KR870007105A - 살충제 n'-치환-n-알킬카르보닐-n-아실히드라진 - Google Patents
살충제 n'-치환-n-알킬카르보닐-n-아실히드라진 Download PDFInfo
- Publication number
- KR870007105A KR870007105A KR870000438A KR870000438A KR870007105A KR 870007105 A KR870007105 A KR 870007105A KR 870000438 A KR870000438 A KR 870000438A KR 870000438 A KR870000438 A KR 870000438A KR 870007105 A KR870007105 A KR 870007105A
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- KR
- South Korea
- Prior art keywords
- alkyl
- unsubstituted
- substituted
- substituents
- alkoxy
- Prior art date
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- 239000002917 insecticide Substances 0.000 title claims 3
- 125000001424 substituent group Chemical group 0.000 claims 30
- -1 wherein Chemical group 0.000 claims 29
- 125000005843 halogen group Chemical group 0.000 claims 22
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims 20
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 20
- 239000000203 mixture Substances 0.000 claims 19
- 125000004423 acyloxy group Chemical group 0.000 claims 17
- 125000000217 alkyl group Chemical group 0.000 claims 17
- 150000001875 compounds Chemical class 0.000 claims 17
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 16
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 16
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims 15
- 125000004093 cyano group Chemical group *C#N 0.000 claims 13
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 9
- 239000000575 pesticide Substances 0.000 claims 9
- 125000004432 carbon atom Chemical group C* 0.000 claims 8
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 claims 7
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims 7
- 241000607479 Yersinia pestis Species 0.000 claims 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 5
- 150000003839 salts Chemical class 0.000 claims 5
- 125000003342 alkenyl group Chemical group 0.000 claims 4
- 125000003545 alkoxy group Chemical group 0.000 claims 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 4
- 125000004966 cyanoalkyl group Chemical group 0.000 claims 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 3
- 125000001624 naphthyl group Chemical group 0.000 claims 3
- 229910052760 oxygen Inorganic materials 0.000 claims 3
- 125000005017 substituted alkenyl group Chemical group 0.000 claims 3
- 125000000547 substituted alkyl group Chemical group 0.000 claims 3
- 229910052717 sulfur Inorganic materials 0.000 claims 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 2
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims 2
- 241000254173 Coleoptera Species 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 241000255777 Lepidoptera Species 0.000 claims 2
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims 2
- 125000005130 alkyl carbonyl thio group Chemical group 0.000 claims 2
- 125000004691 alkyl thio carbonyl group Chemical group 0.000 claims 2
- 125000004414 alkyl thio group Chemical group 0.000 claims 2
