KR900018190A - 저비점 발포제의 존재하에서 우레탄 및 이소시아누레이트 발포체의 제조방법 - Google Patents

저비점 발포제의 존재하에서 우레탄 및 이소시아누레이트 발포체의 제조방법 Download PDF

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Publication number
KR900018190A
KR900018190A KR1019900006514A KR900006514A KR900018190A KR 900018190 A KR900018190 A KR 900018190A KR 1019900006514 A KR1019900006514 A KR 1019900006514A KR 900006514 A KR900006514 A KR 900006514A KR 900018190 A KR900018190 A KR 900018190A
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South Korea
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boiling point
compound
halocarbon
blowing agent
active hydrogen
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KR1019900006514A
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KR0155948B1 (ko
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쟈코부스 마리 그륀바우어 헨리
프레디 스미트 귀도
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리챠드 지. 워터맨
더 다우 케미칼 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/147—Halogen containing compounds containing carbon and halogen atoms only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

내용 없음

Description

저비점 발포제의 존재하에서 우레탄 및 이소시아누레이트 발포체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 유기 폴리이소시아네이트와 활성 수소-함유 화합물을 물 및 발포제의 존재하에서 접촉 및 반응시킴을 포함하여 강성 독립기포 폴리시아네이트계 발포체를 제조함에 있어서, 발포제가 비점이 222K 내지 272K인 1개 이상의 할로카본 화합물을 포함하며 비점이 273K이상인 유기 화합물은 거의 함유하지 않음을 특징으로 하는 방법.
  2. 제1항에 있어서 할로카본 화합물의 비점이 235K 내지 272K인 방법.
  3. 제1항에 있어서, 할로카본이 클로로카본, 브로모카본, 플루오로카본, 클로로플루오로카본 또는 브로모플루오로카본 및 메탄, 에탄 프로판, 에틸렌, 프로필렌, 사이클로알칸 또는 이의 혼합물의 첨가물인 방법.
  4. 제1항 내지 3항중 어느 한 항에 있어서, 할로카본 화합물이 클로로플루오로에탄, 플루오로에탄 또는 이의 혼합물인 방법.
  5. 제4항에 있어서, 클로로플루오로에탄이 클로로펜타플루오로에탄(R-115), 클로로테트라플루오로에탄(R-124 또는 이성체 R-124a)또는 클로로디플루오로에탄(R-142b)인 방법.
  6. 제4항에 있어서, 플루오로에탄이 테트라플루오로 에탄(R-134 또는 이성체 R-134a), 트리플루오로에탄(R-143), 디플루올에탄(R-152a) 또는 플루오로에탄(R-161)인 방법.
  7. 제4항에 있어서, 할로카본 화합물이 클로로 디플루오로에탄(R-142b) 또는 테트라플루오로에탄(R-134) 또는 이성체 (R-134a)인 방법.
  8. 제1항에 내지 7항중 어느 한 항에 있어서, 물이 존재하는 활성 수소-함유 화합물의 총 중량을 기준하여 0.5 내지 10.0중량%로 제공되는 방법.
  9. (a)당량이 50 내지 700인 적어도 1개의 활성 수소-함유 화합물, 및 (b)존재하는 성분(a) 및 (b)의 총중량을 기준하여 1내지 25중량%의 발포제를 포함하는 이소시아네이트 반응성 조성물에 있어서, 발포제가 비점이 222K 내지 272K인 1개 이상의 할로카본 화합물을 포함하며 비점이 273K이상인 유기 화합물은 거의 함유하지 않음을 특징으로하는 조성물.
  10. 유기 폴리이소시아네이트와 활성 수소-함유 화합물을 물 및 발포제의 종재항서 접촉 및 반응시켜 제조한 강성, 독립기포 폴리이소시아네이트계 발포체에 있어서, 생성된 발포체가 그의 기포내에 (a)(a) 및 (b)의 총 몰을 기준하여 비점이 222K 내지 272K 인 적어도 1개의 유기 화합물 10내지 75몰%, 및(b)(a) 및 (b)의 총몰을 기준하여 이산화탄소 25내지 90몰%를 포함하는 가스상 혼합물을 함유함을 특징으로 하는 발포체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900006514A 1989-05-10 1990-05-09 저비점 발포제의 존재하에서 우레탄 및 이소시아누레이트 발포체의 제조방법 KR0155948B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/350,174 US4972003A (en) 1989-05-10 1989-05-10 Foaming system for rigid urethane and isocyanurate foams
US350.174 1989-05-10

