KR910016465A - 고무에 대한 보강재의 접착을 위한 중합체 표면의 처리방법 - Google Patents
고무에 대한 보강재의 접착을 위한 중합체 표면의 처리방법 Download PDFInfo
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- KR910016465A KR910016465A KR1019910005010A KR910005010A KR910016465A KR 910016465 A KR910016465 A KR 910016465A KR 1019910005010 A KR1019910005010 A KR 1019910005010A KR 910005010 A KR910005010 A KR 910005010A KR 910016465 A KR910016465 A KR 910016465A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/123—Treatment by wave energy or particle radiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
- B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/14—Surface shaping of articles, e.g. embossing; Apparatus therefor by plasma treatment
- B29C59/142—Surface shaping of articles, e.g. embossing; Apparatus therefor by plasma treatment of profiled articles, e.g. hollow or tubular articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
- B60C9/0042—Reinforcements made of synthetic materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D30/00—Producing pneumatic or solid tyres or parts thereof
- B29D30/0005—Pretreatment of tyres or parts thereof, e.g. preheating, irradiation, precuring
- B29D2030/0011—Surface activation of tyres or parts thereof, e.g. by plasma treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10S156/91—Bonding tire cord and elastomer: improved adhesive system
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2938—Coating on discrete and individual rods, strands or filaments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
- Y10T428/2969—Polyamide, polyimide or polyester
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Plasma & Fusion (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Tyre Moulding (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Tires In General (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 장치를 나타내고 있다. 제1a도는 본 발명의 장치의 스트링(string)의 분포를 나타내는 측면이다. 제1b도는 제1도의 장치 영역 B를 90℃ 각도로 회전시켜 확대한 것이다. 제2도는 본 발명의 보강 코드(cord)를 사용하여 만든 타이어를 나타내고 있다.
Claims (17)
- (a) 약0.001 내지 1 토르의 압력에서 O2와 CF4의 혼합물을 함유한 플라즈마 챔버(plasma chamber)내에 표면을 갖는 중합체를 배치하는 단계; 및 (b) 상기 중합체 표면을 약 50Hz 내지 2.45GHz의 전기 에너지에 의해 발생된 플라즈마에 노출시키는 단계를 특징으로 하는, 화학적 결합을 위한 중합체 표면의 제조방법.
- 제1항에 있어서, 10% 내지 90%의 O2와 10 내지 0%의 CF4를 포함한 기체 혼합물로 상기 플라즈마 챔버를 충진시키는 단계를 특징으로 하는 방법.
- (a) 중합성 기체를 함유한 플라즈마 챔버내에 보강 중합체를 배치하는 단계; 및 (b) 상기 중합체 표면을 약 50Hz 내지 2.45GHz의 전기 에너지에 의해 발생된 플라즈마에 노출시키는 단계를 특징으로 하는 고무에 직접 결합시키기 위한 보강 중합체 표면의 제조방법.
- (a) 혼합성 기체, 비-혼합성 기체, 불활성 기체, 또는 그의 혼합물을 함유한 제1플라즈마에 챔버내에 보강 중합체를 배치하는 단계; (b) 상기 보강 중합체 표면을 약50Hz내지 2.45GHz의 전기 에너지에 의해 발생된 플라즈마에 노출시키는 단계; (c) 상기 보강 중합체를 중합성 기체를 함유한 플라즈마 챔버내에 배치하는 단계; 및 (d) 상기 보강 중합체 표면을 약 50Hz 내지 2.45GHz의 전기 에너지에 의해 발생된 플라즈마에 노출시키는 단계를 특징으로 하는 고무에 직접 결합시키기 위한 보강 중합체 표면의 제조방법.
- 제4항에 있어서, 상기 플라즈마 챔버에 10 내지 90%의 O2및 10내지 90%의 CF4를 포함한 기체 혼합물을 충전시키는 단계를 특징으로 하는 방법.
- 제4항에 있어서, NH3, O2, N2, CF4, SF6, Ar, He, N2O, H2o 및 그의 혼합물로 구성된 군으로 부터 상기 혼화성 기체, 비-혼화성 기체 또는 불활성 기체를 선택하는 것을 특징으로 하는 방법.
- 제4항에 있어서, 상기 중합체 기체로서 CS2를 선택하는 것을 특징으로 하는 방법.
- 보강 부재가 보강 중합체 표면상에서 고무 결합 중합체를 용착시키는 중합성 기체의 존재하에 플라즈마로 표면 처리된 보강 중합체로 제조되는 것을 특징으로 하는, 한쌍의 보강 비이드(bead), 상기 한쌍의 비이드 주위를 감싸는 카이커스 플라이(carcass ply), 보강 부재, 공기 타이어의 크라운 영역내에 있는 트래드(tread)영역, 및 상기 트래드 및 상기 한쌍의 비이드 사이에 배열되어 있는 측벽을 특징으로 하는 공기 타이어.