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 claims 2
- 125000004663 dialkyl amino group Chemical group 0.000 claims 2
- 239000002270 dispersing agent Substances 0.000 claims 2
- 125000001188 haloalkyl group Chemical group 0.000 claims 2
- 125000000623 heterocyclic group Chemical group 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 claims 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
- 125000002861 (C1-C4) alkanoyl group Chemical group 0.000 claims 1
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims 1
- 125000004454 (C1-C6) alkoxycarbonyl group Chemical group 0.000 claims 1
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 claims 1
- 125000006642 (C1-C6) cyanoalkyl group Chemical group 0.000 claims 1
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 claims 1
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 claims 1
- 125000006771 (C1-C6) haloalkylthio group Chemical group 0.000 claims 1
- 125000006643 (C2-C6) haloalkenyl group Chemical group 0.000 claims 1
- 125000006645 (C3-C4) cycloalkyl group Chemical group 0.000 claims 1
- 125000006555 (C3-C5) cycloalkyl group Chemical group 0.000 claims 1
- 125000006529 (C3-C6) alkyl group Chemical group 0.000 claims 1
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims 1
- 125000006553 (C3-C8) cycloalkenyl group Chemical group 0.000 claims 1
- 125000005919 1,2,2-trimethylpropyl group Chemical group 0.000 claims 1
- 125000004973 1-butenyl group Chemical group C(=CCC)* 0.000 claims 1
- 125000004975 3-butenyl group Chemical group C(CC=C)* 0.000 claims 1
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 claims 1
- 125000004648 C2-C8 alkenyl group Chemical group 0.000 claims 1
- 125000004649 C2-C8 alkynyl group Chemical group 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 125000004466 alkoxycarbonylamino group Chemical group 0.000 claims 1
- 125000005194 alkoxycarbonyloxy group Chemical group 0.000 claims 1
- 125000003282 alkyl amino group Chemical group 0.000 claims 1
- 125000003806 alkyl carbonyl amino group Chemical group 0.000 claims 1
- 125000004422 alkyl sulphonamide group Chemical group 0.000 claims 1
- 125000003368 amide group Chemical group 0.000 claims 1
- 239000005667 attractant Substances 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- 125000001246 bromo group Chemical group Br* 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 1
- 125000005708 carbonyloxy group Chemical group [*:2]OC([*:1])=O 0.000 claims 1
- 125000005518 carboxamido group Chemical group 0.000 claims 1
- 230000031902 chemoattractant activity Effects 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 125000001485 cycloalkadienyl group Chemical group 0.000 claims 1
- 125000000392 cycloalkenyl group Chemical group 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 125000004772 dichloromethyl group Chemical group [H]C(Cl)(Cl)* 0.000 claims 1
- 239000003995 emulsifying agent Substances 0.000 claims 1
