KR870010101A - 포스포늄 염 촉매의 비활성화와 고급화 에폭시 수지의 제조 - Google Patents
포스포늄 염 촉매의 비활성화와 고급화 에폭시 수지의 제조 Download PDFInfo
- Publication number
- KR870010101A KR870010101A KR870004122A KR870004122A KR870010101A KR 870010101 A KR870010101 A KR 870010101A KR 870004122 A KR870004122 A KR 870004122A KR 870004122 A KR870004122 A KR 870004122A KR 870010101 A KR870010101 A KR 870010101A
- Authority
- KR
- South Korea
- Prior art keywords
- phosphonium salt
- salt catalyst
- sulfonic acid
- epoxy resin
- hydrocarbyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003054 catalyst Substances 0.000 title claims 8
- 239000003822 epoxy resin Substances 0.000 title claims 3
- 229920000647 polyepoxide Polymers 0.000 title claims 3
- 230000002779 inactivation Effects 0.000 title 1
- 150000004714 phosphonium salts Chemical class 0.000 title 1
- -1 hydrocarbyl phosphonium salt Chemical class 0.000 claims 7
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 5
- 238000000034 method Methods 0.000 claims 5
- 239000011541 reaction mixture Substances 0.000 claims 3
- 239000004593 Epoxy Substances 0.000 claims 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical group CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229940098779 methanesulfonic acid Drugs 0.000 claims 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/688—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/858,311 US4692504A (en) | 1986-04-30 | 1986-04-30 | Deactivation of phosphonium salt catalyst |
| US858311 | 1986-04-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR870010101A true KR870010101A (ko) | 1987-11-30 |
Family
ID=25328000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR870004122A Withdrawn KR870010101A (ko) | 1986-04-30 | 1987-04-28 | 포스포늄 염 촉매의 비활성화와 고급화 에폭시 수지의 제조 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4692504A (https=) |
| EP (1) | EP0244015B1 (https=) |
| JP (1) | JPS62262749A (https=) |
| KR (1) | KR870010101A (https=) |
| CN (1) | CN1009650B (https=) |
| AT (1) | ATE78274T1 (https=) |
| AU (1) | AU584796B2 (https=) |
| BR (1) | BR8702060A (https=) |
| CA (1) | CA1309548C (https=) |
| DE (1) | DE3780349T2 (https=) |
| ES (1) | ES2041674T3 (https=) |
| GR (1) | GR3005295T3 (https=) |
| ZA (1) | ZA873012B (https=) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4946817A (en) * | 1984-07-17 | 1990-08-07 | The Dow Chemical Company | Latent catalysts for epoxy-containing compounds |
| US5503937A (en) * | 1984-07-17 | 1996-04-02 | The Dow Chemical Company | Curable composition which comprises adducts of heterocyclic compounds |
| US5202051A (en) * | 1987-04-29 | 1993-04-13 | Shell Oil Company | Stabilization of epoxy/nitroparaffin solutions |
| US4933420A (en) * | 1988-09-23 | 1990-06-12 | The Dow Chemical Company | Epoxy resins containing phosphonium catalysts |
| US4939112A (en) * | 1988-10-06 | 1990-07-03 | James River Paper Company, Inc. | Catalyst for synthesis of vesicular phenoxy resins |
| US5310854A (en) * | 1989-08-23 | 1994-05-10 | The Dow Chemical Company | Epoxy resin composition and process therefor |
| US5140079A (en) * | 1990-02-06 | 1992-08-18 | The Dow Chemical Company | Latent, curable, catalyzed mixtures of epoxy-containing and phenolic-hydroxyl-containing compounds containing compounds or complexes formed from contacting organic phosphines or arsines with weak nucleophilic acids |
| US4981926A (en) * | 1990-02-06 | 1991-01-01 | The Dow Chemical Company | Composition of epoxy resin, amino group-containing phosphonium catalyst and curing agent |
| US5208317A (en) * | 1990-02-06 | 1993-05-04 | The Dow Chemical Company | Composition comprising epoxy resin and cationic amine phosphonium catalyst |
| US5721323A (en) * | 1990-05-21 | 1998-02-24 | The Dow Chemical Company | Cure inhibited epoxy resin compositions and laminates prepared from the compositions |
| ZA913801B (en) * | 1990-05-21 | 1993-01-27 | Dow Chemical Co | Latent catalysts,cure-inhibited epoxy resin compositions and laminates prepared therefrom |
| US5169473A (en) * | 1990-05-21 | 1992-12-08 | The Dow Chemical Company | Latent catalysts, epoxy compositions incorporating same, and coating, impregnating and bonding methods employing the compositions |
| US5202407A (en) * | 1992-01-24 | 1993-04-13 | The Dow Chemical Company | Precatalyzed catalyst compositions, process for preparing epoxy resins curable compositions, articles resulting from curing the resultant compositions |
