KR880000801A - 광학반응렌즈 - Google Patents

광학반응렌즈 Download PDF

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Publication number
KR880000801A
KR880000801A KR1019870006133A KR870006133A KR880000801A KR 880000801 A KR880000801 A KR 880000801A KR 1019870006133 A KR1019870006133 A KR 1019870006133A KR 870006133 A KR870006133 A KR 870006133A KR 880000801 A KR880000801 A KR 880000801A
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group
alkyl
aryl
amino
substituent
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KR1019870006133A
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죠지 헬러 해리
니겔 올리버 스테픈
휘탈 죤
브리틀 잭
더블유 바스커빌 마틴
트룬들 크라이브
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알. 니콜슨
더 프레시 캄패니 피엘씨
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Publication of KR880000801A publication Critical patent/KR880000801A/ko

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    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/027—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements containing only one hetero ring
    • C07D295/033—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements containing only one hetero ring with the ring nitrogen atoms directly attached to carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/78—Ring systems having three or more relevant rings
    • C07D311/92—Naphthopyrans; Hydrogenated naphthopyrans
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B3/00—Simple or compound lenses
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/22—Absorbing filters
    • G02B5/23—Photochromic filters

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Silicon Polymers (AREA)
  • Glass Compositions (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Eyeglasses (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Optical Filters (AREA)

Abstract

내용 없음

Description

광학반응렌즈
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 햇빛하에서는 암색으로 변하고 상온의 백색광에서는 연한색 또는 무색으로 변하는 것에 있어서, 헬리오크로믹화합물을 혼합하여 제조하거나 렌즈의 표면에 헬리오크로믹화합물을 도포한 것으로 헬리오크로믹화합물중의 하나는 아다만탄 스피로-벤조피렌 또는 스피로나프토피란으로 구성되고 이중 아다만탄기는 벤조피란 또는 나프토피란고리의 2-스피로 위치에 존재하며, 헬리오크로믹화합물중 제 2의 것은 피란고리의 2위치에 질소를 포함하는 치환체를 가지는 벤조 또는 나프토피란으로 구성됨을 특징으로 하는 대안 또는 플라노렌즈.
  2. 제 1 항의 것에 있어서, 헬리오크로믹화합물중의 하나는 아다만탄-스피로나프토피란이고 제 2의 헬리오크로믹화합물은 다음의 일반식(Ⅰ)의 헬리오크로믹화합물임을 특징으로 하는 렌즈.
    (Ⅰ)
    상기식중 R은 알킬리 또는 질소포함치환체를 포함하는 아릴기이고, R'는 하나 또는 그 이상의 수소, 알킬, 할로겐, 아릴, 하이드록시, 알콕시, 알킬-또는 디알킬아미노, 또는 이성고리기이며, 이중 치환기 R'를 포함하는 고리를 벤젠류화 될 수 있으며, X는 질소를 포함하는 치환체를 갖는 아릴기이다.
  3. 제 2 항의 것에 있어서, X기가 아미노 또는 치환된 아미노치환체를 갖는 페닐기이거나 질소포함 이성고리가 오르토(ortho) 또는 파라위치에 있음을 특징으로 하는 렌즈.
  4. 제 2 항 또는 제 3 항의 것에 있어서, R기가 아미노 또는 치환된 아미노치환체 또는 오르토 및 또는 파라위치에 니크로겐 포함 이성고리임을 특징으로 하는 렌즈.
  5. 제 2 항의 것에 있어서, 제 2의 헬리오크로믹화합물이 다음 일반식(IA)임을 특징으로 하는 렌즈.
    (ⅠA)
    상기식중 R은 청구범위 제 2 항의 것과 동일하고 Y는 수소, 아미노, 알킬 또는 디알킬아미노, 또는 질소를 포함하는 이성고리기를 표시한다.(적어도 Y중의 하나는 질소포함 치환체일 것을 조건으로 한다) 그리고 R'는 수소, 알킬, 할로겐, 알콕시,아릴, 아미노 또는 아미노치환체 또는 이성고리기 또는 치환체를 포함하는 고리이며 R'는 벤젠고리화 되어 있고 R"는 수소, 알킬, 할로겐, 알콕시 또는 아릴이다.
  6. 제 5 항의 것에 있어서, 제 2의 헬리오크로믹화합물이 다음 일반식 (Ⅱ)의 구성을 가짐을 특징으로 하는 렌즈.
    (Ⅱ)
    상기식중 R3와 R4는 하나 이상의 치환체로서 수소, 저급알킬, 아릴, 저급알콕시, 하이드록시 할로겐, 알킬 또는 디알킬아미노 또는 이성고리기로부터 선택된 것임을 특징으로 하는 렌즈.
  7. 제 6 항의 것에 있어서, R3가 알콕시페닐기일을 특징으로 하는 렌즈.
  8. 제 6 항 또는 제 7 항의 것에 있어서, Y가 아미노 또는 치환된 아미노, 모르포리노, 피레리디노, 피리디노 또는 피로리디노기 임을 특징으로 하는 렌즈.
  9. 제 6 항, 제 7 항 또는 제 8 항의 것에 있어서, R3치환체가 저급알콕시, 저급알콕시페닐 또는 할로겐기이고 제 6 위치에 위치함을 특징으로 하는 렌즈.
  10. 제 1 항의 것에 있어서 제 2의 헬리오크로믹화합물이 하기의 일반식(Ⅲ)을 가짐을 특징으로 하는 렌즈.
    (Ⅲ)
    상기식중 R은 알킬기 또는 아릴기이고 Z는 아릴기(치환된 아릴 포함), 알킬 또는 할로겐이다.
  11. 제10항의 것에 있어서, Z는 각각 페닐 또는 제1, 제2, 제3아미노기 또는 질소를 포함하는 이성고리 관능기로 치환된 페닐기이며 R은 알킬기임을 특징으로 하는 렌즈.
  12. 하기의 일반식(IA)을 갖는 피란화합물.
    (ⅠA)
    상기식중 R은 저급알킬, Y는 수소, 아미노 또는 알킬 또는 디알킬아미노 또는 수소를 포함하는 이성고리기이다.
    다만 이때 두개 이상의 Y가 수소를 나타내지 아니할 것을 조건으로 한다. R'은 하나 이상의 치환체로서 수소, 알킬, 할로겐, 알콕시 아릴, 아미노 또는 치환된 아미노 또는 이성고리기로부터 독립적으로 선택되어진 것으로 치환체 R'를 포함하는 고리는 벤질결합화 할 수 있다. R"는 수소, 알킬, 할로겐, 알콕시 또는 아릴로부터 선택한 하나 이상의 치환체이다.
  13. 하기의 알반식(Ⅱ)을 갖는 피란화합물.
    (Ⅱ)
    상기식중 R3, R4는 각각 하나 이상의 치환체로서 수소, 저급알킬, 아릴, 저급알콕시, 하이드록시, 할로겐, 알킬 또는 디알킬아미노 또는 이성고리기로부터 선택된 것이며, Y와 R'는 청구범위 제12항의 것과 동일하다.
  14. 제13항의 것에 있어서, R3치환체가 저급알콕시, 저급알콕시페닐 또는 할로겐기이며 제 6 위치에 위치함을 특징으로 하는 피란화합물.
  15. 제13항 또는 제14항의 것에 있어서, Y로 표시되는 기증 적어도 하나의 기가 알킬, 또는 디알킬아미노기임을 특징으로 하는 피란화합물.
  16. 하기의 알반식(Ⅳ)을 갖는 피란화합물.
    (Ⅳ)
    상기식중 R3와 R4는 각각 수소, 저급알킬, 아릴, 저급알콕시, 하이드록시, 할로겐, 알킬 또는 디알킬 아미노, 또는 이성고리기 중에서 선택된 하나 이상의 치환체이며, R은 알킬 또는 아릴이고, X는 수소, 저급알킬 또는 아릴을 표시한다.
  17. 제16항의 것에 있어서, X가 오르토 또는 파라위치에 아미노 또는 치환된 아미노 또는 질소포함 이성고리치환체를 가지고 있는 페닐기인 피란화합물.
  18. 하기의 알반식(Ⅲ)을 갖는 피란화합물.
    (Ⅲ)
    상기식중 R은 알킬기 또는 아릴기이고, Z는 수소, 알킬 또는 아릴을 표시한다.
  19. 제16항의 것에 있어서, R이 알킬기이고 Z가 페닐기 또는 제 1 차, 제 2 차, 제 3 차의 아미노치환기 또는 질소포함이성고리로 치환된 페닐기인 피란화합물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870006133A 1986-06-17 1987-06-17 광학반응렌즈 KR880000801A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB868614680A GB8614680D0 (en) 1986-06-17 1986-06-17 Photoreactive lenses
GB8614680 1986-06-17