- 125000005280 halo alkyl sulfonyloxy group Chemical group 0.000 claims 1
- 125000004993 haloalkoxycarbonyl group Chemical group 0.000 claims 1
- 125000004692 haloalkylcarbonyl group Chemical group 0.000 claims 1
- 230000000749 insecticidal effect Effects 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 claims 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- MFTGBQRYFLPIEK-UHFFFAOYSA-N n-tert-butyl-n'-(2,2,2-trichloroacetyl)benzohydrazide Chemical compound ClC(Cl)(Cl)C(=O)NN(C(C)(C)C)C(=O)C1=CC=CC=C1 MFTGBQRYFLPIEK-UHFFFAOYSA-N 0.000 claims 1
- CTJAREONWODJPF-UHFFFAOYSA-N n-tert-butyl-n'-(cyclohexanecarbonyl)benzohydrazide Chemical compound C=1C=CC=CC=1C(=O)N(C(C)(C)C)NC(=O)C1CCCCC1 CTJAREONWODJPF-UHFFFAOYSA-N 0.000 claims 1
- 125000002868 norbornyl group Chemical group C12(CCC(CC1)C2)* 0.000 claims 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims 1
- 230000000361 pesticidal effect Effects 0.000 claims 1
- 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 239000011343 solid material Substances 0.000 claims 1
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 claims 1
- 229940124530 sulfonamide Drugs 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims 1
- 125000003396 thiol group Chemical group [H]S* 0.000 claims 1
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 claims 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/72—Hydrazones
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/30—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the groups —CO—N< and, both being directly attached by their carbon atoms to the same carbon skeleton, e.g. H2N—NH—CO—C6H4—COOCH3; Thio-analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
- A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
- A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C243/00—Compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
- C07C243/24—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids
- C07C243/38—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids with acylating carboxyl groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/72—Hydrazones
- C07C251/82—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to carbon atoms of rings other than six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/04—Systems containing only non-condensed rings with a four-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
- C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
Abstract
Description
Claims (26)
- 하기 일반식(의) 살충성 유효 화합물 및 농학적으로 허용되는 그의 염.