| DE19547786A1 (de) * | 1995-12-20 | 1997-06-26 | Basf Lacke & Farben | Aufbau von modifizierten Epoxidharzen für die kathodische Elektrotauchlackierung mit Katalysator-Desaktivierung und Diolmodifizierung |
| JP2004210672A (ja) * | 2002-12-27 | 2004-07-29 | Nippon Chem Ind Co Ltd | ビスホスホニウム塩化合物及びその製造方法 |
| CN1319446C (zh) * | 2004-09-27 | 2007-06-06 | 深圳市绿微康生物工程有限公司 | 新型生物农药－松刚霉素生产方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3477990A (en) * | 1967-12-07 | 1969-11-11 | Shell Oil Co | Process for reacting a phenol with an epoxy compound and resulting products |
| US3547885A (en) * | 1968-03-08 | 1970-12-15 | Sun Oil Co | Process for curing polyepoxides with anhydrides and phosphonium halide catalysts therefor |
| DE2416227C3 (de) * | 1974-04-03 | 1980-04-30 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Entfernung von Katalysatoren aus flüssigen Reaktionsgemischen |
| US3978027A (en) * | 1975-05-07 | 1976-08-31 | Shell Oil Company | Process for reacting a phenol with an epoxy compound |
| US4370465A (en) * | 1980-12-04 | 1983-01-25 | The Dow Chemical Co. | Epoxy resins having improved physical properties when cured |
| US4410596A (en) * | 1980-12-04 | 1983-10-18 | The Dow Chemical Co. | Process for preparing epoxy resins having improved physical properties when cured |
| US4352918A (en) * | 1980-12-04 | 1982-10-05 | The Dow Chemical Company | Process for preparing epoxy resins having improved physical properties when cured using quaternary phosphonium catalysts |
| US4366295A (en) * | 1981-06-01 | 1982-12-28 | The Dow Chemical Company | Stable precatalyzed epoxy resin compositions |
| US4496709A (en) * | 1982-06-23 | 1985-01-29 | The Dow Chemical Company | Process for preparing epoxy resins employing a phosphonium trifluoroacetate catalyst |
| US4438254A (en) * | 1983-02-28 | 1984-03-20 | The Dow Chemical Company | Process for producing epoxy resins |
| GB8420817D0 (en) * | 1984-08-16 | 1984-09-19 | Dow Chemical Rheinwerk Gmbh | Preparing epoxy resins |
-
1986
- 1986-04-30 US US06/858,311 patent/US4692504A/en not_active Expired - Fee Related
-
1987
- 1987-04-07 CA CA000533994A patent/CA1309548C/en not_active Expired - Fee Related
- 1987-04-15 AT AT87200731T patent/ATE78274T1/de active
- 1987-04-15 ES ES198787200731T patent/ES2041674T3/es not_active Expired - Lifetime
- 1987-04-15 DE DE8787200731T patent/DE3780349T2/de not_active Expired - Lifetime
- 1987-04-15 EP EP87200731A patent/EP0244015B1/en not_active Expired - Lifetime
- 1987-04-28 ZA ZA873012A patent/ZA873012B/xx unknown
- 1987-04-28 CN CN87103127A patent/CN1009650B/zh not_active Expired
- 1987-04-28 AU AU72149/87A patent/AU584796B2/en not_active Ceased
- 1987-04-28 KR KR870004122A patent/KR870010101A/ko not_active Withdrawn
- 1987-04-28 BR BR8702060A patent/BR8702060A/pt not_active IP Right Cessation
- 1987-04-28 JP JP62103485A patent/JPS62262749A/ja active Pending
-
1992
- 1992-07-29 GR GR920401626T patent/GR3005295T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GR3005295T3 (https=) | 1993-05-24 |
| EP0244015B1 (en) | 1992-07-15 |
| CA1309548C (en) | 1992-10-27 |
| ES2041674T3 (es) | 1993-12-01 |
| US4692504A (en) | 1987-09-08 |
| ZA873012B (en) | 1987-11-25 |
| JPS62262749A (ja) | 1987-11-14 |
| EP0244015A2 (en) | 1987-11-04 |
| EP0244015A3 (en) | 1989-02-01 |
| AU7214987A (en) | 1987-11-05 |
| DE3780349T2 (de) | 1992-12-17 |
| CN87103127A (zh) | 1987-12-30 |
| BR8702060A (pt) | 1988-02-09 |
| ATE78274T1 (de) | 1992-08-15 |
| AU584796B2 (en) | 1989-06-01 |
| CN1009650B (zh) | 1990-09-19 |
| DE3780349D1 (de) | 1992-08-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19870428 |
|
| PG1501 | Laying open of application | ||
| A201 | Request for examination | ||
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 19920309 Comment text: Request for Examination of Application Patent event code: PA02011R01I Patent event date: 19870428 Comment text: Patent Application |
|
| PC1202 | Submission of document of withdrawal before decision of registration |
Comment text: [Withdrawal of Procedure relating to Patent, etc.] Withdrawal (Abandonment) Patent event code: PC12021R01D Patent event date: 19940614 |
|
| WITB | Written withdrawal of application |