KR900004253A - 식물 병원성 진균을 제어하는 방법 및 살진균 조성물 - Google Patents
식물 병원성 진균을 제어하는 방법 및 살진균 조성물 Download PDFInfo
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- KR900004253A KR900004253A KR1019890013030A KR890013030A KR900004253A KR 900004253 A KR900004253 A KR 900004253A KR 1019890013030 A KR1019890013030 A KR 1019890013030A KR 890013030 A KR890013030 A KR 890013030A KR 900004253 A KR900004253 A KR 900004253A
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- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
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- C07D207/33—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals, directly attached to ring carbon atoms
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- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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Abstract
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Claims (10)
- 하기 일반식(Ⅰ)을 갖는, 살진균하는데에 효과적인량의 화합물과 식물 병원성 진균을 접촉시키는 것으로 구성되는, 식물 병원성 진균을 제어하는 방법:상기식에서, X는 H, F, Cl, Br, I 또는 CF3이고 ; Y는 H, F, Cl, Br, I, CF3또는 CN이며 ; W는 CN 또는 NO2이고 ; A는 H ; 하나의 할로겐 치환제로 임의 치환된 하나의 벤질옥시, 1-3개의 할로겐 원자로 임의 치환된 하나의 페녹시, 1-3개의 할로겐 원자로 또는 C1-3알콕시 또는 C1-3알킬로 임의 치환된 하나의 페닐 또는 1-3개의 할로겐 원자, 하나의 히드록시, 하나의 C1-4알콕시 또는 하나의 C1-4알킬티오도 임의 치환된 C1-4알킬 ; C1-4카르브알콕시메틸 ; 1-3개의 할로겐 원자로 임의 치환된 C3-4알케닐 ; 시아노 ; 하나의 할로겐 원자로 임의 치환된 C3-4알케닐 ; 디-(C1-4알킬)아미노 카르보닐 ; 또는 C4-6시클로알킬아미노카르보닐이며 ; L은 H, F, Cl 또는 Br 이고 ; M과 R은 각각 독립적으로 H, C1-3알킬, C1-3알콕시, C1-3알킬티오, C1-3알키설피닐, C1-3알키설포닐, 시아노, F, Cl, Br, I, 니트로, CF3, R1CF2Z, R2CO 또는 NR3R4이며, M과 R이 근접한 위치상에서 탄소 원자에 부착되었을 때 이들은, MR이 -OCH2O-, OCF2O-또는를 나타내는 고리를 형성할 수 있으며 ; Z는 S(O)o또는 O이고 ; R1은 H, F, CHF2, CHFCl 또는 CF3이며 ; R2는 C1-3알킬, C1-3알콕시 , 또는 NR3R4이고 ; R3는 H 또는 C1-3알킬, 또는 R5CO이고 ; R5는 H 또는 C1-3알킬이며; R4는 H, C1-3알킬이며 ; n은 정수 0, 1 또는 2이고, 단, X 또는 Y 또는 둘다가 H일때는,가 질소원자에 근접한 피롤 고리 상의 두 위치를 하나에 고정되어야만 하고 ; W가 시아노이고 X와 Y가 모두 H일때는, L, M 및 R중 최소한 하나가 H이외의 것이고 ; W가 NO2이고 A가 C1-4알킬이고 X 또는 Y가 Cl일때는 M도 R도 C1-3알콕시가 아니다.
- 제1항에 있어서, 실물 병원성 진균이 오이 노균병(露菌病), 토마토 고조병(枯凋病), 도열병, 밀잎 녹병, 사과 반점병, 포도 노균병, 밀 흰가루병 또는 토양전파성 질병에 대한 원인제인 방법.
- 제1항에 있어서, 화합물이 하기 일반식 :을 갖는 방법.