상기 식중, X 및 X'는 서로 동일하거나 상이한 것으로서, O, S 또는 NR이고, R1는 비치환된(C3-C10) 측쇄 알킬 또는 치환(C1-C4) 직쇄 알킬(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, (C3-C6)시클로 알킬 중 1개 또는 2개임)이고, A는 비치환 또는 치환(C1-C10)알킬 (여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 시아노, 니티로, 히드록시, (C1-C4)알콕시, 카르복시, (C1-C4)알콕시카르보닐, (C1-C4) 알카노일옥시 또는 -NNZ'중 1 내지 4개임), 비치환 또는 치환((C3-C8)시클로알킬는 (C3-C8)시클로알킬((C1-C|4)알킬(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 시아노, 니트로, 히드록시, (C1-C4)알킬, (C1-C4)할로알킬, C1-C4)알콕시. (C1-C4)할로 알콕시, 카르복시, (C1-C4)알카노일(C1-C4) 알콕시카르보닐, (C1-C4)알카노일옥시, 또는 -NZZ' 중 1내지 4개임), 비치환 또는 치환(C2-C8) 알케닐 또는 비치환 또는 치환, (C2-C8)알카디에닐(여기에서, 치환체는 서로 동일하거나 또는 상이한것으로서, 할로, 시아노, 니트로, 히드록시, (C1-C4)(C3-C6)알킬, 시클로알킬, (C1-C4)할로알킬, (C1-C4)할로알킬, (C1-C4)알콕시, (C1-C4)할로알콕시, 카르복시, (C1-C4)알콕시카르보닐, (C1-C4)알카노일옥시, 또는 -NZZ' 중 1개 내지 4개임), 비치환 또는 치환(C3-C8)시클로알케닐 또는 비치환 또는 치환(C3-C8)시클로알카디에닐(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 시아노, 니트로, 히드록시, (C1-C4)알킬, (C1-C4)알콕시, (C1-C4)할로알콕시, 카르복시, (C1-C4)알콕시카르보닐, C1-C4)알카노일옥시 또는 -NZZ' 중 1 내지 4개임), 비치환 또는 치환(C2-C8) 알키닐(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 시아노, 니트로, 히드록시, (C1-C4)알킬, (C1-C|4)할로알킬, (C1-C4)알콕시, (C1-C4)할로알콕시, 카르복시, (C1-C4)알콕시카르보닐, (C1-C4)알카노일옥시 또는 -NZZ' 중 1 내지 4개임), 또는 펜알킬(여기에서, 알킬기는 1 내지 4개의 탄소원자를 가지고, 페닐 고리는 비치환 또는 치환되며, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 시아노, 니트로, 히드록시, (C1-C4)알킬, (C1-C4) 할로알킬, (C1-C4)시아노알킬, (C1-C4)알콕시, (C1-C4)할로알콕시, 카르복시, (C1-C4)알콕시카르보닐, (C1-C4)알카노일옥시, (C2-C|6)알케닐, (C2-C6)할로알케닐, (C2-C6)알키닐, 또는 -NZZ' 중 1 내지 3개임)이고, B는 비치환 또는 치환나프틸(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 한로, 시아노, 니트로, 히드록시, (C1-C4)알콕시, (C1-C4)알킬, 카르복시, (C1-C4)알콕시카르보닐, (C1-C4)알카노일옥시 또는 -NZZ' 중 1 내지 3개임), 또는 비치환 또는 치환 페닐[여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로, 할로, 니트로, 시아노, 히드록시, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)시아노알킬, (C1-C6)알콕시, (C1-C6)할로알콕시, (C1-C6)알콕시알킬(각 알킬기는 독립적으로 일정한 수효의 탄소 원자를 가짐), (C1-C6)알콕시알킬기(각 알킬기는 독립적으로 일정한 수효의 탄소 원자를 가짐)(C1-C6)알콕시카르보닐옥시(-CCO2R), (C-C6)알케닐 )이 알케닐기는 임의로 할로, 시아노, C1-C4)알킬, (C1-C4)알콕시, (C1-C4)할로알콕시, 또는 (C1-C4)알킬티오토치환됨), 카르복시, (C1-C6)알콕시크르복시알킬(각 알킬기는 독립적으로 일정한 수효의 탄소 원자를 가짐)(-ROC2R'), -CO, (C1-C6)할로알킬카르보닐, (C1-C|3)시아노알킬카르보닐, (C1-C6) 니트로알킬카르보닐, (C1-C6)알콕시카르보닐, (C1-)C6)할로알콕시카르보닐, 알카노일옥시(-OCOR), 아미노(-NRR'), 치환아미노(에기서, 치환체는 히드록시, (C1-C4) 알콕시 또는 (C1-C)4)알킬티오기임), 페닐아미노, 디페닐아미노, 카르복스아미도(-NRCOR°), 카르바모일옥시(-OCONRR'), 아미도(NRCOR'), 알콕시카르보닐아미노(-NRCO2), 이미도(-N(COR)COR'), (알킬카르보닐아미노)카르보닐옥시(OCONRCOR'), 술프히드릴, 할로티오, (C1-C6)알킬티오, (C1-C6)할로알킬티오, 술피닐(-SOR), 술포닐(-SO2R), 페닐술포닐, 술포네이트(-OSO2), (C1-C6)할로알킬 술포닐옥시, 술폰아미드(-SO2NRR'), 알킬술폰아미드(-NRSOR', -NRSO2R'), 알킬티오카르보닐(-CSR, -CS2R), 티오아미도(-NRCSR'), 알킬카르보닐티오(-SCOR), 비치환 또는 치환페닐 (여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 시아노, 니트로, 히드록시, (C1-C4)알킬, (C1-C4)알콕시, 카르복시, (C1-C4)알콕시카르보닐, (C1-C4)알카노일옥시 또는 -NZZ' 중 1 내지 3개임), 페녹시(여기에서, 페닐 고리는 비치환 또는 치환되며, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 시아노, 니트로, 히드록시, (C1-C4)알킬, (C1-C4)알콕시, 카르복시, (C1-C4)알콕시카르보닐, (C1-C4)알카노일옥시 또는 -NZZ' 중 1 내지 3개임), 페닐티오(여기에서, 페닐 고리는 비치환 또는 치환되며, 치환체는 서로동일하거나 또는 상이한 것으로서, 할로, 시아네, 니트로, 히드록시, (C1-C4)알킬, (C1-C4)알콕시, 카르복시, (C1-C4)알콕시카르보닐, (C1-C4)알카노일옥시 또는 -NZZ' 중 1 내지 3개임)중 1 내지 5개이거나 또는 페닐 고리의 인접하는 두 위치가 알콕시기로 치환될 경우, 이 기들은 서로 결합하여 5원 또는 6원 디옥솔라노 또는 디옥사노 헤테로시클릭고리를 형성함]이며, 여기에서, R 및 R'는 수소 또는 (C1-C6)알킬이고, Z 및 Z'는 수소 또는 (C1-C4)알킬이다.
