KR850004601A - 가교결합 아크릴중합체 프라이머로 도포된 폴리에스테르 필름 - Google Patents
가교결합 아크릴중합체 프라이머로 도포된 폴리에스테르 필름 Download PDFInfo
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- 229920006267 polyester film Polymers 0.000 title claims 9
- 229920000058 polyacrylate Polymers 0.000 title 1
- 239000002987 primer (paints) Substances 0.000 claims 13
- 239000000178 monomer Substances 0.000 claims 10
- 125000000524 functional group Chemical group 0.000 claims 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 8
- 229920000728 polyester Polymers 0.000 claims 7
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical group OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 claims 6
- 229920001577 copolymer Polymers 0.000 claims 6
- -1 polyethylene terephthalate Polymers 0.000 claims 6
- 239000011248 coating agent Substances 0.000 claims 5
- 239000000203 mixture Substances 0.000 claims 4
- 238000000576 coating method Methods 0.000 claims 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 2
- 239000004593 Epoxy Substances 0.000 claims 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical group CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 2
- 150000008065 acid anhydrides Chemical class 0.000 claims 2
- 125000005250 alkyl acrylate group Chemical group 0.000 claims 2
- 150000001408 amides Chemical class 0.000 claims 2
- 150000001412 amines Chemical group 0.000 claims 2
- 239000011230 binding agent Substances 0.000 claims 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 239000012948 isocyanate Substances 0.000 claims 2
- 150000002513 isocyanates Chemical class 0.000 claims 2
- 125000005641 methacryl group Chemical group 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 claims 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims 2
- 229920000139 polyethylene terephthalate Polymers 0.000 claims 2
- 239000005020 polyethylene terephthalate Substances 0.000 claims 2
- 230000003110 anti-inflammatory effect Effects 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 238000004132 cross linking Methods 0.000 claims 1
- 239000012954 diazonium Substances 0.000 claims 1
- 150000001989 diazonium salts Chemical class 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000001125 extrusion Methods 0.000 claims 1
- 239000008240 homogeneous mixture Substances 0.000 claims 1
- 239000013618 particulate matter Substances 0.000 claims 1
- 239000008188 pellet Substances 0.000 claims 1
- 238000011069 regeneration method Methods 0.000 claims 1
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- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/06—Recovery or working-up of waste materials of polymers without chemical reactions
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B44D—PAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
- B44D3/00—Accessories or implements for use in connection with painting or artistic drawing, not otherwise provided for; Methods or devices for colour determination, selection, or synthesis, e.g. use of colour tables
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- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
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- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
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- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
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- C—CHEMISTRY; METALLURGY
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
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- G03C1/93—Macromolecular substances therefor
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2433/08—Homopolymers or copolymers of acrylic acid esters
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/913—Material designed to be responsive to temperature, light, moisture
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31794—Of cross-linked polyester
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31797—Next to addition polymer from unsaturated monomers
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
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Abstract
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Description
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Claims (25)
- 버진 폴리에스테르와 프라이머 도포된 재생 폴리에스테르의 혼합물로 구성된 거의 비결정성 폴리에스테르필름을 용융압출시키고, 상기 필름을 한 방향 또는 두방향으로 연신하여 배향시킨 다음 상기 필름을 열처리하여 제조하며 ; 여기서 상기 프라이머 도포된 재생 폴리에스테르는 필름의 한측 또는 양측에 연속상 가교결합 아크릴 도포제를 함유하는 프아이머 도포된 연신폴리에스테르필름의 분쇄 생성물이고 ; 상기 아크릴 도포제는 중합된 아크릴 및/또는 메타크릴 단량체 적어도 약 50중량%, 공중합 상태에서 열처리에 의해 분자간 가교결합될 수 있는 공중합된 관능성 그룹-함유 코모노머 약 1 내지 약 15중량%, 및 하나이상의 할로겐-불함유 모노에틸렌계 불포화 공중합 단량체 약 0 내지 49중량%로 구성된 공중합체를 필수적으로 함유하는 연신자립성(oriented self-supporting) 폴리에스테르필름.
