KR900003138A - 복소환식 화합물 - Google Patents

복소환식 화합물 Download PDF

Info

Publication number
KR900003138A
KR900003138A KR1019890011758A KR890011758A KR900003138A KR 900003138 A KR900003138 A KR 900003138A KR 1019890011758 A KR1019890011758 A KR 1019890011758A KR 890011758 A KR890011758 A KR 890011758A KR 900003138 A KR900003138 A KR 900003138A
Authority
KR
South Korea
Prior art keywords
formula
compound
lower alkyl
alkyl
same
Prior art date
Application number
KR1019890011758A
Other languages
English (en)
Inventor
제이.이.디.바톤
Original Assignee
그레함 도날드 아놀드
임페리알 케미칼 인더스트리스 피엘씨
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB888819660A external-priority patent/GB8819660D0/en
Priority claimed from GB898914041A external-priority patent/GB8914041D0/en
Application filed by 그레함 도날드 아놀드, 임페리알 케미칼 인더스트리스 피엘씨 filed Critical 그레함 도날드 아놀드
Publication of KR900003138A publication Critical patent/KR900003138A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/27—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups
    • C07C205/35—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C205/36—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system
    • C07C205/38—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system the oxygen atom of at least one of the etherified hydroxy groups being further bound to a carbon atom of a six-membered aromatic ring, e.g. nitrodiphenyl ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/78—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
    • C07C217/80—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings
    • C07C217/82—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring
    • C07C217/90—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring the oxygen atom of at least one of the etherified hydroxy groups being further bound to a carbon atom of a six-membered aromatic ring, e.g. amino-diphenylethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/16—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms condensed with carbocyclic rings or ring systems
    • C07D249/18—Benzotriazoles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

내용 없음

Description

복소환식 화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 일반식(I)의 화합물 :
    식중 R1은 독립적으로 H,CN,NO2, 할로겐, 저급알킬, 저급할로알킬로 부터 선택되고 : m은 1-4까지의 정수이며, R2는 R1이 상기한 바와같은 CR1또는 N : R3는 일반식(a),(b) 또는 (c)그룹,
    또는 이들의 질소 산화물 또는 4차염 유도체 ;