- 제1항에 있어서, X 및 X'가 O 또는 S이고, R1이 비치환(C3-C8)측쇄 알킬 또는 치환(C1-C4) 직쇄 알킬(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, (C3-C4)시클로알킬 중 1 또는 2개임)이고, A가(C1-C6) 비치환 또는 치환 알킬(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 시아노, 니트로, (C1-C4), 알콕시, 카르복시, (C1-C4)알콜시카르보닐, (C1-C4) 알카노일옥시 또는 -NZZ' 중 1 내지 3개임), (C3-C5)시클로알킬, (C2-C6) 비치환 또는 치환알케닐(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, (C1-C4)알킬(C1-C|4)할로알킬, (C1-C4)알콕시 또는 (C1-C4) 할로알콕시 중 1내지 3개임), (C3-C6) 시클로알케닐, 또는 펜알킬(여기에서, 알킬기는 1 또는 2개의 탄소원자를 가지며, 페닐고리는 비치환 또는 치환되며, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 니트로, 또는(C1-C4) 알칼 중 1 또는 2개임)이고, B가 비치환 나프틸, 또는 비치환 또는 치환페닐[여기에서, 치환체는 서로 동일하거나, 또는 상이한 것으로서, 할로, 니트로, 시아노, (C1-C4)알킬, (C1-C4)할로알킬, (C1-C|4)시아노알킬, (C1-C4)알콕시, (C1-C4)알콕시 알킬(여기에서, 각 알킬기는 일정한 수효의 탄소 원자를 가짐), -COZ, 카르복시, (C1-C4)알콕시카르보닐, (C1-C4)알카노일옥시, -NZZ', (C1-C4)알킬티오, 알킬티오카르보닐(-CSZ, -CS2Z), 알킬카르보닐티오(-SCOZ), 비치환 또는 치환페닐[여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 니트로, (C1-C4)알킬, (C1-C4)알콕시, 카르복시, (C1-C4)알콕시카르보닐, (C1-C4)알카노일옥시, 아미노, (C1-C4)알킬아미노 또는 (C1-C4)디알킬아니노 (여기에서, 각 알킬기는 독립적으로 일정한 수효의 탄소 원자를 가짐)중 1 내지 2개임, 1, 페녹시(여기에서, 페닐 고리는 비치환 또는 치환되며, 치환체는 서로 동일하거나 또는 상이한 것으로서 할로, 니트로, (C1-C4)알킬, (C1-C4)알콕시, 카르복시중 1 또는 2개임), (C1-C4)알콕시카르보닐, (C1-C4)알카노일옥시, 아미노, (C1-C4)알킬아미노 또는 (C1-C4)디알킬아미노 (여기에서, 각 알킬기는 독립적으로 일정한 수효의 탄소원자를 가짐) 중 1 내지 3개이거나 또는 페닐 고리의 인접하는 두 위치가 알콕시기로 치환될 경우, 이 기들은 결합하여 5원 또는 6원 디옥솔라노 또는 디옥사노 헤테로시클릭 고리를 형성함 1인 화합물 및 농학적으로 허용되는 그의 염.
- 제2항에 있어서, X 및 X'가 O 또는 S이고, R1이 측쇄(C3-C8)알킬이고, A가(C1-C6) 비치환 또는 치환알킬(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 시아노, 니트로, 카르복시 또는 (C1-C4)알콕시 카르보닐 중 1 내지 3개임), 시클로헥실, (C2-C6)비치환 또는 치환 알케닐(여기에서 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로 또는 (C1-C4)알킬 중 1 내지 3개임), 시클로헥세닐, 또는 벤질(여기에서, 페닐 고리는 비치환 또는 치환되며, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 메틸 또는 에틸 중 1 또는 2개임)이고, B가 비치환 나프틸, 또는 비치환 또는 치환페닐[여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 니트로, 시아노, (C1-C4)알킬, (C1-C4)할로알킬, (C1-C4)시아노알킬, (C1-C4) 알콕시, -COZ, (C1-C4)알콕시카르보닐, (C1-C4)알카노일옥시, 또는 비치환 또는 치환페닐(여기에서 치환체는 서로 동일하거나 또는 상이한 것으로서 할로,니트로,(C1-C4)알킬,(C1-C4)알콕시,카르복시,(C1-C4)알콕시카르보닐, (C1-C4)알카노일옥시 또는 -NZZ' 중 1 또느 2개임) 중 1 내지 3개임]인 화합물 및 농학적으로 허용되는 그의 염.
- 제3항에 있어서, X 및 X'가 O이고, R1이 측쇄(C4-C7)알킬이고, A가(C1-C6) 비치환 또는 치환알킬(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로 시클로헥실중 1 내지 2개임), (C2-C6)비치환 또는 치환알케닐(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로, 메틸 또는 에틸 1 중 내지 3개임), 시클로헥세닐, 또는 벤질기이고, B가 비치환 또는 치환페닐(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 할로(C1-C4)알킬, (C1-C4)알콕시, 또는 (C1-C4)할로알킬 중 1 내지 3개임)인 화합물 및 농학적으로 허용되는 그의 염.
- 제4항에 있어서, X 및 X'가 O이고, R1이 t-부틸, 네오펜틸(2,2-디메틸프로필) 또는 1,2,2-트리메틸프로필이고, A가(C3-C5)비치환 알킬, 시클로헥실, (C2-C4) 비치환 또는 치환직쇄 알케닐(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 클로로, 브로모 또는 메틸 중 1 내지 3개임), 시클로헥세닐, 또는 벤질기이고, B가 비치환 또는 치환페닐(여기에서, 치환체는 서로 동일하거나 또는 상이한 것으로서, 클로로, 플루오로, 브로모, 요오도, 메틸, 에틸, 메톡시 또는 트리플루오로 메틸 중 1 또는 2개임)인 화합물 및 농학적으로 허용되는 그의 염.
