KR900700386A - 합성 결정성 분자체 및 이의 합성방법 - Google Patents

합성 결정성 분자체 및 이의 합성방법

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Publication number
KR900700386A
KR900700386A KR1019890702092A KR890702092A KR900700386A KR 900700386 A KR900700386 A KR 900700386A KR 1019890702092 A KR1019890702092 A KR 1019890702092A KR 890702092 A KR890702092 A KR 890702092A KR 900700386 A KR900700386 A KR 900700386A
Authority
KR
South Korea
Prior art keywords
molecular sieve
silicon
valence
composition
following
Prior art date
Application number
KR1019890702092A
Other languages
English (en)
Inventor
윌리암 바리오크식 어네스트
Original Assignee
에드워드 에이취. 바란스
모빌오일 코퍼레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/166,571 external-priority patent/US4913796A/en
Priority claimed from US07/166,585 external-priority patent/US4913795A/en
Application filed by 에드워드 에이취. 바란스, 모빌오일 코퍼레이션 filed Critical 에드워드 에이취. 바란스
Publication of KR900700386A publication Critical patent/KR900700386A/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

합성 결정성 분자체 및 이의 합성방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 다음과 같은 X-선 회절라인을 지닌 합성 결정성 분자체;
  2. 제1항에서, MO2(M은 알루미늄 또는 인을 제외한 최소한 한 요소), AIO2 및 PO2의 테트라헤드랄 유니트로 구성된 3차원 골격구조로 이루어져 있으며 또한 다음의 조성을 지닌 분자체:
    위에서 Q 는 원자가 q의 양이온, T는 원자가 t의 음이온, m은 원소 M의 원자가 또는 무게 평균 원자가, 그리고 x, y, I 및 j는 다음의 관계식을 만족하는 수임:
  3. 제2항에서, M이 실리콘 홀로이며 분자체의 조성이 다음과 같이 표현되는 분자체:여기서, 0.01<X<1, 0.01 y<1 및 x+y<1임
  4. 제2항에서, M이 실리콘을 제외한 원소로서 산화수+2 및 이온 반경비 0.52-0.62 이거나 산화수 +3.-+6 및 이온반경 0.15-0.73 인 원소인 분자체.
  5. 제4항에서, M이 In+3, Sb+3, Sn+4Ti+3또는 Ti+4인 분자체.
  6. 제4항에서, M 이 MO2성분중 실리콘: 비실리콘 원자비가 1미만이 되도록 하는 실리콘인 분자체.
  7. AI2O3원, P2O5원, M산화물, 물 및 유기 지향제 R로 이루어져 있으며 다음과 같은 범위의 조성을 지닌 반응 혼합물을 제조하고; 분자체 결정이 형성될 때까지 상기 혼합물을 충분한 조건하에 유지시키고; 이어서 결정성 분자체를 회수하는 단계로 이루어진 제2항에 따른 분자체의 합성방법.
    위에서, R은 C5-C7알킬디아민임.
  8. 제7항에서, 혼합물의 조성이 다음과 같은 범위인 방법;
  9. 제7항에서, 유기 지향제 R이 1, 7-헵탄디아민 또는 1, 5-펜탄디아민인 방법.
  10. 제7항에서, 반응조건이 80-300℃에서 5시간-20일인 방법.
    ※참고사항: 최초출원 내용에 의하여 공개하는 것임.
KR1019890702092A 1988-03-10 1989-02-27 합성 결정성 분자체 및 이의 합성방법 KR900700386A (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US07/166,571 US4913796A (en) 1988-03-10 1988-03-10 Novel crystalline silicoaluminophosphate
US166,571 1988-03-10
US07/166,585 US4913795A (en) 1988-03-10 1988-03-10 Novel crystalline metalloaluminophosphate
US166,585 1988-03-10
PCT/US1989/000824 WO1989008608A1 (en) 1988-03-10 1989-02-27 Synthetic crystalline molecular sieve and its synthesis

Publications (1)

Publication Number Publication Date
KR900700386A true KR900700386A (ko) 1990-08-13

Family

ID=26862365

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890702092A KR900700386A (ko) 1988-03-10 1989-02-27 합성 결정성 분자체 및 이의 합성방법

Country Status (7)

Country Link
EP (1) EP0437429A1 (ko)
JP (1) JPH03503276A (ko)
KR (1) KR900700386A (ko)
AU (1) AU3197989A (ko)
DK (1) DK214990A (ko)
NZ (1) NZ228228A (ko)
WO (1) WO1989008608A1 (ko)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8924262D0 (en) * 1989-10-27 1989-12-13 Shell Int Research Novel crystalline aluminophosphates and related compounds
GB8926602D0 (en) * 1989-11-24 1990-01-17 Shell Int Research Novel crystalline aluminophosphates and related compounds
GB9023847D0 (en) * 1990-11-02 1990-12-12 Shell Int Research Novel crystalline aluminophosphates and related compounds

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4296083A (en) * 1977-04-22 1981-10-20 Mobil Oil Corporation Zeolite synthesis
US4139600A (en) * 1977-04-22 1979-02-13 Mobil Oil Corporation Synthesis of zeolite ZSM-5
CA1128914A (en) * 1979-09-04 1982-08-03 Clive D. Telford Method of preparing improved catalysts and use thereof in hydrocarbon conversion reactions
US4310440A (en) * 1980-07-07 1982-01-12 Union Carbide Corporation Crystalline metallophosphate compositions
US4444900A (en) * 1982-05-05 1984-04-24 Mobil Oil Corporation Activation of zeolites
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4567029A (en) * 1983-07-15 1986-01-28 Union Carbide Corporation Crystalline metal aluminophosphates
US4713227A (en) * 1983-12-19 1987-12-15 Mobil Oil Corporation Method for the synthesis of metallophosphoaluminates
US4673559A (en) * 1983-12-19 1987-06-16 Mobil Oil Corporation Silicoaluminophosphate crystallization using hydrolysis

Also Published As

Publication number Publication date
AU3197989A (en) 1989-10-05
DK214990D0 (da) 1990-09-07
EP0437429A1 (en) 1991-07-24
DK214990A (da) 1990-09-07
WO1989008608A1 (en) 1989-09-21
NZ228228A (en) 1990-09-26
JPH03503276A (ja) 1991-07-25

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