Publications (2)

Publication Number Publication Date
KR900018190A true KR900018190A (ko) 1990-12-20
KR0155948B1 KR0155948B1 (ko) 1998-12-01

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KR1019900006514A KR0155948B1 (ko) 1989-05-10 1990-05-09 저비점 발포제의 존재하에서 우레탄 및 이소시아누레이트 발포체의 제조방법

Country Status (18)

Country Link
US (1) US4972003A (ko)
EP (1) EP0398148B1 (ko)
JP (2) JPH037738A (ko)
KR (1) KR0155948B1 (ko)
AR (1) AR244726A1 (ko)
AT (1) ATE164608T1 (ko)
AU (1) AU622023B2 (ko)
BR (1) BR9002194A (ko)
CA (1) CA2016328C (ko)
DD (1) DD297980A5 (ko)
DE (1) DE69032188T2 (ko)
DK (1) DK0398148T3 (ko)
ES (1) ES2113850T3 (ko)
GR (1) GR3026714T3 (ko)
MX (1) MX166373B (ko)
NO (1) NO179178C (ko)
NZ (1) NZ233595A (ko)
TW (1) TW203620B (ko)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3903336A1 (de) * 1989-02-04 1990-08-09 Bayer Ag Verwendung von c(pfeil abwaerts)3(pfeil abwaerts)- bis c(pfeil abwaerts)5(pfeil abwaerts)-polyfluoralkanen als treibgase
GB8919675D0 (en) * 1989-08-31 1989-10-11 Ici Plc Polymeric foams
ES2101686T3 (es) * 1989-12-12 1997-07-16 Solvay Procedimiento para la preparacion de espumas con fluoroalcanos.
US5516811A (en) * 1990-03-23 1996-05-14 E. I. Du Pont De Nemours And Company Polymer foams containing blocking agents
AU7306691A (en) * 1990-03-23 1991-10-21 E.I. Du Pont De Nemours And Company Polymer foams containing gas barrier resins
US6121337A (en) * 1990-03-23 2000-09-19 E. I. Du Pont De Nemours And Company Compositions containing 1,1,2,2-tetrafluoroethane (HFC-134) for closed-cell polymer foam production
US5912279A (en) * 1990-03-23 1999-06-15 E. I. Du Pont De Nemours And Company Polymer foams containing blocking agents
JP3199375B2 (ja) * 1990-03-23 2001-08-20 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 阻止剤を含有する重合体フォーム
EP0526477B1 (en) * 1990-04-25 1994-12-14 E.I. Du Pont De Nemours And Company Halocarbon blends
US5262077A (en) * 1990-04-25 1993-11-16 E. I. Du Pont De Nemours And Company Halocarbon blends
JP3030106B2 (ja) * 1991-02-22 2000-04-10 三洋電機株式会社 低沸点発泡剤のミキシング装置
US5264464A (en) * 1991-04-29 1993-11-23 Basf Corporation On-site generation of polyurethane foam using an HCFC as a sole blowing agent
US5164419A (en) * 1991-05-20 1992-11-17 E. I. Du Pont De Nemours And Company Blowing agent and process for preparing polyurethane foam
US5093377A (en) * 1991-08-19 1992-03-03 E. I. Du Pont De Nemours And Company Blowing agent and process for preparing polyurethane foam
US5112878A (en) * 1991-09-23 1992-05-12 Olin Corporation Catalysts for extending the shelf life of formulations for producing rigid polyurethane foams
JPH05306880A (ja) * 1992-04-10 1993-11-19 Sanyo Electric Co Ltd 硬質ポリウレタンフォームを使用した断熱箱体
SE470464B (sv) * 1992-09-10 1994-04-18 Electrolux Res & Innovation Isolering för kyl- eller frysskåp
WO1994011460A1 (en) * 1992-11-19 1994-05-26 E.I. Du Pont De Nemours And Company Refrigerant compositions including 1,1,2-trifluoroethane
AU5814894A (en) * 1992-12-23 1994-07-19 Solvay (Societe Anonyme) Mixtures useful for preparing a cellular polymeric material
BE1006443A3 (fr) * 1992-12-23 1994-08-30 Solvay Procede de preparation d'un materiau polymerique cellulaire et premelanges utilisables pour la preparation de ce materiau.
