KR900700515A - 폴리우레탄 분말 피복 조성물 - Google Patents

폴리우레탄 분말 피복 조성물

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Publication number
KR900700515A
KR900700515A KR1019890701473A KR890701473A KR900700515A KR 900700515 A KR900700515 A KR 900700515A KR 1019890701473 A KR1019890701473 A KR 1019890701473A KR 890701473 A KR890701473 A KR 890701473A KR 900700515 A KR900700515 A KR 900700515A
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composition
powder coating
coating composition
intrinsic viscosity
hydroxyl
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KR1019890701473A
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KR970011466B1 (ko
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프레드 위니프레드 2세 라이트
제임스 듀튼 후드
영호 장
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존 디. 후써
이스트만 코닥 컴퍼니
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4202Two or more polyesters of different physical or chemical nature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/80Masked polyisocyanates
    • C08G18/8061Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • C08G18/8074Lactams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2150/00Compositions for coatings
    • C08G2150/20Compositions for powder coatings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2250/00Compositions for preparing crystalline polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31616Next to polyester [e.g., alkyd]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31678Of metal
    • Y10T428/31681Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

내용 없음

Description

폴리우레탄 분말 피복 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. (a)자유 하이드록실 그룹을 함유하고 Tg가 40℃보다 크고 하이드록실 수가 약 20-200이며 고유 점도가 약 0.1-0.5인 최소한 하나의 무정형 폴리에스테르 약 10-80wt%.(b)자유 하이드록실 그룹을 함유하고 Tg가 약-10-약50℃이고, 수평균 분자량이 약 500-10,000이며 용융열이 5cal/g-℃보다 많고, 하이드록 실수가 약 20-200이며 고유 점도가 약 0.1-0.5인 최소한 하나의 반결정형 폴리에스테르 약 10-80wt% 및 폴리이소시아네이트 가교결합제 약 5-30wt%로 구성되고,(a),(b) 및(c)의 합이 100%인 것으로서 특징되어지는 폴리우레탄 분말 피복 조성물.
  2. 제 1항에 있어서, 전기한 무정형 폴리에스테르가 55℃보다 높은 Ta 약 30-80의 하이드록실 수, 약 0.15-0.30의 고유점도를 가지며, 전기한 반 결정형 폴리에스테르가 약 -10-30℃ Tg 약 1000-6000의 수평균 분자량, 야 R80-120℃의 융점, 5cal/g-℃보다 큰△Hf 약 30-80의 하이드록실수, 20이하의 산수 약 0.15-0.30의 고유점도를 갖는 것으로 특징되어지는 폴리우레탄 분말 피복 조성물.
  3. 제 1항에 있어서, 전기한 반결정형 폴리에스테르가 테레프탈산 또는 1.4-시클로헥산디카복실산으로 구성된 산성분 및 1.5-펜탄디올 네오펜딜, 글리콜 1.6-핵산디올 1.10-데칸디올 1,12-도데칸디올 또는 전기한 글리콜의 결합물로 구성된 굴리콜 성분을 갖는 것으로 특징되어지는 폴리우레탄 분말 피복 조성물.
  4. 제 1항에 있어서, 전기한 조성물의 가교결합된 피복물이 160in-1b (20.8J)을 초과하는 앞면 충격 강도 및 뒷면 충격 강도를 갖고, 40℃에서 10일 동안 보관된 후 스스로 흐를 수 있으며, 패널을 200℉ (90℃)에서 20분 동안 건조가열에 의해 가열시키기 전이나 후에 구부린 두 반쪽 사이에 두께가 0이 되도록 하여 패널을 20,000psi (137,900kpa) 압력에서 뒤로 구부릴 때 깨지지 않거나 터지지 않을만큼 유연한 것으로 특징되어지는 폴리우레탄 분말 피복 조성물.
  5. 제 1항에 있어서, 전기한 폴리이소시아네이트 및 전기한 폴리에스테르를 가교 결합시키는데 촉매시킬 수 있는 양의 촉매를 포함하는 것으로 특징되어지는 조성물.
  6. 제 1항에 있어서, 전기한 폴리이소시아네이트 블록되는 것으로 특징되어지는 조성물.
  7. 제 1항에 있어서, 착색재를 포함하는 것으로 특징되어지는 조성물.
  8. 제 1항에 있어서, 유동 조절 보조제 및 피그먼트를 포함하는 것으로 특징되어지는 조성물.
  9. 제 1항에 있어서, 평균 미립자 크기가 약 10-125μ인 미립자 형태인 것으로 특징되어지는 조성물.
  10. 제 1항에 있어서, 미립자가 잘 섞인 성분들의 혼합물로 미립자 형태인 것으로 특징되어지는 조성물.
  11. 제 1항의 조성물로 피복되는 것으로 특징되어지는 기판.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890701473A 1987-12-07 1988-12-05 폴리우레탄 분말 피복 조성물 KR970011466B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US129,514? 1987-12-07
US129,514 1987-12-07
US07/129,514 US4859760A (en) 1987-12-07 1987-12-07 Polyurethane powder coating compositions
PCT/US1988/004308 WO1989005320A1 (en) 1987-12-07 1988-12-05 Polyurethane powder coating compositions

Publications (2)

Publication Number Publication Date
KR900700515A true KR900700515A (ko) 1990-08-13
KR970011466B1 KR970011466B1 (ko) 1997-07-11

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Country Link
US (1) US4859760A (ko)
EP (1) EP0394325B1 (ko)
JP (1) JPH03501744A (ko)
KR (1) KR970011466B1 (ko)
CA (1) CA1334553C (ko)
DE (1) DE3884626T2 (ko)
WO (1) WO1989005320A1 (ko)

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DE2346559B2 (de) * 1973-09-15 1975-09-11 Dynamit Nobel Ag, 5210 Troisdorf Beschichtungspulver auf der Basis von thermoplastischen Polyestern
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JPH0619063B2 (ja) * 1986-04-09 1994-03-16 日本エステル株式会社 粉体塗料用樹脂組成物

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DE3884626T2 (de) 1994-04-28
WO1989005320A1 (en) 1989-06-15
DE3884626D1 (de) 1993-11-04
KR970011466B1 (ko) 1997-07-11
CA1334553C (en) 1995-02-21
US4859760A (en) 1989-08-22
EP0394325B1 (en) 1993-09-29
EP0394325A1 (en) 1990-10-31
JPH03501744A (ja) 1991-04-18

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