- 제1항에 있어서, 상기 프라이머 도포제가 약 10-7내지 10-5인치 범위의 건조두께를 갖는 필름.
- 제2항에 있어서, 버진 폴리에스테르 약 30 내지 95중량% 프라이머 도포된 재생 폴리에스테르 약 5 내지 70중량%를 함유하는 필름.
- 제3항에 있어서, 상기 자립성 폴리에스테르필름이 양축방향으로 연신된 폴리에틸렌 테레프탈레이트필름인 필름.
- 제4항에 있어서, 상기 관능그룹-함유 단량체중에 존재하는 상기 관능그룹이 아민, 아미드, 산무수물, N-메틸올, 카르복실, 하이드록실, 에폭시 및 이소시아네이트로 이루어진 군에서 선택된 필름.
- 제5항에 있어서, 상기 관능그룹-함유 코모노머가 N-메틸올아크릴아미드 및 N-메틸올메타크릴아미드로 이루어진 군에서 선택된 필름.
- 제6항에 있어서, 상기 아크릴 도포제가 저급알킬 아크릴레이트와 저급알킬 메타크릴레이트의 공중합체 약 85 내지 99중량% 및 N-메틸올아크릴아미드 약 1 내지 15중량%로 구성된 공중합체를 함유하는 필름.
- 제7항에 있어서, 상기 프라이머 도포제가 N-메틸올아크릴아미드 약 5 내지 10중량%를 함유하는 필름.
- 제7항에 있어서, 상기 아크릴레이트 단량체가 에틸아크릴레이트이고 상기 메타크릴레이트 단량체가 메틸메타크릴레이트인 필름.
- 제1항에 있어서, 연속상 가교결합 아크릴 도포제가 필름의 한측 또는 양측에 프라이머 도포되며 ; 상기 아크릴 도포제는 한 방향으로 연신되기 전에 한방향으로 연신된 후이나 상호수직 방향으로 연신되기전에 수성매체로부터 상기 필름에 처리되며 ; 상기 아크릴 도포제는 중합된 아크릴 및/또는 메타크릴 단량체 적어도 약 50중량% 공중합상태에서 열처리에 의해 분자간 가교 결합할수 있는 공중합된 관능그룹함유코모노모 약 1내지 약 15중량% 및 하나이상의 할로겐-불함유 모노에틸렌계 불포화 공중합 단량체 약 0 내지 49중량%로 구성된 공중합체를 필수적으로 함유하는 연신 자립성 폴리에스테르 필름.
- 제10항에 있어서, 상기 프라이머 도포제가 약 10-7내지 10-5인치 범위의 건조두께를 갖는 필름.
- 제11항에 있어서, 상기 자립성 폴리에스테르필름이 양축방향으로 연신된 폴리에틸렌 테레프탈레이트 필름인 필름.
- 제12항에 있어서, 상기 관능그룹-함유 단량체중에 존재하는 상기 관능그룹이 아민, 아미드, 산무수물, N-메틸올, 카르복실, 하이드록실, 에폭시 및 이소시아네이트로 이루어진 군에서 선택된 필름.
- 제13항에 있어서, 상기 관능그룹-함유 코모노머가 N-메틸올 아크릴아미드 및 N-메틸올 메타크릴아미드로 이루어진 군에서 선택된 필름.
- 제14항에 있어서, 상기 관능그룹-함유 코모노머가 약 5 내지 10중량% 정도로 존재하는 필름.
- 제14항에 있어서, 상기 프라이머 도포제가 저급알킬 아크릴레이트와 저급알킬 메타크릴레이트의 공중합체 약 85 내지 99중량% 및 N-메틸올아크릴아미드 약 1 내지 15중량%로 구성된 공중합체를 함유하는 필름.
- 제16항에 있어서, 상기 프라이머 도포제가 N-메틸올아크릴아미드 약 5 내지 10중량%를 함유하는 필름.
- 제16항에 있어서, 상기 아크릴레이트 단량체가 에틸아크릴레이트이고 상기 메타크릴레이트 단량체가 메틸메타크릴레이트인 필름.