CA2107274C (en) * 1992-12-31 1998-11-03 Valeri L. Valoppi 1,1,1,2-tetrafluoroethane as a blowing agent in integral skin polyurethane shoe soles
US5539008A (en) * 1993-12-29 1996-07-23 Minnesota Mining And Manufacturing Company Foamable composition containing unsaturated perfluorochemical blowing agent
US5488072A (en) * 1995-02-06 1996-01-30 Basf Corporation Rigid closed cell polyisocyanate based foams for use as positive flotation materials in watercraft
US5409961A (en) * 1994-07-08 1995-04-25 Basf Corporation Rigid closed cell polyisocyanate based foams for use as positive flotation materials in watercraft
US5470891A (en) * 1995-04-10 1995-11-28 Basf Corporation Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture
US5840212A (en) * 1996-10-23 1998-11-24 Bayer Corporation Rigid foams with improved insulation properties and a process for the production of such foams
EP0882760B1 (en) * 1997-06-03 2003-11-05 Asahi Glass Company Ltd. Method for producing foamed synthetic resin
EP1123341B1 (en) 1998-09-10 2005-04-27 Dow Global Technologies Inc. Polyols useful for preparing water blown rigid polyurethane foam
US5958992A (en) * 1998-11-24 1999-09-28 Elf Atochem North America, Inc. Blowing agent blends
US6136877A (en) * 1999-03-26 2000-10-24 Elf Atochem North America, Inc. 142b/124 blowing agent blends
US6117917A (en) * 1999-04-12 2000-09-12 Elf Atochem North America, Inc. Blowing agent blends and use thereof
US6262136B1 (en) 1999-05-26 2001-07-17 Bayer Corporation Storage stable foam-forming system
US6866923B2 (en) * 2000-11-15 2005-03-15 Atlas Roofing Corporation Thermosetting plastic foams and methods of production thereof using adhesion additives
US20040126564A1 (en) * 2000-11-15 2004-07-01 Atlas Roofing Corporation Thermosetting plastic foams and methods of production thereof using adhesion additives
US6534556B2 (en) 2001-02-20 2003-03-18 Basf Corporation Sprayable autofrothing polyisocyanate foam and delivery system
US6753357B2 (en) * 2001-12-18 2004-06-22 Foam Supplies, Inc. Rigid foam compositions and method employing methyl formate as a blowing agent
JP5286953B2 (ja) * 2002-01-16 2013-09-11 旭硝子株式会社 硬質ポリウレタンフォームの製造方法
US20030213189A1 (en) * 2002-05-16 2003-11-20 Goldman Arthur S. Thermoplastic polymer extrusion bending
KR20070053708A (ko) * 2004-08-04 2007-05-25 포움 서플라이즈 인코포레이션 폴리우레탄 폼에서의 반응도 변동 및 촉매 분해
US20060052468A1 (en) * 2004-09-08 2006-03-09 Chris Janzen Resin composition for use in a froth spraying system
US11208536B2 (en) 2007-03-29 2021-12-28 Arkema Inc. Blowing agent compositions of hydrofluoroolefins and hydrochlorofluoroolefins
US8895635B2 (en) 2007-03-29 2014-11-25 Arkema Inc. Blowing agent compositions of hydrochlorofluoroolefins
US9206297B2 (en) 2007-03-29 2015-12-08 Arkema Inc. Blowing agent compositions of hydrochlorofluoroolefins
US11091602B2 (en) 2007-03-29 2021-08-17 Arkema Inc. Blowing agent compositions of carbon dioxide and hydrochlorofluoroolefins
MX2011007960A (es) 2009-01-29 2011-08-17 Arkema Inc Composiciones para agentes de soplado a base de tetrafluropropeno.
US20100216903A1 (en) 2009-02-20 2010-08-26 Bayer Materialscience Llc Foam-forming system with reduced vapor pressure
KR101031081B1 (ko) * 2009-03-04 2011-04-25 주식회사 포스코 에지히터 보호용 냉각수 차단 장치

