KR910000224A - 메탄올 해리 촉매 - Google Patents

메탄올 해리 촉매 Download PDF

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Publication number
KR910000224A
KR910000224A KR1019900009704A KR900009704A KR910000224A KR 910000224 A KR910000224 A KR 910000224A KR 1019900009704 A KR1019900009704 A KR 1019900009704A KR 900009704 A KR900009704 A KR 900009704A KR 910000224 A KR910000224 A KR 910000224A
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South Korea
Prior art keywords
catalyst composition
methanol
catalyst
weight
weight percent
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KR1019900009704A
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English (en)
Inventor
쳉 우-쑨
페레티 오거스트
Original Assignee
제임스 제이. 플린
이.아이.듀퐁 드 네모아 앤드 캄파니
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Publication of KR910000224A publication Critical patent/KR910000224A/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/885—Molybdenum and copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/40—Carbon monoxide

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

메탄올 해리 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 구리 20 내지 99.9중량% 및 무정형 실리카 0.1 내지 20중량%의 비융합 메탄올 해리 촉매를 함유함을 특징으로 하는 촉매 조성물.
  2. 제1항에 있어서, 추가로 크롬 5 내지 75중량%를 함유하는 촉매 조성물.
  3. 제1항 또는 제2항에 있어서, 추가로 마그네슘, 칼슘, 바륨, 스트론튬, 망간, 몰리브덴, 루테늄 및 팔라듐, 및 이들의 산화물 및 수산화물 중에서 선택된 하나이상의 금속을 함유하는 촉매 조성물.
  4. 제3항에 있어서, 무정형 실리카 2 내지 10중량%를 함유하는 촉매 조성물.
  5. 제4항에 있어서, 크롬 10 내지 45중량%를 함유하는 촉매 조성물.
  6. 제5항에 있어서, 바륨 1 내지 15중량%를 함유하는 촉매 조성물.
  7. 제5항에 있어서, 망간 1 내지 5중량%를 함유하는 촉매 조성물.
  8. 제7항에 있어서, 구리65 내지 75중량%, 크롬 20 내지 30중량%, 및 무정형 실리카 2 내지 4주량%를 함유하는 촉매 조성물.
  9. 제3항에 있어서, 하나 이상의 금속이 할로겐 또는 황을 함유하지 않는 촉매 조성물.
  10. 제1항, 2항 또는 3항에 있어서, 최소 표면적이 30㎡/g인 촉매 조성물.
  11. 메탄올을 해리시키는 방법에 있어서, 메탄올을 약 100 내지 약 400℃범위의 온도에서 제1항 또는 2항의 촉매와 접촉시킴을 특징으로 하는 개선된 방법.
  12. 메탄올을 해리시키는 방법에 있어서, 메탄올을 약 100 내지 약 400℃범위의 온도에서 제3항의 촉매와 접촉시킴을 특징으로 하는 개선된 방법.
  13. 메탄올을 해리시키는 방법에 있어서, 메탄올을 약 200 내지 약 300℃범위의 온도에서 제8항의 촉매와 접촉시킴을 특징으로 하는 개선된 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900009704A 1989-06-29 1990-06-29 메탄올 해리 촉매 KR910000224A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US525829 1983-08-23
US37325389A 1989-06-29 1989-06-29
US373253 1989-06-29
US07/525,829 US5106810A (en) 1989-06-29 1990-05-23 Methanol dissociation catalysts

Publications (1)

Publication Number Publication Date
KR910000224A true KR910000224A (ko) 1991-01-29

Family

ID=27006114

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900009704A KR910000224A (ko) 1989-06-29 1990-06-29 메탄올 해리 촉매

Country Status (4)

Country Link
US (1) US5106810A (ko)
EP (1) EP0405958A1 (ko)
KR (1) KR910000224A (ko)
CA (1) CA2020176A1 (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4239247A1 (de) * 1992-11-21 1994-05-26 Huels Chemische Werke Ag Katalysator für ein Verfahren zur Herstellung von 4-Hydroxy-2.2.6.6-tetramethylpiperidin
JP4032248B2 (ja) * 2003-04-25 2008-01-16 本田技研工業株式会社 自動車排ガス浄化用燃焼触媒
US8404908B2 (en) * 2009-10-13 2013-03-26 Uop Llc Process for lignin conversion to chemicals or fuels with H2 generated from lignin depolymerization products
CN110577190A (zh) * 2018-06-11 2019-12-17 河南车权健新能源科技有限公司 一种甲醇裂解制备氢气的工艺
CN110327933B (zh) * 2019-07-25 2022-09-20 甄崇礼 二氧化碳加氢制备甲醇的催化剂及其制备方法和应用

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Publication number Priority date Publication date Assignee Title
US1939708A (en) * 1927-06-28 1933-12-19 Du Pont Catalysts for the production of methanol and other carbon compounds
US2010427A (en) * 1933-01-14 1935-08-06 Carbide & Carbon Chem Corp Dehydrogenation of methanol
NL132671C (ko) * 1960-02-09
US3213145A (en) * 1960-03-28 1965-10-19 Standard Oil Co Catalytic hydrogenation of esters of aromatic monocarboxylic acids to aryl-substituted methanols
GB1010574A (en) * 1963-04-23 1965-11-17 British Petroleum Co Production of hydrogen-containing gases
FR93716E (fr) * 1967-02-27 1969-05-09 Melle Bezons Catalyseurs d'hydrogenation et leur procede de preparation.
DE1940412A1 (de) * 1969-08-08 1971-04-29 Degussa Verfahren zur Herstellung feinteiliger,durch Metalloxid modifizierter Kieselsaeuren
US3826758A (en) * 1972-05-25 1974-07-30 Grace W R & Co Method of preparing exhaust catalyst
DE2506348C3 (de) * 1975-02-14 1980-07-17 Bayer Ag, 5090 Leverkusen Hydrierkatalysator
IT1065295B (it) * 1976-12-23 1985-02-25 Snam Progetti Processo per la produzione di dimetil etere e catalizzatore utilizzabile in detto processo
GB1577069A (en) * 1977-07-27 1980-10-15 British Petroleum Co Process for the production of synthesis gas by the catalysed decomposition of methanol
CA1130265A (en) * 1978-10-06 1982-08-24 William J. Ball Process for the production of amorphous aluminosilicates and their use as catalysts
US4279781A (en) * 1979-10-09 1981-07-21 United Catalysts Inc. Catalyst for the synthesis of methanol
US4407238A (en) * 1981-10-26 1983-10-04 Conoco Inc. Methanol dissociation using a copper-chromium-manganese catalyst
NL8205027A (nl) * 1982-12-29 1984-07-16 Unilever Nv Katalysator voor de methanolbereiding.
ZA848604B (en) * 1983-11-04 1985-06-26 Veg Gasinstituut Nv Process for the production of hydrogen
BE898679A (fr) * 1984-01-13 1984-05-02 Grande Paroisse Azote Et Prod Catalyseurs pour le reformage de l'ethanol, du methanol ou de leurs melanges en presence de vapeur d'eau
US4826798A (en) * 1988-03-04 1989-05-02 E. I. Du Pont De Nemours And Company Carbon dioxide calcination of methanol dissociation catalysts

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EP0405958A1 (en) 1991-01-02
US5106810A (en) 1992-04-21
CA2020176A1 (en) 1990-12-30

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