- 제1항에 있어서, X 및 X'가 O이고, R1이 t-부틸이고, B가 페닐이고, A가 시클로헥실, n-부틸, n-프로필, 벤질, 1-시클로헥세닐, 디클로로메틸 및 트리클로로메틸 중에서 선택된 기이거나, B가 4-클로로페닐이고, A가 n-프로필 및 t-부틸기 이거나, B가 3-메틸페닐이고, A가 노르보르닐, 시클로헥스-3-에닐, 1-부테닐, 3-부테닐, 시스-3,4-디히드록시시클로헥실, 2,2-디메틸-3a,4,5,6,7,7a-헥사히드로벤조[d]-디옥솔라노-5-일, 3-아세틸-2,2-디메틸시클로부틸메틸 및 2-메틸시클로헥실디-2,5-에닐 중에서 선택된 기이거나, 또는 B가 3,5-디메틸페닐이고, A가 이소프로필 및 1-메틸에테닐 중에서 선택된 기인 화합물.
- 제2항에 있어서 B가 비치환 페닐, 4-클로로페닐, 3-치환페닐, 2-치환페닐 또는 이치환 페닐인 화합물.
- 농학적으로 허용되는 담체와 제1항 내지 제6항중 어느 하나의 항의 화합물의 살충 유효량을 함유시킨 살충제 조성물.
- 제7항에 있어서, 유효 화합물이 조성물의 약 0.0001%-약 99중량%인 조성물.
- 제7항에 있어서, 유효 화합물이 조성물의 약 0.001%-약 99중량%인 조성물.
- 제7항에 있어서, 유효 화합물이 조성물의 약 0.01%-약 99중량%인 조성물.
- 제7항에 있어서, 농학적으로 허용되는 담체가 고상물인 살충제 조성물.
- 제11항에 있어서, 추가로 분산제를 함유시킨 수화제 형태의 살충제 조성물.
- 제11항에 있어서, 추가로 액상의 농학적으로 허용되는 담체 및 분산제를 함유시킨 유동제 형태의 살충제 조성물.
- 제11항에 있어서, 분제 형태의 살충제 조성물.
- 제11항에 있어서, 추가로 결합제를 함유시킨 입제 형태의 살충제 조성물.
- 제11항에 있어서, 추가로 유인제를 함유시킨 미끼제 형태의 살충제 조성물.
- 제7항에 있어서, 상기 농학적으로 허용되는 담체가 액체인 살충제 조성물.
- 제7항에 있어서, 추가로 유화제를 함유시킨 유화농축제 형태의 살충제 조성물.
- 제7항에 있어서, 유효 화합물이 N'-t-부틸-N-시클로헥실-카르보닐-N'-벤조일히드라진, N'-t-부틸-N-n-부티릴-N'-(4-클로로벤조일)히드라진, N'-t-부틸-N-n-발레릴-N'-벤조일히드라진 N'-t-부틸-N-n-부티릴-N'-벤조일히드라진, N'-t-부틸-N'-벤조일-N'-벤조일히드라진, N'-t-부틸-N-t-부틸카르보닐-N'-(4-클로로벤조일)히드라진 N'-t-부틸-N-(1-클로로헥세닐)카르보닐-N'-벤조일히드라진 N'-t-부틸-N-디클로로아세틸-N'-벤조일히드라진 및 N'-t-부틸-N-트리클로로아세틸-N'-벤조일히드라진으로 되는 군으로부터 선택된 삽충제 조성물.
- 해충을 제7항의 살충제 조성물과 접촉시켜서 해충을 박멸시키는 방법.
- 해충을 제19항의 살충제 조성물과 접촉시켜서 해충을 박멸시키는 방법.