- 제11항의 도포필름을 분쇄하여 약 270℃ 내지 약 310℃ 범위의 온도로 용융시키고, 상기 필름을 압출 및 양축방향 연신하기 전에 버진 폴리에스테르와 혼합시킴을 특징으로 하는, 버진 폴리에스테르 약 30 내지 95중량%와 상기 도포필림 약 70 내지 5중량%의 균질 혼합물을 함유하는 양축방향 연신폴리에스테르필름.
- 제19항에 있어서, 상기 도포제 약 0.01 내지 1.0 중량%를 함유하는 필름.
- 제1항의 프라이머 도포제에 직접 처리된 감광성 디아조늄염으로 함침된 또는 이를 함유하는 수지상 결합제로 이루어진 감광성층을 갖는 제12항의 필름으로 이루어진 감광성 필름.
- 제1항의 프라이머 도포제에 직접 처리된 미세하게 분리된 입상물질-함유 수지상 결합제로 구성된 소염층을 갖는 제12항의 필름으로 이루어진 그래픽필름.
- 제12항에 있어서, 상기 프라이머 도포제의 적어도 한 부분에 직접 처리된 인쇄용 잉크조성물을 갖는 필름.
- 제11항의 필름을 분쇄 및 펠렛화하고, 상기 펠렛화 필름을 버진 폴리에스테르 약 30 내지 95중량%와 혼합시키고, 상기 혼합물을 용융시켜 폴리에스테르필름의 펠렛 또는 시이트 형태로 압출시킴을 특징으로 하는 폴리에스테르필름의 재생방법.
- 제24항에 있어서, 상기 혼합물이 상기 분쇄된 필름 약 50중량% 및 상기 프레쉬 폴리에스테르 약 50중량%를 함유하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US560648 | 1983-12-12 | ||
US06/560,648 US4571363A (en) | 1983-12-12 | 1983-12-12 | Polyester film primed with crosslinked acrylic polymers |
Publications (2)
Publication Number | Publication Date |
---|---|
KR850004601A true KR850004601A (ko) | 1985-07-25 |
KR890002936B1 KR890002936B1 (ko) | 1989-08-12 |
Family
ID=24238708
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019840007850A KR890002936B1 (ko) | 1983-12-12 | 1984-12-12 | 가교결합 아크릴 중합체 프라이머로 도포된 폴리에스테르 필름 |
Country Status (7)
Country | Link |
---|---|
US (1) | US4571363A (ko) |
EP (1) | EP0144948B2 (ko) |
JP (1) | JPS60149442A (ko) |
KR (1) | KR890002936B1 (ko) |
BR (1) | BR8406333A (ko) |
CA (1) | CA1222114A (ko) |
DE (1) | DE3484924D1 (ko) |
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-
1983
- 1983-12-12 US US06/560,648 patent/US4571363A/en not_active Expired - Lifetime
-
1984
- 1984-11-23 CA CA000468572A patent/CA1222114A/en not_active Expired
- 1984-12-01 DE DE8484114641T patent/DE3484924D1/de not_active Expired - Lifetime
- 1984-12-01 EP EP19840114641 patent/EP0144948B2/de not_active Expired - Lifetime
- 1984-12-10 JP JP59259422A patent/JPS60149442A/ja active Granted
- 1984-12-11 BR BR8406333A patent/BR8406333A/pt not_active IP Right Cessation
- 1984-12-12 KR KR1019840007850A patent/KR890002936B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0144948A3 (en) | 1986-06-04 |
EP0144948A2 (de) | 1985-06-19 |
BR8406333A (pt) | 1985-10-08 |
DE3484924D1 (de) | 1991-09-19 |
JPS6247700B2 (ko) | 1987-10-09 |
EP0144948B1 (de) | 1991-08-14 |
US4571363A (en) | 1986-02-18 |
EP0144948B2 (de) | 1995-02-15 |
JPS60149442A (ja) | 1985-08-06 |
KR890002936B1 (ko) | 1989-08-12 |
CA1222114A (en) | 1987-05-26 |
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