KR880006202A - 아미드 치환 유도체 그 제조 방법 및 농원예용 살균제 - Google Patents

아미드 치환 유도체 그 제조 방법 및 농원예용 살균제 Download PDF

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KR880006202A
KR880006202A KR870012543A KR870012543A KR880006202A KR 880006202 A KR880006202 A KR 880006202A KR 870012543 A KR870012543 A KR 870012543A KR 870012543 A KR870012543 A KR 870012543A KR 880006202 A KR880006202 A KR 880006202A
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carbon atoms
cyano
alkyl
lower alkyl
carboxamide
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히데오 스즈끼
다께시 미다
도시아끼 다께야마
요시노리 오찌아이
마사미 하나우에
마사오 니시구보
가즈히로 야마기시
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나까이 다께오
닛산 가가꾸 고오교오 가부시기 가이샤
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Priority claimed from JP26476386A external-priority patent/JPS63119463A/ja
Application filed by 나까이 다께오, 닛산 가가꾸 고오교오 가부시기 가이샤 filed Critical 나까이 다께오
Publication of KR880006202A publication Critical patent/KR880006202A/ko

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Abstract

내용 없음

Description

아미드 치환 유도체 그 제조방법 및 농원예용 살균제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 일반식(I)의 아미드 유도체.
    우의 일반식에서, A는 다음 구조식의 5원 복소환이고,
    B는 다음 구조식의 5원 복소환이거나, OR7또는 SR7이고,
    D는 시아노, 티오카르바모일 또는 -CSNHCOR8, -CSNH2또는 -CH의 아실티오카르바모일이고 위의 구조식에서, R1은 수소, 탄수소 1 내지 24의 저급알킬, 탄소수 1내지 4의 할로겐화 알킬, 탄소수 2 내지 4의 알켄일, 탄소수 2 내지 4의 할로겐하알켄일, 탄소수 2 내지 4의 알킬일 또는 탄소수 3 내지 5의 알렌일이고, R2,R3및 R4는 각각 수소, 탄소수 1 내지 4의 저급 알킬, 할로겐원자, 탄소수 1 내지 4의 할로겐화알킬, 탄소수 1 내지 4의 알콕시, 시아노 또는 탄소수 1 내지 4의 저급 알킬티오이고, R4,R5및 R6은 각각 수소, 탄소수 1 내지 4의 저급 알킬, 할로겐원자, 탄소수 1 내지 4의 할로겐화알킬이고, R7은 탄소수 1 내지 4의 저급알킬, 탄소수 1 내지 4의 할로겐화알킬, 탄소수 2 내지 4의 알킨일, 탄소수 2 내지 4의 알킨일, 탄소수 3 내지 4의 알콕시알킬, 탄소수 3 내지 6의 할로겐화알킨일, 탄소수 2 내지 4의 시아노알킬 또는 탄소수 2 내지 4의 할로겐화알켄일이고, R8은 탄소수 1 내지 4의 저급알킬, 시클로헥실 또는 페닐이다.
  2. 제1항에 있어서, 일반식(I)이 다음과 같이 정의되는 아미드 유도체.
    위에서, A는 다음 구조식의 5원 복소환이고,
    B는 다음 구조식의 5원 복소환이거나, OR7또는 SR7이고,
    D는 시아노, 티오카르바모일 또는 -CSNHCOR8, -CSNH2또는 -CH의 아실티오카르바모일이고 위의 구조식에서, R1은 수소, 탄수소 1 내지 4의 저급알킬, 탄소수 1내지 4의 할로겐화 알킬, 탄소수 2 내지 4의 알켄일, 탄소수 2 내지 4의 할로겐하알켄일, 탄소수 2 내지 4의 알킬일 또는 탄소수 3 내지 5의 알렌일이고, R2및 R3은 각각 수소, 탄소수 1 내지 4의 저급알킬, 할로겐원자, 탄소수 1 내지 4의 할로겐화 알킬, 탄소수 1 내지 4의 알콕시, 시아노 또는 탄소수 1 내지 4의 저급알킬티오이고, R4, R5및 R6은 각각 수소, 탄소수 1내지 4의 저급알킬, 할로겐원자 또는 탄소수 1내지 4의 할로겐화 알킬이고,R7은 탄소수 1 내지 4의 저급알킬, 탄소수 1내지 4의 할로겐화알킬, 탄소수 2 내지 4의 알켄일, 탄소수 2 내지 4의 알킨일, 탄소수 3 내지 4의 알콕시알킬, 탄소수 3 내지 6의 할로겐하 알킨인, 탄소수 2 내지 4의 시아노알킬 또는 탄소수 2 내지 4의 할로겐하 알켄일이고, R8은 탄소수 1 내지 4의 저급알킬, 시클로헥실 또는 페닐이다.
  3. 제1항에 있어서, 일반식(IA)로 표시되는 아미드 유도체.