- 보강 부재가 보강 중합체 표면으로 부터 수소 결합증 및 약하게 결합된 종을 제거하여 상기 종합체내의 반응 부위가 노출되도록 혼화성, 비-혼화성 또는 불활성 기체의 존재하에 플라즈마로 표면처리시킨 후, 상기 보강 중합체 표면상에 고무결합 중합체를 용착시키는 중합성 기체에 노출시킨 보강 중합체로 제조된 것을 특징으로 하는, 적어도 한쌍의 비이드, 상기 한쌍의 비이드 주위를 감싸는 적어도 하나의 카아커스 플라이, 공기 타이어의 크라운 영역내에 있는 임의의 부가적인 보강 구조물, 상기 카아커스 플라이 및 상기 임의의 부가적인 및 임의로 상기 타이어의 기타 영역에 배열되어 있는 보강 부재, 상기 타이어의 크라운 영역내에 있는 트레드, 상기 트레드 및 상기 한쌍의 비이드 사이에 배열되어 있는 측벽을 특징으로 하는 공기 타이어.
- 제8항에 있어서, 상기 중합체 기체가 CS2인 공기 타이어.
- 제8항에 있어서, 상기 보강 부재가 중합성 기체의 존재하에 상기 플라즈마에 노출시키기 전에 플라즈마로 표면 처리되는 공기 타이어.
- 제11항에 있어서, 상기 보강 부재가 CS2중합성 기체로 표면 처리되는 공기 타이어.
- 제12항에 있어서, 상기 보강 부재가 중합성 기체의 존재하에 상기 플라즈마에 노출시키기 전에, 혼화성 기체, 비-혼화성 기체 또는 불활성 기체의 존재하에 플라즈마로 표면 처리되는 공기 타이어.
- 제13항에 있어서, 상기 혼화성 기체, 비-혼화성 기체 또는 불활성 기체가 NH3, O2, N2, CF4, SF6, Ar, He, F 및 그의 혼합물로 구성된 군으로 부터 선택된되는 공기 타이어.
- 제9항에 있어서, 상기 보강 부재가 필라멘트, 토우(tow), 코드(cord) 또는 단섬유의 형태로 되어 있는 공기 타이어.
- 엘라스토머 또는 플라스틱과 반응하는 부류의 플라즈마 용착물을 포함하는 표면을 갖는 열가소성 재료를 포함하는 엘라스토머 또는 플라스틱용 보강 요소.
- 제16항에 있어서, 상기 열가소성 재료가 폴리에스테르, 폴라아미드 및 폴리방향족 아미드로 부터 선택되는 보강요소.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/501,564 US5053246A (en) | 1990-03-30 | 1990-03-30 | Process for the surface treatment of polymers for reinforcement-to-rubber adhesion |
US501,564 | 1990-03-30 |
Publications (2)
Publication Number | Publication Date |
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KR910016465A true KR910016465A (ko) | 1991-11-05 |
KR0171588B1 KR0171588B1 (ko) | 1999-03-30 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR1019910005010A KR0171588B1 (ko) | 1990-03-30 | 1991-03-29 | 고무에 대한 보강재의 접착을 위한 중합체 표면의 처리방법 |
Country Status (12)
Country | Link |
---|---|
US (2) | US5053246A (ko) |
EP (1) | EP0451425B1 (ko) |
JP (1) | JPH04249545A (ko) |
KR (1) | KR0171588B1 (ko) |
AT (1) | ATE138954T1 (ko) |
AU (1) | AU626511B2 (ko) |
BR (1) | BR9101131A (ko) |
CA (1) | CA2021907A1 (ko) |
DE (1) | DE69027303T2 (ko) |
ES (1) | ES2090115T3 (ko) |
MX (1) | MX166219B (ko) |
TR (2) | TR26059A (ko) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100433669B1 (ko) * | 2001-07-05 | 2004-05-31 | 사단법인 고등기술연구원 연구조합 | 상압 플라즈마를 이용한 분말의 재활용 장치 |
KR20070095703A (ko) * | 2006-03-22 | 2007-10-01 | 금호타이어 주식회사 | 내오존크랙성과 외관이 향상된 타이어 사이드월을 구비한타이어 |
Families Citing this family (56)
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CA2088814A1 (en) * | 1992-10-05 | 1994-04-06 | Dane Kenton Parker | Process for improving the interfacial bonding between fibers and rubber |
US5959634A (en) * | 1993-12-09 | 1999-09-28 | Canon Kabushiki Kaisha | Character generating system employing thickening or narrowing of characters |
DE4423471A1 (de) * | 1994-07-05 | 1996-01-11 | Buck Chem Tech Werke | Vorrichtung zur Plasmabehandlung von feinkörnigen Gütern |
WO1996023834A1 (en) * | 1995-02-01 | 1996-08-08 | Schneider (Usa) Inc. | Process for hydrophilicization of hydrophobic polymers |
AUPN820396A0 (en) * | 1996-02-21 | 1996-03-14 | Commonwealth Scientific And Industrial Research Organisation | Method for reducing crazing in a plastics material |
AU712565B2 (en) * | 1996-02-21 | 1999-11-11 | Commonwealth Scientific And Industrial Research Organisation | Method for reducing crazing in a plastics material |
