KR850008145A - 회전 오븐중에서 황산과 형석을 반응시켜 플루오르산을 제조하는 방법 - Google Patents

회전 오븐중에서 황산과 형석을 반응시켜 플루오르산을 제조하는 방법 Download PDF

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Publication number
KR850008145A
KR850008145A KR1019850003194A KR850003194A KR850008145A KR 850008145 A KR850008145 A KR 850008145A KR 1019850003194 A KR1019850003194 A KR 1019850003194A KR 850003194 A KR850003194 A KR 850003194A KR 850008145 A KR850008145 A KR 850008145A
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KR
South Korea
Prior art keywords
fluorspar
sulfuric acid
acid
rotary oven
producing
Prior art date
Application number
KR1019850003194A
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English (en)
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KR890003670B1 (ko
Inventor
삐에르 라로슈 (외 2)
Original Assignee
미셀 로쉐
소시에떼 아토샹
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Application filed by 미셀 로쉐, 소시에떼 아토샹 filed Critical 미셀 로쉐
Publication of KR850008145A publication Critical patent/KR850008145A/ko
Application granted granted Critical
Publication of KR890003670B1 publication Critical patent/KR890003670B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/19—Fluorine; Hydrogen fluoride
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/19—Fluorine; Hydrogen fluoride
    • C01B7/191—Hydrogen fluoride
    • C01B7/192—Preparation from fluorspar

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Silicon Compounds (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

내용 없음

Description

회전 오븐중에서 황산과 형석을 반응시켜 플로오르산을 제조하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. 전환율이 40 내지 50%인 분말상 생성물을 출구에서 생산하기 위하여 작동하는 예비반응 또는 예비혼합 장치에 황산과 형석을 공급한 후(a), 약 80 내지 350°C에서 작동하는 회전오븐에 20 내지 120°C의 온도로 상기의 분말상 생성물을 도입하여 플루오르산과 황산칼슘을 형성함과 동시에 (b), 오븐중에서 반응생성물을 재순환시켜 오븐에 공급되는 분말상 생성물에 함유된 플루오르화 칼슘 단위 몰당 황산칼슘 3 내지 3.5 몰이 재순환(c)됨을 특징으로하는 형석과 황산을 반응시켜 플루오르산을 제조하는 방법.
  2. 제1항에 있어서, 80내지 120°C의 온도로 예열된 황산과 형석을 예비 반응기에 공급하여, 예비 반응기중의 평균 잔류 시간은 8 내지 15분, 단계(a)를 수행시킴을 특징으로하는 방법.
  3. 제1항에 있어서, 예열되거나, 예열되지 않은 형석과 황산 및 초기에 도입되는 플루오르화 칼슘 단위 몰당 약 0.7 내지 1몰의 황산칼슘의 비율로 황산칼슘을 예비 배합기에 공급하여 단계(a)를 수행시킴을 특징으로 하는 방법.
  4. 제1 내지 3항중의 어느 한항에 있어서, 회전 오븐중에서 생성물의 평균 잔류 시간이 60내지 150분임을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850003194A 1984-05-18 1985-05-10 회전 오븐 중에서 황산과 형석을 반응시켜 플루오르산을 제조하는 방법 KR890003670B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8407719 1984-05-18
FR8407719A FR2564449B1 (fr) 1984-05-18 1984-05-18 Procede de fabrication d'acide fluorhydrique par reaction de l'acide sulfurique sur le spath fluor dans un four tournant

Publications (2)

Publication Number Publication Date
KR850008145A true KR850008145A (ko) 1985-12-13
KR890003670B1 KR890003670B1 (ko) 1989-09-30

Family

ID=9304120

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019850003194A KR890003670B1 (ko) 1984-05-18 1985-05-10 회전 오븐 중에서 황산과 형석을 반응시켜 플루오르산을 제조하는 방법

Country Status (18)

