KR880003933A - N'-치환-n,n'-디아실 히드라진의 5원자 헤테로고리 유도체 - Google Patents

N'-치환-n,n'-디아실 히드라진의 5원자 헤테로고리 유도체 Download PDF

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KR880003933A
KR880003933A KR1019870003677A KR870003677A KR880003933A KR 880003933 A KR880003933 A KR 880003933A KR 1019870003677 A KR1019870003677 A KR 1019870003677A KR 870003677 A KR870003677 A KR 870003677A KR 880003933 A KR880003933 A KR 880003933A
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substituted
unsubstituted
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nitro
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KR950013856B1 (ko
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치-퉁수 아담
팻 레 다트
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롬 앤드 하스 캄파니
윌리엄 이. 램버트 3세
롬 앤드 하스 캄 파니
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    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
    • C07D263/08—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D263/16—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
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    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/10—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
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    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/04—1,2,3-Triazoles; Hydrogenated 1,2,3-triazoles
    • C07D249/06—1,2,3-Triazoles; Hydrogenated 1,2,3-triazoles with aryl radicals directly attached to ring atoms
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    • C07—ORGANIC CHEMISTRY
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    • C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
    • C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
    • C07D261/06—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
    • C07D261/10—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D275/03—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07—ORGANIC CHEMISTRY
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    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/38—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals

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  • Organic Chemistry (AREA)
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  • Plural Heterocyclic Compounds (AREA)
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  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Furan Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

내용 없음

Description

N'-치환-N,N'-디아실 히드라진의 5원자 헤테로고리 유도체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (23)

