. Process to produce functionalized polymer
WO2015094580A1 (en) * 2013-12-19 2015-06-25 Exxonmobil Chemical Patents Inc. Process to produce functionalized polymer
WO2020096032A1 (ja) * 2018-11-09 2020-05-14 味の素株式会社 粘着組成物

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3477990A (en) * 1967-12-07 1969-11-11 Shell Oil Co Process for reacting a phenol with an epoxy compound and resulting products
BE791204A (fr) * 1971-11-12 1973-05-10 Dow Chemical Co Procede de preparation de resines epoxy solides
US4119592A (en) * 1977-02-25 1978-10-10 The B. F. Goodrich Company Rubbery bladders from epoxy compositions
US4399241A (en) * 1980-03-21 1983-08-16 Scm Corporation Base for a graft polymer, novel graft polymer compositions, solvents and water-reducible coatings incorporating the novel graft polymers, and processes for making them
JPS57149369A (en) * 1981-03-11 1982-09-14 Asahi Chem Ind Co Ltd Novel adhesive
JPS5817160A (ja) * 1981-07-24 1983-02-01 Asahi Chem Ind Co Ltd 熱硬化性樹脂組成物
JPS62501299A (ja) * 1985-06-26 1987-05-21 ザ　ダウ　ケミカル　カンパニ− ゴム改質エポキシ化合物
US4734468A (en) * 1986-02-28 1988-03-29 Shell Oil Company Epoxy resin composition
US4804581A (en) * 1987-05-14 1989-02-14 Ppg Industries, Inc. Chip resistant coatings
JPH07108934B2 (ja) * 1987-06-09 1995-11-22 財団法人接着剤研究所 水添ブロツク共重合体分散液状エポキシ樹脂組成物
US5264503A (en) * 1990-01-29 1993-11-23 Shell Oil Company Phenol-terminated epoxy resin with functional elastomer

Also Published As

Publication number Publication date
KR0177167B1 (ko) 1999-05-15
DE69129476D1 (de) 1998-07-02
ES2116274T3 (es) 1998-07-16
EP0449359A3 (en) 1992-07-08
EP0449359B1 (en) 1998-05-27
JPH04224818A (ja) 1992-08-14
DE69129476T2 (de) 1998-11-05
US5115019A (en) 1992-05-19
EP0449359A2 (en) 1991-10-02
JP3023515B2 (ja) 2000-03-21
DK0449359T3 (da) 1998-10-12
CA2039273A1 (en) 1991-10-01

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