KR900003209A - 저장안정성의 개질전분유화제 및 그 제조방법 - Google Patents

저장안정성의 개질전분유화제 및 그 제조방법 Download PDF

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KR900003209A
KR900003209A KR1019890006094A KR890006094A KR900003209A KR 900003209 A KR900003209 A KR 900003209A KR 1019890006094 A KR1019890006094 A KR 1019890006094A KR 890006094 A KR890006094 A KR 890006094A KR 900003209 A KR900003209 A KR 900003209A
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치우 정-와이
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허버트 제이. 범가튼
내쇼날 스타지 앤드 케미칼 코포레이숀
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Abstract

내용 없음.

Description

저장안정성의 개질전분유화제 및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (20)

  1. 전분의 비분해단말로부터 1, 4-알파-D-글루코시드 결합을 분열시킬 수 있으나 전분의 1, 6-알파-D-글루코시드 결합을 분열시킬 수 없는 엑소효소에 의하여 열화된 70중량% 이하의 히드로포브기 또는 히드로필기와 히드로포브기 양자를 함유하는 전분유도체로 이루어지는 저장중의 오일링 및 겔링에 대한 안정성 및 저항성이 개선된 에멀젼의 유화특성을 가지는 개질전분.
  2. 제1항에 있어서, 상기 전분은 약 60이하의 WF로 산 또는 열변환되거나 알파-아밀라제에 의하여 변환된 개질전분.
  3. 제1항에 있어서, 상기 엑소효소는 베타-아밀라제이고, 상기 전분은 왁스 메이즈 전분이고, 상기 전분은 교질화되고, 전분건조 중량기준으로 0.25% 이상의 옥테닐숙신산 무수물로 처리하여 유도된 개질전분.
  4. 제3항에 있어서, 상기 전분은 히드록시프로필기를 포함하도록 더욱 유도된 개질전분.
  5. 제1항에 있어서, 상기 히드로포브기를 함유하는 전분유도체는 교질화되고, 상기 히드로포브기는 탄소원자수 5이상의 알킬, 알케닐, 아랄킬 또는 아랄케닐기로 이루어지는 개질전분.
  6. 제1항에 있어서, 상기 히드로필기와 히드로포브기 양자를 함유하는 전분유도체는 교질화되고, 다음식을 가지는 치환기를 함유하는 개질전분.
    식중 R은 디메틸렌 및 트리메틸렌기의 클라스로부터의 기이고, R′는 탄소원자수 5이상의 알킬, 알케닐, 아랄킬 또는 아랄케닐기로 이루어지는 히드로포브기이고, 카르복실기 COOH는 히드로필기이다.
  7. (a) 각 치환기가 히드로포브기 또는 히드로필기와 히드로포브기 양자를 함유하는 교질화된 전분유도체를 제조하고, (b) 전분의 비분해단말로부터 1, 4-알파-D-글루코시드 결합을 분열시킬 수 있으나 전분의 1, 6-알파-D-글루코시드 결합을 분열시킬 수 없는 엑소효소에 의하여 전분유도체의 70중량% 이하를 맥아당으로 열화하는 단계로 이루어지는 저장중의 오일링 및 겔링에 대한 안정성 및 저항성이 개선된 에멀젼의 유화특성을 가지는 개질전분의 제조방법.
  8. 제7항에 있어서, 상기 전분은 왁스 메이즈 전분이고, 전분의 비분해단말로부터 1, 4-알파-D-글루코시드 결합을 분열시킬 수 있으나 전분의 1, 6-알파-D-글루코시드 결합을 분열시킬 수 없는 엑소효소에 의하여 처리하기 이전에, 상기 전분은 약 60이하의 WF로 산 또는 열변환되거나, 또는 알파-아밀라제에 의하여 변환되고, 상기 전분은 그 전분건조 중량기준으로 0.25% 이상의 옥테닐숙신산 무수물로 처리하여 유도되는 개질전분의 제조방법.
  9. 제7항에 있어서, 상기 효소는 베타-아밀라제이고, 건조중량 기준으로 전분의 100g당 당화력 334-1,110의 효소농도, pH 3-10, 20-75℃의 온도로 33% 이하의 고형물을 함유하는 수성분산물내에서 효소열화가 행하여지는 개질전분의 제조방법.
  10. 제7항에 있어서, 상기 전분유도체는 히드로포브기를 함유하고, 히드로포브기는 탄소원자수 5이상의 알킬, 알케닐, 아릴킬 또는 아랄케닐기로 이루어지는 개질전분의 제조방법.
  11. 제7항에 있어서, 상기 히드로필기와 히드로포브기 양자를 함유하는 전분유도체는 다음식을 가지는 치환기를 함유하는 개질전분의 제조방법.
    식중 R은 디메틸렌 및 트리메틸렌기의 클라스로부터의 기이고, R′는 탄소원자수 5이상의 알킬, 알케닐, 아랄킬 또는 아랄케닐기로 이루어지는 히드로포브기이고, 카르복실기 COOH는 히드로필기이다.
  12. (a) 전분의 비분해단말로부터 1, 4-알파-D-글루코시드 결합을 분열시킬 수 있으나 전분의 1, 6-알파-D-글루코시드 결합을 분열시킬 수 없는 엑소효소에 의하여 교질화된 전분의 70중량% 이하를 맥아당으로 열화하고, (b) 효소적으로 열화된 전분과 시약을 반응시켜 히드로포브기 또는 히드로필기와 히드로포브기 양자를 함유하는 전분유도체를 제조하는 단계로 이루어지는 저장중의 오일링 및 겔링에 대한 안정성 및 저항성이 개선된 에멀젼의 유화특성을 가지는 개질전분의 제조방법.
  13. 제12항에 있어서, 상기 전분은 왁스 메이즈 전분이고, 전분의 비분해단말로부터 1, 4-알파-D-글루코시드 결합을 분열시킬 수 있으나 전분의 1, 6-알파-D-글루코시드 결합을 분열시킬 수 없는 엑소효소에 의하여 처리하기 이전에, 상기 전분은 약 60이하의 WF로 산 또는 열변환되거나, 또는 알파-아밀라제에 의하여 변환되고, 상기 전분은 그 전분건조 중량기준으로 0.25% 이상의 옥테닐숙신산 무수물로 처리하여 유도되는 개질전분의 제조방법.
  14. 제12항에 있어서, 상기 효소는 베타-아밀라제이고, 건조중량 기준으로 전분의 100g당 당화력 334-1,110의 효소농도, pH 3-10, 20-75℃의 온도로 33% 이하의 고형물을 함유하는 수성분산물내에서 효소열화가 행하여지는 개질전분의 제조방법.
  15. 제12항에 있어서, 상기 전분유도체는 히드로포브기를 함유하고, 히드로포브기는 탄소원자수 5이상의 알킬, 알케닐, 아릴킬 또는 아랄케닐기로 이루어지는 개질전분의 제조방법.
  16. 제12항에 있어서, 상기 히드로필기와 히드로포브기 양자를 함유하는 전분유도체는 다음식을 가지는 치환기를 함유하는 개질전분의 제조방법.
    식중 R은 디메틸렌 및 트리메틸렌기의 클라스로부터의 기이고, R′는 탄소원자수 5이상의 알킬, 알케닐, 아랄킬 또는 아랄케닐기로 이루어지는 히드로포브기이고, 카르복실기 COOH는 히드로필기이다.
  17. 제1항의 개질전분을 함유하는 산업적 응용물을 위한 에멀젼.
  18. 제7항의 방법으로 제조된 개질전분을 함유하는 산업적 응용물을 위한 에멀젼.
  19. 제12항의 방법으로 제조된 개질전분을 함유하는 산업적 응용물을 위한 에멀젼.
  20. 전분의 비분해단말로부터 1, 4-알파-D-글루코시드 결합을 분열시킬 수 있으나 전분의 1, 6-알파-D-글루코시드 결합을 분열시킬 수 없는 엑소효소와의 반응에 의하여 맥아당으로 열화된 70중량% 이하의 히드로포브기 또는 히드로필기와 히드로포브기 양자를 함유하는 전분유도체를 사용하여 에멀젼이 제조된 저장중의 오일링 및 겔링에 대한 안정성 및 저항성이 개선된 에멀젼으로 이루어지는 식료품 및 음료.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890006094A 1988-03-11 1989-05-08 저장안정성의 개질전분유화제 및 그 제조방법 KR920010521B1 (ko)

