KR900004869A - 가요성 피막용 중합체 조성물 - Google Patents

가요성 피막용 중합체 조성물 Download PDF

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KR900004869A
KR900004869A KR1019890012611A KR890012611A KR900004869A KR 900004869 A KR900004869 A KR 900004869A KR 1019890012611 A KR1019890012611 A KR 1019890012611A KR 890012611 A KR890012611 A KR 890012611A KR 900004869 A KR900004869 A KR 900004869A
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polymer component
reactive polymer
composition
molecular weight
average molecular
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KR0145078B1 (ko
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브랜돈 윌슨 브루스
에드워드 그룬징거 레인몬드
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도날드 밀러 셀
미네소타 마이닝 앤드 매뉴팩츄어링 컴패니
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    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F13/00—Illuminated signs; Luminous advertising
    • G09F13/16—Signs formed of or incorporating reflecting elements or surfaces, e.g. warning signs having triangular or other geometrical shape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/126—Reflex reflectors including curved refracting surface
    • G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/913—Material designed to be responsive to temperature, light, moisture
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/903—Interpenetrating network
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y10T428/24868—Translucent outer layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y10T428/24868—Translucent outer layer
    • Y10T428/24876—Intermediate layer contains particulate material [e.g., pigment, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31688—Next to aldehyde or ketone condensation product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31692—Next to addition polymer from unsaturated monomers
    • Y10T428/31699—Ester, halide or nitrile of addition polymer

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Theoretical Computer Science (AREA)
  • Materials Engineering (AREA)
  • Geometry (AREA)
  • Organic Chemistry (AREA)
  • Optics & Photonics (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Illuminated Signs And Luminous Advertising (AREA)
  • Road Signs Or Road Markings (AREA)

Abstract

내용 없음

Description

가요성 피막용 중합체 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 따라 렌즈내장역반사피막을 가지는 번호판의 정면도.
제2도는 제1도에 도시한 번호판의 측면도.
제3도는 제1도의 3-3선을 따라 취한 횡단면의 확대도.

Claims (20)

