KR910004769A - 접착제 수지조성물, 이 조성물을 접착층으로 하는 적층제 및 그의 제조방법 - Google Patents

접착제 수지조성물, 이 조성물을 접착층으로 하는 적층제 및 그의 제조방법 Download PDF

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Publication number
KR910004769A
KR910004769A KR1019900012079A KR900012079A KR910004769A KR 910004769 A KR910004769 A KR 910004769A KR 1019900012079 A KR1019900012079 A KR 1019900012079A KR 900012079 A KR900012079 A KR 900012079A KR 910004769 A KR910004769 A KR 910004769A
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South Korea
Prior art keywords
weight
parts
resin composition
vinyl acetate
ethylene
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KR1019900012079A
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English (en)
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KR930011760B1 (ko
Inventor
미끼오 나까가와
마사하루 미또
Original Assignee
다께바야시 쇼오고
미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤
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Priority claimed from JP1204508A external-priority patent/JP2820242B2/ja
Priority claimed from JP1242775A external-priority patent/JP2760595B2/ja
Application filed by 다께바야시 쇼오고, 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 filed Critical 다께바야시 쇼오고
Publication of KR910004769A publication Critical patent/KR910004769A/ko
Priority to KR1019930014168A priority Critical patent/KR940004763B1/ko
Application granted granted Critical
Publication of KR930011760B1 publication Critical patent/KR930011760B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04—Homopolymers or copolymers of vinyl acetate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

내용 없음.

Description

접착제 수지조성물, 이 조성물을 접착층으로 하는 적층제 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 에틸렌/초산비닐 공중합체 96∼45중량부(a), 스티렌 중합체수지 30~1 중량부(b), 불포화 카르복시산을 또는 그의 유도체로 그래프트 변성된 폴리에틸렌 15∼1중량부(c), 모노비닐 방향족 탄화수소/올레핀 블록 공중합체 엘라스토머 20~1중량부(d). 및 상기 성분(a),(b).(c),(d)와의 합계량이 100중량부가 되는 양의 에틸렌/α-올레핀 공중합체(e)로 구성된 접착 수지 조성물.
  2. 금속과 열가소성 수지간에 제1항의 접착 수지 조성물을 개재시켜 된 적층제.
  3. 열질중합체 100중량부, 불포화 카르복시산 또는 그의 유도체의 그래프트량이 0.05∼15중량%인 부분 또는 완전 그래프트 변성된 폴리에틸렌 1~30중량부로 구성 돼 있고, 상기 연질 중합체는 스티렌 앨라스 토머인 접착수지 조성물.
  4. 연질 중합체 100중량부, 불포화 카르복시산 또는 그의 유도체의 그래프트량이 0.05∼15중량%인 부분 또는 완전 그래프트변성 폴리에틸렌 1∼30중량부로 구성돼 있고, 상기 연질 중합체가, 스티렌 앨라스토머 (a) 20~100중량%와 에틴렌 함량이 45~75몰%인 에틴렌 α-올레핀 공중합체(b) 80-0중량%로 구성된 접착수지 조성물.
  5. 연질중합체 100중량부와, 불포화 카르복시산 또는 그의 유도체의 그래프트량이 0.05~15중량%이 부분 또는 완전 그래프트 변성 폴리에틸렌 1~30중량부로 구성 돼 있고, 상기 연질중합체는 스티렌 앨라스토머(a) 2~100중량%의 초산 비닐 함량이 5~40 중량%인 에틸렌/초산 비닐 공중합(C) 80~0중량%로 구성된 접착수지 조성물.
  6. 연질중합체 100중량부와, 불포화 카르복시산 또는 그의 유도체의 그래프트량이 0.05~15중량%인 부분 또는 완전 그래프트 변성 폴리에틸렌 1~30중량부로 구성돼 있고, 상기 연질중합체는 스티렌 앨라스토머(a) 20~100중량%, 에틸렌 함량이 45~95몰%인 에틸렌/α-올레핀 공중합체(b) 0~80 중량% 및, 초산 비닐함량이 5~40중량%인 에틸렌 초산 비닐 공중합체(C) 0~80중량%로 구성된 접착수지 조성물.
  7. 폴리알킬렌 테레프탈레이트 수지층(1), 제3항~제6항중 임의 1항의 수지조성물로 된 접착층(Ⅱ) 및 비누화 올레핀/초산비닐 공중합체층(Ⅲ)로 구성된 적층체.
  8. 폴리카보네이트 수지층(Ⅰ), 제3항~제6항중 임의의 1항의 수지 조성물로 된 접착층(Ⅱ) 및 비누화 올레핀/초산비틸 공중합체 층으로 구성된 적층체.
  9. 접착수지 조성물의 필름 또는 쉬트를 형성하고, 이 필름 또는 쉬트를 금속과 열가소성 필름 또는 쉬트 사이에 개재시킨후 용융 접착시키는 것이 특징인 제2항의 적층체의 제조방법.
  10. 폴리알킬렌 테레프탈레이트 수지, 또는 폴리카보네이트수지(Ⅰ), 접착 수지조성물(Ⅱ) 및, 올레핀/초산비닐 공중합체의 비누화물을 용융시킨후, 다층 구조의 다이에 공급하여, 상기 접착수지 조성물이 폴리 에스테르수지와 가스밀페 수지사이에 개재되도록 상기 용융물을 공압출하는 것이 특징인 제7항 또는 제8항의 적층제의 제조방법.
  11. 폴리알킬렌 테레프탈레이트 수지 또는 폴리카보네이트 수지층(Ⅰ)과, 올레핀/초산비닐 공중합체의 비누화물인 폴리에스테르 수지층(Ⅲ)을 형성한후, 이 두층 사이에 접착수지 조성물(Ⅱ)을 용융 압출하는 것이 특징인 제7항 또는 제8항의 적층체의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900012079A 1989-08-07 1990-08-07 접착제 수지조성물, 이 조성물을 접착층으로 하는 적층체 및 그의 제조방법 KR930011760B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019930014168A KR940004763B1 (ko) 1989-08-07 1993-07-26 접착제 수지 조성물, 이 조성물을 접착층으로 하는 적층체

