KR890005223A - 열경화성 수지조성물 - Google Patents

열경화성 수지조성물 Download PDF

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Publication number
KR890005223A
KR890005223A KR1019880012529A KR880012529A KR890005223A KR 890005223 A KR890005223 A KR 890005223A KR 1019880012529 A KR1019880012529 A KR 1019880012529A KR 880012529 A KR880012529 A KR 880012529A KR 890005223 A KR890005223 A KR 890005223A
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South Korea
Prior art keywords
resin composition
thermosetting resin
component
composition according
compound
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KR1019880012529A
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English (en)
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KR910008321B1 (ko
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마사오 가메야마
시게유끼 구마가와
Original Assignee
원본미기재
미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤
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Publication of KR890005223A publication Critical patent/KR890005223A/ko
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Publication of KR910008321B1 publication Critical patent/KR910008321B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014—Nitrogen containing compounds
    • C08G59/4042—Imines; Imides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/04—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonamides, polyesteramides or polyimides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
  • Reinforced Plastic Materials (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

내용 없음

Description

열경화성 수지조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. 필수성분으로서 폴리아미노 화합물과 불포화 비스말레이미드 화합물간의 예비반응 생성물(a), 에폭시 그룹 함유 비닐화합물(b), 비닐 그룹 비함유 지방족 또는 방향족 할로겐화 에폭시 화합물(b'), 에폭시경화제(c) 및 래디칼 중합개시재(d)를 포함하며, 상기 성분(a)인 예비반응 생성물은 성분(b)인 에폭시 그룹 함유 비닐화합물의 비존재하에서 수행되는 예비반응에 의해 생성되는 것이 특징인 열경화성 수지조성물.
  2. 제1항에서, 성분(b)인 에폭시 그룹 함유 비닐화합물은 다음 일반식으로 나타낸 화합물인 것이 특징인 열경화성 수지조성물.
    여기서, R4는 탄화수소 그룹을 함유하는 일가비닐 그룹을 나타내며, R5,R6및 R7은 수소원자 또는 각각 4탄소원자까지 갖는 알킬그룹, R5및 R7은 함께 결합되어 선형 알키렌 그룹을 형성하며, 1,m 및 n은 0또는 1의 정수이다.
  3. 제2항에서, 성분(b)인 에폭시 그룹 함유 비닐 화합물은 글리시딜 아크릴에이트, 글리시딜 메타크릴에이트 및 아릴글리시딜 에테르로 구성되는 그룹으로부터 선택되는 것이 특징인 열경화성 수지조성물.
  4. 제1항에서, 성분(b')인 지방족 또는 방향족 할로겐화 에폭시 화합물은 다음 일반식으로 나타낸 화합물인 것이 특징인 열경화성 수지 조성물.
    여기서, X는 모노-, 디-, 트리- 또는 테트라- 원자가 할로겐- 치환 지방족 또는 방향족 탄화수소 그룹을 나타내며, R8, R9및 R10은 수소원자 또는 1-4탄소원자를 갖는 알킬그룹을 나타내며, p, q및r은 각각 0또는 1의 정수이고, s는 1-4의 정수이다.
  5. 제4항에서, 성분(b')인 디브로모네오펜틸글리콜 디글리시딜 에테르, 디브로모크레실 글리시딜 에테르, 브로모페놀노보락 글리시딜 에테르 및 2, 6, 2', 6'-테트라브로모비스페놀 디글리시딜 에테르로 구성되는 그룹으로부터 선택되는 것이 특징인 열경화성 수지조성물
  6. 제1항에서, 성분(b)의 양은 성분(a)의 100중량부당 2-140중량부이며, 성분(b')의 양은 성분(b)의 100중량부당 4-100중량부이며, 성분(c)의 양은 성분(a), (b) 및 (b')의 합 100중량부당 0.01-100중량부이며, 또한 성분(d)의 양은 성분(a), (b) 및 (b')의 합 100중량부당 0.01-10중량부인 것이 특징인 열경화성 수지조성물.
  7. 제1항에서, 성분(a)에서, 불포화 비스말레이미드 화합물은 폴리아미노 화합물의 그람당량당 0.1-10그람당량의 양으로 사용되는 것이 특징인 열경화성 수지조성물.
  8. 제1항에서, 내염제(e) 및/또는 충전재(f)를 더 포함하는 것이 특징인 열경화성 수지조성물.
  9. 제8항에서, 내염제(e)는 안티모니 트리옥사이드인 것이 특징인 열경화성 수지조성물.
  10. 제8항에서, 내염제(e)는 0.3-30중량％의 양으로 혼합되는 것이 특징인 열경화성 수지조성물.
  11. 제8항에서, 충전재는 절단된 유리섬유인 것이 특징인 열경화성 수지조성물.
  12. 제11항에서, 절단된 유리섬유는 20-70중량％의 양으로 혼합되는 것이 특징인 열경화성 수지조성물.
  13. 제11항에서, 충전재(f)는 유리구슬들로 구성되는 것이 특징인 열경화성 수지조성물.
  14. 제13항에서, 유리구슬들은 30중량％까지의 양으로 혼합되는 것이 특징인 열경화성 수지조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880012529A 1987-09-30 1988-09-28 열경화성 수지조성물 KR910008321B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP62244247A JPH0721042B2 (ja) 1987-09-30 1987-09-30 熱硬化性樹脂組成物
JP244,247 1987-09-30
JP62-244247 1987-09-30

Publications (2)

Publication Number Publication Date
KR890005223A true KR890005223A (ko) 1989-05-13
KR910008321B1 KR910008321B1 (ko) 1991-10-12

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Application Number Title Priority Date Filing Date
KR1019880012529A KR910008321B1 (ko) 1987-09-30 1988-09-28 열경화성 수지조성물

Country Status (9)

Country Link
US (1) US4985478A (ko)
EP (1) EP0310424B1 (ko)
JP (1) JPH0721042B2 (ko)
KR (1) KR910008321B1 (ko)
CN (1) CN1027278C (ko)
AT (1) ATE99712T1 (ko)
CA (1) CA1305582C (ko)
DE (1) DE3886866T2 (ko)
MY (1) MY103402A (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2742101B2 (ja) * 1989-08-25 1998-04-22 三井化学株式会社 ターボファンエンジンのファンケース内部構造材
US5393887A (en) * 1993-10-04 1995-02-28 Monsanto Company Bisimide compositions
US5302723A (en) * 1993-10-04 1994-04-12 Monsanto Company Process for preparing flame retardant bisimide compositions
AU4802199A (en) * 1998-07-28 2000-02-21 Hitachi Chemical Company, Ltd. Semiconductor device and method for manufacturing the same
CN101696349B (zh) * 2009-11-03 2012-11-21 中国西电集团公司 一种胶黏剂及其制备方法暨以该胶黏剂制备的环氧玻璃坯布
EP3632941B1 (en) * 2018-10-01 2023-08-23 Cubicure GmbH Resin composition
CN110846108B (zh) * 2019-11-14 2021-11-30 安徽金德润滑科技有限公司 一种公路车辆齿轮油及其制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4005154A (en) * 1971-06-24 1977-01-25 Rhone-Poulenc S.A. Curing 1,2-epoxy with prepolymer based on polyamines and oligomers possessing imide groups
US3998904A (en) * 1971-10-18 1976-12-21 Rhone-Poulenc S.A. Polyamines with imide groups
JPS4943912A (ko) * 1972-09-01 1974-04-25
JPS4945996A (ko) * 1972-09-11 1974-05-02
FR2201313B1 (ko) * 1972-10-02 1975-01-03 Rhone Poulenc Sa
JPS5628215A (en) * 1979-08-17 1981-03-19 Hitachi Chem Co Ltd Preparation of imide prepolymer
JPS5952905B2 (ja) * 1980-03-26 1984-12-21 新神戸電機株式会社 難燃性フエノ−ル樹脂組成物
US4528305A (en) * 1984-04-13 1985-07-09 Ciba-Geigy Corporation Epoxy resin modeling stock
US4595623A (en) * 1984-05-07 1986-06-17 Hughes Aircraft Company Fiber-reinforced syntactic foam composites and method of forming same
JPS60252628A (ja) * 1984-05-28 1985-12-13 Mitsui Petrochem Ind Ltd 熱硬化性樹脂組成物
JPS61272227A (ja) * 1985-05-28 1986-12-02 Mitsui Petrochem Ind Ltd 熱硬化性樹脂組成物

Also Published As

Publication number Publication date
CN1032802A (zh) 1989-05-10
MY103402A (en) 1993-06-30
EP0310424A3 (en) 1990-07-11
CA1305582C (en) 1992-07-21
ATE99712T1 (de) 1994-01-15
JPH0721042B2 (ja) 1995-03-08
DE3886866D1 (de) 1994-02-17
CN1027278C (zh) 1995-01-04
EP0310424A2 (en) 1989-04-05
US4985478A (en) 1991-01-15
KR910008321B1 (ko) 1991-10-12
EP0310424B1 (en) 1994-01-05
JPS6490218A (en) 1989-04-06
DE3886866T2 (de) 1994-07-14

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