KR870011125A - 프토크로믹 스피로피란 화합물 - Google Patents

프토크로믹 스피로피란 화합물 Download PDF

Info

Publication number
KR870011125A
KR870011125A KR870004781A KR870004781A KR870011125A KR 870011125 A KR870011125 A KR 870011125A KR 870004781 A KR870004781 A KR 870004781A KR 870004781 A KR870004781 A KR 870004781A KR 870011125 A KR870011125 A KR 870011125A
Authority
KR
South Korea
Prior art keywords
alkyl
aryl
spiropyran
atom
group
Prior art date
Application number
KR870004781A
Other languages
English (en)
Inventor
죠지 헬러 해리
니겔 올리버 스테픈
휘탈 죤
톰린슨 아지반
Original Assignee
더 프레시 캄페니 피엘씨
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 더 프레시 캄페니 피엘씨 filed Critical 더 프레시 캄페니 피엘씨
Publication of KR870011125A publication Critical patent/KR870011125A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/96—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings spiro-condensed with carbocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1545—Six-membered rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pyrane Compounds (AREA)
  • Eyeglasses (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Optical Filters (AREA)

Abstract

내용 없음

Description

프토크로믹 스피로피란 화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
도면에 있어서 : 도면 Ⅰ은 무색의 상태인 실시예 1,6 또는 7에 얻은 화합물들의 흡수 스펙트라를 보여준다.
도면 2 : 천연색 사진의 카메라 섬광장치의 노출 전과 후에 실시예 6 화합물의 자외선및 가시스펙트라를 보여준다.
도면 3 : 천연색 사진의 카메라 섬광장치의 노출 전과 후에 실시예 8 화합물이 스펙트라를 보여준다.

Claims (17)

  1. 변조하는 또는 나프토피란환의 2의지에 스피로-아다만탄그룹이 도입된 포토크로믹 스피로-벤조피란류와 스피로나프토피란류.
  2. 일반식(Ⅰ), (Ⅱ) 또는 (Ⅲ)의 프토크로믹 스피로피란류.
    상기 식중 R3,R4,R5,R6,R7,R8,R9,R10은 각각 독립적으로 수소원자, C1-C5의 저급알킬, 아릴, 알콕시수산기, 알킬 또는 디알킬아미노, 할로겐 또는 복소환식그룹을 나타내며 단, R3또는 R4는 수산기, 알콕시, 알킬 또는 디알킬아미노기로 치환될 수 없고 또한 일반식 Ⅰ, Ⅱ 또는 Ⅲ의 경우에서 벤젠또는 나프탈렌환은 복소환으로 벤잔넬화 또는 안넬화한다.
  3. 청구범위 2항에 있어서, 복소환식 안넬화된환은 산소 또는 황을 함유하는 5원환 또는 6원환의 프토크로믹 스피로피란.
  4. 청구범위 2항에 있어서, 일반식(Ⅱ)의 R5-R6위에 벤잔넬화된 포로크로믹 스피로피란.
  5. 청구범위 3항에 있어서, 일반식(Ⅰ)의 R6-R7또 R7-R8위에 융합된 티오젠, 푸란, 피톤환이 도입된 포토크로믹 스피로피란.
  6. 청구범위 2,3,4 또는 5항중 어느 한항에 있어서, R3-R4는 둘다 수소인 포토크로믹 스피로피란.
  7. 청구범위 6항에 있어서, R3는 수소이고 R4는 메틸, 페닐, 파라메톡시-페닐 또는 할로겐인 포토크로믹 스피로피란.
  8. 다음 일반식을 갖는 헬리오크로믹 스피로-나프토피란
    상기 식중 R5,R6,R7,R8,R9,및 R10은 수소원자, 저급알킬, 염소원자, 프롬원자, 아릴, 수산기, 알콕시, 알콕시아릴, 알킬 또는 디알킬아미노, 아ㄴ미노아릴 또는 알킬아미노-아릴, 또는 5 또는 6원의 복소환그룹 또는 R6-R7,R5-R6또는 R7-R8위에 융합된 리오펜, 푸란 또는 피톤환이 도입됐고 그리고 R4-은 수소원자, 알킬, 할로겐원자 또는 아릴그룹을 나타낸다.
  9. 청구범위 8항에 있어서 R6은 페닐, 염소원자, 파라-메톡시 페닐, 메톡시, 티에닐 또는 푸릴인 헬리오크로믹 스피로-나프로피란.
  10. 다음 일반식의 헬리오크로믹스피로피란
    상기 식중 R1과 R2는 각각 수소원자, 저급알킬, 할로겐원자, 아릴(치환아릴포함), 수산기, 알킬또는 디알킬아미노, 알콕의 또는 복소환그룹에서 선택된 1 또는 그이상 치환을 나타내고 Ad는 아다만튼그룹을 나태낸다.
  11. 다음 일반식 헬리오크로믹 스피로피란
    상기식중 R5,R6,R7,및 R8은 수소원자, 저급알킬, 할로겐원자 알콕시, 알콕시아릴, 5또는 6원 복소환식 그룹 또는 R6과 R7은 함께 융합된 프론환을 나타낸다.
  12. 햇빛에서는 검고 표준주의온도하 백색광에서는 본래의 희미한 또는 무색상태로 변하는 안 또는 평민렌즈 여기서 렌즈는 전항의 어는 것 중 하나에서 요구된 헬리오크로믹화합물의 유효량을 부형화 또는 코팅한 렌즈이다.
  13. 청구범위 12항에서 있어서 폴리카보네이트, 알킬아실레이트 또는 알킬메타아크릴레이트 프라티스틱 물질로 성형된 렌즈.
  14. 청구범위 12항에서 있어서 디알킬렌 글리콜비스(아릴카보네이트)의 폴리머로 성형된 렌즈.
  15. 청구범위 12, 13 또는 14항 중 어느한 항에 있어서 검은 상태의 것을 햇빛에서 갈색 또는 회색으로 하기 위하여 헬리오크로믹화합물 2 또는 그 이상을 결합 용융한 렌즈.
  16. 페놀과 프로파르길 알콜유도체를 용매내에서 180℃이하의 온도 및 촉매존재하에 가열시켜 일단계 클라이젠전위에 의한 크로펜유도체의 제조방법.
  17. 청구범위 16항에서 있어서 프로파르길알콕유도체는 프로파르길 아세테이트이고 촉매는 알루피아나인 크로펜유도체의 제조방법.
    ※ 참고사항 : 최초출원내용에 의하여 공개하는 것임.
KR870004781A 1986-05-15 1987-05-15 프토크로믹 스피로피란 화합물 KR870011125A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8611837 1986-05-15
GB868611837A GB8611837D0 (en) 1986-05-15 1986-05-15 Photochromic spiropyran compounds