- 하기 일반식(Ⅰ)을 갖는, 살진균하는데에 효과적인량의 화합물을 오이, 토마토, 사과, 포도, 밀, 벼와 같은 식물에 적용하는 것으로 구성되는, 오이 노균병, 토마토 고조병, 사과 반점병, 포도 노균병, 밀 흰가루병, 도열병 또는 밀잎녹병에 대한 원인제인 식물병원성 진균에 의한 공격으로부터 농작물을 보호하는 방법 :상기식에서, X는 H, F, Cl, Br, I또는 CF3이고 : Y는 H, F, Cl, Br, I, CF3또는 CN이며 ; W는 CN또는 NO2이고 ; A는 H ; 하나의 할로겐 치환체인 임의 치환된 하나의 벤질옥시, 1-3개의 할로겐 원자로 임의 치환된 하나의 페녹시, 1-3개의 할로겐 원자로 또는 C1-3알콕시 또는 C1-3알킬로 임의 치환된 하나의 페닐 또는 1-3개의 할로겐 원자, 하나의 히드록시, 하나의 C1-4알콕시 또는 하나의 C1-4알킬티오도 임의 치환된 C1-4알킬 ; C1-4카르브알콕시메틸 ; 1-3개의 할로겐 원자로 임의 치환된 C3-4알케닐 ; 시아노 ; 하나의 할로겐 원자로 임의 치환된 C3-4알키닐 ; 디-(C1-4알킬)아미노카르보닐 ; 또는 C4-6시클로 알킬아미노 카르보닐이며 ; L은 H, F, Cl 또는 Br이고 ; M과 R은 각각 독립적으로 H, C1-3알킬, C1-3알콕시, C1-3알킬티오, C1-3알키설피닐, C1-3알키설포닐, 시아노, F, Cl, Br, I, 니트로, CF3, R1CF2Z, R2CO 또는 NR3R4이며, M과 R이 근접한 위치상에서 탄소 원자에 부착되었을때 이들은, MR이 -OCH2, OCF2O-또는를 나타내는 고리를 형성할 수 있으며 ; Z는 S(O)n또는 O이고 ; R1은 H, F, CHF2, CHFCl 또는 CF3이며 ; R2는 C1-3알킬, C1-3알콕시 , 또는 NR3R4이고 ; R3는 H 또는 C1-3알킬이며 ; R4는 H, C1-3알킬, 또는 R5CO이고 ; R5는 H 또는 C1-3알킬이며 ; n은 정수 0, 1 또는 2이고, 단, X 또는 Y 또는 둘다가 H일때는,가 질소원자에 근접한 피롤 고리 상의 두 위치 중 하나에 고정되어야만 하고 ; W가 시아노이고 X와 Y가 모두 H일때는, L, M 및 R중 최소한 하나가 H이외의 것이고 ; W가 NO2이고 A가 C1-4알킬이고 X 또는 Y가 Cl일때는 M도 R도 C1-3알콕시가 아니다.
- 제4항에 있어서, 화합물이 하기 일반식 :을 갖는 방법.
- 하기 일반식(Ⅰ)을 갖는, 살진균하는데에 효과적인량의 화합물을 오이, 토마토, 사과, 포도, 밀, 벼와 같은 식물 주변의 모양에 적용하는 것으로 구성되는, 오이 노균병, 토마토 고조병, 사과 반점병, 포도 노균병, 밀 흰가루병, 도열병 또는 밀 잎 녹병에 대한 원인제인 식물병원성 진균에 의한 공격으로부터 농작물을 보호하는 방법 :상기식에서, X는 H, F, Cl, Br, I또는 CF3이고 : Y는 H, F, Cl, Br, I, CF3또는 CN이며 ; W는 CN또는 NO2이고 ; A는 H ; 하나의 할로겐 치환제로 임의 치환된 하나의 벤질옥시, 1-3개의 할로겐 원자로 임의 치환된 하나의 페녹시, 1-3개의 할로겐 원자로 또는 C1-3알콕시 또는 C1-3알킬로 임의 치환된 하나의 페닐 또는 1-3개의 할로겐 원자, 하나의 히드록시, 하나의 C1-4알콕시 또는 하나의 C1-4알킬티오로 임의 치환된 C1-4알킬 ; C1-4카르브 알콕시메틸 ; 1-3개의 할로겐 원자로 임의 치환된 C3-4알케닐 ; 시아노 ; 하나의 할로겐 원자로 임의 치환된 C3-4알케닐 ; 시아노 ; 하나의 할로겐 원자로 임의 치환된 C3-4알키닐 ; 디-(C1-4알킬)아미노카르보닐 ; 또는 C4-6시클로알킬아미노카르보닐이며 ; L은 H, F, Cl 또는 Br이고 ; M과 R은 각각 독립적으로 H, C1-3알킬, C1-3알콕시, C1-3알킬티오, C1-3알키설피닐, C1-3알키설포닐, 시아노, F, Cl, Br, I, 니트로, CF3, R1CF2Z, R2CO 또는 NR3R4이며, M과 R이 근접한 위치상에서 탄소 원자에 부착되었을 때 이들은, MR이 -OCH2O-, OCF2O-또는를 나타내는 고리를 형성할 수 있으며 ; Z는 S(O)n또는 O이고 ; R1은 H, F, CHF₂, CHFCl 또는 CF3이며 ; R2는 C1-3알킬, C1-3알콕시, 또는 NR3R4이고 ; R3는 H 또는 C1-3알킬이며 ; R4는 H, C1-3알킬이며, R4는 C1-3알킬, 또는 R5CO이고 ; R5는 H 또는 C1-3알킬이며 ; n은 정수 0, 1 또는 2이고, 단, X 또는 Y 또는 둘다가 H일때는,가 질소원자에 근접한 피롤 고리상의 두 위치 중 하나에 고정되어야만 하고 ; W가 시아노이고 X와 Y가 모두 H일때는, L, M 및 R중 최소한 하나가 H이외의 것이고 ; W가 NO2이고 A가 C1-4알킬이고 X 또는 Y가 Cl일때는 M도 R도 C1-3알콕시가 아니다.
- 제6항에 있어서, 화합물이 하기 일반식 ;을 갖는 방법.
- 하기 일반식(Ⅰ)을 갖는, 살진균하는데에 효과적인 량의 화합물로 구성되는 살진균 조성물 :상기식에서, X는 H, F, Cl, Br, I 또는 CF3이고 ; Y는 H, F, Cl, Br, I, CF3또는 CN이며 ; W는 CN또는 NO2이고 ; A는 H ; 하나의 할로겐 치환제로 임의 치환된 하나의 벤질옥시, 1-3개의 할로겐 원자로 임의 치환된 하나의 페녹시, 1-3개의 할로겐 원자로 또는 C1-3알콕시 또는 C1-3알킬로 임의 치환된 하나의 페닐 또는 1-3개의 할로겐 원자, 하나의 히드록시, 하나의 C1-4알콕시 또는 하나의 C1-4알킬티오로 임의 치환된 C1-4알킬 ; C1-4카르브알콕시메틸 ; 1-3개의 할로겐 원자로 임의 치환된 C3-4알케닐 ; 시아노 ; 하나의 할로겐 원자로 임의 치환된 C3-4알케닐 ; 디-(C1-4알킬)아미노 카르보닐 ; 또는 C4-6시클로알킬아미노카르보닐이며 ; L은 H, F, Cl 또는 Br 이고 ; M과 R은 각각 독립적으로 H, C1-3알킬, C1-3알콕시, C1-3알킬티오, C1-3알키설피닐, C1-3알키설포닐, 시아노, F, Cl, Br, I, 니트로, CF3, R1CF2Z, R2CO 또는 NR3R4이며, M과 R이 근접한 위치상에서 탄소 원자에 부착되었을 때 이들은, MR이 -OCH2O-, OCF2O-또는를 나타내는 고리를 형성할 수 있으며 ; Z는 S(O)n또는 O이고 ; R1은 H, F, CHF2, CHFCl 또는 CF3이며 ; R2는 C1-3알킬, C1-3알콕시, 또는 NR3R4이고 ; R3는 H 또는 C1-3알킬이며 ; R4는 H, 또는 C1-3알킬, 또는 R5CO이고 ; R5는 H 또는 C1-3알킬이며 ; n은 정수 0, 1 또는 2이고, 단, X 또는 Y 또는 둘다가 H일때는,가 질소원자에 근접한 피롤 고리상의 두 위치중 하나에 고정되어야만 하고 ; W가 시아노이고 X와 Y가 모두 H일때는, L, M 및 R중 최소한 하나가 H이외의 것이고 ; W가 NO2이고 A가 C1-4알킬이고 X 또는 Y가 Cl일때는 M도 R도 C1-3알콕시가 아니다.
