KR900006482A - 산화 방지성 히드록시 페닐카르복시산 에스테르 화합물 - Google Patents

산화 방지성 히드록시 페닐카르복시산 에스테르 화합물 Download PDF

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KR900006482A
KR900006482A KR1019890015433A KR890015433A KR900006482A KR 900006482 A KR900006482 A KR 900006482A KR 1019890015433 A KR1019890015433 A KR 1019890015433A KR 890015433 A KR890015433 A KR 890015433A KR 900006482 A KR900006482 A KR 900006482A
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alkyl
phenyl
compound
cycloalkyl
cyclohexyl
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에반스 사무엘
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베르너 발데크
시바 가이기 아게
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Abstract

내용 없음

Description

산화방지성 히드록시페닐카르복시산 에스테르 화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (28)

  1. a) 산화, 열 또는 화학선에 의해 분해되기 쉬운 유기 물질 1이상 및 b) 하기 일반식(I)의 화합물 1이상을 함유하는 조성물;
    상기 식에서, R1은 C1-C18알킬, C5-C12시클로알킬, 페닐 또는 C7-C9아랄킬이고, R2는 -H, C1-C18알킬, C5-C12시클로알킬, 페닐 또는 C7-C9아랄킬이며, 또 R3은 -H 또는 CH3이고, n은 1내지 4 또는 6이며; n이 1일때, A는 -OR4또는이고, R4는 -H, C1-C45알킬, C5-C12시클로알킬, C2-C18알켄일,또는 -CH2-CH2-XR5a이며, R5및 R6각각은 서로 독립적으로 -H, C1-C20알킬, , 페닐, C5-C12시클로알킬, C1-C4알킬에 의해 치환된 C5-C12시클로알킬, C3-C8알켈일, C7-C10아랄 또는이고, 또한 R5는 -NH2이며, R9는 -H, C1-C8알킬,R10, -O' 또는 -OR9'이고, R9'은 -H, C1-C25알킬 또는X는 -O-, -S- 또는이며, R5a는 -H, C1-C24알킬, 페닐, C5-C12시클로알킬 또는이며, R10은 C1-C20이고, Ra는 -H 또는 -CH3이고, Rb는 -H 또는 C1-C24알킬이고, Rc는 -H 또는 -CH3이고, 단 Ra및 Rc는 동시에 -CH3이 아니며, R6a는 C1-C18알킬, 페닐, 총 1내지 24개의 탄소원자를 갖는 1이상의 알킬기에 의해 치환된 페닐, 또는 C5-C8시클로알킬이고; 또는 n이 2일때, A는 -O-CxH2x-O-, -O-(CH2CH2O)aCH2CH2O-, -O-CH2-CH2-B-CH2-CH2-O-,
    이고, a는 1내지 30이고, x는 2내지 20이며, B는 -S-,또는이고, RA는 C1-C20알킬, 페닐, 총 1내지 20개의 탄소원자를 갖는 1이상의 알킬기에 의해 치환된 페닐, 시클로헥실 또는이고, R11, R12및 R13각각은 서로 독립적으로 -H, C1-C12알킬 또는 페닐이고, 또는 R12및 R13은 그들이 결합되어 있는 탄소원자와 함께 C5-C12시클로알킬 고리를 형성하며, b1은 2 내지 10이고, b2는 0내지 6이며; 또는 n이 3일때, A는또는이고; 또는 n이 4일때, A는이고; 또는 n이 6일때, A는이다.
  2. 제1항에 있어서, R1은 C1-C18알킬, C5-C12시클로알킬, 페닐 또는 벤질이고 R2가 -H, C1-C18알킬, C5-C12시클로알킬, 페닐 또는 벤질이고, R3이 -H이고, 또 n이 1내지 4 또는 6이며; n이 1일때, A는 -OR4또는이고, R4가 -H, C1-C20알킬, 시클로헥실, C2-C18알켄일 또는 -CH2CH2-XR5a이며, R5가 -H, C1-C12알킬, 페닐, 시클로헥실, C1-C4알킬에 의해 치환된 C5-C12시클로알킬, C3-C8알켄일, 벤질 또는 -NH2이며, R6이 -H 또는 C1-C12알킬이고, X가 -O-, -S- 또는이며, R5a가 -H, C1-C12알킬, 페닐, 시클로헥실 또는이며, R6a가 C1-C12알킬, 페닐 또는 총 1 내지 18개의 탄소 원자를 갖는 1이상의 알킬기에 의해 치환된 페닐이고; 또는 n이 2일때, A는 -O-CxH2x-O-, -O-(CH2CH2O)aCH2CH2O-, -O-CH2-CH2-B-CH2-CH2-O-,