Publications (1)

Publication Number Publication Date
KR870011125A true KR870011125A (ko) 1987-12-21

Family

ID=10597906

Family Applications (1)

Application Number Title Priority Date Filing Date
KR870004781A KR870011125A (ko) 1986-05-15 1987-05-15 프토크로믹 스피로피란 화합물

Country Status (12)

Country Link
US (1) US4826977A (ko)
EP (1) EP0246114B1 (ko)
JP (1) JPS6366178A (ko)
KR (1) KR870011125A (ko)
CN (1) CN87104184A (ko)
AT (1) ATE80160T1 (ko)
AU (1) AU610496B2 (ko)
BR (1) BR8702511A (ko)
DE (1) DE3781454T2 (ko)
GB (2) GB8611837D0 (ko)
IN (1) IN170732B (ko)
ZA (1) ZA873457B (ko)

Families Citing this family (178)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8611837D0 (en) * 1986-05-15 1986-06-25 Plessey Co Plc Photochromic spiropyran compounds
GB8614680D0 (en) * 1986-06-17 1986-07-23 Plessey Co Plc Photoreactive lenses
US5021196A (en) * 1988-01-25 1991-06-04 Ppg Industries, Inc. Method for preparing variable-light transmittance article
US4968454A (en) * 1988-01-25 1990-11-06 Ppg Industries, Inc. Variable-light transmittance article and method for preparing same
WO1990003379A1 (de) * 1988-10-01 1990-04-05 Optische Werke G. Rodenstock Photochrome substanzen
US4931221A (en) * 1988-12-30 1990-06-05 Ppg Industries, Inc. Photochromic spiropyran compounds
FR2642065B1 (fr) * 1989-01-24 1991-05-24 Lipha Derives d'acides benzocycloalcenyl dihydroxy alcanoiques, procede de preparation et medicaments les contenant
US5112869A (en) * 1989-04-04 1992-05-12 Sloan-Kettering Institute For Cancer Research Substituted 1-phenylnaphthalenes
DE69015886T2 (de) * 1989-06-05 1995-08-03 Tokuyama Corp Fotochromische Verbindung, deren Zusammensetzung und Verwendung.
US4980089A (en) * 1989-07-12 1990-12-25 Ppg Industries, Inc. Photochromic spiropyran compounds
JP2755444B2 (ja) * 1989-09-28 1998-05-20 株式会社トクヤマ クロメン組成物
US5066818A (en) * 1990-03-07 1991-11-19 Ppg Industries, Inc. Photochromic naphthopyran compounds
US5200116A (en) * 1990-07-23 1993-04-06 Ppg Industries, Inc. Photochromic chromene compounds
US5244602A (en) * 1990-12-03 1993-09-14 Ppg Industries, Inc. Photochromic naphthopyrans
US5585042A (en) * 1992-02-24 1996-12-17 Transitions Optical, Inc. Photochromic naphthopyrans
US5238981A (en) * 1992-02-24 1993-08-24 Transitions Optical, Inc. Photochromic naphthopyrans
US5474715A (en) * 1992-09-10 1995-12-12 Tdk Corporation Photochromic material, photochromic thin film, clay thin film, and their preparation
DE69327410T2 (de) * 1992-09-25 2000-05-11 Ppg Ind Ohio Inc Photochrome zusammensetzungen mit verbesserter lichtermüdungsbeständigkeit
US5274132A (en) * 1992-09-30 1993-12-28 Transitions Optical, Inc. Photochromic naphthopyran compounds
US5552091A (en) * 1993-03-12 1996-09-03 Ppg Industries, Inc. Benzopyran compounds
WO1994020869A1 (en) * 1993-03-12 1994-09-15 Ppg Industries, Inc. Novel benzopyrans
IT1265072B1 (it) * 1993-05-18 1996-10-30 Mini Ricerca Scient Tecnolog Composti spiro-piranici dotati di caratteristiche fotocromatiche
US5552090A (en) * 1993-06-21 1996-09-03 Ppg Industries, Inc. Photochromic naphthopyran compounds
US5578252A (en) * 1993-06-21 1996-11-26 Transitions Optical, Inc. Photochromic substituted naphthopyran compounds
US5466398A (en) * 1993-06-21 1995-11-14 Transitions Optical, Inc. Photochromic substituted naphthopyran compounds
US5384077A (en) * 1993-06-21 1995-01-24 Transitions Optical, Inc. Photochromic naphthopyran compounds
GB9316890D0 (en) * 1993-08-13 1993-09-29 Pilkington Plc Photochromic compounds
GB9316858D0 (en) * 1993-08-13 1993-09-29 Pilkington Plc Photochromic compounds
US5651923A (en) * 1993-12-09 1997-07-29 Transitions Optical, Inc. Substituted naphthopyrans
US5650098A (en) * 1993-12-09 1997-07-22 Transitions Optical, Inc. Substituted naphthopyrans