    R4는 그룹는 독립적으로 H, 저급알킬, 할로겐으로부터 선택되거나 또는 R5와 R6기 함께 =CH2를 형성하거나 또는 R5,R6와 탄소원자가 함께 연결되어 C3-6시클로알킬 고리를 형성하며 ;
    SO3H ; R9은 저급 알킬 ; R10은 저급알킬 또는 페닐 : n은 0.1 또는 2 ; R11은 수소, 임의로 치환된 저급알킬, 임의로 치환된 저급 알케닐, 임의로 치환된 저급 알키닐,〔(CH2)2O〕p(CH2)qOR10,-N=C(R10), -N=C(R10)2, 임의로 치횐된 페닐, 임의로 치환된 벤질, 임의로 치환된 시클로알킬 ; p는 0.1 또는 2; q는 2-5의 정수 ; R12는 H 또는 저급 알킬 ; R13및 R14는 독립적으로 H, 저급알킬, 저급시킬로알킬, 알케닐, 알키닐, SO2R10,N(R12)2,(R10)3로 부터 선택되고 ; R14는 임의의 하이드록시-또는 페닐-치환된 C1-4알킬 라디칼, 페닐라디칼 또는 클로로 페닐라디칼, C1-4알콕시 라디칼, 또는 R15는 수소 또는 C1-4알킬이고, R16은 수소 C1-4알킬, 페닐인 -NR15R16그룹, 또는 5원 또는 6원 복소환식 고리를 구성하거나 알킬 4차 유도체, R8이 카복실 그룹일때는 이의 염을 구성하게되는 -NR13R14그룹일 수 있다.
  2. (R)에난티오머 형태인 일반식(I) 화합물.
  3. 제1항 또는 제2항에 있어서, R3가
    인 화합물.
  4. 전기한 항중 어느 한 항에 있어서 R4가 -인 화합물.
    식중, n, R6,R11은 제1항에서와 동일함.
  5. 제4항에 있어서, R11이 C1-4알킬이고 R6가 H 또는 C1-4알킬이고 R6가 H또는 C1-4알킬인 화합물.
  6. 제1항에 일반식(I) 화합물과 담체 또는 회석제가 결합된 것으로 구성된 제초용 조성물.
  7. 제1항의 일반식(I) 화합물을 효용량 식물 또는 식물이 소재하는 곳에 살포하는 것으로 이루어지는 불필요한 식물의 성장을 억제하거나 또는 죽이는 방법.
  8. a) 일반식(II) 화합물을
    식중, R1,R2및 m은 제1항에서와 동일. 염기의 존재하에서 일반식(III) 화합물과 반응시키거나
    식중, R5, R6, R7, R8은 일반식(I)에서와 동일하고 X는 이탈기.
    또는 염기의 존재하에서 일반식(IV) 화합물과 반응시키고
    식중, R21과 R22는 독립적으로 H 또는 저급알킬 ; R23은 R34가 저급알킬인 COOR24, CHO 또는 CN
    B)R3이 부분그룹(b)이고 R4가 그룹 R25-CH-R26, R25는 CH2OH, COOH, COO-M=, COOR25또는 P
    (OC2H5)2'MF양이온, R29는 저급알킬, R26은 수소 또는 저급알킬인 경우에는 일반식(V) 화합물을 고리로
    만들고;
    c) R3이 부분그룹(a) 또는 (b)인 경우에는 일반(VIII)화합물을
    식중, R4는 일반식(I)에서와 동일. 일반식(VIII)화합물과 반응시키고
    식중, R1, R2및 m은 일반식(I)에서와 동일, Y는 할로 또는
    d) R3이 부분그룹(b)이고 R3는 R27이 H 또는 저급알킬인인 경우에는 일반식 (VI)화합물을
    일반식(Ⅶ)화합물과 반응시킨뒤 필요하다면 i) 일반식 (I)의 R8이 알콕시카보닐일때
    당해 산으로 가수분해시키고 ii) 일반식 I)의 R8이 COOH일때 에스테르화하거나 또는 염, 아미드,설폰아미드, 하이드라지드 또는 하이드라지늄 유도체로 만들고 iii)일반식(I)의 R8이 알콤일때 COOH 또는 CHO로 산화시키는; 단계중 하나 이상의 단계를 실행하는 것으로 구성된; 제1항의 일반식
    (I) 화합물의 제조방법.
  9. 일반식(Ⅴ) 화합물 :
    식중, (R1)m, R2, R25, 및 R26은 제8항에서와 동일.
  10. 일반식(II) 화합물:
    식중, 일반식(II)가 5-2-클로로-4-(트리플루오로메틸)페복시-1H-벤조트리아졸이 아니라면 (R1)m과
    R2는 제8항에서와 동일.
  11. 일반식(ⅧA) 화합물
    식중, R4는 제8항에서와 동일함.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890011758A 1988-08-18 1989-08-18 복소환식 화합물 KR900003138A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB888819660A GB8819660D0 (en) 1988-08-18 1988-08-18 Heterocyclic compounds
GB8819660.5 1988-08-18
GB898914041A GB8914041D0 (en) 1989-06-19 1989-06-19 Heterocyclic compounds
GB8914041.2 1989-06-19