    이고, a가 1내지 12이며, x가 2내지 12이고, B는 -S- 또는이고, RA는 C1-C12알킬, 페닐, 총 1내지 18개의 탄소원자를 갖는 1이상의 알킬기에 의해 치환된 페닐이고, R11이 -H, C1-C12알킬 또는 페닐이며, b1은 2 내지 6이고, b2는 0내지 6이며; 또는 n이 3일때, A가또는이고; 또는 n이 4일때, A가이고; 또는 n이 6일때, A가인 일반식(I)의 화합물 1이상을 함유하는 조성물.
  3. 제1항에 있어서, R1이 C1-C8알킬, 시클로헥실 또는 페닐이고, R2가 -H, C1-C8알킬, 시클로헥실 또는 페닐이고, R3이 -H이며, 또n이 1이고, A가 -OR4또는이고, R4는 -H, C1-C18알킬, 시클로헥실, -CH2CH=CH2, -(CH2)7-CH=CH-(CH2)7CH3,또는 -CH2-CH2-XR5a이며, R~가 -H, C1-C4알킬, -O; -O-C1-C4알킬 또는 시클로헥실이고, X가 -O-, -S- 또는이며, R5a가 -H, C1-C18알킬, 페닐,또는이며, Rb가 C1-C24알킬이고, Ra가 -H 또는 -CH3이며, Rc가 -H이고, R6a가 -H이고, R6a가 C1-C12알킬 또는 페닐이고, R5및 R6각각은 서로 독립적으로 -H, C1-C12알킬, 페닐 또는이고, R9가 상기에서 정의된 바와 같으며, 또는 Rb가 -NH2이고, R6이 -H이며; 또는 n이 2일때, 또는 n이 2일때, A는 -O-CxH2x-O-이고,x가 2 내지 8인 일반식(I)의 화합물 1이상을 함유하는 조성물.
  4. 제1항에 있어서, R1이 3급-부틸이고, R2가 -H, 메틸 또는 3급-부틸이며, R3이 -H이고, 또n이 1인경우, A가 -OR4또는이고, R4가 C1-C18알킬, -(CH2)7-CH=CH-(CH2)7CH3,또는 -CH2-CH2-SR5a이며, R5a가 -H 또는이고, Rb가 n-C4H9내지 n-C8H17또는 3급-C4H9내지 3급 -C8H17이며; 또는n이 2인 경우, A가 -O-CxH2x-O-이고,x가 2 내지 8이며; 또는 A가 -O-(CH2-CH2-O)a-CH2-CH2-O이고,a가 1 내지 4이며; 또는 A가 -O-CH2-CH2-B-CH2-CH2-O-이며, B가 -S-,또는이고, RA가 C4-C8알킬 또는 페닐이며, R12가 H 또는 C1-C8알킬이고, R13이 H, C1-C8알킬 또는 페닐이고; 또는 A가이고,b 1은 2 내지 6이며, A가 -O-CH2-CH=CH-CH2-O-, -O-CH2-C=C-CH2-O-,
    이며,
    b 2가 0 내지 6이며, 또 R11이 -H 또는 C1-C8알킬인 일반식(I)의 화합물 1이상을 함유하는 조성물.
  5. 제1항에 있어서, R1이 3급 부틸이고, R2가 -H, -CH3또는 3급-부틸이며, R3이 -H이고, 또 n이 1인경우, A가 -OR4이며, R4가 C1-C18알킬인 일반식(I)의 화합물 1이상을 함유하는 조성물.
  6. 제1항에 있어서, R1이 3급 부틸이고, R2가 -H, -CH3또는 3급-부틸이며, R3이 -H이고,n이 2이고, A는 -O-CxH2x-O-이고,x가 2내지 6이며, 또는 A가 -O-(CH2-CH2-O)-CH2-CH2-O-이고,a가 1 내지 3이며; 또는 A가 -O-(CH2-CH2-O)a-CH2-CH2-O-이고,a가 1내지 3이며; 또는 A가 -O-CH2-CH2-B-CH2-CH2-O-이며, B가 -S- 또는이며, 또는 A가이고; 또는 A가 -NH-NH인 일반식(I)의 화합물 1이상을 함유하는 조성물.
  7. 제1항에 있어서, R1이 3급 부틸이고, R2가 -H, -CH3또는 3급-부틸이며, R3이 -H이고, n이 1이고, A가 -OR4이며, R4가 C1-C18알킬이고; 또는 n이 2이고, A가 -O-CxH2x-O-이고, x가 2 내지 6이고; 또는 A가 -OCH2CH2-S-CH2CH2O- 또는 -O(CH2CH2O)aCH2CH2-O-이고, a가 1내지 4인 일반식(I)의 화합물 1이상을 함유하는 조성물.
  8. 제7항에 있어서, a가 1또는 일반식(I)의 화합물 1이상을 함유하는 조성물.