US5458814A (en) * 1993-12-09 1995-10-17 Transitions Optical, Inc. Substituted naphthopyrans
US5464567A (en) * 1994-04-08 1995-11-07 Transitions Optical, Inc. Photochromic tetraphenyl naphthodipyrans
US5693830A (en) * 1994-04-08 1997-12-02 Tokuyama Corporation Process for preparing the spiropyrone compounds
US5451344A (en) * 1994-04-08 1995-09-19 Transitions Optical, Inc. Photochromic naphthopyran compounds
AU676536B2 (en) * 1994-04-12 1997-03-13 Tokuyama Corporation Process for preparing the spiropyrone compounds
US5395567A (en) * 1994-04-18 1995-03-07 Ppg Industries, Inc. Photochromic spironaphthopyran compounds
US5514817A (en) * 1994-08-04 1996-05-07 Ppg Industries, Inc. Substituted phenanthropyrans
US5628935A (en) * 1994-10-28 1997-05-13 Vision-Ease Lens, Inc. Photochromic spironaphthopyran compounds
US5645767A (en) * 1994-11-03 1997-07-08 Transitions Optical, Inc. Photochromic indeno-fused naphthopyrans
US5679805A (en) * 1995-06-07 1997-10-21 Vision-Ease Lens, Inc. Photochromic spironaphthopyran compounds
US5658501A (en) * 1995-06-14 1997-08-19 Transitions Optical, Inc. Substituted naphthopyrans
US5656206A (en) * 1995-06-14 1997-08-12 Transitions Optical, Inc. Substituted naphthopyrans
US5658500A (en) * 1995-06-14 1997-08-19 Transitions Optical, Inc. Substituted naphthopyrans
US5702645A (en) * 1995-10-30 1997-12-30 Vision-Ease Lens, Inc. Photochromic chromene derivatives
US5658502A (en) * 1995-10-30 1997-08-19 Vision-Ease Lens, Inc. Photochromic articles
US5744070A (en) * 1995-12-20 1998-04-28 Transitions Optical, Inc. Photochromic substituted naphthopyran compounds
FR2757513B1 (fr) * 1996-12-23 1999-03-26 Corning Inc 2-adamantyl benzopyranes, les compositions et matrices (co)polymeres les renfermant
US5753146A (en) * 1996-03-29 1998-05-19 Transitions Optical, Inc. Photochromic naphthopyran compositions of neutral color
US5770115A (en) * 1996-04-19 1998-06-23 Ppg Industries, Inc. Photochromic naphthopyran compositions of improved fatigue resistance
US5698141A (en) * 1996-06-17 1997-12-16 Ppg Industries, Inc. Photochromic heterocyclic fused indenonaphthopyrans
US5955520A (en) * 1996-06-17 1999-09-21 Ppg Industries, Inc. Photochromic indeno-fused naphthopyrans
US5723072A (en) * 1996-06-17 1998-03-03 Ppg Industries, Inc. Photochromic heterocyclic fused indenonaphthopyrans
ES2175443T3 (es) * 1996-07-25 2002-11-16 Corning Inc Compuestos de naptopirano y articulos que los contienen.
FR2751648B1 (fr) * 1996-07-25 1998-09-25 Corning Inc Naphtopyranes photochromiques, compositions et articles les contenant
US5965680A (en) * 1996-11-27 1999-10-12 Ppg Industries Ohio, Inc. Optical resin composition from polyol((meth)acryloyl carbonate) monomer
US5981634A (en) * 1996-11-27 1999-11-09 Ppg Industries Ohio, Inc. Method of preparing photochromic articles
US5973093A (en) * 1996-11-27 1999-10-26 Ppg Industries Ohio, Inc. Polymerizable polyol (allyl carbonate) composition
US5739243A (en) * 1996-11-27 1998-04-14 Ppg Industries, Inc. Polymerizable composition
US5888432A (en) * 1996-12-23 1999-03-30 Corning Incorporated 2-Adamantyl benzopyrans the compositions and (co)polymer matrices containing them
BR9807006A (pt) 1997-03-21 2000-03-14 Corning Inc Derivados nafitopiranos as composições e matrizes (co) polìmeros contendo-os
AU746229B2 (en) 1997-06-19 2002-04-18 Tokuyama Corporation Chromene compounds
US5998520A (en) * 1997-07-02 1999-12-07 Bayer Corporation Photochromic compositions having improved fade rate
US6478989B1 (en) 1997-09-19 2002-11-12 Transitions Optical, Inc. Aromatic substituted naphthopyrans
US5808063A (en) * 1997-10-01 1998-09-15 Ppg Industries, Inc. Photochromic spiro(indoline) fluoranthenoxazine compounds
US5891368A (en) * 1997-10-01 1999-04-06 Ppg Industries, Inc. Fluoranthenopyrans
