KR890008114A - 살진균제 아졸릴- 유도체 - Google Patents

살진균제 아졸릴- 유도체 Download PDF

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Publication number
KR890008114A
KR890008114A KR1019880014721A KR880014721A KR890008114A KR 890008114 A KR890008114 A KR 890008114A KR 1019880014721 A KR1019880014721 A KR 1019880014721A KR 880014721 A KR880014721 A KR 880014721A KR 890008114 A KR890008114 A KR 890008114A
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South Korea
Prior art keywords
compound
formula
hydroxy
compound according
triazolyl
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KR1019880014721A
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KR960016122B1 (ko
Inventor
콜레 로베르토
카마기 지오반니
라티 귀셉피나
가라바글리아 카를로
미렌나 루이가
Original Assignee
원본미기재
프레시덴자 델 콘시글리오 데이 미니스트로 우피시오델 미니스트로 페르 일 코오르니나 멘토 델레 이니지아타베 페르 라 라세르타 사이엔티피카 에테크놀로지카
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Publication of KR890008114A publication Critical patent/KR890008114A/ko
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Publication of KR960016122B1 publication Critical patent/KR960016122B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/52—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C07D233/60—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms with hydrocarbon radicals, substituted by oxygen or sulfur atoms, attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

Abstract

내용 없음

Description

살진균제 아졸릴-유도체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하기 일반식(Ⅰ)의 화합물.
    식중, R1는 F, Cl, Br, CF3, 페닐, C1∼C2할로알콕시, 알킬티오, 할로알킬티오라디칼로 이루어진 군으로부터 선택되며, 상기 할로겐은 F, Cl, Br이며 ; R2H, F, Cl, Br, CF3로 이루어진 군으로부터 선택되고 ; R3, R4, R5는 동일하거나 상이할 수 있으며, H, C1∼C4알킬 또는 C3∼C6시클로알킬라디칼이고, 단, R4H, R5와 R3는 상이하며 ; Y는 H, CH3, OH, CN, F로 이루어진 군으로부터 선택되고 ; n은 1,2이며 ; m은 0.1이고 ; X는 0 또는 S이며 ; Rf는 C1∼C5폴리플루오로알킬, C2∼C4폴리플루오로알케닐, 폴리플루오로알콕시알킬 및 폴리플루오로알콕시알케닐라디칼로 이루어진 군으로부터 선택되며, 상기 화합물 모두는 적어도 2개의 불소원자 및 임의적으로 Cl 및 Br로 부터 선택된 다른 할로겐원자를 함유하고 ; Z는 CH 또는 N이다.
  2. 제 1 항에 있어서, 1-(1,2,4-트리아졸릴)-2-히드록시-2-(4-클로로페닐)-3-메틸-4-(1,1,2,2-테트라플루오로에톡시)부탄인 화합물.
  3. 제 1 항에 있어서, 1-(1,2,4-틀리아졸릴)-2-히드록시-2-(2,4-디클로로페닐)-3-메틸-4-(1,1,2,2-테트라플루오로에톡시)부탄인 화합물.
  4. 제 1 항에 있어서, 1-(1,2,4-틀리아졸릴)-2-히드록시-2-(2,4-디클로로페닐)-3-메틸-4-(1,1,2,2-테트라플루오로에톡시)핵산인 화합물.
  5. 제 1 항에 있어서, 1-(1,2,4-트리아졸릴)-2-히드록시-2-(4-클로로페닐)-3,3-디메틸-4-(1,1,2,2-테트라플루오로에톡시)부탄인 화합물.
  6. -20℃ 내지 100℃의 온도에서, 촉매량, 또는 화학양론적양의 강염기 존재하의, 비양성자성 또는 알코올 용매중에서 하기 일반식(Ⅱ)의 화합물을 하기 일반식(A)의 플루오로올레핀과 반응시켜서 하기일반식(Ia) 화합물을 수득하고 임의적으로 일반식(Ia)화합물을 탈불화수소화 반응에 적용시켜서 하기 일반식(Ib)의 불포화된 화합물을 수득함을 특징으로 하는, 제 1 항에 따른 일반식(Ⅰ)화합물의 제조방법.
    식중, X1은 F, Cl, CF3또는 -OX3인데, 상기 X3는 적어도 3개의 불소원자 및 임의적으로 Cl 및 Br로 부터 선택된 다른 할로겐원자를 함유한, 탄소수 1∼3의 폴리플루오로알킬라디칼이며 ; R1, R2, R3, R4, R5, n, x 및 z는 제 1 항에서 정의된 바와 같은 의미이다.
  7. 하기 일반식 (XⅢa)의 화합물.
    식중, X는 O 또는 S이며 ; X2는 F, Cl, CF3이고 ; X3는 F, Cl, CF3또는 -OX3이며, 상기 X3는 적어도 3개의 불소원자 및 임의적으로 Cl 및 Br로 부터 선택된 다른 할로겐원자를 함유한, C1∼C3폴리플루오로알킬라디칼이며 ; n은 1.2이고 ; R은 에틸 또는 메틸라디칼이다.
  8. -20℃ 내지 100℃의 온도에서, 촉매량 또는 화학양론적양의 강염기 존재하의, 비양성자성 또는 알코올용매중에서 하기 일반식(XⅡ)의 히드록시(또는 메르캅토)에스테르를 하기 일반식(A)의 플루오로올레핀과 반응시킴을 특징으로 하는, 제 7 항에 따른 일반식(XⅢa)의 화합물의 제조방법.
    식중, X, X1, X2, X4, X5, n 및 R은 제 7 항에서 정의한 바와 같은 의미이다.
  9. 진균감염이 예상되거나 이미 진행되고 있을때, 1종 이상의 제 1 내지 5 항에 따른 화합물을 그 자체 또는 적합한 조성물의 형태로서 유효량을 식물, 종자 또는 식물에 인접한 지역에 살포함을 특징으로 하는 유용식물의 진균감염퇴치방법.
  10. 활성 성분인 1종 이상의 제 1 내지 5 항에 따른 화합물과 함께 고형 또는 액체담체 및 임의적으로 다른 첨가제를 가지는 살진균제조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880014721A 1987-11-09 1988-11-09 살진균제 아졸릴-유도체 KR960016122B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT22560A/87 1987-11-09
IT8722560A IT1232943B (it) 1987-11-09 1987-11-09 Azolilderivati fungicidi.