  9. 제1항에 있어서, R1이 3급 부틸이고, R2가 -H, -CH3또는 3급-부틸이며, R3이 -H이고, 또 n이 3이고, A가이며; 또는 n이 4이고, A가이고; 또는 n이 6이고, A가인 일반식(I)의 화합물 1이상을 함유하는 조성물.
  10. 제1항에 있어서, 하기 일반식 계열의 화합물 1이상을 함유하는 조성물 :
    상기식에서, R4는 C1-C18알킬이다.
  11. 제1항에 있어서, a) 윤활제, 작동액 및 금속 탈활성화제로부터의 기능액 또는 합성 중합체 및 b) 제1항에 따른 일반식(I)의 화합물 1이상을 함유하는 조성물.
  12. 제1항에 있어서, a) 광물유, 합성유 또는 이들의 혼합물로부터의 윤활제 및 b) 제1항에 따른 일반식(I)의 화합물 1이상을 함유하는 조성물.
  13. 제1항에 있어서, 제10항에 따른 화합물 1이상을 함유하는 조성물.
  14. 제1항에 있어서, a) 합성 중합체 및 b) 제1항에 따른 일반식(I)의 화합물 1이상을 함유하는 조성물.
  15. 제14항에 있어서, a) 폴리올레핀 및 b) 제1항에 따른 일반식(I)의 화합물 1이상을 함유하는 조성물.
  16. 하기 일반식(Ia)의 화합물 :
    상기식에서, R1은 C1-C18알킬, C5-C12시클로알킬, 페닐 또는 C7-C9아랄킬이고, R2는 -H, C1-C18알킬, C5-C12시클로알킬, 페닐 또는 C7-C9아랄킬이며, 또 R3은 -H 또는 CH3이고, n은 1내지 4 또는 6이며; n이 1일때, A는 -OR4또는이고, R4는 -H, C1-C45알킬, C5-C12시클로알킬, C2-C18알켄일,또는 -CH2-CH2-XR5a이며, R5및 R6각각은 서로 독립적으로 -H, C1-C20알킬, , 페닐, C5-C12시클로알킬, C1-C4알킬에 의해 치환된 C5-C12시클로알킬, C3-C8알켄일, C7-C10아랄킬 또는 이고, 또한 R5는 -NH2이며, R9는 -H, C1-C8알킬,-O' 또는 -OR9'이고, R9'은 -H, C1-C25알킬 또는이고, X는 -O-, -S- 또는이며, R5a는 -H, C1-C24알킬, 페닐, C5-C12시클로알킬 또는이며, R10은 C1-C20이고, Ra는 -H 또는 -CH3이고, Rb는 -H 또는 C1-C24알킬이고, Rc는 -H 또는 -CH3이고, 단 Ra및 Rc는 동시에 -CH3이 아니며, R6a는 C1-C18알킬, 페닐, 총 1내지 24개의 탄소원자를 갖는 1이상의 알킬기에 의해 치환된 페닐, 또는 C5-C8시클로알킬이고; 또는 n이 2일때, A는 -O-CxH2x-O-, -O-(CH2CH2O)aCH2CH2O-, -O-CH2-CH2-B-CH2-CH2-O-,
    이고, a는 1내지 30이고, x는 2내지 20이며, B는 -S-,
    또는이고, RA는 C1-C20알킬, 페닐, 총 1내지 20개의 탄소원자를 갖는 1이상의 알킬기에 의해 치환된 페닐, 시클로헥실 또는이고, R11, R12및 R13각각은 서로 독립적으로 -H, C1-C12알킬 또는 페닐이고, 또는 R12및 R13은 그들이 결합되어 있는 탄소원자와 함께 C5-C12시클로알킬 고리를 형성하며, b1은 2 내지 10이고, b2는 0내지 6이며; 또는 n이 3일때, A는또는이고; 또는 n이 4일때, A는이고; 또는 n이 6일때, A는이다.
  17. 제16항에 있어서, R1이 C1-C18알킬, C5-C12시클로알킬, 페닐 또는 벤질이고 R2가 -H, C1-C18알킬, C5-C12시클로알킬, 페닐 또는 벤질이고, R3이 -H이고, 또 n이 1내지 4 또는 6이며; n이 1일때, A는 -OR4또는이고, R4가 -H, C1-C20알킬, 시클로알킬, C2-C18알켄일 또는 -CH2CH2-XR5a이며, R5가 -H, C1-C12알킬, 페닐, 시클로헥실, C1-C4알킬에 의해 치환된 C5-C12시클로알킬, C3-C8알켄일, 벤질 또는 -NH2이며, R6이 -H 또는 C1-C12알킬이고, X가 -O-, -S- 또는이며, R5a가 -H, C1-C12알킬, 페닐, 시클로헥실 또는이며, R6a가 C1-C12알킬, 페닐 또는 총 1 내지 18개의 탄소 원자를 갖는 1이상의 알킬기에 의해 치환된 페닐이고; 또는 n이 2일때, A는 -O-CxH2x-O-, -O-(CH2CH2O)aCH2CH2O-, -O-CH2-CH2-B-CH2-CH2-O-,
    a가 1내지 12이며, x가 2내지 12이고, B가 -S- 또는이고, RA가 C1-C12알킬, 페닐, 총 1내지 18개의 탄소원자를 갖는 1이상의 알킬기에 의해 치환된 페닐이고, R11이 -H, C1-C12알킬 또는 페닐이며, b1은 2 내지 6이고, b2는 0내지 6이며; 또는 n이 3일때, A가또는이고; 또는 n이 4일때, A가이고; 또는 n이 6일때, A가인 일반식(Ia)의 화합물.
