KR900702124A - 폴리카르복실산으로 면직물을 포름알데하이드-유리 DP가공(Durable Press Finishing)하기 위한 촉매와 그 방법 - Google Patents

폴리카르복실산으로 면직물을 포름알데하이드-유리 DP가공(Durable Press Finishing)하기 위한 촉매와 그 방법

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KR900702124A
KR900702124A KR1019900700321A KR900700321A KR900702124A KR 900702124 A KR900702124 A KR 900702124A KR 1019900700321 A KR1019900700321 A KR 1019900700321A KR 900700321 A KR900700321 A KR 900700321A KR 900702124 A KR900702124 A KR 900702124A
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acid
group
carboxyl group
aliphatic
carboxyl groups
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KR1019900700321A
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KR930005933B1 (ko
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클럭 엠. 웰치
베들레헴 케이. 앤드류스
Original Assignee
찰스 에이. 베베락쿠어
더 유나이티드 스테이츠 오브 아메리카, 에즈 리프레젠티드 바이 더 시크레타리, 유나이티드 스테이츠 디파트먼트 오브 코머스
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Priority claimed from US07/207,461 external-priority patent/US4820307A/en
Application filed by 찰스 에이. 베베락쿠어, 더 유나이티드 스테이츠 오브 아메리카, 에즈 리프레젠티드 바이 더 시크레타리, 유나이티드 스테이츠 디파트먼트 오브 코머스 filed Critical 찰스 에이. 베베락쿠어
Publication of KR900702124A publication Critical patent/KR900702124A/ko
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Publication of KR930005933B1 publication Critical patent/KR930005933B1/ko