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP204508 1989-08-07
JP1204508A JP2820242B2 (ja) 1989-08-07 1989-08-07 接着用樹脂組成物
JP1-204508 1989-08-07
JP1-242775 1989-09-19
JP1242775A JP2760595B2 (ja) 1989-09-19 1989-09-19 積層体
JP242775 1989-09-19

Related Child Applications (1)

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KR1019930014168A Division KR940004763B1 (ko) 1989-08-07 1993-07-26 접착제 수지 조성물, 이 조성물을 접착층으로 하는 적층체

Publications (2)

Publication Number Publication Date
KR910004769A true KR910004769A (ko) 1991-03-29
KR930011760B1 KR930011760B1 (ko) 1993-12-20

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Country Status (6)

Country Link
EP (1) EP0412503B1 (ko)
KR (1) KR930011760B1 (ko)
CN (2) CN1035619C (ko)
AT (1) ATE118235T1 (ko)
CA (1) CA2022799C (ko)
DE (1) DE69016711T2 (ko)

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KR100792614B1 (ko) * 2005-09-01 2008-01-09 쇼사부로 수미 금속조 화장 시트 및 화장 금속판

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JP3061398B2 (ja) * 1990-05-28 2000-07-10 三井化学株式会社 積層体
JP3312984B2 (ja) * 1994-01-25 2002-08-12 三菱化学株式会社 接着性樹脂組成物
US5597865A (en) * 1994-11-21 1997-01-28 Quantum Chemical Corporation Adhesive blends for polystyrene
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US6184298B1 (en) 1998-06-19 2001-02-06 E. I. Du Pont De Nemours And Company Adhesive compositions based on blends of grafted polyethylenes and non-grafted polyethylenes and styrene container rubber
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US9321941B2 (en) * 2008-01-02 2016-04-26 Equistar Chemicals, Lp Tie-layer adhesives for styrene polymers and articles
KR102169618B1 (ko) * 2020-05-07 2020-10-23 방만혁 접착제 조성물과, 그 제조 방법, 이 접착제 조성물을 이용한 복합관, 및 적층 쉬트

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JPS51134732A (en) * 1975-05-19 1976-11-22 Du Pont Mitsui Polychem Co Ltd Adhesive composition
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JPS6114272A (ja) * 1984-06-29 1986-01-22 Ube Ind Ltd 接着性ポリエチレン組成物及びその金属積層体
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KR100792614B1 (ko) * 2005-09-01 2008-01-09 쇼사부로 수미 금속조 화장 시트 및 화장 금속판

Also Published As

Publication number Publication date
CN1083869C (zh) 2002-05-01
EP0412503B1 (en) 1995-02-08
CA2022799A1 (en) 1991-02-08
CA2022799C (en) 1997-06-17
EP0412503A3 (en) 1992-07-01
EP0412503A2 (en) 1991-02-13
KR930011760B1 (ko) 1993-12-20
DE69016711D1 (de) 1995-03-23
CN1035619C (zh) 1997-08-13
CN1049672A (zh) 1991-03-06
CN1154991A (zh) 1997-07-23
DE69016711T2 (de) 1995-07-13
ATE118235T1 (de) 1995-02-15

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