Country Link
EP (1) EP0163565B1 (ko)
JP (1) JPS6110004A (ko)
KR (1) KR890003670B1 (ko)
AT (1) ATA148885A (ko)
AU (1) AU578285B2 (ko)
BR (1) BR8502327A (ko)
CA (1) CA1307093C (ko)
DE (1) DE3560446D1 (ko)
EG (1) EG17428A (ko)
ES (1) ES543251A0 (ko)
FR (1) FR2564449B1 (ko)
GB (1) GB2159136B (ko)
IL (1) IL75016A (ko)
IN (1) IN164746B (ko)
IT (1) IT1187822B (ko)
MA (1) MA20432A1 (ko)
MX (1) MX163416B (ko)
ZA (1) ZA853260B (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6440224B1 (en) 1999-03-15 2002-08-27 Ecolab Inc. Hydrofluoric acid generating composition and method of treating surfaces
JP4599673B2 (ja) 2000-07-10 2010-12-15 ダイキン工業株式会社 フッ化水素製造装置および製造方法
MX2009008086A (es) * 2007-02-02 2009-08-12 Solvay Fluor Gmbh Preparacion de fluoruro de hidrogeno a partir de fluoruro de calcio y acido sulfurico.
JP5428594B2 (ja) 2009-07-06 2014-02-26 ダイキン工業株式会社 フッ化水素の製造方法
CN106660791B (zh) * 2014-07-11 2019-09-03 大金工业株式会社 氟化氢的制造方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1050374A (ko) *
GB554127A (en) * 1941-11-18 1943-06-22 Wilhelm Siegel Improvements in and relating to the production of hydrofluoric acid and other gaseous fluorine compounds from fluorspar
CH319931A (de) * 1953-06-29 1957-03-15 Buss Ag Verfahren zur kontinuierlichen Herstellung von Flusssäure
FR1356982A (fr) * 1963-01-30 1964-04-03 Electro Chimie Soc D Perfectionnements aux procédés d'obtention d'acide fluorhydrique
US3404953A (en) * 1964-06-02 1968-10-08 Ici Ltd Manufacture of hydrogen fluoride
FR1436984A (fr) * 1965-06-02 1966-04-29 Ici Ltd Perfectionnements à la fabrication de l'acide fluorhydrique
GB1304781A (ko) * 1969-11-11 1973-01-31
DE2435512A1 (de) * 1974-07-24 1976-02-05 Bayer Ag Verfahren zur herstellung von fluorwasserstoff und calciumsulfat
DE3372854D1 (en) * 1982-06-11 1987-09-10 Asahi Glass Co Ltd Process for producing hydrogen fluoride

Also Published As

Publication number Publication date
ES8603788A1 (es) 1986-01-01
MX163416B (es) 1992-05-11
IL75016A0 (en) 1985-08-30
KR890003670B1 (ko) 1989-09-30
GB8511935D0 (en) 1985-06-19
FR2564449B1 (fr) 1988-06-03
MA20432A1 (fr) 1985-12-31
EG17428A (en) 1991-08-30
BR8502327A (pt) 1986-01-21
IL75016A (en) 1988-10-31
AU578285B2 (en) 1988-10-20
GB2159136B (en) 1988-03-02
ATA148885A (de) 1996-01-15
AU4253985A (en) 1985-11-21
IN164746B (ko) 1989-05-20
IT8567448A0 (it) 1985-05-16
JPS6110004A (ja) 1986-01-17
CA1307093C (fr) 1992-09-08
FR2564449A1 (fr) 1985-11-22
GB2159136A (en) 1985-11-27
ZA853260B (en) 1985-12-24
ES543251A0 (es) 1986-01-01
DE3560446D1 (en) 1987-09-17
EP0163565A1 (fr) 1985-12-04
IT1187822B (it) 1987-12-23
JPH0440282B2 (ko) 1992-07-02
EP0163565B1 (fr) 1987-08-12

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