KR900003096A - 치환된(2-할로알콕시-1,1,2-트리플루오로에톡시)스티렌, 이의 제조방법 및 이의 용도 - Google Patents

치환된(2-할로알콕시-1,1,2-트리플루오로에톡시)스티렌, 이의 제조방법 및 이의 용도 Download PDF

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KR900003096A
KR900003096A KR1019890011752A KR890011752A KR900003096A KR 900003096 A KR900003096 A KR 900003096A KR 1019890011752 A KR1019890011752 A KR 1019890011752A KR 890011752 A KR890011752 A KR 890011752A KR 900003096 A KR900003096 A KR 900003096A
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styrene
formula
general formula
partially
following general
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KR1019890011752A
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푸스 안드레아스
힌쩌 클라우스
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베른하르트 벡크, 하인리히 벡커
훽스트 아크티엔게젤샤프트
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Publication of KR900003096A publication Critical patent/KR900003096A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/14—Unsaturated ethers
    • C07C43/164—Unsaturated ethers containing six-membered aromatic rings
    • C07C43/166—Unsaturated ethers containing six-membered aromatic rings having unsaturation outside the aromatic rings
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/039—Macromolecular compounds which are photodegradable, e.g. positive electron resists
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/225—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/575—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D319/10—1,4-Dioxanes; Hydrogenated 1,4-dioxanes
    • C07D319/12—1,4-Dioxanes; Hydrogenated 1,4-dioxanes not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by hetero atoms or groups containing heteroatoms
    • C08F12/22—Oxygen

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  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Polymers & Plastics (AREA)
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  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

치환된(2-할로알콕시-1,1,2-트리플루오로에톡시)스티렌, 이의 제조방법 및 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 하기 일반식(I)의 스티렌.
    상기식에서, R1은 부분적으로 또는 전체적으로 할로겐화된 C1-C10-알킬 또는 하기 일반식(Ⅱ) 또는 (Ⅲ)의 래티칼이고;
    R2는 수소, 할로겐 또는 부분적으로 또는 전체적으로 할로겐화된 C1-C8-알킬 그룹이고, 여기에서 알킬그룹 R1및 R2는 동일하거나 상이하며; m은 1,2,3 또는 4의 정수이고; n은 1,2 또는 3의 정수이며; o는 1,2,3 또는 4의 정수이고; p는 1,2,3,4,5,6,7,8,9 또는 10의 정수이며; X는 수소 또는 할로겐이고, 단, m과 n의 합은 5보다 크지 않다.
  2. 제1항에 있어서, R1및 R2가 각각 부분적으로 또는 전체적으로 할로겐화된 C1-C3-알킬 그룹인 스티렌.
  3. 제1항에 있어서, 할로겐이 염소 또는 브롬인 스티렌.
  4. 제1항에 있어서, 할로겐이 불소인 스티렌.
  5. 불활성 비양성자성 용매(C1)의 존재하에 하기 일반식(Ⅳ)의 하이드록시벤즈알데히드와 하기 일반식(Ⅴ)의 비닐 에테르 n몰 이상을 -100℃ 내지 100℃의 온도에서 염기(B1)의 존재하에 반응시켜 하기 일반식(Ⅵ)의 알데히드를 수득하고, 계속해서 일반식(Ⅵ)의 화합물과 메틸트리아릴포스포늄 할라이드를 염기(B2)의 존재하에 불활성 무수 용매(C2)중에 -100℃ 내지 100℃의 온도에서 반응시켜 화합물(I)을 수득함을 특징으로 하여, 일반식(I)의 스티렌을 제조하는 방법.
    상기식에서, R1,R2,m 및 n은 제1항에서 정의한 바와 같다.
  6. 제5항에 있어서, 사용된 염기 (B1)가 탄산 나트륨 또는 탄산칼륨이고, 사용된 염기(B2)는 나트륨 아미드인 방법.
  7. 제5항에 있어서, 불활성 비양성자성 용매(C1)가 아세토니트릴이고, 불활성 용매(C2)는 테트라하이드로푸란인 방법.
  8. 제5항에 있어서, 일반식(I)의 R1및 R2가 각각 부분적으로 또는 전체적으로 할로겐화된 C1-C3-알킬그룹인 방법.
  9. 하기 일반식(Ⅶ)의 아세톡시스티렌을 우선 알칼리금속 수산화물(B3)과 불활성 비양성자성 용매(C1)중에서 반응시킨후, 일반식(Ⅴ)의 비닐에테르와 반응시킴(여기에서, 각각의 공정 단계의 온도는 -100℃ 내지 100℃이다)을 특징으로 하여, 일반식(I)의 스티렌을 제조하는 방법.
    상기식에서, R2,m 및 n은 제1항에서 정의한 바와 같다.
  10. 제9항에 있어서, 불활성 비양성자성 용매(C1)가 아세토니트릴이고, 불활성 용매(C2)는 테트라하이드로푸란인 방법.
  11. 제9항에 있어서, 일반식(I)의 R1및 R2가 각각 부분적으로 또는 전체적으로 할로겐화된 C1-C3-알킬 그룹인 방법.
  12. 제1항에 있어서, 청구된 일반식(I)의 스티렌으로부터 제조된 중합체.
  13. 제12항에 있어서, 광학 시스템용 물질로서, 내식막으로서, 성형물 및 접착제로서의, 크로마토그래피 방법을 위한 담체 물질 형태인 중합체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890011752A 1988-08-18 1989-08-18 치환된(2-할로알콕시-1,1,2-트리플루오로에톡시)스티렌, 이의 제조방법 및 이의 용도 KR900003096A (ko)