    위의 일반식에서, R1은 탄소수 1 내지 3의 알킬이고, R2는 수소, 메틸, 메톡시 또는 할로겐원자이고, D는 -CN 또는 -C-NH2이고,
    B는,
  4. 제1항에 있어서, 아미드 유도체가 하기 화합물중의 하나인 아미드 유도체.
    N-(시아노-3-티에닐메틸)-1,3-디메틸-1H-피라졸-5-카르복수아미드; N-(시아노-2-티에닐메틸)-1,3-디메틸-1H-피라졸-5-카르복스아미드; 1,3-디메틸-N-[3-티에틸(티오카르바모일)메틸]--1H-피라졸-5-카르복스아미드; 1,3-디메틸-N-[2-티에틸(티오카르바모일)메틸]-1H-피라졸-5-카르복스아미드;N-(시아노-2-푸라닐메틸)-1H-피라졸-4-카르복스아미드;N-(시아노-1H-피라졸-1-일메틸-1-일메틸)-1-메틸-1H-피라졸-4-카르복스아미드;N-(시아노-2-푸라닐메틸)-1,3-디메틸-1H-피라졸-5-카르복스아미드;1-에틸-3-메틸-N-3[3-티에닐(티오카르바모일)메틸]-1H-피라졸-5-카르복스아미드;N-(시아노-1H-피라졸-1-일메틸)-1,3-디메틸-1H-피라졸-5-카르복스아미드;N-(시아노-3-푸라닐메틸)-1,3-디메틸-1H-피라졸-5-카르복스아미드;N-(시아노-3-푸라닐메틸)-1-에틸-3-메틸-1H-피라졸-5-카르복스아미드;N-(시아노-3-티에닐메틸)-1-에틸-3-메틸-1H-피라졸-5-카르복스아미드;N-(시아노-2-티에닐메틸)-1-메틸-1H-피라졸-4-카르복스아미드;3-클로로-N-(시아노-3-티에닐메틸)-1-1H-피라졸-5-카르복스아미드;N-(시아노-2-푸라닐메틸)-3-메톡시-1-1H-피라졸-5-카르복스아미드.
  5. 일반식(3)의 아미노 아세토니트릴 유도체를 일반식(4)의 산할라이드와 산수용체 존재하에 반응시켜, 일반식(5)의 화합물을 제조하는 방법.
    위의 일반식에서, A는 다음 구조식의 5원 복수환이고,
    R1은 수소, 탄소수 1 내지 4의 저급알킬, 탄소수 1 내지 4의 할로겐화알킬, 탄소수 2 내지 4의 알켄일, 탄소수 2 내지 4의 할로겐화알켄일, 탄소수 2 내지 4의 알킨일 또는 탄소수 3 내지 5의 알렌일이고, R2및 R3은 각각 수소, 탄소수 1 내지 4의 저급알킬, 할로겐원자, 탄소수 1 내지 4의 할로겐화알킬, 탄소수 1 내지 4의 알콕시, 시아노 또는 탄소수 1 내지 4의 저급알킬티오이고, B는 다음 구조식의 5원 복소환이거나, OR7또는 SR7이고,
    R4, R5및 R6은 각각 수소, 탄소수 1 내지 4의 저급알킬, 할로겐원자 또는 탄소수 1 내지 4의 할로겐화알킬이고, R7은 탄소수 1 내지 4의 저급알킬, 탄소수 1 내지 4의 할로겐화알킬, 탄소수 2 내지 4의 알켄일, 탄소수 2 내지 4의 알킨일, 탄소수 3 내지 4의 알콕시알킬, 탄소수 3 내지 6의 할로겐화알킨일, 탄소수 2 내지 4의 시아노알킬 또는 탄소수 2 내지 4의 할로겐화 알킬일이고, X는 할로겐원자이다.
  6. 일반식(I)의 화합물을 유효성분으로 함유하는 살균제.
    위의 일반식에서, A는 다음 구조식의 5원 복소환이고,
    B는 다음 구조식의 복소환이거나, OR7또는 SR7이고,
    D는 시아노,티오카르바모일 또는 -CSNHCOR8, -CSNH2또는 -CN의 아실티오카르바모일이고 위의 구조식에서, R1은 수소, 탄수소 1 내지 4의 저급알킬, 탄소수 1내지 4의 할로겐화 알킬, 탄소수 2 내지 4의 알켄일, 탄소수 2 내지 4의 할로겐화알켄일, 탄소수 2 내지 4의 알킬일 또는 탄소수 3 내지 5의 알렌일이고, R2및 R3은 각각 수소, 탄소수 1 내지 4의 저급알킬, 할로겐원자, 탄소수 1 내지 4의 할로겐화 알킬, 탄소수 1 내지 4의 알콕시, 시아노 또는 탄소수 1 내지 4의 저급알킬티오이고, R4, R5및 R6은 각각 수소, 탄소수 1내지 4의 저급알킬, 할로겐원자 또는 탄소수 1내지 4의 할로겐화 알킬이고,R7은 탄소수 1 내지 4의 저급알킬, 탄소수 1내지 4의 할로겐화알킬, 탄소수 2 내지 4의 알켄일, 탄소수 2 내지 4의 알킨일, 탄소수 3 내지 4의 알콕시알킬, 탄소수 3 내지 6의 할로겐화 알킨인, 탄소수 2 내지 4의 시아노알킬 또는 탄소수 2 내지 4의 할로겐화 알켄일이고, R8은 탄소수 1 내지 4의 저급알킬, 시클로헥실 또는 페닐이다.
  7. 제6항에 있어서, 유효성분이 청구범위 제2항의 화합물인 살균제.
  8. 제6항에 있어서, 유효성분이 청구범위 제3항의 화합물인 살균제.
  9. 제6항에 있어서, 유효성분이 청구범위 제4항의 화합물인 살균제.
  10. 청구범위 제1항의 화합물을 사용하여 병인성균 피코미세테스(Phycomycetes)를 살균하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR870012543A 1986-11-06 1987-11-06 아미드 치환 유도체 그 제조 방법 및 농원예용 살균제 KR880006202A (ko)

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JP62-103044 1987-04-28
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