Publications (1)

Publication Number Publication Date
KR900003138A true KR900003138A (ko) 1990-03-23

Family

ID=26294298

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890011758A KR900003138A (ko) 1988-08-18 1989-08-18 복소환식 화합물

Country Status (18)

Country Link
EP (1) EP0355049A3 (ko)
JP (1) JPH02111764A (ko)
KR (1) KR900003138A (ko)
CN (1) CN1040367A (ko)
AU (1) AU618116B2 (ko)
CA (1) CA1338191C (ko)
DK (1) DK405489A (ko)
FI (1) FI96203C (ko)
GB (1) GB8916722D0 (ko)
HU (1) HU205748B (ko)
IL (1) IL91140A (ko)
NO (1) NO170333C (ko)
NZ (1) NZ230146A (ko)
PE (1) PE10290A1 (ko)
PL (1) PL163043B1 (ko)
PT (1) PT91465B (ko)
RU (1) RU1836360C (ko)
YU (1) YU156589A (ko)

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL91997A0 (en) * 1988-11-03 1990-07-12 American Cyanamid Co Aryloxy benzotriazole herbicidal agents and methods for the preparation thereof
US5324711A (en) * 1988-11-03 1994-06-28 American Cyanamid Company Aryloxy benzotriazole herbicidal agents and methods for the preparation thereof
GB9003553D0 (en) * 1990-02-16 1990-04-11 Ici Plc Herbicidal compositions
TR24928A (tr) * 1990-02-16 1992-07-01 Ici Plc Herbisid terkipler
US5322853A (en) * 1990-06-21 1994-06-21 Ciba-Geigy Corporation Microbicidal benzotriazole compounds
EP0462931B1 (de) * 1990-06-21 1994-04-13 Ciba-Geigy Ag Benzotriazol-1-sulfonylderivate mit mikrobiziden Eigenschaften
GB9113987D0 (en) * 1991-06-28 1991-08-14 Ici Plc Herbicidal compositions
EP0549532A1 (de) * 1991-12-20 1993-06-30 Ciba-Geigy Ag Benztriazolsulfonsäure-Derivate und ihre Verwendung als Mikrobizide
DE4302461A1 (de) * 1993-01-29 1994-08-04 Bayer Ag Fluorierte Benzotriazole
EP2470527A4 (en) * 2009-08-20 2013-02-27 Merck Sharp & Dohme BENZOTRIAZOLE D ETHER DERIVATIVES
EP2651407B1 (en) 2010-12-15 2016-12-21 Olatec Industries LLC 3-methanesulfonylpropionitrile for treating inflammation and pain
CA2864181C (en) 2012-02-27 2020-06-02 Olatec Industries Llc Process for preparing 3-methylsulfonylpropionitrile
MX366309B (es) 2012-06-05 2019-07-04 Olatec Ind Llc Composicion farmaceutica para el tratamiento de inflamacion y dolor.
US11467605B2 (en) 2019-04-10 2022-10-11 Deere & Company Zonal machine control
US11178818B2 (en) 2018-10-26 2021-11-23 Deere & Company Harvesting machine control system with fill level processing based on yield data
US11240961B2 (en) 2018-10-26 2022-02-08 Deere & Company Controlling a harvesting machine based on a geo-spatial representation indicating where the harvesting machine is likely to reach capacity
US11641800B2 (en) 2020-02-06 2023-05-09 Deere & Company Agricultural harvesting machine with pre-emergence weed detection and mitigation system
US12069978B2 (en) 2018-10-26 2024-08-27 Deere & Company Predictive environmental characteristic map generation and control system
US11672203B2 (en) 2018-10-26 2023-06-13 Deere & Company Predictive map generation and control
US11957072B2 (en) 2020-02-06 2024-04-16 Deere & Company Pre-emergence weed detection and mitigation system
US11589509B2 (en) 2018-10-26 2023-02-28 Deere & Company Predictive machine characteristic map generation and control system
US11079725B2 (en) 2019-04-10 2021-08-03 Deere & Company Machine control using real-time model
US11778945B2 (en) 2019-04-10 2023-10-10 Deere & Company Machine control using real-time model
US11234366B2 (en) 2019-04-10 2022-02-01 Deere & Company Image selection for machine control
US12035648B2 (en) 2020-02-06 2024-07-16 Deere & Company Predictive weed map generation and control system
US11477940B2 (en) 2020-03-26 2022-10-25 Deere & Company Mobile work machine control based on zone parameter modification
US11895948B2 (en) 2020-10-09 2024-02-13 Deere & Company Predictive map generation and control based on soil properties
US11874669B2 (en) 2020-10-09 2024-01-16 Deere & Company Map generation and control system
US11635765B2 (en) 2020-10-09 2023-04-25 Deere & Company Crop state map generation and control system
US11849672B2 (en) 2020-10-09 2023-12-26 Deere & Company Machine control using a predictive map
US11946747B2 (en) 2020-10-09 2024-04-02 Deere & Company Crop constituent map generation and control system
US11844311B2 (en) 2020-10-09 2023-12-19 Deere & Company Machine control using a predictive map
US11864483B2 (en) 2020-10-09 2024-01-09 Deere & Company Predictive map generation and control system
US11927459B2 (en) 2020-10-09 2024-03-12 Deere & Company Machine control using a predictive map
US11727680B2 (en) 2020-10-09 2023-08-15 Deere & Company Predictive map generation based on seeding characteristics and control
US11592822B2 (en) 2020-10-09 2023-02-28 Deere & Company Machine control using a predictive map
US11845449B2 (en) 2020-10-09 2023-12-19 Deere & Company Map generation and control system
US11889788B2 (en) 2020-10-09 2024-02-06 Deere & Company Predictive biomass map generation and control
US11871697B2 (en) 2020-10-09 2024-01-16 Deere & Company Crop moisture map generation and control system
US11711995B2 (en) 2020-10-09 2023-08-01 Deere & Company Machine control using a predictive map
US11983009B2 (en) 2020-10-09 2024-05-14 Deere & Company Map generation and control system
US11474523B2 (en) 2020-10-09 2022-10-18 Deere & Company Machine control using a predictive speed map
US11675354B2 (en) 2020-10-09 2023-06-13 Deere & Company Machine control using a predictive map
US12069986B2 (en) 2020-10-09 2024-08-27 Deere & Company Map generation and control system
US12013245B2 (en) 2020-10-09 2024-06-18 Deere & Company Predictive map generation and control system
US11825768B2 (en) 2020-10-09 2023-11-28 Deere & Company Machine control using a predictive map
US11650587B2 (en) 2020-10-09 2023-05-16 Deere & Company Predictive power map generation and control system
US11889787B2 (en) 2020-10-09 2024-02-06 Deere & Company Predictive speed map generation and control system
US12082531B2 (en) 2022-01-26 2024-09-10 Deere & Company Systems and methods for predicting material dynamics
US12058951B2 (en) 2022-04-08 2024-08-13 Deere & Company Predictive nutrient map and control