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/2035—Aromatic acids

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

폴리카르복실산으로 면직물을 포름알데하이드-유리 DP가공(Durable Press Finishing)하기 위한 촉매와 그 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 폴리카르복실산과 경화촉매를 함유하는 처리용액을 섬유상 셀룰로오스 물질에 침투시키고; 폴리카르복실산은 올레핀 포화 또는 불포화된 지방족, 지환 족 및 방향족 산으로 구성되고 분자당 적어도 3개의 카르복실그룹을 보유하는 그룹으로부터 선택되고; 지방족, 지환족 및 방향족 산은 분자당 2개의 카르복실 그룹을 보유하고 상기 카르복실 그룹 중 하나 또는 양쪽 모두에 대해, α-, β-로 배치된 탄소-탄소 이중결합을 보유하며; 지방족산은 올레핀 포화 또는 불포화되어 있고 분자당 적어도 3개의 카르복실 그룹을 보유하며, 하이드록실 그룹은 분자의 카르복실 그룹중 하나에 부착된 탄소원자상에 존재하고; 상기 지방족 및 지환족산은 카르복실 그룹이 부착되어 있는 체인 또는 링에 산소 또는 황원자를 포함하며; 하나의 카르복실 그룹은 지방족 및 지환족 산에서 2 또는 3개의 탄소원자에 의해 두번째 카르복실 그룹으로부터 분리되어 있고; 하나의 카르복실 그룹은 방향족내의 두번째 카르복실 그룹에 대해 오르토-로 존재하며; 하나의 카르복실 그룹은 2개의 카르복실 그룹이 탄소-탄소 이중결합에 의해 분리되거나 또는 2개 모두 동일 링에 결합되어 있는 두번째 카르복실 그룹에 관련하여 시스-배위로 존재하고; 경화 촉매는 알칼리 금속 하이포포스파이트, 알카리 금속 포스파이트, 및 알카리 금속 폴리포스페이트로 구성되는 그룹으로부터 선택되며; 폴리카르복실산으로서 상기 섬유상 셀룰로오스 물질내에 셀룰로오스의 에스테르화와 가교결합을 생성시키기 위해 상기 물질을 가열시키는 단계로 구성되는, 섬유상 셀룰로오스의 처리방법.
  2. 제1항에 있어서, 폴리카르복실산은 말레산; 시트라코닉산; 시트로산; 이타코닉산; 트리카르발릴산; 트란스-아코니틱산; 1,2,3,4-부탄테트라카르복실산; 시스-1,2,3,4-사이클로펜탄테트라카르복실산; 멜리틱산; 옥시디숙신산; 및 티오디숙신산으로 구성되는 그룹으로부터 선택되는 섬유상 셀룰로오스 물질의 처리 방법.
  3. 제2항에 있어서, 경화촉매는 소디움 하이포포스파이트, 디소디움 포스파이트, 디소디움에시드 피로포스페이트, 테트라소디움 피로포스페이트, 펜타소디움 트리폴리포스페이트, 및 소디움 헥사메타포스페이트로 구성되는 그룹으로부터 선택되는 섬유상 셀룰로오스 물질의 처리 방법.
  4. 제1항에 있어서, 섬유상 셀룰로오스 물질은 면, 아마, 황마, 대마, 모시 및 재생 대체 목질 셀룰로오스로 구성되는 그룹으로부터 선택된 30중량%이상의 셀룰로오스 섬유를 포함하는 섬유상 셀룰로오스 물질의 처리 방법.
  5. 폴리카르복실산과 경화 촉매를 함유하는 처리용액을 섬유상 셀룰로오스 물질에 침투시키고; 폴리카르복실산은 올레핀 포화 또는 불포화된 지방족, 지환족 및 방향족 산으로 구성되고 분자당 적어도 3개의 카르복실그룹을 보유하는 그룹으로부터 선택되고; 지방족, 지환족 및 방향족 산은 분자당 2개의 카르복실 그룹을 보유하고 상기 카르복실 그룹 중 하나 또는 2개 모두에 대해, α-, β-로 배치된 탄소-탄소 이중결합을 보유하며, 지방족산은 올레핀 포화 또는 불포화되어 있고 분자당 적어도 3개의 카르복실 그룹을 보유하고, 하이드록실 그룹은 분자의 카르복실 그룹중 하나에 부착된 탄소원자상에 존재하고, 상기 지방족 및 지환족산은 카르복실 그룹이 부착되어 있는 체인 또는 링에서 산소 또는 황원자를 포함하며; 하나의 카르복실 그룹은 지방족 및 지환족 산에서 2 또는 3개의 탄소원자에 의해 두번째 카르복실 그룹으로부터 분리되어 있고; 하나의 카르복실 그룹은 방향족산내의 두번째 카르복실그룹으로부터 분리되어 있고; 하나의 카르복실 그룹은 방향족산내의두번째 카르복실 그룹에 대해 오르트-로 존재하며; 하나의 카르복실 그룹은 2개의 카르복실 그룹이 탄소-탄소 이중결합에 의해 분리되거나 2개 모두 동일 링에 결합되어 있는 두번째 카르복실 그룹에 대해 시스배위로 존재하며; 경화촉매는 알칼리 금속 하이포포스파이트, 알카리 금속 포스파이트, 및 알카리금속 폴리포스페이트로 구성되는 그룹으로부터 선택되고; 폴리카르복실산으로서 상기 섬유상 셀룰로오스 물질내에 셀룰로오스의 에스테르화와 가교결합을 생성시키기 위해 섬유상 셀룰로오스물질을 가열하는 것으로 구성되는 방법에 의해 처리된 섬유상 셀룰로오스 물질.
  6. 제5항에 있어서, 폴리카르복실산은 말레산; 시트라코닉산; 시트로산; 이타코닉산; 트리카르발릴산; 트란스-아코니틱산; 1,2,3,4-부탄테트라카르복실산; 시스-1,2,3,4-사이클로펜탄테트라카르복실산; 멜리틱산; 옥시디숙신산; 및 티오디숙신산으로 구성되는 그룹으로부터 선택되는 섬유상 셀룰로오스 물질.
  7. 제6항에 있어서, 경화촉매는 소디움 하이포포스파이트, 디소디움 포스파이트, 디소디움에시드 피로포스테이트, 테트라소디움 피로포스페이트, 펜타소디움 트리폴리포스페이트, 및 소디움 헥사메타포스페이트로 구성된 그룹으로부터 선택되는 섬유상 셀룰로오스 물질.
  8. 제5항에 있어서, 폴리카르복실산은 1,2,3,4-부탄테트라카르복실산이고, 경화촉매는 소다움 하이포포스파이트, 디소시움 포스파이트, 디소디움 에시드 피로포스페이트, 테트라소디움 피로포스페이트, 펜타소디움 트리폴리포스페이트, 및 소디움 헥사메타포스페이트로 구성되는 그룹으로부터 선택되는 섬유상 셀룰로오스 물질.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900700321A 1988-06-16 1989-06-16 폴리카르복실산으로 면직물을 포름알데하이드-유리 DP가공(Durable Press Finishing)하기 위한 촉매와 그 방법 KR930005933B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US07/207,461 US4820307A (en) 1988-06-16 1988-06-16 Catalysts and processes for formaldehyde-free durable press finishing of cotton textiles with polycarboxylic acids
US207,461 1988-06-16
US335,346 1989-04-10
US07/335,346 US4936865A (en) 1988-06-16 1989-04-10 Catalysts and processes for formaldehyde-free durable press finishing of cotton textiles with polycarboxylic acids
PCT/US1989/002628 WO1989012714A1 (en) 1988-06-16 1989-06-16 Catalysts and processes for formaldehyde-free durable press finishing of cotton textiles with polycarboxylic acids

Publications (2)

Publication Number Publication Date
KR900702124A true KR900702124A (ko) 1990-12-05
KR930005933B1 KR930005933B1 (ko) 1993-06-29

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KR1019900700321A KR930005933B1 (ko) 1988-06-16 1989-06-16 폴리카르복실산으로 면직물을 포름알데하이드-유리 DP가공(Durable Press Finishing)하기 위한 촉매와 그 방법

Country Status (12)

Country Link
US (1) US4936865A (ko)
EP (1) EP0354648B1 (ko)
JP (1) JPH0726321B2 (ko)
KR (1) KR930005933B1 (ko)
AT (1) ATE106472T1 (ko)
AU (1) AU3845989A (ko)
DE (1) DE68915640T2 (ko)
ES (1) ES2055058T3 (ko)
MX (1) MX168920B (ko)
PH (1) PH25255A (ko)
PT (1) PT90877B (ko)
WO (1) WO1989012714A1 (ko)

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EP0354648A2 (en) 1990-02-14
DE68915640T2 (de) 1995-02-09
PH25255A (en) 1991-03-27
PT90877B (pt) 1994-12-30
PT90877A (pt) 1989-12-29
US4936865A (en) 1990-06-26
WO1989012714A1 (en) 1989-12-28
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