- 제8항에 있어서, 화합물이 하기 일반식 :을 갖는 조성물.
- 제8항에 있어서, 화합물이 분무액, 초음파로써 제조된 미세 현탁액, 또는 분진이나 과립 배합물로서 배합되는 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US24164888A | 1988-09-08 | 1988-09-08 | |
US7/241,648 | 1988-09-08 | ||
US39112689A | 1989-08-11 | 1989-08-11 | |
US7/391,126 | 1989-08-11 |
Publications (1)
Publication Number | Publication Date |
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KR900004253A true KR900004253A (ko) | 1990-04-12 |
Family
ID=26934471
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019890013030A KR900004253A (ko) | 1988-09-08 | 1989-09-07 | 식물 병원성 진균을 제어하는 방법 및 살진균 조성물 |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0358047A3 (ko) |
JP (1) | JPH02167203A (ko) |
KR (1) | KR900004253A (ko) |
BR (1) | BR8904519A (ko) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5102904A (en) * | 1989-12-08 | 1992-04-07 | American Cyanamid Company | N-oxygenated arylpyrrole insecticidal, acaricidal and nematicidal agents and use thereas |
IL98235A (en) * | 1990-07-31 | 1999-07-14 | American Cyanamid Co | Process for the preparation of 2-aryl - 5 -) trifluoromethyl compounds (pyrolytic insecticides, acaricides and nematicides and their intermediates |
US5106985A (en) * | 1990-11-16 | 1992-04-21 | American Cyanamid Company | Process for the preparation of insecticidal, nematicidal and acaricidal 4-substituted-5-(trifluoromethyl)pyrrole-3-carbonitrile compounds |
ES2148142T3 (es) * | 1990-12-26 | 2000-10-16 | American Cyanamid Co | Compuestos de 2-aril-5-(trifluorometil)-2-pirrolina y procedimiento para la fabricacion de insecticidas de 2-aril-1-(alcoximetil)-4-halo-5-(trifluorometil)pirrol. |
US5194630A (en) * | 1990-12-26 | 1993-03-16 | American Cyanamid Company | Process for the manufacture of insecticidal 2-aryl-1-(alkoxymethyl)-4-halo-5-(trifluoromethyl)pyrroles |
DE4117752A1 (de) * | 1991-05-30 | 1992-12-03 | Bayer Ag | Substituierte 2-arylpyrrole |
US5233051A (en) * | 1991-05-30 | 1993-08-03 | Bayer Aktiengesellschaft | Substituted 2-arylpyrroles |
US5145986A (en) * | 1991-09-09 | 1992-09-08 | American Cyanamid Company | Process for the manufacture of insecticidal, nematicidal and acaricidal 2-aryl-3-substituted-5-(trifluoromethyl)pyrrole compounds from N-(substituted benzyl)-2,2,2-trifluoro-acetimidoyl chloride compounds |
US5306827A (en) * | 1991-12-04 | 1994-04-26 | American Cyanamid Company | Haloalkylthio, -sulfinyl and -sulfonyl arylpyrrole insecticidal and acaricidal agents |
EP0545103A1 (en) * | 1991-12-04 | 1993-06-09 | American Cyanamid Company | Insecticidal, acaricidal and molluscicidal 1-(substituted) thioalkylpyrroles |
DE4217722A1 (de) * | 1992-05-29 | 1993-12-02 | Bayer Ag | Substituierte 2-Arylpyrrole |
DE4217725A1 (de) * | 1992-05-29 | 1993-12-02 | Bayer Ag | Substituierte 2-Arylpyrrole |
WO1995018122A2 (en) * | 1993-12-30 | 1995-07-06 | Ciba-Geigy Ag | Heteroarylpyrroles |
US5597940A (en) * | 1994-03-16 | 1997-01-28 | Sumitomo Chemical Company, Limited | Process for producing β-nitroenamine |