US5910341A (en) * | 1996-10-31 | 1999-06-08 | International Business Machines Corporation | Method of controlling the spread of an adhesive on a circuitized organic substrate |
DE19715296C2 (de) * | 1997-04-11 | 1999-05-27 | Continental Ag | Verfahren zur Herstellung eines Rohlings für Fahrzeugreifen |
US6238787B1 (en) * | 1997-10-01 | 2001-05-29 | Park-Ohio Industries | Method of attaching a strip to a rubber molded part |
FR2770425B1 (fr) * | 1997-11-05 | 1999-12-17 | Air Liquide | Procede et dispositif pour le traitement de surface d'un substrat par decharge electrique entre deux electrodes dans un melange gazeux |
DE19847774C2 (de) * | 1998-10-16 | 2002-10-17 | Peter Foernsel | Vorrichtung zur Plasmabehandlung von stab- oder fadenförmigem Material |
US6096156A (en) * | 1999-03-11 | 2000-08-01 | Milliken & Company | Vinyl compound plasma pre-treatment for promoting the adhesion between textiles and rubber compounds |
US6733847B2 (en) * | 2000-02-08 | 2004-05-11 | Ciba Specialty Chemicals Corporation | Process for the production of strongly adherent surface-coatings by plasma-activated grafting |
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-
1990
- 1990-03-30 US US07/501,564 patent/US5053246A/en not_active Expired - Lifetime
- 1990-07-25 CA CA002021907A patent/CA2021907A1/en not_active Abandoned
- 1990-12-18 EP EP90630243A patent/EP0451425B1/en not_active Expired - Lifetime
- 1990-12-18 ES ES90630243T patent/ES2090115T3/es not_active Expired - Lifetime
- 1990-12-18 DE DE69027303T patent/DE69027303T2/de not_active Expired - Fee Related
- 1990-12-18 AT AT90630243T patent/ATE138954T1/de not_active IP Right Cessation
-
1991
- 1991-03-18 TR TR92/0448A patent/TR26059A/xx unknown
- 1991-03-18 TR TR91/0295A patent/TR26292A/xx unknown
- 1991-03-19 MX MX024970A patent/MX166219B/es unknown
- 1991-03-22 BR BR919101131A patent/BR9101131A/pt not_active IP Right Cessation
- 1991-03-28 AU AU73964/91A patent/AU626511B2/en not_active Ceased
- 1991-03-29 JP JP3089255A patent/JPH04249545A/ja active Pending
- 1991-03-29 KR KR1019910005010A patent/KR0171588B1/ko not_active IP Right Cessation
- 1991-08-13 US US07/726,436 patent/US5283119A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100433669B1 (ko) * | 2001-07-05 | 2004-05-31 | 사단법인 고등기술연구원 연구조합 | 상압 플라즈마를 이용한 분말의 재활용 장치 |
KR20070095703A (ko) * | 2006-03-22 | 2007-10-01 | 금호타이어 주식회사 | 내오존크랙성과 외관이 향상된 타이어 사이드월을 구비한타이어 |
Also Published As
Publication number | Publication date |
---|---|
AU626511B2 (en) | 1992-07-30 |
EP0451425B1 (en) | 1996-06-05 |
TR26059A (tr) | 1994-12-15 |
KR0171588B1 (ko) | 1999-03-30 |
BR9101131A (pt) | 1991-11-05 |
US5053246A (en) | 1991-10-01 |
MX166219B (es) | 1992-12-23 |
AU7396491A (en) | 1991-10-03 |
EP0451425A3 (en) | 1992-07-15 |
DE69027303D1 (de) | 1996-07-11 |
ATE138954T1 (de) | 1996-06-15 |
EP0451425A2 (en) | 1991-10-16 |
JPH04249545A (ja) | 1992-09-04 |
US5283119A (en) | 1994-02-01 |
ES2090115T3 (es) | 1996-10-16 |
TR26292A (tr) | 1995-03-15 |
CA2021907A1 (en) | 1991-10-01 |
DE69027303T2 (de) | 1997-01-23 |
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