US5783116A (en) * 1997-10-16 1998-07-21 Ppg Industries, Inc. Derivatives of carbocyclic fused naphthopyrans
US5811034A (en) * 1997-10-23 1998-09-22 Ppg Industries, Inc. 7-methylidene-5-oxo-furo fused naphthopyrans
WO1999024438A1 (de) * 1997-11-07 1999-05-20 Optische Werke G. Rodenstock Heterozyklisch annellierte photochrome 2h- und 3h-naphthopyransysteme, verfahren zu ihrer herstellung und ihre verwendung
US6106744A (en) * 1997-12-03 2000-08-22 Ppg Industries Ohio, Inc. Photochromic pyrano-fused naphthopyrans
US5879592A (en) * 1997-12-10 1999-03-09 Ppg Industries, Inc. Water soluble photochromic compounds, compositions and optical elements comprising the compounds
US5869658A (en) * 1997-12-15 1999-02-09 Ppg Industries, Inc. Photochromic indeno-fused naptho 2,1-b!pyrans
US6630597B1 (en) 1997-12-15 2003-10-07 Transitions Optical, Inc. Photochromic 6-aryl substituted 3H-naphtho(2,1-b)pyrans
US5917006A (en) * 1998-01-16 1999-06-29 Ppg Industries Ohio, Inc. Optical resin composition
US5932681A (en) * 1998-03-09 1999-08-03 Ppg Industries Ohio, Inc. Method of preparing an optical polymerizate
US5976422A (en) * 1998-03-09 1999-11-02 Ppg Industries Ohio, Inc. Optical resin composition
US5942158A (en) * 1998-03-09 1999-08-24 Ppg Industries Ohio, Inc. One-component optical resin composition
US6068797A (en) * 1998-12-11 2000-05-30 Ppg Industries Ohio, Inc. Method of preparing a shaped article having a photochromic coating thereon
FR2789680B1 (fr) 1999-02-17 2002-05-17 Corning Sa Naphtopyranes et phenanthropyranes anneles en c5-c6 avec un groupe bicyclique et les compositions et matrices (co)polymeres les renfermant
US6669873B1 (en) 1999-04-22 2003-12-30 Ppc Industries Ohio, Inc. Optical resin composition comprising thiol-ene prepolymer
US6316570B1 (en) 1999-06-23 2001-11-13 Ppg Industries Ohio, Inc. Polymerizable composition of aliphatic polyol (allyl carbonate)
US6342571B1 (en) 1999-08-20 2002-01-29 Ppg Industries Ohio, Inc. High refractive index optical resin composition
US6348604B1 (en) 1999-09-17 2002-02-19 Ppg Industries Ohio, Inc. Photochromic naphthopyrans
US6296785B1 (en) 1999-09-17 2001-10-02 Ppg Industries Ohio, Inc. Indeno-fused photochromic naphthopyrans
FR2800739B1 (fr) 1999-11-04 2002-10-11 Corning Sa Naphtopyranes avec un heterocycle en position 5,6, preparation et compositions et matrices (co) polymeres les renfermant
FR2800738B1 (fr) 1999-11-04 2002-02-08 Corning Sa Naphtopyranes ayant un substituant perfluoroalkyle en position 5, preparation et compositions et matrices (co)polymeres les renfermant
FR2801052B1 (fr) 1999-11-17 2004-04-02 Corning Sa Naphtopyranes anneles en c5-c6 par un carbocycle de type indene ou dihydronaphtalene et les compositions et matrices (co) polymeres les renfermant
US7098290B1 (en) 1999-11-18 2006-08-29 Ppg Industries Ohio, Inc. Method of preparing an optical polymerizate
US7087698B1 (en) 1999-11-18 2006-08-08 Ppg Industries Ohio, Inc. Method of preparing an optical polymerizate
US7473754B1 (en) 2000-10-17 2009-01-06 Ppg Industries Ohio, Inc. Optical resin composition
US7214754B2 (en) * 1999-12-13 2007-05-08 Ppg Industries Ohio, Inc. Polymerizable polyol (allyl carbonate) compositions
US6631021B2 (en) 2000-03-20 2003-10-07 Ppg Industries Ohio, Inc. Polyfunctional thiirane compounds
US6506864B1 (en) 2000-04-10 2003-01-14 Ppg Industries Ohio, Inc. Polymerizable composition of allyl functional monomers
US6521753B1 (en) * 2000-05-31 2003-02-18 Johnson & Johnson Vision Care, Inc. Indolinospiropyran compounds and methods for their manufacture
FR2815034B1 (fr) * 2000-10-11 2003-02-07 Corning Sa Naphtopyranes anneles en c5-c6 par un carbocycle de type dihydrobenzocycloheptatriene et les compositions et matrices les refermant