NZ309151A (en) * | 1995-06-07 | 2000-01-28 | Nippon Shinyaku Co Ltd | a 3-substituted cyano or carbamoyl pyrrole derivative and pharmaceutical composition |
IT1312355B1 (it) * | 1999-06-17 | 2002-04-15 | Isagro Ricerca Srl | Composti pirrolici aventi elevata attivita' erbicida e loro utilizzoagronomico |
AU2003272989A1 (en) * | 2002-10-16 | 2004-05-04 | Nippon Soda Co., Ltd. | Pyrrole derivative, intermediate, and agricultural or horticultural bactericide |
PE20070182A1 (es) | 2005-07-29 | 2007-03-06 | Wyeth Corp | Derivados cianopirrol-fenil amida como moduladores del receptor de progesterona |
KR101814357B1 (ko) | 2009-02-25 | 2018-01-04 | 다케다 야쿠힌 고교 가부시키가이샤 | 피롤 화합물의 제조 방법 |
WO2015039073A1 (en) | 2013-09-16 | 2015-03-19 | Kellogg Glen E | Polysubstituted pyrroles having microtubule-disrupting, cytotoxic and antitumor activities and methds of use thereof |
PT108096B (pt) * | 2014-12-12 | 2019-07-12 | Inst Superior Tecnico | Processo de funcionalização de biocidas para imobilização em matrizes poliméricas |
CN111153868B (zh) * | 2020-01-07 | 2021-07-13 | 山东省联合农药工业有限公司 | 一种4-(4-氯苯基)-2-三氟甲基-3-恶唑-5-酮的合成方法 |
CN111393348B (zh) * | 2020-04-24 | 2023-03-28 | 黑龙江大学 | 一种氮位取代苯基吡咯类化合物及其在植物杀菌中的用途 |
CN111499554B (zh) * | 2020-04-24 | 2023-06-23 | 黑龙江大学 | 苯基吡咯类化合物及其杀菌活性的应用 |
CN115286551A (zh) * | 2022-04-15 | 2022-11-04 | 陕西美邦药业集团股份有限公司 | 一种虫螨腈及类似物的制备方法 |
CN115010641B (zh) * | 2022-07-18 | 2023-04-11 | 青岛农业大学 | 一种β-取代吡咯衍生物、其制备方法及应用 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5511524A (en) * | 1978-07-10 | 1980-01-26 | Nippon Soda Co Ltd | Cyanopyrrole derivative, its preparation and agricultural and horticultural fungicide |
JPS58111689A (ja) * | 1981-12-23 | 1983-07-02 | Meiji Seika Kaisha Ltd | 新抗生物質ピロロマイシンeおよびその製造法 |
BG43855A3 (en) * | 1983-06-17 | 1988-08-15 | Ciba - Geigy Ag | Fungicide means and method for protection from phytopathogenic fungi |
US5010098A (en) * | 1987-07-29 | 1991-04-23 | American Cyanamid Company | Arylpyrrole insecticidal acaricidal and nematicidal agents and methods for the preparation thereof |
BR8803788A (pt) * | 1987-07-29 | 1989-02-21 | American Cyanamid Co | Composto pesticida,processo para controlar insetos,processo para proteger plantas em crescimento de ataque de insetos,nematodios e acaros e processo para preparar um novo composto de aril-pirrol |
US4929634A (en) * | 1987-10-23 | 1990-05-29 | American Cyanamid Company | Method of and bait compositions for controlling mollusks |
-
1989
- 1989-08-23 EP EP19890115558 patent/EP0358047A3/en not_active Withdrawn
- 1989-09-06 BR BR898904519A patent/BR8904519A/pt not_active Application Discontinuation
- 1989-09-07 KR KR1019890013030A patent/KR900004253A/ko not_active Application Discontinuation
- 1989-09-07 JP JP1232680A patent/JPH02167203A/ja active Pending
Also Published As
Publication number | Publication date |
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JPH02167203A (ja) | 1990-06-27 |
EP0358047A2 (en) | 1990-03-14 |
EP0358047A3 (en) | 1991-05-29 |
BR8904519A (pt) | 1990-04-24 |
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