KR910000964A - 잠열형 양 이온 중합 개시제 및 이것을 함유하는 수지합성물 - Google Patents

잠열형 양 이온 중합 개시제 및 이것을 함유하는 수지합성물 Download PDF

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KR910000964A
KR910000964A KR1019900008291A KR900008291A KR910000964A KR 910000964 A KR910000964 A KR 910000964A KR 1019900008291 A KR1019900008291 A KR 1019900008291A KR 900008291 A KR900008291 A KR 900008291A KR 910000964 A KR910000964 A KR 910000964A
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alkyl
halogen
alkoxy
nitro
hydroxy
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신지 나까노
사또시 우라노
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사사끼 가즈오
닛뽄 페인트 가부시끼가이샤
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Priority claimed from JP24468189A external-priority patent/JPH0699391B2/ja
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    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C07D213/16—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom containing only one pyridine ring
    • C07D213/20—Quaternary compounds thereof
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
    • C07D263/04—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08—Saturated oxiranes
    • C08G65/10—Saturated oxiranes characterised by the catalysts used
    • C08G65/105—Onium compounds
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G85/00—General processes for preparing compounds provided for in this subclass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
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    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/35—Heterocyclic compounds having nitrogen in the ring having also oxygen in the ring
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups

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  • Epoxy Resins (AREA)
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Abstract

내용 없음

Description

잠열형 양 이온 중합 개시제 및 이것을 함유하는 주시합성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 다음식 Ⅰ,Ⅱ 및 Ⅲ의 화합물의 전술한 수지의 경화반응을 개시하는데 유효한 경화촉매와 촉매량의 존재하에 가열에 의하여 경화될 수 있는 필름형성용수지를 함유하는 것을 특징으로 하는 수지성 합성물 :
    여기서, R1,R2 및 R3는 각각 수소, 할로겐, 알킬, 알콕시, 니트로, 아미노, 알콕시아미노, 시오노, 알콕시카보닐, 또는 카바모일이고, R4는 수소, 할로겐 또는 알킬이고, R5는 할로겐 또는 알킬이고, R6, R7 및 R8은 각각 히드록시, 카복실, 알콕시, 니트로, 시마노 또는 알키노일옥시로 임의적으로 치환된 알킬 또는 알케닐이거나 알킬, 할로겐, 니트로, 시아노, 알콕시, 아미노, 또는 디알킬아미로 임의적으로 치환된 페닐이고, M은 As, Sb, B 또는 P이고 X는 할로겐이고, N은 원소M의 가전자에 1을 더한 것이다.
    여기서, R1, R2, R3, R4, R5, M, X 및 N은 다만 R4가 할로겐을 대표할 수 없다는 조건으로 전술한 것과 동일하게 정의한다.
    R9 및 R10은 각각 수고, 알킬, 할로겐, 니트로시아노, 알콕시, 아미노, 또는 디알킬아미노이다 :
    여기서 M,X 및 전술한 것과 동일하게 정의한다.
    R11 및 R12는 히드록시, 알킬, 알콕시, 할로겐, 니트로, 또는 알킬아미노로 임의적으로 치환된 수소, 알킬, 알케닐, 또는 페닐이고, R13 및 R14는 각각 히드록시, 알킬, 알콕시, 할로겐 니트로, 또는 알킬아미노로 임의적으로 치환된 알킬, 알케닐 또는 페닐이고, R15 및 R16은 각각 히드록시알킬, 알콕시, 할로겐, 니트로, 또는 페닐이고, M은 1~4의 정수이다.
  2. 제1항에 있어서 전술한 필름형성용 수지가 양이온 중합가능한 관능을 갖는 단량체 또는 중합체이거나 또는 이들의 혼합물인 것을 특징으로 하는 하는 수지성 합성물.
  3. 제2항에 있어서 전술한 양이온 중합가능한 관능이 에폭시도, 환식이면, 환식에테르 또는 환식에스테르인 것을 특징으로 하는 수지성 합성물.
  4. 제2항에 있어서 전술한 필름형성용 수지가 폴리올을 더 갖고 있는 것을 특징으로 하는 수지성 합성물.
  5. 제4항에 있어서 폴리올 성분이 전술한 양이온 중합가능한 관능에 대하여 1~100몰%에 해당하는 양으로 혼합되어 있는 것을 특징으로 하는 수지성 합성물.
  6. 제1항에 있어서 전술한 필름형성용 수지는 복수의 히드록시 그룹을 갖는 필름 형성용 수지와 멜리민 수지의 혼합물인 것을 특징으로 하는 수지성 합성물.
  7. 제6항에 있어서 전술한 멜라민 수지는 전술한 혼합물의 고형분중에서 5~50%차지하는 것을 특징으로 하는 수지성 합성물.
  8. 제1항에 있어서 전술한 필름형성용 수지가 복수의 알콜시실릴 그룹을 갖는 실리콘수지인 것을 특징으로 하는 수지성 화합물.
  9. 제8항에 있어서 폴리올을 더 함유하는 것을 특징으로 하는 수지성 합성물.
  10. 제9항에 있어서 전술한 폴리올 성분이 히드록시 그룹대 알콕시실릴 그룹의 몰비가 0.1~10이 되는 양으로 혼합하는 것을 특징으로 하는 수지성 합성물.
  11. 다음식 Ⅰ,Ⅱ 및 Ⅲ 의 화합물 :
    여기서 R1, R2 및 R3는 각각 수소, 할로겐, 알킬, 알콕시, 니트로, 아미노, 알킬아미노, 시아노, 알콕시카보닐, 또는 카바모일이고, R4는 수소, 할로겐 또는 알킬이고, R5는 할로겐 또는 알킬이고, R6, R7 및 R8은 각각 히드록시, 카복실, 알콕시, 니트로, 시아노 또는 알카노일옥시로 임의적으로 치환된 알킬 또는 알케닐이거나 또는 알킬, 할로겐, 니트로, 시아노, 알콕시, 아미노, 또는 디알킬아미로 임의적으로 치환된 페닐이다.
    M은 As, Sb, B 또는 P이고 X는 할로겐이고, N은 원소M의 가전자에 1을 더한것과 같다.
    여기서, R1, R2, R3, R4, R5, M, X 및 N은 R4가 할로겐을 대표할 수 없다는 조건으로 전술한 것과 동일하게 정의한다.
    R9 및 R10은 각각 수소, 알킬, 할로겐, 니트로, 시아노, 알콕시, 아미노, 또는 디알킬아미노이다 : 또한
    여기서 M,X 및 N은 전술한 것과 동일하게 정의한다. R11 및 R12는 각각 히드록시, 알킬, 알콕시, 할로겐, 니트로, 또는 알킬아미노로 임의적으로 치환된 수소, 알킬, 알케닐, 또는 페닐이고, R13 및 R14는 각각 히드록시, 알킬, 알콕시, 할로겐 니트로, 또는 알킬아미노로 임의적으로 치환된 알킬, 알케닐 또는 페닐이고, R15 및 R16은 각각 히드록시 알킬, 알콕시, 할로겐, 니트로, 또는 알킬아미노로 임의적으로 치환된 수소, 히드록시, 알킬, 알콕시 또는 페닐이고, M은 1~4의 정수이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900008291A 1989-06-05 1990-06-05 잠열형 양이온 중합 개시제 및 이것을 함유하는 수지합성물 KR0157622B1 (ko)