  18. 제16항에 있어서, R1이 C1-C8알킬, 시클로헥실 또는 페닐이고, R2가 -H, C1-C8알킬, 시클로헥실 또는 페닐이고, R3이 -H이며, 또 n이 1이고, A가 -OR4또는이고, R4는 -H, C1-C18알킬, 시클로헥실, -CH2CH=CH2, -(CH2)7-CH=CH-(CH2)7CH3,또는 -CH2-CH2-XR5a이며, R9가 -H, C1-C4알킬, -O, -O-C1-C4알킬 또는 시클로헥실이고, X가 -O-, -S- 또는이며, R5a가 -H, C1-C18알킬, 페닐,
    이며, Rb가 C1-C24알킬이고, Ra가 -H 또는 -CH3이며, Rc가 -H이고, R6a가 -H이고, R6a가 C1-C12알킬 또는 페닐이고, R5및 R6각각은 서로 독립적으로 -H, C1-C12알킬, 페닐 또는이고, R9가 상기에서 정의된 바와 같으며, 또는 R5가 -NH2이고, R6이 -H이며; 또는 n이 2일때, A가 -O-CxH2x-O-이고, x가 2 내지 8인 일반식(Ia)의 화합물.
  19. 제16항에 있어서, R1이 3급-부틸이고, R2가 -H, -CH3또는 3급-부틸이며, R3이 -H이고, n이 1인경우, A가 -OR4또는이고, R4가 C6-C18알킬, -(CH2)7-CH=CH-(CH2)7CH3,또는 -CH2CH2-SR5a이며, R5a가 -H 또는이고, Rb가 n-C4H9내지 n-C8H17또는 3급-C4H9내지 3급 -C8H17이며; 또는 n이 2인 경우, A가 -O-CxH2x-O-이고, x가 2 내지 8이며; 또는 A가 -O-(CH2-CH2-O)a-CH2-CH2-O이고, a가 1 내지 4이며; 또는 A가 -O-CH2-CH2-B-CH2-CH2-O-이며, B가 -S-,또는이고, RA가 C4-C8알킬 또는 페닐이며, R12가 H 또는 C1-C8알킬이고, R13이 H, C1-C8알킬 또는 페닐이고; 또는 A가
    이고, b1은 2 내지 6이며, 또는 A가 -O-CH2-CH=CH-CH2-O-, -O-CH2-C=C-CH2-O-,
    이며, b2가 0 내지 6이며, 또 R11이 -H 또는 C1-C8알킬인 일반식(Ia)의 화합물.
  20. 제16항에 있어서, R1이 3급 부틸이고, R2가 -H, -CH3또는 3급-부틸이며, R3이 -H이고, n이 1이고, A가 -OR4이고, R4가 C6-C18알킬인 일반식(Ia)인 화합물.
  21. 제16항에 있어서, R1이 3급 부틸이고, R2가 -H, -CH3또는 3급-부틸이며, R3이 -H이고, n이 2이고, A는 -O-CxH2x-O-이고, x가 2내지 6이며, 또는 A가 -O-(CH2-CH2-O)-CH2-CH2-O-이고, a가 1 내지 3이며; 또는 A가 -O-(CH2-CH2-O)a-CH2-CH2-O-이고, B가 -S- 또는이며, 또는 A가이고; 또는 A가 -NH-NH인 일반식(Ia)의 화합물.
  22. 제16항에 있어서, R1이 3급 부틸이고, R2가 -H, -CH3또는 3급-부틸이며, R3이 -H이고, n이 1이고, A가 -OR4이며, R4가 C1-C18알킬이고; 또는 n이 2이고, A가 -O-CxH2x-O-이고, x가 2 내지 8이고; 또는 A가 -OCH2CH2-S-CH2CH2O- 또는 -O(CH2CH2O)aCH2CH2-O-이고, a가 1내지 4인 일반식(Ia)의 화합물.
  23. 제22항에 있어서, a가 1 또는 2인 일반식(Ia)인 화합물.
  24. 제16항에 있어서, R1이 3급 부틸이고, R2가 -H, -CH3또는 3급-부틸이며, R3이 -H이고, 또 n이 3이고, A가이며; 또는 n이 4이고, A가이고; 또는 n이 6이고, A가인 일반식(Ia)의 화합물.
  25. 제16항에 있어서, R4가 C9-C18알킬인 일반식(Ia)의 화합물.
  26. 제16항에 있어서, 하기 일반식 계열의 화합물.
    상기식에서, R4는 C8-C18알킬이다.
  27. 제1항에 따른 일반식(I)의 화합물 1이상을 산화, 열 또는 화학선에 의해 분해에 민감한 유기 물질에 혼입시킴으로써 언급한 유기 물질의 산화방지 특성을 개선시키는 방법.
  28. 제1항에 따른 일반식(I)의 화합물 1이상을 윤활제에 혼입시킴으로써 언급한 윤활제의 산화 방지 특성을 개선시키는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890015433A 1988-10-25 1989-10-25 산화 방지성 히드록시 페닐카르복시산 에스테르 화합물 KR900006482A (ko)

