KR890013112A - 자외선 복사 경화성 매체 - Google Patents

자외선 복사 경화성 매체 Download PDF

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KR890013112A
KR890013112A KR1019890002297A KR890002297A KR890013112A KR 890013112 A KR890013112 A KR 890013112A KR 1019890002297 A KR1019890002297 A KR 1019890002297A KR 890002297 A KR890002297 A KR 890002297A KR 890013112 A KR890013112 A KR 890013112A
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blend
trifunctional
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제이. 크로우샤르 더글라스
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베르너 발데크
시바-가이기 아게
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    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
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    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
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    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
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    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
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    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
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    • C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
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    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a single or double bond to nitrogen
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/022—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polycondensates with side or terminal unsaturations
    • C08F299/024—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polycondensates with side or terminal unsaturations the unsaturation being in acrylic or methacrylic groups
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    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/06—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/06—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes
    • C08F299/065—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes from polyurethanes with side or terminal unsaturations

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Abstract

내용 없음.

Description

자외선 복사 경화성 매체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. (a) 1개 이상은 이 작용기성 또는 삼작용기성 폴리에스테르 아크릴레이트 또는 메타크릴레이트이고 기 나머지 1개 이상이 이 작용기성 또는 삼작용기성 폴리우레탄 아크릴레이트 또는 메타크릴레이트인, 아크릴레이트 또는 메타크릴레이트 작용성 말단기를 함유하는 2개 이상의 중합성 액체 올리고머 ; (b) 1개 이상의 단량체형 모노아크릴레이트 또는 모노메타크릴레이트, ; (c) 1개 이상의 지방족 펜타아크릴레이트 또는 펜타메타크릴레이트 ; 및 (d) 치환된 티오크산톤 화합물, 아민 화합물 및 아세토페논 유도체를 포함하는, 유효광개량의 광 개시제계를 포함하는 자외선 복사 경화성 매체.
  2. 제1항에 있어서, 성분(a)가 이작용기성 또는 삼작용기성 폴리에스테르 아크릴레이트 및 이 작용기성 또는 삼작용기성 폴리우레탄 아크릴레이트의 블렌드이고, 또 성분(d)가 치환된 티오크산톤 화합물, 아미노벤조 산의 에스테르 및 2-페닐 아세토페논 화합물의 블렌드인 자외선 복사 경화성 매체.
  3. 제1항에 있어서, 중량%로서, 1 내지 25%의 폴리에스테르 아크릴레이트, 1 내지 25%의 폴리우레탄 아크릴레이트, 10 내지 50%의 성분(b), 1 내지 35%의 성분(c), 0.5 내지 5.0%의 치환된 티오크산톤 화합물, 0.5 내지 5.0%의 아미노벤조산의 에스테르 및 0.5 내지 15.0%의 2-페닐아세토페논 화합물을 포함하는 자외선 복사 경화성 매체.
  4. 제1항에 있어서, 성분(a)가 이 작용기성 또는 삼작용기성 폴리에스테르 아크릴레이트 및 이작용기성 또는 삼작용기성 폴리우레탄 아크릴레이트의 블렌드이고, 성분(b)가 2-페녹시에틸 아크릴레이트이며, 성분(c)가 디펜타에리트리톨 펜타아크릴레이고, 또 성분(d)가 2-이소프로필티오크산톤, 에틸 4-디메틸아미노벤조에이트 및 2,2-디메톡시-2-페닐 아세토페논의 블렌드의 자외선 복사 경화성 매체.
  5. 제1항에 있어서, 유동 촉진제를 약 5.0 중량%까지 또한 함유하는 자외선 복사 경화성 매체.
  6. 제5항에 있어서, 상기 유동 촉진제가 폴리부텐인 매체.
  7. 매체 및 에나멜리 1 : 2 내지 1 : 5.5 범위인 중량비로 존재하는 경우, 제1항에 따른 매체 및 유리 에나멜을 포함하는 자외선 복사 경화성 피복 조성물.
  8. 제7항에 있어서, 상기 유리 에마멜이 금속 산화물들의 결합물을 포함하는 조성물.
  9. 제7항에 있어서, 상기 중량비가 1 : 4인 조성물.
  10. 제7항에 있어서, 상기 매체가 성분(a)로서 이작용기성 또는 삼작용기성 폴리에스테르 아크릴레이트 및 이작용기성 또는 삼작용기성 폴리우레탄 아크릴레이트의 블렌드, 성분(b)로서 2-페녹시에틸 아크릴레이트 성분(c)로서 디펜타에리트리톨 펜타아크릴레이트, 및 성분(d)로서 2-이소프로필티오크산톤, 에틸(4-디메틸아미노)벤조에이트 및 2,2-디메톡시-2-페닐아세토페논의 블렌드를 포함하는 조성물.
  11. (1) 제7항에 정의한 바와같이 피복 조성물을 내열 기판에 도포하고, (2) 그것을 기판에 도포한 후 피복을 자외선 복사로 경화시킨 다음, 또 (3) 그후 매체를 연소시키고 에나멜을 기판에 융합시키기에 충분한 온도에서 피복된 기판을 소성시키는 것을 포함하는, 내열기판을 피복시키는 방법.
  12. 제11항에 있어서, 상기 피복 조성물이, 성분(a)로서 이 작용기성 또는 삼작용기성 폴리에스테르 아크릴레이트 및 이작용기성 또는 삼작용기성 폴리우레탄 아크릴레이트의 블렌드, 성분(b)로서 2-페녹시에틸 아크릴레이트, 성분(c)로서 디펜타에리트리톨 펜타아크릴레이트, 및 성분(d)로서 2-이소프로필티오크산톤, 에틸(4-디메틸아미노) 벤조에이트 및 2,2-디메톡시 -2-페닐아세토페논의 블렌드를 포함하는 매체를 함유하는 방법.
  13. (1) 제7항에 정의한 바와같이, 유리 에나멜 및 매체를 포함하는 제1피복 조성물을 내열 기판에 도포하고 ; (2) 그것을 기판에 도포한 후 자외선 복사를 이용하여 제1피복을 경화시키며 ; (3) 저 융점 세라믹 후릿트, 전도성 금속 분말 및 수지성 매체를 포함하는 제2피복 조성물을 내열 기판에 일부분 이상을 겹쳐 도포하고 또 (4) 그후 도포되고 경화된 피복 조성물을 갖는 기판을 겹침 인쇄된 전기 전도층을 제공하기 위해, 매체가 연소되고 또 후릿트가 기판에 융합되기에 충분한 온도에서 소성시키는 것을 포함하는, 내열 기판을 피복시키는 방법.
KR1019890002297A 1988-02-26 1989-02-25 자외선 복사 경화성 매체 KR0130205B1 (ko)

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US160740 1988-02-26
US07/160,740 US4900763A (en) 1988-02-26 1988-02-26 Ultraviolet radiation curable vehicles
CH160740 1988-02-26

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KR890013112A true KR890013112A (ko) 1989-09-21
KR0130205B1 KR0130205B1 (ko) 1998-04-07

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JP (1) JPH01256509A (ko)
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KR0130205B1 (ko) 1998-04-07
BR8900870A (pt) 1989-10-17
EP0330619A3 (de) 1991-09-04
EP0330619A2 (de) 1989-08-30
AU2877589A (en) 1989-08-31
CA1311320C (en) 1992-12-08
DE58904586D1 (de) 1993-07-15
AU609931B2 (en) 1991-05-09
JPH01256509A (ja) 1989-10-13
US4900763A (en) 1990-02-13
ES2041440T3 (es) 1993-11-16
EP0330619B1 (de) 1993-06-09

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