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Application Number Priority Date Filing Date Title
JP1142541A JPH0737426B2 (ja) 1989-06-05 1989-06-05 新規ベンジルアンモニウム塩
JP1-142541 1989-06-05
JP1-191659 1989-07-24
JP19165989A JPH0742277B2 (ja) 1989-07-24 1989-07-24 新規複素環式アンモニウム塩
JP24468189A JPH0699391B2 (ja) 1989-09-19 1989-09-19 α，α―ジ置換ベンジルピリジニウム塩
JP1-244681 1989-09-19

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KR910000964A true KR910000964A (ko) 1991-01-30
KR0157622B1 KR0157622B1 (ko) 1999-02-18

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AU (3) AU627316B2 (ko)
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JPH04295483A (ja) * 1991-03-22 1992-10-20 Nippon Paint Co Ltd 新規アンモニウム塩
US6762260B2 (en) 2002-03-05 2004-07-13 Dow Global Technologies Inc. Organoborane amine complex polymerization initiators and polymerizable compositions
US6777512B1 (en) 2003-02-28 2004-08-17 Dow Global Technologies Inc. Amine organoborane complex initiated polymerizable compositions containing siloxane polymerizable components
KR20060081656A (ko) 2003-06-09 2006-07-13 다우 글로벌 테크놀로지스 인크. 안정화된 유기보란 중합 개시제 및 중합성 조성물
CN1898082B (zh) 2003-12-22 2010-09-29 陶氏环球技术公司 促进的有机硼烷胺络合物引发的可聚合组合物

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US3576795A (en) * 1967-12-01 1971-04-27 Polaroid Corp Reaction products of novel tetrahydro oxazonium compounds and gelatin
NL7402361A (nl) * 1974-02-21 1975-08-25 Shell Int Research Organische hexafluorantimoonzure zouten en hun toepassing als katalysatoren voor kationische polymerisaties.
US5070161A (en) * 1988-05-27 1991-12-03 Nippon Paint Co., Ltd. Heat-latent, cationic polymerization initiator and resin compositions containing same

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EP0401770A2 (en) 1990-12-12
KR0157622B1 (ko) 1999-02-18
EP0401770A3 (en) 1992-12-09
EP0651002A2 (en) 1995-05-03
AU627316B2 (en) 1992-08-20
CA2018173C (en) 1998-06-30
EP0401770B1 (en) 1997-05-02
DE69030600D1 (de) 1997-06-05
EP0651002A3 (en) 1995-12-06
DE69030600T2 (de) 1997-12-18
AU640085B2 (en) 1993-08-12
AU640086B2 (en) 1993-08-12
CA2018173A1 (en) 1990-12-05
AU1722792A (en) 1992-08-13
AU1722892A (en) 1992-08-13

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