US6433043B1 (en) * 2000-11-28 2002-08-13 Transitions Optical, Inc. Removable imbibition composition of photochromic compound and kinetic enhancing additive
US6863843B2 (en) 2000-12-21 2005-03-08 Vision-Ease Lens, Inc. Naphthopyran compounds, photoresponsive compositions and lenses
US20030074808A1 (en) * 2001-08-01 2003-04-24 Elan-Polo, Inc. Article of footwear containing a photoreactive composition
US6608215B2 (en) 2001-09-20 2003-08-19 Vision-Ease Lens, Inc. Oxygen-containing heterocyclic fused naphthopyrans
US6998072B2 (en) * 2001-11-01 2006-02-14 Transitions Optical, Inc. Photochromic polymerizable compositions
US20070142604A1 (en) * 2005-12-16 2007-06-21 Nina Bojkova Polyurethanes and sulfur-containing polyurethanes and methods of preparation
US20030096935A1 (en) * 2001-11-16 2003-05-22 Nagpal Vidhu J. Impact resistant polyureaurethane and method of preparation
US20030149217A1 (en) * 2001-11-16 2003-08-07 Bojkova Nina V. High impact poly (urethane urea) polysulfides
US20070142602A1 (en) * 2005-12-16 2007-06-21 Rukavina Thomas G Polyurethanes and sulfur-containing polyurethanes and methods of preparation
US20070142603A1 (en) * 2005-12-16 2007-06-21 Rukavina Thomas G Polyurethane(urea) and sulfur-containing polyurethane(urea) and methods of preparation
US20040138401A1 (en) * 2002-11-05 2004-07-15 Nina Bojkova High impact poly (urethane urea) polysulfides
US7144969B2 (en) * 2001-11-16 2006-12-05 Ppg Industries Ohio, Inc. Impact resistant polyureaurethane and polyureaurethane prepolymer having low NCO/OH ratio
US8017720B2 (en) * 2005-12-16 2011-09-13 Ppg Industries Ohio, Inc. Sulfur-containing oligomers and high index polyurethanes prepared therefrom
US20060241273A1 (en) * 2001-11-16 2006-10-26 Bojkova Nina V High impact poly (urethane urea) polysulfides
US20070142606A1 (en) * 2005-12-16 2007-06-21 Bojkova Nina V Polyurethane (ureas) and sulfur-containing polyurethane (ureas) methods of preparation
US20050282991A1 (en) * 2001-11-16 2005-12-22 Bojkova Nina V High impact poly (urethane urea) polysulfides
US7008568B2 (en) 2001-11-20 2006-03-07 Vision-Ease Lens, Inc. Photochromic naphthopyran compounds: compositions and articles containing those naphthopyran compounds
US20040021133A1 (en) * 2002-07-31 2004-02-05 Nagpal Vidhu J. High refractive index polymerizable composition
EP2325234B1 (en) 2002-12-20 2017-03-29 PPG Industries Ohio, Inc. High impact poly(urethane urea) polysulfides
US7009032B2 (en) * 2002-12-20 2006-03-07 Ppg Industries Ohio, Inc. Sulfide-containing polythiols
US8698117B2 (en) 2003-07-01 2014-04-15 Transitions Optical, Inc. Indeno-fused ring compounds
US8211338B2 (en) 2003-07-01 2012-07-03 Transitions Optical, Inc Photochromic compounds
US20110140056A1 (en) * 2003-07-01 2011-06-16 Transitions Optical, Inc. Indeno-fused ring compounds
JP2007505842A (ja) * 2003-09-18 2007-03-15 ローデンストック．ゲゼルシャフト．ミット．ベシュレンクテル．ハフツング 置換されたフェナントロピラン
ES2326215T3 (es) * 2003-11-05 2009-10-05 Corning Incorporated Piranos condensados fotocromicos sustituidos con fenilo que porta un grupo carbamilo o urea.
US8927675B2 (en) * 2004-09-01 2015-01-06 Ppg Industries Ohio, Inc. Poly(ureaurethane)s, articles and coatings prepared therefrom and methods of making the same
US11008418B2 (en) 2004-09-01 2021-05-18 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US20070148471A1 (en) * 2004-09-01 2007-06-28 Rukavina Thomas G Impact resistant polyurethane and poly(ureaurethane) articles and methods of making the same
US20070167601A1 (en) * 2004-09-01 2007-07-19 Rukavina Thomas G Polyurethanes prepared from polycarbonate polyols, articles and coatings prepared therefrom and methods of making the same