- 제20항에 있어서, 상기 조성물을 유효 화합물 약 10g-약 10㎏/㏊의 양으로 살포시키는 방법.
- 제20항에 있어서, 상기 조성물을 유효 화합물 약 100g-약 5㎏/㏊의 양으로 살포시키는 방법.
- 제20항에 있어서, 상기 해충이 나비목(Lepidoptera) 또는 딱정벌레목(Coleoptera)종인 방법.
- 제21항에 있어서, 상기 해충이 나비목 또는 딱정벌레 목종인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US82118786A | 1986-01-22 | 1986-01-22 | |
US821187 | 1986-01-22 |
Publications (2)
Publication Number | Publication Date |
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KR870007105A true KR870007105A (ko) | 1987-08-14 |
KR910000856B1 KR910000856B1 (ko) | 1991-02-11 |
Family
ID=25232748
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019870000438A KR910000856B1 (ko) | 1986-01-22 | 1987-01-21 | 살충제 n'-치환-n-알킬카르보닐-n-아실히드라진 |
Country Status (14)
Country | Link |
---|---|
EP (1) | EP0232075B1 (ko) |
JP (1) | JP2618234B2 (ko) |
KR (1) | KR910000856B1 (ko) |
AR (1) | AR242555A1 (ko) |
AT (1) | ATE61569T1 (ko) |
AU (1) | AU604472B2 (ko) |
BR (1) | BR8700246A (ko) |
CA (1) | CA1338289C (ko) |
DE (1) | DE3768515D1 (ko) |
EG (1) | EG18196A (ko) |
ES (1) | ES2037076T3 (ko) |
GR (1) | GR3001621T3 (ko) |
IL (1) | IL81360A (ko) |
ZA (1) | ZA87430B (ko) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
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IE59962B1 (en) * | 1986-09-26 | 1994-05-04 | Rohm & Haas | Five-membered heterocyclic derivatives of n'-substituted-n, n'-diacylhydrazines |
US5110986A (en) * | 1988-04-26 | 1992-05-05 | Rohm And Haas Company | Synthesis of n-t-alkyl-1,2-diacylhydrazines |
NZ229536A (en) * | 1988-06-15 | 1992-05-26 | Rohm & Haas | N'-substituted-n'-substituted carbonyl-n-substituted carbonyl-hydrazines and pesticidal compositions |
NZ240155A (en) * | 1990-10-29 | 1992-10-28 | Ishihara Sangyo Kaisha | Heterocyclyl acyl and (hexahydro) indanyl acyl substituted hydrazine derivatives, preparation thereof and pesticidal compositions |
IL100643A (en) * | 1991-01-25 | 1996-10-31 | Nippon Kayaku Kk | History of hydrazine and pesticides containing these histories as an active ingredient |
US5399589A (en) * | 1992-12-17 | 1995-03-21 | Basf Aktiengesellschaft | Oxalyl hydrazide-hydroxamic acid derivatives, their preparation and their use as fungicides |
US5358966A (en) * | 1993-06-08 | 1994-10-25 | Rohm And Haas Company | Turfgrass insecticides |
EP0639558B1 (en) * | 1993-07-20 | 1996-10-23 | Nippon Kayaku Kabushiki Kaisha | Process for preparation of 1-acyl-2-substituted-hydrazines |
EP0717591A4 (en) * | 1993-09-06 | 1996-08-28 | Commw Scient Ind Res Org | INSECTICIDE COMPOSITION |
US7304161B2 (en) | 2003-02-10 | 2007-12-04 | Intrexon Corporation | Diaclhydrazine ligands for modulating the expression of exogenous genes in mammalian systems via an ecdysone receptor complex |
US7456315B2 (en) | 2003-02-28 | 2008-11-25 | Intrexon Corporation | Bioavailable diacylhydrazine ligands for modulating the expression of exogenous genes via an ecdysone receptor complex |
JP5186751B2 (ja) * | 2005-10-14 | 2013-04-24 | 住友化学株式会社 | ヒドラジド化合物およびその有害生物防除用途 |