  1. 반투입중합체 네트웍을 포함하는 가요성의 칫수적으로 안정한 피막을 제조하는데 사용하기 위한 경화성조성물에 있어서, 상기 조성물이 하기 (a) 및 (b)로 구성되는 조성물: (a) 반응성 중합체 성분, 및 (b) 약 7,000 내지 약 30,000의 중량평균분자량을 가지며, 상기 조성물의 경화시에 적어도 40%가 추출가능한 비반응성중합체성분.
  2. 제1항에 있어서, 상기 비반응성 중합체성분이 가소제인 조성물.
  3. 제1항에 있어서, 상기 조성물이 적어도 2작용성이며 아미노플라스트수지로 구성되는 가교결합제를 포함하는 조성물.
  4. 제3항에 있어서, 상기 가교결합제가 메톡시메틸화 멜라민인 조성물.
  5. 제1항에 있어서, 상기 반응성 중합체성분이 약 30,000 내지 200,000의 중량 평균 분자량과 100 내지 200의 히드록실수를 가지는 중합체 물질인 조성물.
  6. 제5항에 있어서, 상기 반응성 중합체성분이 폴리비닐 아세탈, 아크릴공중합체, 폴리우레탄, 폴리에스테르, 폴리아미드, 폴리에스테르-아미드 및 이들의 혼합물로 이루어지는 군에서 선택되는 조성물.
  7. 제6항에 있어서, 상기 반응성 중합체가 폴리비닐부티랄물질인 조성물.
  8. 제1항에 있어서, 상기 비반응성 중합체성분이 폴리카프로락톤 물질인 조성물.
  9. 제1항에 있어서, 상기 조성물이 (a) 약 55-95중량%의 반응성 중합체성분과, (b) 약 5-25중량%의 비반응성 중합체성분을 포함하는 조성물.
  10. 제9항에 있어서, 상기 가교결합제가 조성물의 5-15중량%의 분량이 존재하며 아미노플라스트수지, 아지리딘, 에폭시수지, 이소시아네이트, 알데히드, 아즈락톤 및 이들의 혼합물로 이루어지는 군에서 선택되는 조성물.
  11. 하기 (a),(b) 및 (c)의 열경화 반응생성물인 반투입 중합체 네트웍으로 구성되는 가요성 경화수지: (a) 반응성 중합체성분, (b) 상기 반응성 중합체성분과의 반응에 대하여 적어도 2작용성인 가교결합제, 및 (c) 약 7,000 내지 30,000의 중량평균분자량을 가지는 비반응성 중합체성분.
  12. 제11항에 있어서, 상기 반응성 중합체성분이 폴리비닐 부티랄 중합체인 수지.
  13. 제11항에 있어서, 상기 비반응성 중합체성분이 폴리카프로락톤 중합체인 수지.
  14. 제13항에 있어서, 상기 가교결합제가 아미노플라스트수지, 아지리딘, 에폭시수지, 이소시아네이트, 알데히드, 아즈락톤 및 이들의 혼합물로 이루어지는 군에서 선택되는 방법.
  15. 공간피막을 포함하는 렌즈매립역반사시이트에 있어서, 상기 공간피막이 하기 (a),(b) 및 (c)를 함유하는 반투입중합체 네트웍으로 구성되는 역반사시이트: (a) 가교결합된 반응성 중합체성분, (b) 반응성 중합체성분과의 반응에 대하여 적어도 2작용성인 가교결합체, 및 (c) 약 7,000 내지 30,000의 중량평균분자량을 가지는 비반응성 중합체성분.
  16. 제15항에 있어서, (a) 상기 가교결합제가 아미노플라스트 수지이고, (b) 상기 반응성 중합체성분이 폴리비닐아세탈물질로 구성되고 (c) 상기 비반응성 중합체성분이 중량평균분자량 15,000당 약 10 이하의 작용성 히드록시기를 가지는 폴리카프로락톤 중합체인 역반사시이트.
  17. 제16항에 있어서, (a) 상기 가교결합제가 메톡시 메틸화 멜라민이고, (b) 상기 반응성 중합체성분이 폴리비닐부티랄이고, (c) 상기 비반응성 중합체성분이 히드록시말단 폴리카프로락톤 중합체인 역반사시이트.
  18. 하기 (a) 및 (b)로 구성되는 부각가능한 번호판 구조물: (a) 번호판 기판, 및 (b) 상기 번호판에 접착되며, (i) 가교결합된 반응성 중합체성분, (ii) 반응성 중합체성분과의 반응에 대하여 적어도 2작용성인 가교결합제, 및 (iii) 약 7,000 내지 30,000의 중량평균 분자량을 가지는 비반응성 중합체성분을 함유하는 반투입 중합체 네트웍으로 구성되는 역반사시이트.
  19. 제18항에 있어서, (a) 상기 가교결합제가 아미노플라스트 수지이고, (b) 상기 반응성 중합체성분이 폴리비닐아세탈물질로 구성되고, (c) 상기 비반응성 중합체성분이 중량평균분자량 15,000당 약 10 이하의 작용성 히드록시기를 가지는 폴리카프로락톤인 구조물.
  20. 하기 단계 (a),(b) 및 (c)로 구성되는 부각가능한 기판의 역반사시이트용 공간피막을 형성시키는 방법: (a) 상기 공간피막을 제조하기 위한 수지로서 (i) 폴리비닐아세탈물질로 구성되는 반응성 중합체성분, (ii) 중량평균분자량 15,000당 약 10 이하의 작용성 히드록시기와, 약 7,000 내지 약 30,000의 중량평균분자량을 가지며, 경화후에 적어도 40%가 추출가능한 폴리카프로락톤으로 구성되는 비반응성 중합체성분, 및 (iii) 적어도 2작용성인 가교결합제를 포함하는 반-IPN을 준비하는 단계, (b) 상기 수지를 공간피막으로서 도포하는 단계, 및 (c) 상기 수지를 열경화시키는 단계.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890012611A 1988-09-02 1989-09-01 가요성피막용 중합체 조성물 KR0145078B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US239950 1988-09-02
US07/239,950 US5008142A (en) 1988-09-02 1988-09-02 Embedded lens retroreflective sheeting with flexible, dimensionally stable coating

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KR900004869A true KR900004869A (ko) 1990-04-13
KR0145078B1 KR0145078B1 (ko) 1998-07-15

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US (1) US5008142A (ko)
EP (1) EP0360420B1 (ko)
JP (2) JP3038218B2 (ko)
KR (1) KR0145078B1 (ko)
AT (1) ATE136124T1 (ko)
AU (1) AU619878B2 (ko)
CA (1) CA1336300C (ko)
DE (1) DE68926081T2 (ko)
IE (1) IE73485B1 (ko)
ZA (1) ZA895913B (ko)

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IE73485B1 (en) 1997-06-04
US5008142A (en) 1991-04-16
EP0360420B1 (en) 1996-03-27
IE892485L (en) 1990-03-02
JP3038218B2 (ja) 2000-05-08
CA1336300C (en) 1995-07-11
JPH02113078A (ja) 1990-04-25
KR0145078B1 (ko) 1998-07-15
AU619878B2 (en) 1992-02-06
JP3250615B2 (ja) 2002-01-28
DE68926081D1 (de) 1996-05-02
EP0360420A3 (en) 1992-04-01
AU3923489A (en) 1990-03-08
JPH11288231A (ja) 1999-10-19
ATE136124T1 (de) 1996-04-15
EP0360420A2 (en) 1990-03-28
DE68926081T2 (de) 1996-11-28
ZA895913B (en) 1990-05-30

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