US20070173601A1 (en) * 2004-09-01 2007-07-26 Rukavina Thomas G Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US8734951B2 (en) * 2004-09-01 2014-05-27 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US8653220B2 (en) * 2004-09-01 2014-02-18 Ppg Industries Ohio, Inc. Poly(ureaurethane)s, articles and coatings prepared therefrom and methods of making the same
US20090280329A1 (en) * 2004-09-01 2009-11-12 Ppg Industries Ohio, Inc. Polyurethanes, Articles and Coatings Prepared Therefrom and Methods of Making the Same
US20070225468A1 (en) * 2004-09-01 2007-09-27 Rukavina Thomas G Polyurethanes prepared from polyester polyols and/or polycaprolactone polyols, articles and coatings prepared therefrom and methods of making the same
US8207286B2 (en) * 2004-09-01 2012-06-26 Ppg Industries Ohio, Inc Methods for preparing polyurethanes
US8889815B2 (en) * 2004-09-01 2014-11-18 Ppg Industries Ohio, Inc. Reinforced polyurethanes and poly(ureaurethane)s, methods of making the same and articles prepared therefrom
US20070167600A1 (en) * 2004-09-01 2007-07-19 Rukavina Thomas G Polyurethanes prepared from polycaprolactone polyols, articles and coatings prepared therefrom and methods of making the same
US20090280709A1 (en) * 2004-09-01 2009-11-12 Ppg Industries Ohio, Inc. Polyurethanes, Articles and Coatings Prepared Therefrom and Methods of Making the Same
US20070149749A1 (en) * 2004-09-01 2007-06-28 Rukavina Thomas G Polyurethanes prepared from polycarbonate polyols, articles and coatings prepared therefrom and methods of making the same
US8933166B2 (en) * 2004-09-01 2015-01-13 Ppg Industries Ohio, Inc. Poly(ureaurethane)s, articles and coatings prepared therefrom and methods of making the same
US9464169B2 (en) 2004-09-01 2016-10-11 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US11149107B2 (en) 2004-09-01 2021-10-19 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US8399559B2 (en) * 2004-09-01 2013-03-19 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US9598527B2 (en) * 2004-09-01 2017-03-21 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
WO2014153046A2 (en) 2013-03-14 2014-09-25 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US8859680B2 (en) * 2004-09-01 2014-10-14 Ppg Industries Ohio, Inc Poly(ureaurethane)s, articles and coatings prepared therefrom and methods of making the same
US8399094B2 (en) * 2004-09-01 2013-03-19 Ppg Industries Ohio, Inc. Multilayer laminated articles including polyurethane and/or poly(ureaurethane) layers and methods of making the same
US8604153B2 (en) * 2004-09-01 2013-12-10 Ppg Industries Ohio, Inc. Poly(ureaurethane)s, articles and coatings prepared therefrom and methods of making the same
US8349986B2 (en) * 2004-09-01 2013-01-08 Ppg Industries Ohio, Inc. Poly(ureaurethane)s, articles and coatings prepared therefrom and methods of making the same
US11591436B2 (en) 2004-09-01 2023-02-28 Ppg Industries Ohio, Inc. Polyurethane article and methods of making the same
US11248083B2 (en) 2004-09-01 2022-02-15 Ppg Industries Ohio, Inc. Aircraft windows
US20070251421A1 (en) * 2004-09-01 2007-11-01 Rukavina Thomas G Powder coatings prepared from polyurethanes and poly(ureaurethane)s, coated articles and methods of making the same
CA2585847C (en) * 2004-10-21 2013-07-02 Rodenstock Gmbh Photochromic h-fused benzo[f]chromene derivatives
US7910022B2 (en) * 2006-09-15 2011-03-22 Performance Indicator, Llc Phosphorescent compositions for identification
US20110140002A1 (en) * 2004-12-20 2011-06-16 Performance Indicator, Llc Photoluminescent Compositions, Methods of Manufacture and Novel Uses
AU2005319365B2 (en) * 2004-12-20 2011-02-03 Performance Indicator L.L.C. High-intensity, persistent photoluminescent formulations and objects, and methods for creating the same