Publications (1)

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KR880000801A true KR880000801A (ko) 1988-03-29

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Country Link
US (1) US4818096A (ko)
EP (1) EP0250193B1 (ko)
JP (1) JPS6347721A (ko)
KR (1) KR880000801A (ko)
CN (1) CN87104827A (ko)
AT (1) ATE96436T1 (ko)
AU (1) AU598273B2 (ko)
BR (1) BR8703053A (ko)
CA (1) CA1306643C (ko)
DE (1) DE3787932T2 (ko)
GB (2) GB8614680D0 (ko)
IN (1) IN170758B (ko)
ZA (1) ZA874317B (ko)

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ZA874317B (en) 1987-12-17
CN87104827A (zh) 1988-03-02
EP0250193A2 (en) 1987-12-23
EP0250193B1 (en) 1993-10-27
ATE96436T1 (de) 1993-11-15
AU598273B2 (en) 1990-06-21
US4818096A (en) 1989-04-04
EP0250193A3 (en) 1990-01-17
DE3787932T2 (de) 1994-02-24
AU7441687A (en) 1987-12-24
BR8703053A (pt) 1988-03-08
CA1306643C (en) 1992-08-25
IN170758B (ko) 1992-05-16
GB2193005A (en) 1988-01-27
GB8614680D0 (en) 1986-07-23
DE3787932D1 (de) 1993-12-02
GB8713930D0 (en) 1987-07-22
JPS6347721A (ja) 1988-02-29

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