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DE3828063A DE3828063A1 (de) 1988-08-18 1988-08-18 Substituierte (2-haloalkoxy-1.1.2-trifluoraethoxy)-styrole, verfahren zu ihrer herstellung und ihre verwendung
DEP3828063.9 1988-08-18

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100332915B1 (ko) * 1997-12-23 2002-10-25 주식회사 포스코 접착력 및 내식성이 개선된 강판 피복용 스티렌 고분자 킬레이트 접착제 제조방법

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69918117T2 (de) * 1998-06-25 2005-06-30 E.I. Du Pont De Nemours And Co., Wilmington Aromatische polymere mit fluorierten ionischen gruppen
US7279522B2 (en) 2001-09-05 2007-10-09 3M Innovative Properties Company Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant
US20070274867A1 (en) * 2005-02-28 2007-11-29 Honeywell International Inc. Stationary phase for a micro fluid analyzer
US7671112B2 (en) 2005-07-15 2010-03-02 3M Innovative Properties Company Method of making fluoropolymer dispersion
GB0514398D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
US20080015304A1 (en) 2006-07-13 2008-01-17 Klaus Hintzer Aqueous emulsion polymerization process for producing fluoropolymers
GB0523853D0 (en) 2005-11-24 2006-01-04 3M Innovative Properties Co Fluorinated surfactants for use in making a fluoropolymer
GB0525978D0 (en) 2005-12-21 2006-02-01 3M Innovative Properties Co Fluorinated Surfactants For Making Fluoropolymers
US7728087B2 (en) 2005-12-23 2010-06-01 3M Innovative Properties Company Fluoropolymer dispersion and method for making the same
US7754795B2 (en) 2006-05-25 2010-07-13 3M Innovative Properties Company Coating composition
US20070299276A1 (en) * 2006-06-22 2007-12-27 Andrew Edward Feiring Preparation of fluoroalkoxystyrenes
US8119750B2 (en) 2006-07-13 2012-02-21 3M Innovative Properties Company Explosion taming surfactants for the production of perfluoropolymers
US20080264864A1 (en) 2007-04-27 2008-10-30 3M Innovative Properties Company PROCESS FOR REMOVING FLUORINATED EMULSIFIER FROM FLUOROPOLMER DISPERSIONS USING AN ANION-EXCHANGE RESIN AND A pH-DEPENDENT SURFACTANT AND FLUOROPOLYMER DISPERSIONS CONTAINING A pH-DEPENDENT SURFACTANT
WO2008147796A1 (en) 2007-05-23 2008-12-04 3M Innovative Properties Company Aqueous compositions of fluorinated surfactants and methods of using the same
JP5453250B2 (ja) 2007-06-06 2014-03-26 スリーエム イノベイティブ プロパティズ カンパニー フッ素化エーテル組成物及びフッ素化エーテル組成物の使用方法
JP2011528659A (ja) 2008-07-18 2011-11-24 スリーエム イノベイティブ プロパティズ カンパニー フッ素化エーテル化合物及びその使用方法
WO2010080473A1 (en) 2008-12-18 2010-07-15 3M Innovative Properties Company Method of contacting hydrocarbon-bearing formations with fluorinated ether compositions
US8962879B2 (en) 2012-11-14 2015-02-24 E I Du Pont De Nemours And Company Perfluoropolyvinyl modified aryl intermediates/monomers
US9365476B2 (en) 2012-11-14 2016-06-14 E I Du Pont De Nemours And Company Aryl compounds modified with perfluorovinyl ethers
US9145356B2 (en) * 2012-11-14 2015-09-29 E I Du Pont De Nemours And Company Perfluoropolyvinyl modified aryl intermediates and monomers
US9193702B2 (en) 2013-10-31 2015-11-24 E I Du Pont De Nemours And Company Fluorinated aryl epoxide compounds
WO2016032738A1 (en) * 2014-08-27 2016-03-03 3M Innovative Properties Company Novel polyfluoroalkylated alkenes and silane compounds prepared therefrom
US9975834B2 (en) 2014-08-27 2018-05-22 3M Innovative Properties Company Polyfluoroalkylated alkenes and silicon compounds prepared therefrom
US9938380B2 (en) 2014-08-27 2018-04-10 3M Innovative Properties Company Polyfluoroalkylated alkenes and silicone compounds prepared therefrom
US10822533B2 (en) 2016-08-10 2020-11-03 3M Innovative Properties Company Fluorinated pressure sensitive adhesives and articles thereof
CN109563389A (zh) 2016-08-10 2019-04-02 3M创新有限公司 氟化压敏粘合剂

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2936237A1 (de) * 1979-09-07 1981-03-19 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von fluorsubstituierten styrolen
US4543397A (en) * 1984-06-18 1985-09-24 Loctite (Ireland) Ltd. Styryloxy resins and compositions thereof
US4603101A (en) * 1985-09-27 1986-07-29 General Electric Company Photoresist compositions containing t-substituted organomethyl vinylaryl ether materials
DE3828064A1 (de) * 1988-08-18 1990-03-01 Hoechst Ag Polymerisate aus substituierten (2-haloalkoxy-1,1,2-trifluoraethoxy)-styrolen, verfahren zu ihrer herstellung und ihre verwendung

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100332915B1 (ko) * 1997-12-23 2002-10-25 주식회사 포스코 접착력 및 내식성이 개선된 강판 피복용 스티렌 고분자 킬레이트 접착제 제조방법

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DE3828063A1 (de) 1990-02-22
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