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54144375A (en) * 1978-04-27 1979-11-10 Ishihara Sangyo Kaisha Ltd 4-(5-trifluoromethyl-2-pyridyloxy)phenoxyalkane derivative and herbicide containing the same
US4240822A (en) * 1978-12-04 1980-12-23 American Cyanamid Company Method for controlling undesirable plants using 1H-benzotriazole and 2H-benzotriazole compounds
DE3238804A1 (de) * 1982-10-20 1984-04-26 Celamerck Gmbh & Co Kg, 6507 Ingelheim Neue benzotriazole, ihre herstellung und ihre verwendung als biozide wirkstoffe
GB8327658D0 (en) * 1983-10-14 1983-11-16 Fbc Ltd Herbicides
GB8426367D0 (en) * 1984-10-18 1984-11-21 Shell Int Research Heteroaromatic ether herbicides
IL91997A0 (en) * 1988-11-03 1990-07-12 American Cyanamid Co Aryloxy benzotriazole herbicidal agents and methods for the preparation thereof

Also Published As

Publication number Publication date
YU156589A (en) 1991-02-28
AU3941689A (en) 1990-02-22
IL91140A (en) 1994-05-30
PT91465B (pt) 1995-05-31
PL163043B1 (pl) 1994-02-28
RU1836360C (ru) 1993-08-23
HU205748B (en) 1992-06-29
AU618116B2 (en) 1991-12-12
NO170333C (no) 1992-10-07
CA1338191C (en) 1996-03-26
NO170333B (no) 1992-06-29
NO893304L (no) 1990-02-19
HUT50794A (en) 1990-03-28
DK405489D0 (da) 1989-08-17
PT91465A (pt) 1990-03-08
EP0355049A2 (en) 1990-02-21
GB8916722D0 (en) 1989-09-06
EP0355049A3 (en) 1990-06-13
FI96203C (fi) 1996-05-27
NZ230146A (en) 1992-03-26
FI96203B (fi) 1996-02-15
PE10290A1 (es) 1991-01-18
NO893304D0 (no) 1989-08-17
JPH02111764A (ja) 1990-04-24
DK405489A (da) 1990-02-19
FI893902A0 (fi) 1989-08-18
CN1040367A (zh) 1990-03-14
FI893902A (fi) 1990-02-19

Similar Documents

Publication Publication Date Title
KR900003138A (ko) 복소환식 화합물
FI892787A0 (fi) Analogiamenetelmä terapeuttisesti käyttökelpoisten 1-indolyylialkyyli-4-(substituoitu pyridinyyli)piperatsiinien valmistamiseksi
EP0256503A3 (en) Pyridinecarboxamide derivatives and their use as fungicide
TW231258B (ko)
IL93443A0 (en) Trifluoromethylphenylazolyl-methyloxirane derivatives and fungicides containing these compounds
AU539399B2 (en) Substituted oxonicotinates
IL66591A0 (en) Biologically active amide derivatives
AU1395283A (en) 1-carboxyalkanoylindoline-2-carboxylic acid esters
IE43651L (en) Benzisoquinolin-piperidine derivatives
DE69607890D1 (de) Aromatische Hydroxamsäure-Verbindungen, ihre Herstellung und Verwendung
IL66393A (en) Nitro derivatives of pyridyloxyphenylphosphonic acids,their preparation and their use as herbicides and/or plant growth regulators and/or microbicides
AU562778B2 (en) Substituted pyridazines
ATE31310T1 (de) Herbizidmittel, heterocyclische pentaleneenthaltend.
DE68914237D1 (de) Chemische Hybridisierung von Dikotylen.
ATE126504T1 (de) 1-phenoxycarbonyl-2-pyrrolidon-derivate und nootrope wirkstoffe.
BR8503049A (pt) Composto e composicao herbicida,processo para controlar ervas daninhas e processo para produzir um composto herbicida
TH2970A (th) สารฆ่าวัชพืชไธโอฟีนซัลโฟแนมีดและพิริดีนซัลโฟแนมีด
DE3464053D1 (en) Pyrazine compounds, their preparation and their use, compositions containing them and method of combating undesired plant growth

Legal Events

Date Code Title Description
A201 Request for examination
N231 Notification of change of applicant
E902 Notification of reason for refusal
SUBM Surrender of laid-open application requested