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KR100530092B1 (ko) * 1997-02-03 2006-03-17 시바 스페셜티 케미칼스 홀딩 인크. 연료윤활성을증진시키기위한액체다관능성첨가제

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EP0415883A3 (en) * 1989-08-28 1991-08-21 Ciba-Geigy Ag Stabilizers for colour photographic materials
US5177246A (en) * 1989-10-02 1993-01-05 Ciba-Geigy Corporation Hydroxphenylcarboxylic acid esters as stabilizers
EP1457545A3 (en) 1992-11-24 2004-12-22 Commonwealth Scientific And Industrial Research Organisation Oxygen scavengers independent of transition metal catalysts
JP3401348B2 (ja) * 1994-12-07 2003-04-28 新日本石油株式会社 潤滑油組成物
US5912212A (en) * 1995-12-28 1999-06-15 Nippon Oil Co., Ltd. Lubricating oil composition
US7645726B2 (en) * 2004-12-10 2010-01-12 Afton Chemical Corporation Dispersant reaction product with antioxidant capability
WO2006111234A1 (de) * 2005-04-19 2006-10-26 Merck Patent Gmbh Uv schutz
JP5970291B2 (ja) 2012-08-20 2016-08-17 出光興産株式会社 潤滑油組成物
CN114195659B (zh) * 2021-11-30 2023-11-24 天集化工助剂（沧州）有限公司 一种多酚型抗氧剂及其制备方法和应用

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3644482A (en) * 1961-10-30 1972-02-22 Geigy Ag J R (4-hydroxy-5-alkylphenyl) alkanoic acid esters of polyols
US4529809A (en) * 1983-08-29 1985-07-16 General Electric Company Method for production of aryl substituted esters

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100530092B1 (ko) * 1997-02-03 2006-03-17 시바 스페셜티 케미칼스 홀딩 인크. 연료윤활성을증진시키기위한액체다관능성첨가제

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DE58903802D1 (de) 1993-04-22
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MX18065A (es) 1993-09-01
AU4363289A (en) 1990-05-10
DD288830A5 (de) 1991-04-11
CA2001241A1 (en) 1990-04-25
AU630631B2 (en) 1992-11-05
RU1826989C (ru) 1993-07-07
JPH02209843A (ja) 1990-08-21
EP0366040B1 (de) 1993-03-17
ZA898041B (en) 1990-07-25
EP0366040A1 (de) 1990-05-02

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