KR850001249A - 에폭시 수지 또는 티오에폭사이드와 다가페놀, 다가티오페놀, 카복실산 또는 카복실산무수물의 반응을 촉진시키는 방법 - Google Patents

에폭시 수지 또는 티오에폭사이드와 다가페놀, 다가티오페놀, 카복실산 또는 카복실산무수물의 반응을 촉진시키는 방법 Download PDF

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KR850001249A
KR850001249A KR1019840004401A KR840004401A KR850001249A KR 850001249 A KR850001249 A KR 850001249A KR 1019840004401 A KR1019840004401 A KR 1019840004401A KR 840004401 A KR840004401 A KR 840004401A KR 850001249 A KR850001249 A KR 850001249A
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South Korea
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polyhydric phenol
independently
hydrocarbon radical
thioepoxide
carboxylic acid
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KR1019840004401A
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KR910006813B1 (ko
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에이. 두라키언(외 1) 죠지
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리차드 고든 워터맨
더 다우 케미칼 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5442—Aromatic phosphonium compounds (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5456—Arylalkanephosphonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/688—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing phosphorus

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Epoxy Resins (AREA)

Abstract

내용 없음

Description

에폭시 수지 또는 티오에폭사이드와 다가페놀, 다가티오페놀, 카복실산 또는 카복실산무수물의 반응을 촉진시키는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 상승된 온도에서, (a) 분자당 비시날 에폭사이드 또는 티오에폭사이드 그룹을, 평균 하나이상 함유하는 에폭시수지 또는 티오에폭사이드를, (b) 다가페놀, 다가티오페놀, 카복실산 또는 카복실산 무수물과 반응시키는 방법에 있어서, 다음 일반식에 상응하는 잔기를 분자당 평균 하나이상 함유하는 (c) 트리하이드로 카빌 포스핀 또는 4급 포스포늄 양이온 충분량의 존재하에서 수행시킴을 특징으로 하여, 상기 (a)와 (b) 및 (c)와의 반응을 촉진시키는 방법.
    상기 식에서, Z는 -O- 또는 -S-이고, R3는 독립적으로 반응에 거의 불활성인 잔기이고, W는 0 내지 4의 정수이다.
  2. 제1항에 있어서, (c) 또는 이의 유도체의 25중량 퍼센트미만 [최초에 존재하는 (c)의 양기준]이 물 또는 메탄올 중에서 생성된 수지로부터 추출됨을 특징으로 하는 방법.
  3. 제1항에 있어서, (c)가 다음 일반식(I),(II) 및 (III)중 하나인 방법.
    상기 식에서, R 및 R2는 각기 독립적으로 일반식의 라디칼이거나, 1가 탄화수소 라디칼이고, X는 적합한 음이온이며, R1은 염소, 브롬, 포스핀, 포스포늄, 페닐 및 티오페닐 잔기를 임의 포함하는 1가 탄화수소 라디칼이고, Z는 독립적으로 -O- 또는 -S-이며, A는 하나이상의 탄소원자상에 총(n+1)에 해당하는 원자가를 갖는 탄화수소 라디칼이고, n은 1,2 또는 3이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840004401A 1983-07-21 1984-07-21 에폭시수지 또는 티오에폭사이드와 다가페놀, 다가티오페놀, 카복실산 또는 카복실산 무수물의 반응을 촉진시키는 방법 KR910006813B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US515824 1983-07-21
US06/515,824 US4477645A (en) 1983-07-21 1983-07-21 Immobilized epoxy advancement initiators

Publications (2)

Publication Number Publication Date
KR850001249A true KR850001249A (ko) 1985-03-16
KR910006813B1 KR910006813B1 (ko) 1991-09-02

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019840004401A KR910006813B1 (ko) 1983-07-21 1984-07-21 에폭시수지 또는 티오에폭사이드와 다가페놀, 다가티오페놀, 카복실산 또는 카복실산 무수물의 반응을 촉진시키는 방법

Country Status (10)

Country Link
US (1) US4477645A (ko)
EP (1) EP0132789B1 (ko)
JP (1) JPS60500962A (ko)
KR (1) KR910006813B1 (ko)
AU (1) AU554910B2 (ko)
CA (1) CA1230194A (ko)
DE (1) DE3468034D1 (ko)
ES (1) ES8605003A1 (ko)
SG (1) SG75989G (ko)
WO (1) WO1985000612A1 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
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KR102205111B1 (ko) * 2019-11-05 2021-01-19 설진만 Frp 제품 제조 방법 및 이 방법에 사용되는 frp 분사 건

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IL75806A (en) * 1984-07-17 1988-10-31 Dow Chemical Co Partially advanced epoxy resin compositions and products resulting from reacting and curing said compositions
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US4647648A (en) * 1985-08-26 1987-03-03 The Dow Chemical Company Polyhydroxyethers from hydroxybiphenyls
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US5310854A (en) * 1989-08-23 1994-05-10 The Dow Chemical Company Epoxy resin composition and process therefor
US4981926A (en) * 1990-02-06 1991-01-01 The Dow Chemical Company Composition of epoxy resin, amino group-containing phosphonium catalyst and curing agent
US5208317A (en) * 1990-02-06 1993-05-04 The Dow Chemical Company Composition comprising epoxy resin and cationic amine phosphonium catalyst
US5140079A (en) * 1990-02-06 1992-08-18 The Dow Chemical Company Latent, curable, catalyzed mixtures of epoxy-containing and phenolic-hydroxyl-containing compounds containing compounds or complexes formed from contacting organic phosphines or arsines with weak nucleophilic acids
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US6812013B2 (en) * 2000-03-30 2004-11-02 Canon Kabushiki Kaisha Polyhydroxyalkanoate synthase and gene encoding the same
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Publication number Priority date Publication date Assignee Title
KR102205111B1 (ko) * 2019-11-05 2021-01-19 설진만 Frp 제품 제조 방법 및 이 방법에 사용되는 frp 분사 건

Also Published As

Publication number Publication date
EP0132789A1 (en) 1985-02-13
US4477645A (en) 1984-10-16
JPS632972B2 (ko) 1988-01-21
EP0132789B1 (en) 1987-12-09
SG75989G (en) 1990-04-20
DE3468034D1 (en) 1988-01-21
KR910006813B1 (ko) 1991-09-02
ES534498A0 (es) 1985-10-01
CA1230194A (en) 1987-12-08
AU554910B2 (en) 1986-09-04
JPS60500962A (ja) 1985-06-27
WO1985000612A1 (en) 1985-02-14
AU3214984A (en) 1985-03-04
ES8605003A1 (es) 1985-10-01

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