EP2004717B1 (en) 2005-12-16 2013-04-17 PPG Industries Ohio, Inc. Poly(ureaurethane)s, articles and coatings prepared therefrom and methods of making the same
WO2007070627A2 (en) 2005-12-16 2007-06-21 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
DK2027186T3 (da) * 2006-05-05 2014-04-14 Prc Desoto Int Inc Forseglings- og elektriske indstøbningsformuleringer omfattende thioetherfunktionelle polythiololigomerer
US20070261273A1 (en) * 2006-05-09 2007-11-15 James Cheung Shoe having photoreactive components
US20080071016A1 (en) * 2006-09-14 2008-03-20 Ppg Industries Ohio, Inc. Polyureaurethane composition having improved color stability
US7547894B2 (en) * 2006-09-15 2009-06-16 Performance Indicator, L.L.C. Phosphorescent compositions and methods for identification using the same
CN101772420A (zh) * 2007-08-02 2010-07-07 奥森迪克斯公司 产品的验证
US8039193B2 (en) * 2007-09-13 2011-10-18 Performance Indicator Llc Tissue markings and methods for reversibly marking tissue employing the same
US7842128B2 (en) * 2007-09-13 2010-11-30 Performance Indicatior LLC Tissue marking compositions
US8765978B2 (en) 2010-12-16 2014-07-01 Transitions Optical, Inc. Method of making indeno-fused naphthol materials
US8779168B2 (en) 2010-12-16 2014-07-15 Transitions Optical, Inc. Lactone compounds and materials made therefrom
US9139571B2 (en) 2010-12-16 2015-09-22 Transitions Optical, Inc. Methods of making fused ring compounds
US9334345B2 (en) 2011-09-08 2016-05-10 Ppg Industries Ohio, Inc. Polymerizable compositions containing (meth)acrylate monomers having sulfide linkages
US9568643B2 (en) 2012-12-13 2017-02-14 Ppg Industries Ohio, Inc. Polyurethane urea-containing compositions and optical articles and methods for preparing them
CN108299447A (zh) * 2018-03-05 2018-07-20 天津孚信阳光科技有限公司 一种有色变无色金刚烷类光致变色化合物
CN108148569A (zh) * 2018-03-05 2018-06-12 天津孚信阳光科技有限公司 一种一次性光致变色化合物
CN109324425A (zh) * 2018-09-27 2019-02-12 镇江奥视达光学有限公司 一种防蓝光护目镜片及其制备方法
CN109529952B (zh) * 2018-11-30 2020-03-31 宁波航天米瑞科技有限公司 光催化复合材料及其制备方法
WO2021167027A1 (ja) * 2020-02-18 2021-08-26 株式会社トクヤマ フォトクロミック環状化合物、及び該フォトクロミック環状化合物を含む硬化性組成物
US20210284778A1 (en) 2020-03-11 2021-09-16 Alcon Inc. Photochromic polydiorganosiloxane vinylic crosslinkers
EP4158392A1 (en) 2020-06-02 2023-04-05 Alcon Inc. Method for making photochromic contact lenses
US11945181B2 (en) 2020-10-28 2024-04-02 Alcon Inc. Method for making photochromic contact lenses
EP4240579A1 (en) 2020-11-04 2023-09-13 Alcon Inc. Method for making photochromic contact lenses
WO2022097048A1 (en) 2020-11-04 2022-05-12 Alcon Inc. Method for making photochromic contact lenses
TW202235254A (zh) 2021-03-08 2022-09-16 瑞士商愛爾康公司 用於製造光功能接觸鏡片之方法
KR20230144634A (ko) 2021-04-01 2023-10-16 알콘 인코포레이티드 광변색성 콘택트 렌즈의 제조 방법
WO2023208941A1 (en) 2022-04-26 2023-11-02 Essilor International Photochromic optical article having a mirror coating
TW202406726A (zh) 2022-04-28 2024-02-16 瑞士商愛爾康公司 用於製造ｕｖ吸收性和ｈｅｖｌ吸收性眼科鏡片之方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2542386A (en) * 1947-12-03 1951-02-20 John O Beattie Manufacture of plastic lenses from monomeric materials
NL127064C (ko) * 1959-07-16
US3404861A (en) * 1965-02-22 1968-10-08 Optics Australia Pty Ltd Optical casting gasket
US3567605A (en) * 1966-03-30 1971-03-02 Ralph S Becker Photochemical process
US3627690A (en) * 1969-10-01 1971-12-14 Itek Corp Photochromic naphthopyran compositions
US3944637A (en) * 1974-02-11 1976-03-16 Buckbee-Mears Company Increasing the yield of cast plastic lenses
GB2146327B (en) * 1983-09-07 1986-11-26 Plessey Co Plc Photochromic fused-ring organic compounds and their use in photoreactive lenses
US4637698A (en) * 1983-11-04 1987-01-20 Ppg Industries, Inc. Photochromic compound and articles containing the same
GB8611837D0 (en) * 1986-05-15 1986-06-25 Plessey Co Plc Photochromic spiropyran compounds

