KR900018231A - 입자형태의 발포성 중합체 - Google Patents

입자형태의 발포성 중합체 Download PDF

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Publication number
KR900018231A
KR900018231A KR1019890007043A KR890007043A KR900018231A KR 900018231 A KR900018231 A KR 900018231A KR 1019890007043 A KR1019890007043 A KR 1019890007043A KR 890007043 A KR890007043 A KR 890007043A KR 900018231 A KR900018231 A KR 900018231A
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KR
South Korea
Prior art keywords
particles
aliphatic
saturated hydrocarbons
weight
blowing agent
Prior art date
Application number
KR1019890007043A
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English (en)
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KR970008856B1 (ko
Inventor
베버 하인쯔
닌쯔 엑카르트
발터 만프레트
발베버 디이터
오스터마이어 베르트랑
Original Assignee
방에르트, 바르츠
바스프 악티엔게젤샤프트
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Publication of KR900018231A publication Critical patent/KR900018231A/ko
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Publication of KR970008856B1 publication Critical patent/KR970008856B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C08J9/18—Making expandable particles by impregnating polymer particles with the blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2371/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2371/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08J2371/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08J2371/12—Polyphenylene oxides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S521/91—Plural blowing agents for producing nonpolyurethane cellular products

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

입자형태의 발포성 중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. a)20내지 94.9중량%의 스티렌 중합체, b)0.1내지 75중량%의 폴리페닐렌 에테르, c)50:1 내지 1:1의 c1:c2의 중량비로, c1)C1-C7지방족 또는 시클로지방족 포화탄화수소와 c2)C7-C8방향족 포화 탄화수소, C2-C4알콜, C3-C5케톤, C4-C6지방족 에테르, C4-C6에스테르 및/또는 1개 또는 2개 탄소원자와 2개 또는 3개 염소원자의 클로로탄화수소로 이루어지는 5내지20중량%의 발포제 혼합물, 그리고 임의로 d)유효량의 첨가물을 함유하는 것을 특징으로 하는 입자형태의 발포성 중합체.
  2. 제1항에 있어서, 0.2 내지 4mm의 평균입자직경을 갖는 것을 특징으로하는 입자형태의 발포성 중합체.
  3. 제1항에 있어서, 30내지 93중량%의 성분 a)와 2내지 65중량%의 성분 b)를 함유하는 것을 특징으로 하는 입자 형태의 발포성 중합체.
  4. 수성현탁액중의 입자형태로 a)스티렌중합체, b)폴리페닐렌에테르 및 필요하다면 d)유효량의 통상적인 첨가물들의 친밀 혼합물을 100내지 250℃의 온도 및 초대기압하에서, c1) C3-C7지방족 또는 시클로지방족 포화 탄화수소 및 c2)C7-C8방향족 포화 탄화수소, C2-C4알콜, C3-C5케톤, C4-C6고리형 에테르, C4-C6지방족 에테르, C4-C6에스테르 및/또는 1개 또는 2개 탄소원자와 2개 또는 3개 염소원자의 클로로탄화수소로 이루어진 발포제혼합물 c)로 함침함을 특징으로 하는, 제1항에 청구된 입자형태의 발포성 중합체의 제조방법.
  5. 수성현탁액중의 입자형태로 a)스티렌중합체, b)폴리페닐렌에테르 및 필요하다면, d)유효량의 통상적인 첨가물들의 친밀혼합물을 100 내지 250℃의 온도 및 초대기압하에서, c1)C3-C7지방족, 또는 시클로 지방족 포화 탄화수소 및 (2) C7-C8방향족 포환탄화수소 C2-C4알콜, C3-C5케톤, C4-C6고리형 에테르, C4-C6지방족 에테르, C4-C6에스테르 및/또는 1개 또는 2개 탄소원자와 2개 또는 3개 염소원자의 클로로탄화수소로 이루어진 발포제 혼합물 c)로 함침한후, 뜨거운 현탁액을 낮은 압력하의 대기중의 강하시키거나 또는 그 현탁액을 냉각하고 이어서 발포제를 함유하는 입자들을 단리하고 뜨거운 가스로 처리하여 발포시키는 것을 특징으로 하는 5내지 200kg/㎥의 밀도를 갖는 포움 입자들의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890007043A 1988-05-25 1989-05-25 입자형태의 발포성 중합체 KR970008856B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP3817631.9 1988-05-25
DE3817631A DE3817631A1 (de) 1988-05-25 1988-05-25 Expandierbare polymere in partikelform

