KR860007152A - 구리 알루미늄 보레이트 및 그의 제조방법 - Google Patents

구리 알루미늄 보레이트 및 그의 제조방법 Download PDF

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KR860007152A
KR860007152A KR1019860001716A KR860001716A KR860007152A KR 860007152 A KR860007152 A KR 860007152A KR 1019860001716 A KR1019860001716 A KR 1019860001716A KR 860001716 A KR860001716 A KR 860001716A KR 860007152 A KR860007152 A KR 860007152A
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aluminum borate
copper
borate
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copper aluminum
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즈레쯔 알렉스
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아모코 코포레이션
랠프 챨스 메더스트, 제레미아에스, 샤논
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
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    • C01B35/00—Boron; Compounds thereof
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    • C01B35/12—Borates
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B35/00—Boron; Compounds thereof
    • C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
    • C01B35/10—Compounds containing boron and oxygen
    • C01B35/12—Borates
    • C01B35/128—Borates containing plural metal or metal and ammonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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Abstract

내용 없음

Description

구리 알루미늄 보레이트 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. 온도프로그램된환원(Temperature Programmed Reduction)조건하에 350℃ 이하의 온도에서 수소에 의해 적어도 부분적으로 환원될 수 있는 결정성 구리알루미늄 보레이트.
  2. 표면적이 5㎡/g 이상이고 공극용적이 0.04cc/g 이상인 결정성 구리 알루미늄 보레이트.
  3. 온도-프로그램된 환원 조건하에 350℃이하의 온도에서 수소에 의해 적어도 부분적으로 환원될 수 있는 구조식 Cu2-xAlB4O17Mx(여기서, M은 아연, 코발트, 닉켈 및 마그네슘중에서 선택된 2가 금속이고 X는 0.01 내지 0.8이다)의 결정성 구리 알루미늄 보레이트,
  4. 제3항에 있어서, 실제로 다음 표 A와 같은 X-선회절도를 갖는 구리 알루미늄 보레이트.
  5. 결정성 구리 알루미늄 보레이트와 알루미늄보레이트로 이루어진 조성물.
  6. 결정성구리알루미늄 보레이트와 구리 크로마이트로 이루어진 조성물.
  7. (1) 2가 구리, 3가 알루미늄 및 산화물 또는 보레이트 형태의 붕소 공급원을 혼합하고 : (2) 조성물을 건조시킨 다음: (3) 결성정 구리알루미늄 보레이트를 형성시키기에 충분히 높은 온도에서 조성물을 하소시킴을 특징으로 하여, 구리알루미늄 보레이트를 제조하는 방법.
  8. 제7항에 있어서, 단계(1)을 수성매질내에서 수행하는 방법.
  9. 제8항에 있어서, 단계(1)을 수성 암모니아 또는 수성암모늄염 존재하에서 수행하는 방법.
  10. 알루미늄 보레이트로 구성된 지지체상의 미세한 0가 구리로 이루어진 조성물.
  11. 제10항에 있어서, 알루미늄, 보레이트가 Al4B2O9인 조성물.
  12. 제11항에 있어서, 알루미늄 보레이트가 실제로 상기 표 A와 같은 X선 회절도를 갖는 구리알루미늄보레이트로 이루어진 조성물.
  13. 구리알루미늄 보레이트를 환원제와 접촉시킴을 특징으로하여, 알루미늄보레이트로 구성된 지지체상의 미세한 O가 구리로 이루어진 조성물을 제조하는 방법.
  14. 175℃이상의 온도에서 구조식 Cu2-xAl6-yB4O17MmM´|nM˝y(여기서, M은 2가 금속이고, M'는 1가 금속이며, m은 0 내지 0.8이고, n은 0 내지 1.6이며, x는 0내지 0.8이고 m+n/2의 합과 동일하며, M"는 3가 금속이고, y는 0 내지 1.2이다)의 구리알루미늄보레이트를 환원제와 접촉시킴을 특징으로하여 알루미늄보레이트 상의 미세한 0가 구리로 이루어진 조성물을 제조하는 방법.
  15. 제14항에 있어서, 구리알루미늄 보레이트가 실제로 상기표 A에 기술된 x-선회절도를 갖는 방법.
  16. 제14항에 있어서, 환원제가 수소인 방법.
  17. Al4B2O9및 구조식 Cu2-xAl6-yB4-O17MmM'nM"y(여기서, M은 2가 금속이고, M'는 1가 금속이며, m은 0 내지 0.8이고, n은 0 내지 1.6이며, x는 0내지 0.8이고 m+n/2의 합과 동일하며, M"는 3가 금속이고, y는 0 내지 1.2이다)인 구리 알루미늄 보레이트중에서 선택된 적어도 하나의 성분을 필수적으로 함유하는 지지체 상의 미세한 0가 구리로 이루어진 조성물.
  18. 구리 알루미늄 보레이트로 구성된 지지체상의 미세한 0가 구리로 이루어진 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860001716A 1985-03-11 1986-03-11 구리 알루미늄 보레이트 및 그의 제조방법 KR900009150B1 (ko)

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US06/709,790 US4729979A (en) 1985-03-11 1985-03-11 Copper aluminum borate
US709790 1985-03-11

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US (1) US4729979A (ko)
EP (1) EP0194828B1 (ko)
JP (1) JPS61242913A (ko)
KR (1) KR900009150B1 (ko)
CN (1) CN1010302B (ko)
AT (1) ATE76332T1 (ko)
CA (1) CA1269222A (ko)
DE (1) DE3685348D1 (ko)
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JPS61242913A (ja) 1986-10-29
ATE76332T1 (de) 1992-06-15
CN86101428A (zh) 1986-09-10
DE3685348D1 (de) 1992-06-25
MX169868B (es) 1993-07-29
CN1010302B (zh) 1990-11-07
US4729979A (en) 1988-03-08
JPH0542369B2 (ko) 1993-06-28
EP0194828A2 (en) 1986-09-17
CA1269222A (en) 1990-05-22
KR900009150B1 (ko) 1990-12-22
MX9206449A (es) 1994-06-30
EP0194828A3 (en) 1988-05-11

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