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US16705188A 1988-03-11 1988-03-11
US167051 1988-03-11
US07/234,070 US4977252A (en) 1988-03-11 1988-08-18 Modified starch emulsifier characterized by shelf stability
US234070 1988-08-18
US234,070 1989-08-18

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KR920010521B1 KR920010521B1 (ko) 1992-12-04

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US (1) US4977252A (ko)
EP (1) EP0332027B1 (ko)
KR (1) KR920010521B1 (ko)
AT (1) ATE199092T1 (ko)
CA (1) CA1333894C (ko)
DE (1) DE68929281T2 (ko)
DK (1) DK116589A (ko)
ES (1) ES2155432T3 (ko)
FI (1) FI891091A (ko)
MX (1) MX163960B (ko)
NO (1) NO175262C (ko)
NZ (1) NZ228451A (ko)
PH (1) PH27035A (ko)
PT (1) PT89979B (ko)

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NO175262B (no) 1994-06-13
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US4977252A (en) 1990-12-11
ES2155432T3 (es) 2001-05-16
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ATE199092T1 (de) 2001-02-15
MX163960B (es) 1992-07-06
CA1333894C (en) 1995-01-10
DK116589D0 (da) 1989-03-10
EP0332027B1 (en) 2001-02-07
DK116589A (da) 1989-09-12
NO175262C (no) 1994-09-21
DE68929281D1 (de) 2001-03-15
PT89979B (pt) 1994-05-31
NZ228451A (en) 1991-04-26
NO891039D0 (no) 1989-03-10
EP0332027A1 (en) 1989-09-13
PH27035A (en) 1993-02-01
NO891039L (no) 1989-09-12

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