KR910011929A - 신규의 중합체 및 그것을 포함하는 폴리프로필렌 수지조성물 - Google Patents

신규의 중합체 및 그것을 포함하는 폴리프로필렌 수지조성물 Download PDF

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KR910011929A
KR910011929A KR1019900022130A KR900022130A KR910011929A KR 910011929 A KR910011929 A KR 910011929A KR 1019900022130 A KR1019900022130 A KR 1019900022130A KR 900022130 A KR900022130 A KR 900022130A KR 910011929 A KR910011929 A KR 910011929A
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South Korea
Prior art keywords
carbon atoms
hydrogen
formula
polypropylene resin
alkenylsilane
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KR1019900022130A
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KR940000791B1 (ko
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타다시 아사누마
가오루 가와니시
히로시 마츠자와
유카리 니시모리
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사와무라 하루오
미쓰이도오아쓰 가가쿠 가부시키가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F30/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F30/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F30/06—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing boron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C08F230/085—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/10—Peculiar tacticity
    • C08L2207/12—Syndiotactic polypropylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
    • C08L43/04—Homopolymers or copolymers of monomers containing silicon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

내용 없음

Description

신규의 중합체 및 그것을 포함하는 폴리프로필렌 수지조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본발명의 실시예 1의 신디오탁틱구조의 트리메틸 알릴실란의 폴리머의 적외흡수 스펙트럼이다.

Claims (4)

  1. 식(Ⅰ)의 반복단위
    (식중,n는 0-10의 정수, X는 수소, 할로겐원자 또는 탄소수 1-20의 탄화수소 잔기이며, 3개의 X는 동일하거나 달라져 있어도 좋다)와, 식(Ⅰ)의 반복 단위보다 적은 량의 식(Ⅱ)의 반복단위
    (식중, R은 수소 또는 탄소수 1-23의 직쇄 또는 분기알킬기 이다)와 에서 만들어지며, 135℃의 테트라린 용액으로 측정한 극한점도가 0.01이상인 실질적으로 신디오탁틱구조를 가지는 일케닐실란 함유 폴리머.
  2. 비대칭한 서로 연결한 배위자를 가진 천이금속 화합물에서 만들어지는 촉매의 조재하, 식(Ⅵ)
    H2C=CH-(CH2)n-SiX3(Ⅵ)
    (식중 n는 0-10의 정수, X는 수소, 할로겐원자 또는 탄소수 1-20의 탄화수소잔기이고, 3개의 X는 동일하거나 달라도 좋다)의 알케닐 실란과 소망에 따라 그것보다 적은 량의 탄소수 2-25의 분기하여도 좋은α-올레핀과를 부가중합하는 것을 특징으로 하는 청구항 1에 기재한 알케닐실란 함유 폴리머의 제조방법.
  3. 촉매를 2회 이상으로 분할하여 장입하는 청구항 2에 기재한 방법.
  4. 청구항 1에 기재한 알케닐실란 함유 폴리머와 결정성 폴리프로필렌으로 이루어진 폴리프로필렌수지 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900022130A 1989-12-28 1990-12-28 신규의 중합체 및 그것을 포함하는 폴리프로필렌 수지조성물 KR940000791B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP1-338203 1989-12-28
JP33820389 1989-12-28
JP1242090 1990-01-24
JP2-012420 1990-01-24

Publications (2)

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KR910011929A true KR910011929A (ko) 1991-08-07
KR940000791B1 KR940000791B1 (ko) 1994-01-31

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Country Status (8)

Country Link
US (1) US5225507A (ko)
EP (1) EP0438710B1 (ko)
JP (1) JP2974404B2 (ko)
KR (1) KR940000791B1 (ko)
CN (1) CN1035620C (ko)
CA (1) CA2033286C (ko)
DE (1) DE69019719T2 (ko)
ES (1) ES2074518T3 (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3024685B2 (ja) * 1989-11-28 2000-03-21 三井化学株式会社 α―オレフィン―アルケニルシラン共重合体およびその製造方法
US6211109B1 (en) 1995-07-18 2001-04-03 Fina Technology, Inc. Process for treating silica with alumoxane
CA2181413A1 (en) 1995-07-18 1998-01-18 Edwar S. Shamshoum Process for the syndiotactic propagation of olefins
US6624254B1 (en) 1999-01-21 2003-09-23 The Dow Chemical Company Silane functionalized olefin interpolymer derivatives
CA2376908A1 (en) * 1999-07-29 2001-02-08 Francis J. Timmers Improved silane functionalized olefin interpolymers and derivatives thereof
CN114716599B (zh) * 2021-01-05 2024-02-13 中国石油化工股份有限公司 一种烯烃共聚物及其制备方法与应用
WO2023108584A1 (en) * 2021-12-17 2023-06-22 Dow Global Technologies Llc Olefin/silane interpolymer compositions with reduced residual aldehyde and/or ketone content

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BE574128A (ko) * 1957-12-23
BE591537A (ko) * 1959-06-06
US3240768A (en) * 1961-06-09 1966-03-15 Exxon Research Engineering Co Copolymers of alpha olefin and reactive omega alkenyl silanes
GB1143570A (ko) * 1966-11-30
US5045597A (en) * 1987-11-17 1991-09-03 Mitsui Toatsu Chemicals, Inc. α-olefin block copolymers and processes for preparing the same
CA1312980C (en) * 1987-11-17 1993-01-19 Mitsui Chemicals, Incorporated –-olefin block copolymer
CA1312166C (en) * 1987-12-16 1992-12-29 Mitsui Chemicals, Incorporated Polyolefin resin composition
KR920005671B1 (ko) * 1987-12-16 1992-07-13 미쯔이도오아쯔가가꾸 가부시끼가이샤 함규소 폴리머의 제조방법
DE68925488T2 (de) * 1988-03-01 1996-08-01 Mitsui Toatsu Chemicals Blockcopolymere aus Propylen und Verfahren zu ihrer Herstellung
JP2667676B2 (ja) * 1988-07-11 1997-10-27 三井東圧化学株式会社 プロピレンの共重合体の製造方法
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
JP2998964B2 (ja) * 1988-09-16 2000-01-17 三井化学株式会社 ポリオレフィン樹脂組成物およびその製造方法およびその用途
EP0363990A3 (en) * 1988-10-14 1991-09-11 Aristech Chemical Corporation Incorporation of functional groups in polymers

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CA2033286A1 (en) 1991-06-29
EP0438710B1 (en) 1995-05-24
JPH03255112A (ja) 1991-11-14
ES2074518T3 (es) 1995-09-16
CA2033286C (en) 1996-10-08
DE69019719D1 (de) 1995-06-29
US5225507A (en) 1993-07-06
JP2974404B2 (ja) 1999-11-10
DE69019719T2 (de) 1995-12-21
KR940000791B1 (ko) 1994-01-31
EP0438710A3 (en) 1992-01-22
EP0438710A2 (en) 1991-07-31
CN1035620C (zh) 1997-08-13
CN1053071A (zh) 1991-07-17

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