Publications (2)

Publication Number Publication Date
KR900018231A true KR900018231A (ko) 1990-12-20
KR970008856B1 KR970008856B1 (ko) 1997-05-30

Family

ID=6355027

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890007043A KR970008856B1 (ko) 1988-05-25 1989-05-25 입자형태의 발포성 중합체

Country Status (6)

Country Link
US (1) US4927859A (ko)
EP (1) EP0343473B1 (ko)
JP (1) JP2688248B2 (ko)
KR (1) KR970008856B1 (ko)
DE (2) DE3817631A1 (ko)
ES (1) ES2052808T3 (ko)

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DE3904370A1 (de) * 1989-02-14 1990-08-16 Basf Ag Perlfoermige expandierbare formmassen mit hoher waermeformbestaendigkeit und verfahren zu ihrer herstellung
US5262445A (en) * 1989-09-23 1993-11-16 Basf Aktiengesellschaft Heat distortion resistant, expandable styrene polymers having a high capacity for expansion
US5173514A (en) * 1989-09-23 1992-12-22 Basf Aktiengesellschaft Heat distortion resistant, expandable styrene polymers having a high capacity of expansion
US5064869A (en) * 1989-12-27 1991-11-12 General Electric Company Polyphenlene ether foams from low i.v. polyphenylene ether expandable microparticles
US5091256A (en) * 1989-12-27 1992-02-25 General Electric Company Polyphenylene ether foams from low I.V. polyphenylene ether expandable microparticles
DE4005164A1 (de) * 1990-02-17 1991-08-22 Basf Ag Schaumstoffplatten mit hoher waermeformbestaendigkeit
BR9101167A (pt) * 1990-04-06 1991-11-05 Dow Chemical Co Composicao polimerica espumavel,processo para produzir um produto de espuma e produto de espuma
US5189072A (en) * 1990-04-06 1993-02-23 The Dow Chemical Company Polymeric composition comprising transient foam control agent
CA2041537A1 (en) * 1990-05-30 1991-12-01 Walter R. Harfmann Method for production of styrenic foam using an alcohol-alkane blowing agent composition
US5189071A (en) * 1992-04-06 1993-02-23 The Dow Chemical Company Polymeric composition comprising transient foam control agent
DE4236579A1 (de) * 1992-06-04 1993-12-09 Basf Ag Verfahren zur Herstellung von Schaumstoffplatten mit hoher Druckfestigkeit aus Styrolpolymerisaten
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DE19540420A1 (de) * 1995-10-30 1997-05-07 Bayerische Motoren Werke Ag Formkörper für eine Sonnenblende
JP2001139920A (ja) * 1999-11-16 2001-05-22 Toppan Forms Co Ltd 感圧接着剤組成物およびそれを用いた感圧接着性シート
US6545729B1 (en) * 2000-08-18 2003-04-08 Mitsubishi Digital Electronics America, Inc. Foam cabinetry for electronic devices
US20040209968A1 (en) * 2001-05-07 2004-10-21 Jos Bastiaens Flame retardant expandable poly(arylene ether)/polystyrene compositions and preparation thereof
ITMI20020584A1 (it) * 2002-03-20 2003-09-22 Polimeri Europa Spa Composizioni a base di polimeri vinilaromatici espandibili a migliorata espandibilita'
IT1393962B1 (it) 2009-05-05 2012-05-17 Polimeri Europa Spa Articoli espansi con ottima resistenza allo irraggiamento solare e ottime proprieta' termoisolanti e meccaniche
BRPI1011186A2 (pt) * 2009-08-13 2016-11-29 Asahi Kasei Chemicals Corp contas expandíveis, corpo moldado, e, método de produção para o mesmo

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Also Published As

Publication number Publication date
EP0343473A2 (de) 1989-11-29
KR970008856B1 (ko) 1997-05-30
EP0343473A3 (en) 1990-03-07
US4927859A (en) 1990-05-22
DE3817631A1 (de) 1989-11-30
JP2688248B2 (ja) 1997-12-08
DE58902323D1 (en) 1992-10-29
JPH0218428A (ja) 1990-01-22
EP0343473B1 (de) 1992-09-23
ES2052808T3 (es) 1994-07-16

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