KR860003293A - 가황물질의 특성개량 및 천연 및 합성고무 강화용 조성물 - Google Patents
가황물질의 특성개량 및 천연 및 합성고무 강화용 조성물 Download PDFInfo
- Publication number
- KR860003293A KR860003293A KR1019850007490A KR850007490A KR860003293A KR 860003293 A KR860003293 A KR 860003293A KR 1019850007490 A KR1019850007490 A KR 1019850007490A KR 850007490 A KR850007490 A KR 850007490A KR 860003293 A KR860003293 A KR 860003293A
- Authority
- KR
- South Korea
- Prior art keywords
- composition
- sulfur
- ester
- acid
- prepared
- Prior art date
Links
- 239000000463 material Substances 0.000 title 1
- 229920003052 natural elastomer Polymers 0.000 title 1
- 229920001194 natural rubber Polymers 0.000 title 1
- 230000003014 reinforcing effect Effects 0.000 title 1
- 229920003051 synthetic elastomer Polymers 0.000 title 1
- 239000005061 synthetic rubber Substances 0.000 title 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 7
- 239000002253 acid Substances 0.000 claims 6
- 238000000034 method Methods 0.000 claims 6
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims 6
- 150000002148 esters Chemical class 0.000 claims 5
- 229910052717 sulfur Inorganic materials 0.000 claims 4
- 239000011593 sulfur Substances 0.000 claims 4
- 125000004354 sulfur functional group Chemical group 0.000 claims 4
- 238000006243 chemical reaction Methods 0.000 claims 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical group SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical group C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- -1 aryl isothiocyanates Chemical class 0.000 claims 1
- 238000006482 condensation reaction Methods 0.000 claims 1
- 239000012084 conversion product Substances 0.000 claims 1
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 150000008117 polysulfides Polymers 0.000 claims 1
- 238000007086 side reaction Methods 0.000 claims 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 claims 1
- 150000003464 sulfur compounds Chemical class 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/372—Sulfides, e.g. R-(S)x-R'
- C08K5/3725—Sulfides, e.g. R-(S)x-R' containing nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Noodles (AREA)
- Exchange Systems With Centralized Control (AREA)
- Control Of Steam Boilers And Waste-Gas Boilers (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (13)
- 황작용기의 담체를 테트라-에틸렌 펜타민을 기초로 하는 조성물과 반응시켜 수득함을 특징으로 하는 조성물.
- 제1항에 있어서, 상술한 최소한 하나의 황작용기를 함유하는 화합물과 테트라에틸렌펜타민을 기초로 하는 상기 조성물사이의 반응을 적절한 온도조건하에서 실시함으로써 황작용기의 분해와 부반응의 발생을 피하는 것을 특징으로 하는 조성물.
- 제1항 또는 2항에 있어서, 황작용기를 에스테르로부터 제조함을 특징으로 하는 조성물.
- 제3항에 있어서, 반응을 30-100℃의 온도에서 수행하는 조성물.
- 제1항 또는 2항에 있어서, 황작용기를 산으로부터 제조함을 특징으로 하는 조성물.
- 제5항에 있어서, 축합제의 존재하에 산으로부터 황작용기를 제조함을 특징으로 하는 조성물.
- 제6항에 있어서, 축합제가 디시클로헥실-카르보디이미드인 조성물.
- 제1항 또는 2항에 있어서, 황작용기를 알킬 및 아릴 이소티오시아네이트의 군으로부터 선택된 화합물로부터 제조함을 특징으로 하는 조성물.
- 제1항 또는 2항에 있어서, a) 공지의 방법에 따라 메르캅토-산을 제조하고, b) 메르캅토산을 알코올에 의한 에스테르화하고, c) 메르캅토-에스테를 TEPA와 반응시켜 수득한, 최소한 하나의 메르캅탄기를 함유하는 조성물.
- 제9항에 있어서, 메르캅토-에스테르와 TEPA의 반응을 방향족 탄화수소의 존재하에 30∼100℃사이에 실시함을 특징으로 하는 조성물.
- 제1항에 있어서, a) 공지의 방법으로 메르캅토산을 제조하고, b) 수득한 황화합물의 조성물은 용해시키지만 축합제의 전환생성물은 용해시키지 않는 매질내에서 축합재의 존재하에 메르캅토산을 TEPA에 의한 축합반응시킴으로써 수득함을 특징으로 하는 메르캅탄기함유 조성물
- 제1항 또는 2항에 있어서, a) 황을 단일 불포화 에스테르와 반응시켜 황에 첨가된 에스테르를 수득하고 b) 황이 첨가된 에스테르/TEPA의 몰비율은 1∼3으로 하고 30∼100℃로 가열하면서 황이 첨가된 에스테르를 TEPA와 반응시켜 수득한, 최소한 하나의 다황화물기를 함유하는 조성물.
- ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR84/15654 | 1984-10-12 | ||
| FR8415654A FR2571721B1 (fr) | 1984-10-12 | 1984-10-12 | Compositions notamment dans le but d'ameliorer les proprietes des vulcanisats et le renforcement des caoutchoucs naturels et synthetiques |
| FR15654 | 1984-10-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR860003293A true KR860003293A (ko) | 1986-05-23 |
| KR920000446B1 KR920000446B1 (ko) | 1992-01-14 |
Family
ID=9308594
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019850007490A KR920000446B1 (ko) | 1984-10-12 | 1985-10-11 | 가황 물질의 특성 개량 및 천연고무 및 합성고무 강화용 조성물 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4701492A (ko) |
| EP (1) | EP0179707B1 (ko) |
| JP (1) | JPS61111345A (ko) |
| KR (1) | KR920000446B1 (ko) |
| AT (1) | ATE31922T1 (ko) |
| BR (1) | BR8505061A (ko) |
| CA (1) | CA1259986A (ko) |
| DE (1) | DE3561393D1 (ko) |
| DK (1) | DK465785A (ko) |
| ES (2) | ES8605479A1 (ko) |
| FI (1) | FI853957L (ko) |
| FR (1) | FR2571721B1 (ko) |
| NO (1) | NO165404C (ko) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3002230B1 (fr) | 2013-02-15 | 2016-02-05 | Arkema France | Utilisation de mercapto-esters methyliques en tant qu'agents de transfert de chaine |
| CN112159198A (zh) * | 2020-09-18 | 2021-01-01 | 沪宝新材料科技（上海）股份有限公司 | 一种抗冻融型透气混凝土界面剂 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2692871A (en) * | 1950-06-29 | 1954-10-26 | Columbia Southern Chem Corp | Compounded rubber stock |
| DE1570078A1 (de) * | 1965-09-23 | 1970-02-05 | Baerlocher Chem | Verwendung von Umsetzprodukten aus Aminoalkoholen mit Schwefel als Vulkanisiermittel fuer synthetischen Kautschuk |
| US3464969A (en) * | 1968-04-18 | 1969-09-02 | Nat Starch Chem Corp | Sulfur-containing polyamines |
| DE2134214A1 (de) * | 1971-07-09 | 1973-01-25 | Degussa | Vulkanisieren von natuerlichen und synthetischen kautschuken aus halogenfreien dienen |
| US3768537A (en) * | 1972-11-09 | 1973-10-30 | Ppg Industries Inc | Tire |
| US3994742A (en) * | 1973-10-11 | 1976-11-30 | Ppg Industries, Inc. | Rubber additive of silica and organic coupling agent |
| US4096085A (en) * | 1976-10-29 | 1978-06-20 | The Dow Chemical Company | Gas scrubbing system |
| US4377418A (en) * | 1980-03-21 | 1983-03-22 | Imperial Chemical Industries Limited | Particulate filler, coated with material bonded thereto and containing a sulfur-containing group which releases sulfur as a curing agent for s-curable unsaturated polymers |
| US4332967A (en) * | 1980-06-19 | 1982-06-01 | Petrolite Corporation | Compounds containing sulfur and amino groups |
| US4519430A (en) * | 1982-07-29 | 1985-05-28 | The B. F. Goodrich Company | Energy saving tire with silica-rich tread |
| US4463125A (en) * | 1982-08-18 | 1984-07-31 | The Goodyear Tire & Rubber Company | N-(Substituted oxymethyl)melamine derivatives as silica coupling agents |
-
1984
- 1984-10-12 FR FR8415654A patent/FR2571721B1/fr not_active Expired
-
1985
- 1985-10-08 AT AT85401955T patent/ATE31922T1/de not_active IP Right Cessation
- 1985-10-08 DE DE8585401955T patent/DE3561393D1/de not_active Expired
- 1985-10-08 EP EP85401955A patent/EP0179707B1/fr not_active Expired
- 1985-10-10 NO NO854031A patent/NO165404C/no unknown
- 1985-10-11 DK DK465785A patent/DK465785A/da not_active Application Discontinuation
- 1985-10-11 JP JP60225030A patent/JPS61111345A/ja active Pending
- 1985-10-11 ES ES547785A patent/ES8605479A1/es not_active Expired
- 1985-10-11 FI FI853957A patent/FI853957L/fi not_active Application Discontinuation
- 1985-10-11 KR KR1019850007490A patent/KR920000446B1/ko active IP Right Grant
- 1985-10-11 BR BR8505061A patent/BR8505061A/pt unknown
- 1985-10-11 CA CA000492789A patent/CA1259986A/fr not_active Expired
- 1985-10-15 US US06/787,067 patent/US4701492A/en not_active Expired - Fee Related
-
1986
- 1986-02-24 ES ES552327A patent/ES8707990A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CA1259986A (fr) | 1989-09-26 |
| ES8605479A1 (es) | 1986-03-16 |
| FR2571721B1 (fr) | 1988-04-08 |
| FI853957L (fi) | 1986-04-13 |
| EP0179707B1 (fr) | 1988-01-13 |
| NO165404B (no) | 1990-10-29 |
| ES8707990A1 (es) | 1987-09-01 |
| ES552327A0 (es) | 1987-09-01 |
| KR920000446B1 (ko) | 1992-01-14 |
| JPS61111345A (ja) | 1986-05-29 |
| DK465785A (da) | 1986-04-13 |
| DK465785D0 (da) | 1985-10-11 |
| DE3561393D1 (en) | 1988-02-18 |
| ATE31922T1 (de) | 1988-01-15 |
| FI853957A0 (fi) | 1985-10-11 |
| NO165404C (no) | 1991-02-06 |
| FR2571721A1 (fr) | 1986-04-18 |
| NO854031L (no) | 1986-04-14 |
| ES547785A0 (es) | 1986-03-16 |
| BR8505061A (pt) | 1986-07-29 |
| US4701492A (en) | 1987-10-20 |
| EP0179707A1 (fr) | 1986-04-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| G160 | Decision to publish patent application | ||
| E701 | Decision to grant or registration of patent right | ||
| NORF | Unpaid initial registration fee |