  1. 살충활성을 갖는 다음 일반식(I)의 화합물 및 농경학적으로 허용되는 그의 염.
    식중, X와 X'는 각각 산소(O), 황(S) 또는 NR기이고,
    R1은 비치환 분지쇄(C3-C10)알킬기이거나 또는 2개 이하의 서로 같거나 다른(C3-C6)시클로알킬기로 치환된 직쇄(C1-C4)알킬기이고, A와 B는 각각 비치환 페닐기 ; 또는 할로겐; 니트로조; 니트로; 시아노; 수산기; (C1-C6)알킬기; (C1-C6)시아노알킬기; (C1-C6)알콕시기; (C1-C6)할로알콕시기; 각 알킬그룹이 C1-C6인 알콕시알킬기; 각 알킬그룹이 C1-C6인 알콕시알콕시기; (C1-C6)알콕시카보닐옥시기(-OCO2R) ; 할로겐, 시아노, (C1-C4)알킬기, (C1-C4)알콕시기, (C1-C4)할로알콕시기 또는(C1-C4)알킬티오기로 치환된 또는 치환되지 않은(C2-C6)알케닐기; (C2-C6)알케닐카보닐기; (C2-C6)알카디에닐기; 할로겐, 시아노, 니트로, 수산기, (C1-C4)알콕시기, (C1-C4)할로알콕시기 또는(C1-C4)알킬티오기로 치환된 또는 치환되지 않은(C2-C6)알키닐기; (C2-C6)알키닐가보닐기; 카르복시기; 각 알킬그룹이 C1-C6인 카르복시알킬기(-RCO2R'); -COR; (C1-C6)할로알킬카보닐기; (C1-C6)시아노알킬카보닐기; (C1-C6)니트로알킬카보닐기;(C1-C6)알콕시카보닐기; (C1-C6)할로알콕시카보닐기; (C1-C6)알칸오일옥시기(-OCOR); 아미노기(-NRR'); 수산기, (C1-C4)알콕시기 또는 (C1-C4)알킬 티오기로 치환된 아미노기; 페닐아미노기; 디페닐아미노기; 카르복스아미도기(-CONRR'); 카바모일 옥시기(-OCONRR'); 아미디노기(-C(NR)NR'R"); 알킬아조기(-N=NR); 페닐아조기; 아미도기(-NRCOR'); 알콕시카보닐아미노기(-NRCO2R'); 아미도기(-N(COR)COR'); 알킬카보닐아미노카보옥시기(-OCONRCOR'); 술프히드릴기; 할로티오기; 티오시아나토기; (C1-C6)알킬티오기; (C1-C6)할로알킬티오기; 술피닐기(-SOR);술포닐기(-SO2R); 페닐술포닐기; 술포네이트기(-OSO2R); (C1-C6)할로알킬술포닐옥시기; 술폰아미드기(-SO2-NRR');알킬술폰아미드기(-NRSOR', -NRSO2R'); 알킬티오카보닐기(-SCOR); 각 알킬그룹이 C1-C6인 트리알킬실릴기; 할로겐, 시아노, 니트로, 수산기, (C1-C4)알킬기, (C1-C4)알콕시기, 카르복시기, (C1-C4)알콕시카보닐기, (C1-C4)알칸오일옥시기 및 아미노기로 구성된 그룹으로부터 선택된 서로 같거나 다른 3개이하의 치환체로 치환된 또는 치환되지 않은 페닐기; 페닐고리가 할로겐, 시아노, 니트로, 수산기, (C1-C4)알킬기, (C1-C4)알콕시기, 카르복시기, (C1-C4)알콕시카보닐기, (C1-C4)알칸오일옥시기 및 아미노기로 구성된 그룹으로부터 선택된 서로 같거나 다른 3개 이하의 치환체로 치환된 또는 치환되지 않은 펜옥시기; 페닐고리가 할로겐 시아노, 니트로, 수산기, (C1-C4)알킬기, (C1-C4)알콕시기, 카르복시기, (C1-C4)알콕시카보닐기, (C1-C4)알칸오일옥시기 및 아미노기로 구성된 그룹으로부터 선택된 서로 같거나 다른 3개이하의 치환체로 치환된 또는 치환되지 않은 벤조일기; 페닐고리가 할로겐, 시아노, 니트로, 수산기, (C1-C4)알킬기, (C1-C4)알콕시기, 카르복시기, (C1-C4)알콕시카보닐기, (C1-C4)알칸오일옥시기 및 아미노기로 구성된 그룹으로부터 선택된 서로 같거나 다른 3개 이하의 치환체로 치환된 또는 치환되지 않은 펜옥시 카보닐기 및 페닐고리가 할로겐, 시아노, 니트로, 수산기, (C1-C4)알킬기, (C1-C4)알콕시기, 카르복시기, (C1-C4)알콕시카보닐기, (C1-C4)알칸오일옥시기 및 아미노기로 구성된 그룹으로부터 선택된 서로 같거나 다른 3개 이하의 치환체로 치환된 또는 치환되지 않은 페닐티오기로 구성된 그룹으로부터 선택되 서로 같거나 다른 5개 이하의 치환체로 치환된 페닐기, 또는 페닐고리의 인접 두 위치가 알콕시기로 치환되어 5원자-또는 6원자-디옥소라노 또는 디옥사노 헤테로 고리를 형성하도록 치환된 페닐기; 또는 할로겐; 니트로; 수산기; (C1-C6)알킬기; (C1-C6)알콕시기; 카르복시기; (C1-C6)알콕시카보닐기; (C1-C6)카르복시알킬기(-RCO2R'); 카르복스아미도기(-CONRR')아미노기(-NRR'); (C1-C6)알킬티오기; 아미도기(-NRCOR'); 및 할로겐, 니트로, (C1-C6)알킬기,(C1-C6)할로알킬기, (C1-C6)알콕시기, (C1-C6)할로알콕시기, 카르복시기, (C1-C4)알콕시카보닐기 및 아미노기로 구성된 그룹으로부터 선택된 서로 같거나 다른 3개이하의 치환체로 치환된 또는 치환되지 않은 페닐기로 구성된 그룹으로부터 선택된 3개이하의 서로 같거나 다른 치환체로 치환된 또는 치환되지 않은, 푸릴기, 티에닐기, 트리아졸릴기, 피롤릴기, 이소피롤릴기, 피라졸릴기, 이소이미다졸릴기, 티아졸릴기, 이소티아졸릴기, 옥사졸릴기 및 이소옥사졸릴기로 구성된 그룹으로부터 선택된 치환 또는 비치환 5원자 헤테로고리기임. 단, A와 B중 하나는 반드시 치환 또는 비치환 5원자 헤테로고리기임.
  2. 제1항에 있어서, 일반식(Ⅰ)에서 X,X', R1, A및 B가 각각 다음과 같은 화합물 및 농경학적으로 허용되는 그의염.
    X와 X'는 각각 산소(O) 또는 황(S)이고, R1은 분지쇄(C3-C8)알킬기이며, A와 B는 각각 비치환 페닐기; 또는 할로겐; 니트로;시아노;(C1-C4)알킬기;(C1-C4)할로알킬기;(C1-C4)시아노알킬기;(C1-C4)알콕시기;(C1-C4)알콕시알킬기;-COZ;(C1-C4)알콕시카보닐기;(C1-C4)알칸오일옥시기; 할로겐, 니트로, (C1-C4)알킬기, (C1-C4)알콕시기,카르복시기, (C1-C4)알콕시카보닐기, (C1-C4)알칸오일옥시기 및 -NZZ'로 구성된 그룹으로부터 선택된 서로 같거나 다른 2개 이하의 치환체로 치환되었거나 또는 치환되지 않은 페닐기; 및 페닐고리가 할로겐, 니트로, (C1-C4)알킬기, (C1-C4)알콕시기,카르복시기, (C1-C4)알콕시카보닐기, (C1-C4)알칸오일옥시기 및 -NZZ'로 구성된 그룹으로부터 선택된 서로 같거나 다른 2개 이하의 치환체로 치환된 또는 치환되지 않은 페녹시기로 구성된 그룹으로부터 선택된 서로 같거나 다른 3개이하의 치환체로 치환된 페닐기;또는 할로겐;니트로;
    (C1-C4)알킬기; (C1-C4)알콕시기; -NZZ'및 할로겐, 니트로, (C1-C4)알킬기, (C1-C4)할로알킬기, (C1-C4)알콕시기, (C1-C4)할로알콕시기, 카르복시기 및 -NZZ'로 구성된 그룹으로부터 선택된 서로 같거나 다른 2개 이하의 치환체로 치환된 또는 치환되지 않은 페닐기로 구성된 그룹으로부터 선택된 서로 같거나 다른 2개이하의 치환체로 치환되었거나 또는 치환되지않은, 푸릴기, 티에닐기, 트리아졸릴기, 피롤릴기 및 옥사졸릴기로 구성된 그룹으로부터 선택된 치환 또는 비치환 5원자 헤테로고리기임.
    단, A와 B중 하나는 치환 또는 비치환, 5원자 헤테로 고리기이며, 상기 설명중 미설명부호인 Z와 Z'는 각각 수소 또는 (C1-C4)알킬기임.
  3. 제2항에 있어서, 일반식(I)에서 X,X',R1, A 및 B가 각각 다음과 같은 화합물 및 농경학적으로 허용되는 그의 염.
    X와 X'는 각각 산소(O)이고, R1은 분지쇄(C4-C7)알킬기이며, A와 B는 각각 비치환페닐기 또는 할로겐, 니트로, (C1-C4)알킬기,(C1-C4)알콕시기 및 (C1-C4)할로알킬기로 구성된 그룹으로부터 선택된 3개 이하의 치환체로 치환된 페닐기; 또는 할로겐, 니트로, (C1-C4)알킬기, 및 (C1-C4)알콕시기로 구성된 그룹으로부터 선택된 서로 같거나 다른 2개이하의 치환체로 치환되었거나 또는 치환되지 않은, 푸릴기, 티에닐기, 피롤틸기 및 옥사졸릴기로 구성된 그룹으로부터 선택된 치환 또는 비치환 5원자헤테로고리기임.
    단,A와 B중 하나는 치환 또는 비치환 5원자 헤테로고리기임.
  4. 제3항에 있어서, 일반식(I)에서 X,X',R1, A 및 B가 각각 다음과 같은 화합물 및 농경학적으로 허용되는 그의 염.
    X와 X'는 각각 산소(O)이고, R1은 t-부틸, 네오펜틸, 2,2-디메틸프로필 또는 1,2,2-트리메틸프로필이고, A와 B는 각각 비치환 페닐기; 또는 클로로, 플루오로, 브로모, 요오도, 니트로, 메틸, 에틸, 메톡시 및 트리플루오로메틸로 구성된 그룹으로부터 선택된 서로 같거나 다른 2개 이하의 치환체로 치환된 페닐기; 또는 비치환 푸릴, 비치환 티에닐, 비치환 피롤릴 또는 (C1-C4)알킬기로 치환된 피롤릴기로부터 선택된 치환 또는 비치환 5원자 헤테로고리기임.
    단, A와 B중 하나는 치환 또는 비치환 5원자 헤테로고리기임.
  5. 살충효과적인 양의 상기 제1항 내지 4항의 어느 한항에 기재한, 살충활성화합물 및 농경학적으로 허용되는 매개체로 구성된, 살충제조성물.
  6. 제5항에 있어서, 살출활성 화합물의 함량이 0.0001내지 99wt%임을 특징으로 하는, 살충제조성물.
  7. 제5항에 있어서, 살출활성 화합물의 함량이 0.001내지 99wt%임을 특징으로 하는, 살충제조성물.
  8. 제5항에 있어서, 살출활성 화합물의 함량이 0.01내지 75wt%임을 특징으로 하는, 살충제조성물.
  9. 제5항에 있어서, 농경학적으로 허용되는 매개체가 고체임을 특징으로 하는, 살충제조성물.
  10. 제9항에 있어서, 상기 조성물이 분산제를 부가적으로 포함하며 습윤분말 형태임을 특징으로 하는, 살충제조성물.
  11. 제9항에 있어서, 상기 조성물이 농경학적으로 허용되는 액체매개체 및 분산제를 부가적으로 포함하며 유동성농축물 형태임을 특징으로 하는 살충제조성물.
  12. 제9항에 있어서, 상기 조성물이 건조분말 형태임을 특징으로 하는, 살충제조성물.
  13. 제9항에 있어서, 상기 조성물이 결합제를 부가적으로 포함하며 과립형태임을 특징으로 하는, 살충제조성물.
  14. 제9항에 있어서, 상기 조성물이 유인물질을 부가적으로 포함하며 미끼 형태임을 특징으로 하는 살충조성물.
  15. 제5항에 있어서, 농경학적으로 허용되는 매개체가 액체임을 특징으로하는, 살충제조성물.
  16. 제5항에 있어서, 상기 조성물이 유화제를 부가적으로 포함하며 유화농축물 형태임을 특징으로 하는 살충제조성물.
  17. 제5항에 있어서, 살출활성 화합물이 N'-t-부틸-N-벤조일-N'-(2-티오펜카보닐)히드라진, N'-t-부틸-N-(3-티오펜카보닐)-N'-벤조일히드라진 및 N'-t-부틸-N-(3-푸로일)-N'-벤조일히드라진으로 구성된 그룹으로부터 선택된 화합물임을 특징으로 하는 살충제조성물.
  18. 해충을 제5항에 기재한 살충제조성물에 접촉시킴을 특징으로 하는, 해충의 구제방법.
  19. 해충을 제17항에 기재한 살충제 조성물에 접촉시킴을 특징으로 하는, 해충의 구제방법.
  20. 제18항에 있어서, 헥타아르당 10g 내지 10kg의 살충활성 화합물의 수준으로 살충제 조성물을 적용시킴을 특징으로 하는, 해충의 구제방법.
  21. 제18항에 있어서, 헥타아르당 100g 내지 5kg의 살충활성 화합물의 수준으로 살충제 조성물을 적용시킴을 특징으로 하는, 해충의 구제방법.
  22. 제18항에 있어서, 구제되어야 할 해충이 레피도프테라 또는 클레오프테라종의 해충임을 특징으로 하는, 해충의 구제방법.
  23. 제19항에 있어서, 구제되어야 할 해충이 레피도프테라 또는 클레오프테라종의 해충임을 특징으로 하는, 해충의 구제방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870003677A 1986-09-26 1987-04-17 N' - 치환 - n, n' - 디아실히드라진의 5원자 헤테로고리 유도체 및 이를 함유한 살충조성물 KR950013856B1 (ko)

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NZ240155A (en) * 1990-10-29 1992-10-28 Ishihara Sangyo Kaisha Heterocyclyl acyl and (hexahydro) indanyl acyl substituted hydrazine derivatives, preparation thereof and pesticidal compositions
IL100643A (en) * 1991-01-25 1996-10-31 Nippon Kayaku Kk History of hydrazine and pesticides containing these histories as an active ingredient
IL102676A0 (en) * 1991-08-07 1993-01-14 Ciba Geigy Ag Butyric acid amides
US5358966A (en) * 1993-06-08 1994-10-25 Rohm And Haas Company Turfgrass insecticides
EP0717591A4 (en) * 1993-09-06 1996-08-28 Commw Scient Ind Res Org INSECTICIDE COMPOSITION
US5523325A (en) * 1993-09-09 1996-06-04 Jacobson; Richard M. Amidrazones and their use as pesticides
US6723531B2 (en) 1996-04-05 2004-04-20 The Salk Institute For Biological Studies Method for modulating expression of exogenous genes in mammalian systems, and products related thereto
WO2004007477A1 (fr) * 2002-07-04 2004-01-22 Aventis Pharma S.A. Nouveaux derives acyl hydrazino du thiophene, leur procede de preparation, leur application a titre de medicaments, compositions pharmaceutiques et nouvelle utilisation
CN103483288B (zh) * 2013-10-12 2016-03-30 南开大学 一类3，4-二氯异噻唑双酰肼类化合物及其制备方法和用途

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FR2499074A1 (fr) * 1981-02-05 1982-08-06 Sandoz Sa Nouveaux derives de l'acide phenylhydrazine-carboxylique, leur preparation et leur utilisation comme agents fongicides
CA1338289C (en) * 1986-01-22 1996-04-30 Raymond August Murphy Insecticidal n'-substituted-n-alkylcarbonyl- n'-acylhydrazines
CA1295618C (en) * 1986-02-28 1992-02-11 Adam Chi-Tung Hsu Insecticidal n'-substituted-n-acyl -n'-alkylcarbonylhydrazines
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EG18453A (en) 1993-04-30
JPH085854B2 (ja) 1996-01-24
GR3006571T3 (ko) 1993-06-30
KR950013856B1 (ko) 1995-11-17
AU7147287A (en) 1988-03-31
ES2053535T3 (es) 1994-08-01
IL82244A (en) 1992-07-15
JPS6383063A (ja) 1988-04-13
EP0261755A2 (en) 1988-03-30
ZA872738B (en) 1988-06-29
PT84718B (pt) 1990-05-31
IE870845L (en) 1988-03-26
ATE83481T1 (de) 1993-01-15

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