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3391093A (en) * 1959-04-01 1968-07-02 Gen Tire & Rubber Co Polyester-polyurethane foams and method of making same
JPS5837331B2 (ja) * 1974-06-17 1983-08-16 ニツポンポリウレタンコウギヨウ カブシキガイシヤ テイハツポウアツポリウレタンフオ−ムノ セイゾウホウホウ
JPS5740533A (en) * 1980-08-22 1982-03-06 Daikin Ind Ltd Foaming agent for polyurethane
US4636529A (en) * 1985-05-13 1987-01-13 Pennwalt Corporation Polyurethane foams from isocyanate, polyester polyol and chlorodifluoromethane
JPH0730311B2 (ja) * 1987-09-21 1995-04-05 ダイキン工業株式会社 冷 媒
JPH01103689A (ja) * 1987-10-15 1989-04-20 Daikin Ind Ltd 冷媒
BR8900726A (pt) * 1988-02-22 1989-10-17 Du Pont Processo para preparacao de uma mistura util na fabricacao de espuma de poliuretano,e espuma de poliuretano
DE3824354A1 (de) * 1988-07-19 1990-01-25 Basf Ag Verfahren zur herstellung von zellhaltigen kunststoffen nach dem polyisocyanat-polyadditionsverfahren mittels lagerstabiler, treibmittelhaltiger emulsionen und diese emulsionen
US5091434A (en) * 1989-04-07 1992-02-25 Asahi Glass Company Ltd. Polyol composition and method for producing a rigid polyurethane foam using the same
DE3913328A1 (de) * 1989-04-22 1990-10-25 Basf Ag Verbundelemente mit verbesserter bestaendigkeit gegen spannungsrisskorrosion, insbesondere fuer kuehlmoebelgehaeuse
JPH02284912A (ja) * 1989-04-27 1990-11-22 Hitachi Ltd 硬質ポリウレタンフォーム及びその製造方法と断熱材並びにそれを用いた冷蔵庫

Also Published As

Publication number Publication date
AU5482690A (en) 1990-11-15
NO179178B (no) 1996-05-13
AR244726A1 (es) 1993-11-30
DK0398148T3 (da) 1999-01-11
NO902046D0 (no) 1990-05-09
US4972003A (en) 1990-11-20
BR9002194A (pt) 1991-08-13
KR0155948B1 (ko) 1998-12-01
MX166373B (es) 1993-01-05
NO902046L (no) 1990-11-12
JPH037738A (ja) 1991-01-14
TW203620B (ko) 1993-04-11
DD297980A5 (de) 1992-01-30
NO179178C (no) 1996-08-21
EP0398148A2 (en) 1990-11-22
CA2016328C (en) 2000-06-27
JP2002234927A (ja) 2002-08-23
EP0398148A3 (en) 1991-03-27
CA2016328A1 (en) 1990-11-10
DE69032188T2 (de) 1998-07-30
NZ233595A (en) 1993-04-28
AU622023B2 (en) 1992-03-26
EP0398148B1 (en) 1998-04-01
ATE164608T1 (de) 1998-04-15
GR3026714T3 (en) 1998-07-31
ES2113850T3 (es) 1998-05-16
DE69032188D1 (de) 1998-05-07

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