Also Published As

Publication number Publication date
GB8711511D0 (en) 1987-06-17
ZA873457B (en) 1988-04-27
DE3781454T2 (de) 1993-04-15
IN170732B (ko) 1992-05-09
AU610496B2 (en) 1991-05-23
DE3781454D1 (de) 1992-10-08
GB8611837D0 (en) 1986-06-25
CN87104184A (zh) 1988-06-29
ATE80160T1 (de) 1992-09-15
EP0246114A2 (en) 1987-11-19
US4826977A (en) 1989-05-02
EP0246114A3 (en) 1990-01-17
BR8702511A (pt) 1988-02-23
GB2190379A (en) 1987-11-18
EP0246114B1 (en) 1992-09-02
GB2190379B (en) 1990-05-02
JPS6366178A (ja) 1988-03-24
AU7310487A (en) 1987-11-19

Similar Documents

Publication Publication Date Title
KR870011125A (ko) 프토크로믹 스피로피란 화합물
KR900008851B1 (ko) 광가변색화합물을 함유하는 광가변색 제품
US7300727B2 (en) Method for forming temporary image
KR880000801A (ko) 광학반응렌즈
KR850002263A (ko) 가변색 물품(可變色物品)의 제조방법
EP1591830B1 (en) Reimageable medium
US4784474A (en) Spiro-oxazine compounds and preparation thereof and photochromic shaped article
JPH01500740A (ja) フォトクロミック化合物による物品の標識
ATE22183T1 (de) Lichtempfindliches farbfotografisches silberhalogenidmaterial.
KR920011991A (ko) 광호변성 나프타센퀴논, 이의 제조방법 및 이의 용도
GB1495317A (en) Silver halide colour photographic materials
KR850002328A (ko) 가변색 화합물과 그 제조방법 및 이를 이용한 가변색 렌즈
JPH0745490B2 (ja) スピロピラン化合物及びその製造方法
US3486898A (en) Sensitivity of triarylmethane light sensitive systems
JPS6413539A (en) Silver halide photographic sensitive material
US3714187A (en) Spiro(indoline-2,2'-2h'-chromene)photochromic compounds
JPS5456833A (en) Color photographic material
JPH0739420B2 (ja) スピロオキサジン化合物及び該化合物を使用した感光材料
JPS63303984A (ja) スピロオキサジン系化合物および該化合物を使用した感光材料
US3578680A (en) Photochromic compound
PT71960A (de) Diazoverbindungen enthaltendes aufzeichnungsmaterial und verfahren zur herstellung desselben
US3917484A (en) Photographic compositions, elements and processes for the production of formazan dye images of enhanced red absorption
WO1991010571A1 (en) Imaging process
JPH02157283A (ja) 感光材料
JPH04112885A (ja) スピロピラン化合物及びその製造方法

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid