KR880014059A - 혼합 폴리아미드 올리고머 - Google Patents

혼합 폴리아미드 올리고머 Download PDF

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KR880014059A
KR880014059A KR1019880005516A KR880005516A KR880014059A KR 880014059 A KR880014059 A KR 880014059A KR 1019880005516 A KR1019880005516 A KR 1019880005516A KR 880005516 A KR880005516 A KR 880005516A KR 880014059 A KR880014059 A KR 880014059A
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mixture
nhco
conh
oligomer
composite
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알.루보위쯔 하이만
에이취 쉐파아드 클리드
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제이 피터 모흔
더 보잉 컴파니
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/42Polyamides containing atoms other than carbon, hydrogen, oxygen, and nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/903Interpenetrating network
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/2964Artificial fiber or filament
    • Y10T428/2967Synthetic resin or polymer
    • Y10T428/2969Polyamide, polyimide or polyester

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyamides (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Reinforced Plastic Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

혼합 폴리아미드 올리고머
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 다음 일반식의 가교 결합성 폴리아미드 올리고머의 혼합물과 : E-CONH-P-NHCO-[-Q-CONH-P-NHCO-]m-E; E-NHCO-Q-CONH-[-P-NHCO-Q-CONH-]m-E; Ar-[-CONH-P-NHCO-Q-CONH-E]n; Ar-[-NHCO-Q-CONH-P-NHCO-E]n; Ar-[-COHN-E]n; Ar-[-NHCO-E]n; Ar-[-COHN-P-NHCO-E]n; 또는 Ar-[-NHCO-Q-CONH-E]n가교 결합을 못하는 비교되는 폴리머로 구성되는 올리고머 혼합물. 여기서 m=작은 정수 : E=진보된 복합체에서 경화된 올리고머의 내용매성을 개선하기 위한 가교 결합성 앤드 캡의 잔유물 : P 그리고 Q=각각의 디아민의 선형 잔유물(P), 그리고 디에시드 할라이드(Q) ; n=3 또는 4 Ar=방향성 부분이다.
  2. 청구범위 1의 혼합물에 있어서, 비교되는 플리머의 뼈대는 실질적으로 가교 결합 올리고머의 뼈대와 동일한 것을 특징으로하는 올리고머 혼합물.
  3. 청구범위 2의 혼합물에 있어서, 비교되는 플리머는 아닐린 또는로 구성되는 구룹으로부터 선택되는 방향족 화합물로 캡되는 것을 특징으로 하는 올리고머 혼합물.
  4. 청구범위 2의 혼합물에 있어서, 가고 결합성 올리고머 및 비교되는 폴리머는 실질적으로 선형의 뼈대를 가지는 것을 특징으로 하는 올리고머 혼합물.
  5. 청구범위 1의 혼합물에 있어서, 혼합물은 실질적으로 동일 물량의 올리고머 및 폴리머로 구성되는 것을 특징으로 하는 올리고머 혼합물.
  6. 청구범위 1의 혼합물에 있어서, 가교 결합 앤드캡(E)는 다음으로 구성되는 그룹으로부터 선택된다.
    R1=저급알킬, 저급알콕시, 아릴, 아릴옥시, 치환알킬, 치환아릴, 할로겐, 또는 그의 혼합물. j=0, 1, 또는 2 : G=-CH2-, -O-, -S-, 또는 -SO2-; Me=메틸 ; 그리고 T=알릴 또는 메타알릴 이다.
  7. 프리프래그로서, 제 1 항의 혼합물과 섬유형 또는 입자형 보강용 첨가제로 구성된 프리프래그.
  8. 복합체로서, 청구범위 7의 경화 프리프래그로 구성되는 복합체.
  9. 복합체로서 청구범위 1의 경화 혼합물로 구성되는 복합체.
  10. 청구범위 1의 혼합물에 있어서, 올리고머는 일반식 : E-CONH-P-NHCO-[-Q-CONH-P-NHCO-]m-E; 또는 E-NHCO-Q-CONH-[-P-NHCO-Q-CONH-]m-E;을 갖는 것을 특징으로 하는 올리고머 혼합물.
  11. 청구범위 1의 혼합물에 있어서, 디아민(P)와 디에시드 할라이드(Q)는 각각 다음으로 구성되는 그룹으로 부터 선택되는 것을 특징으로 하는 올리고머 혼합물 :
    여기서, q=-SO2-, -CO-, -S-, 또는 -(CF3)2C-, 그리고 바람직하게는 -SO2- 또는 -CO-; Me=메틸; m=일반적으로 5보다 작은 정수, 그리고 바람직하게는 0 또는 1 : D=-CO-, -SO2-, 또는 -(CF3)2C-의 어떤것 : A=-NH2또는 -COX; B=A=-NH2라면, -NH2그리고 A=-COX라면, -COX; X=할로겐 : 그리고
    R1=C2에서 C12의 2가 지방성, 지환성 또는 방향성 라디칼이다.
  12. 청구범위 1의 혼합물에 있어서, 올리고머 또는 혼합물중의 최소한 하나는 적절하게 도우프된 복합체로 반도전성 또는 도전성을 전달하기 위한 Schiff 염기, 옥사졸, 티아졸 또는 이미다졸 결합으로 구성되는 그룹으로부터 선택되는 도전성 결합을 포함하는 것을 특징으로 하는 올리고머 혼합물.
  13. 청구범위 12의 혼합물에 있어서, 혼합물은 적절한 도펀트의 충분한 양으로 구성되는 것을 특징으로 하는 올리고머 혼합물.
  14. 청구범위 13의 혼합물에 있어서, 결합은 Schiff 염기 결합이며, 따라서 올리고머 또는 폴리머의 최소한 하나는 다음으로 구성되는 그룹으로부터 선택된 라디칼을 포함하는 것을 특징으로 하는 올리고머 혼합물 :
    여기서 R=-CH2-, -SO2-, -O-, -CO-, -(CH3)2C-, 또는 -(CF3)2C-의 어떤 것과 결합된 아릴 부분의 대다수를 포함하는 짧은 아릴 사슬 또는 방향족의 일부분 : 그리고 q=0-4이다.
  15. 청구범위 14의 혼합물에 있어서, 올리고머 및 폴리머는 실질적으로 동일한 뼈대를 갖는 것을 특징으로 하는 올리고머 혼합물.
  16. 프리프래그로서, 청구범위 13의 혼합물과 섬유형 또는 입자형 보강용 첨가재로 구성된 프리프래그.
  17. 복합체로서, 청구범위 13의 경화 혼합물로 구성되는 복합체.
  18. 청구범위 6의 혼합물에 있어서, i=2인것을 특징으로 하는 올리고머 혼합물.
  19. 청구범위 18의 혼합물에 있어서, 올리고머는 일반식 : E=CONH-P-NHCO-[-Q-CONH-P-NHCO-]m-E; E-NHCO-Q-CONH-[-P-NHCO-Q-CONH-]m-E;을 가지며, 폴리머는 올리고머와 실질적으로 동일한 뼈대를 가지는 것을 특징으로 하는 올리고머 혼합물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880005516A 1987-05-18 1988-05-12 혼합 폴리아미드 올리고머 KR920007527B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/051,884 US4847333A (en) 1985-09-30 1987-05-18 Blended polyamide oligomers
US051,884 1987-05-18
US51884 1987-05-18

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KR880014059A true KR880014059A (ko) 1988-12-22
KR920007527B1 KR920007527B1 (ko) 1992-09-05

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US (1) US4847333A (ko)
EP (1) EP0292677A3 (ko)
JP (1) JPS63305165A (ko)
KR (1) KR920007527B1 (ko)
CA (1) CA1319214C (ko)
IL (1) IL86317A (ko)

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IL86317A (en) 1992-05-25
IL86317A0 (en) 1988-11-15
CA1319214C (en) 1993-06-15
EP0292677A2 (en) 1988-11-30
JPS63305165A (ja) 1988-12-13
KR920007527B1 (ko) 1992-09-05
US4847333A (en) 1989-07-11
EP0292677A3 (en) 1990-05-16

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