DK2970106T3 (en) | 2013-03-15 | 2018-08-13 | Intrexon Corp | CONTAINING DIACYL HYDRAZINES |
US9944659B2 (en) | 2014-09-17 | 2018-04-17 | Intrexon Corporation | Boron-containing diacylhydrazine compounds |
CN113248351B (zh) * | 2021-05-26 | 2022-10-11 | 绍兴上虞新银邦生化有限公司 | 6-氯-2-甲氧基甲苯的制备方法及甲氧虫酰肼的合成工艺 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
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HU162374B (ko) * | 1969-04-03 | 1973-02-28 | ||
JPS52106836A (en) * | 1976-03-02 | 1977-09-07 | Kureha Chem Ind Co Ltd | N-trichloroacetyl-n#-chlorobenzoylhydrazine derivatives and germicide s for agriculture and horticulture containing thereof |
DE3228631A1 (de) * | 1982-07-31 | 1984-02-02 | Hoechst Ag, 6230 Frankfurt | Neue (di)-thiophosphor- und phosphonsaeure-derivate, verfahren zu ihrer herstellung, sie enthaltende mittel und ihre verwendung im pflanzenschutz |
DK483586A (da) * | 1985-10-21 | 1987-04-22 | Rohm & Haas | Insecticide n'-substituerede-n,n'-diacylhydraziner |
EP0228564B1 (en) * | 1985-12-09 | 1992-01-29 | American Cyanamid Company | Novel insecticidal diacylhydrazine compounds |
CA1295618C (en) * | 1986-02-28 | 1992-02-11 | Adam Chi-Tung Hsu | Insecticidal n'-substituted-n-acyl -n'-alkylcarbonylhydrazines |
-
1987
- 1987-01-08 CA CA000526935A patent/CA1338289C/en not_active Expired - Fee Related
- 1987-01-14 AR AR87306479A patent/AR242555A1/es active
- 1987-01-21 ZA ZA87430A patent/ZA87430B/xx unknown
- 1987-01-21 AU AU67894/87A patent/AU604472B2/en not_active Ceased
- 1987-01-21 BR BR8700246A patent/BR8700246A/pt unknown
- 1987-01-21 EG EG32/87A patent/EG18196A/xx active
- 1987-01-21 KR KR1019870000438A patent/KR910000856B1/ko not_active IP Right Cessation
- 1987-01-22 EP EP87300534A patent/EP0232075B1/en not_active Expired - Lifetime
- 1987-01-22 AT AT87300534T patent/ATE61569T1/de not_active IP Right Cessation
- 1987-01-22 DE DE8787300534T patent/DE3768515D1/de not_active Expired - Fee Related
- 1987-01-22 ES ES87300534T patent/ES2037076T3/es not_active Expired - Lifetime
- 1987-01-22 JP JP62011487A patent/JP2618234B2/ja not_active Expired - Lifetime
- 1987-01-22 IL IL81360A patent/IL81360A/xx not_active IP Right Cessation
-
1991
- 1991-03-14 GR GR90401045T patent/GR3001621T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
EP0232075A1 (en) | 1987-08-12 |
EG18196A (en) | 1992-09-30 |
EP0232075B1 (en) | 1991-03-13 |
GR3001621T3 (en) | 1992-11-23 |
ZA87430B (en) | 1988-11-30 |
ES2037076T3 (es) | 1995-04-01 |
JPS62209053A (ja) | 1987-09-14 |
KR910000856B1 (ko) | 1991-02-11 |
CA1338289C (en) | 1996-04-30 |
AR242555A1 (es) | 1993-04-30 |
DE3768515D1 (de) | 1991-04-18 |
IL81360A0 (en) | 1987-08-31 |
JP2618234B2 (ja) | 1997-06-11 |
AU604472B2 (en) | 1990-12-20 |
BR8700246A (pt) | 1987-12-01 |
IL81360A (en) | 1990-12-23 |
ATE61569T1 (de) | 1991-03-15 |
AU6789487A (en) | 1987-07-23 |
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