Publications (2)

Publication Number Publication Date
KR890008114A true KR890008114A (ko) 1989-07-08
KR960016122B1 KR960016122B1 (ko) 1996-12-04

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Application Number Title Priority Date Filing Date
KR1019880014721A KR960016122B1 (ko) 1987-11-09 1988-11-09 살진균제 아졸릴-유도체

Country Status (18)

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US (1) US5021442A (ko)
EP (1) EP0315946B1 (ko)
JP (1) JP2651933B2 (ko)
KR (1) KR960016122B1 (ko)
AT (1) ATE125533T1 (ko)
AU (1) AU615488B2 (ko)
BR (1) BR8805808A (ko)
CA (1) CA1333069C (ko)
DE (1) DE3854224T2 (ko)
DK (1) DK171479B1 (ko)
ES (1) ES2074992T3 (ko)
GR (1) GR3017516T3 (ko)
HU (1) HU204515B (ko)
IL (1) IL88312A (ko)
IT (1) IT1232943B (ko)
NO (1) NO884974L (ko)
SU (2) SU1676447A3 (ko)
ZA (1) ZA888295B (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE59108565D1 (de) * 1990-08-09 1997-04-03 Bayer Ag Halogenalkyl-azolyl-Derivate
US5358939A (en) * 1992-06-25 1994-10-25 Rohm And Haas Company Fungicidal 2-aryl-2,2-disubstituted ethyl-1,2,4-triazoles
NZ270418A (en) * 1994-02-07 1997-09-22 Eisai Co Ltd Polycyclic triazole & imidazole derivatives, antifungal compositions
IT1273509B (it) * 1995-04-07 1997-07-08 Zambon Spa Composti azolici ad attivita' antimicotica per uso umano e veterinario
IT1283038B1 (it) * 1996-02-28 1998-04-07 Zambon Spa Composti azolici ad attivita' antimicotica per uso umano e veterinario
IT1296924B1 (it) 1997-12-05 1999-08-03 Zambon Spa Composti diolici intermedi per la preparazione di composti ad attivita' antimicotica
IT1296925B1 (it) * 1997-12-05 1999-08-03 Zambon Spa Procedimento per la preparazione di composti ad attivita' antimicotica

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2918894A1 (de) * 1979-05-10 1980-11-20 Bayer Ag Fluorierte 1-triazolyl-butan-derivate, verfahren zu ihrer herstellung und ihre verwendung als fungizide
EP0052424B2 (en) * 1980-11-19 1990-02-28 Imperial Chemical Industries Plc Triazole compounds, a process for preparing them, their use as plant fungicides and fungicidal compositions containing them
JPS5998073A (ja) * 1982-11-02 1984-06-06 フアイザ−・コ−ポレ−シヨン トリアゾ−ル系抗真菌剤
CH658654A5 (de) * 1983-03-04 1986-11-28 Sandoz Ag Azolderivate, verfahren zu ihrer herstellung und mittel die diese verbindungen enthalten.
IT1204773B (it) * 1986-01-23 1989-03-10 Montedison Spa Azolilderivati fungicidi
AU615887B2 (en) * 1986-12-23 1991-10-17 Agrimont S.R.L. Fungicide azolyl-derivatives
IT1198240B (it) * 1986-12-23 1988-12-21 Agrimont Spa Azolilderivati fungicidi
JPH0819109A (ja) * 1994-07-01 1996-01-19 Matsushita Electric Ind Co Ltd モータの制御方法

Also Published As

Publication number Publication date
EP0315946A2 (en) 1989-05-17
EP0315946A3 (en) 1991-04-10
KR960016122B1 (ko) 1996-12-04
IL88312A (en) 1993-01-31
NO884974D0 (no) 1988-11-08
IT8722560A0 (it) 1987-11-09
DK621888A (da) 1989-05-10
EP0315946B1 (en) 1995-07-26
NO884974L (no) 1989-05-10
SU1676436A3 (ru) 1991-09-07
HUT49461A (en) 1989-10-30
IL88312A0 (en) 1989-06-30
JP2651933B2 (ja) 1997-09-10
DE3854224T2 (de) 1995-12-07
US5021442A (en) 1991-06-04
DE3854224D1 (de) 1995-08-31
SU1676447A3 (ru) 1991-09-07
AU2476688A (en) 1989-05-11
DK621888D0 (da) 1988-11-08
CA1333069C (en) 1994-11-15
AU615488B2 (en) 1991-10-03
IT1232943B (it) 1992-03-10
ZA888295B (en) 1989-07-26
JPH01301665A (ja) 1989-12-05
HU204515B (en) 1992-01-28
ES2074992T3 (es) 1995-10-01
DK171479B1 (da) 1996-11-18
ATE125533T1 (de) 1995-08-15
GR3017516T3 (en) 1995-12-31
BR8805808A (pt) 1989-08-01

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