KR850000028A - 광학적 활성 페녹시프로피오네이트의 제조방법 - Google Patents
광학적 활성 페녹시프로피오네이트의 제조방법 Download PDFInfo
- Publication number
- KR850000028A KR850000028A KR1019840002935A KR840002935A KR850000028A KR 850000028 A KR850000028 A KR 850000028A KR 1019840002935 A KR1019840002935 A KR 1019840002935A KR 840002935 A KR840002935 A KR 840002935A KR 850000028 A KR850000028 A KR 850000028A
- Authority
- KR
- South Korea
- Prior art keywords
- diluent
- general formula
- enantiomer
- necessary
- alkoxyalkyl
- Prior art date
Links
- WROZTZHKRRNHBS-UHFFFAOYSA-N phenyl propaneperoxoate Chemical compound CCC(=O)OOC1=CC=CC=C1 WROZTZHKRRNHBS-UHFFFAOYSA-N 0.000 title claims 2
- 239000003085 diluting agent Substances 0.000 claims 8
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims 4
- 239000002253 acid Substances 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 150000002148 esters Chemical class 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- 239000003054 catalyst Substances 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims 2
- 230000000802 nitrating effect Effects 0.000 claims 2
- 125000004665 trialkylsilyl group Chemical group 0.000 claims 2
- SXERGJJQSKIUIC-UHFFFAOYSA-N 2-Phenoxypropionic acid Chemical class OC(=O)C(C)OC1=CC=CC=C1 SXERGJJQSKIUIC-UHFFFAOYSA-N 0.000 claims 1
- BDSSZTXPZHIYHM-UHFFFAOYSA-N 2-phenoxypropanoyl chloride Chemical compound ClC(=O)C(C)OC1=CC=CC=C1 BDSSZTXPZHIYHM-UHFFFAOYSA-N 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims 1
- 235000010290 biphenyl Nutrition 0.000 claims 1
- 239000004305 biphenyl Substances 0.000 claims 1
- 125000006267 biphenyl group Chemical group 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 claims 1
- 229910052736 halogen Chemical group 0.000 claims 1
- 150000002366 halogen compounds Chemical class 0.000 claims 1
- 150000002367 halogens Chemical group 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 150000002440 hydroxy compounds Chemical class 0.000 claims 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 1
- 150000005599 propionic acid derivatives Chemical class 0.000 claims 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G41/00—Compounds of tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/40—Unsaturated compounds
- C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
- C07C59/64—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings
- C07C59/66—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings
- C07C59/68—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings the oxygen atom of the ether group being bound to a non-condensed six-membered aromatic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/27—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups
- C07C205/35—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C205/36—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system
- C07C205/38—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system the oxygen atom of at least one of the etherified hydroxy groups being further bound to a carbon atom of a six-membered aromatic ring, e.g. nitrodiphenyl ethers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (1)
- 다음 일반식(II)의 페녹시프로피온산 클로라이드의 R에난티오머를, 필요에 따라 산 수용체 존재하 및 필요에 따라 희석제 존재하에서, 일반식(III)의 하이드록시 화합물과 반응시키고, 필요에 따라 형성된 에스테르를 희석제 존재하에서, 가수분해시키거나; 다음 일반식(VI)의 디페닐 에테르 유도체를, 필요에 따라 산 수용체 존재하 및 필요에 따라 희석제 존재하에서, 일반식(V)의 프로피온산 유도체의 S에난티오머와 반응시킨 후 생성된 일반식(VI)의 디페닐에테르유도체의 R에난티오머를, 필요에 따라 촉매 존재하 및 필요에 따라 희석제 존재하에서, 니트로화제와 반응시키고, 필요에 따라 형성된 에스테르를 희석제 존재하에서 가수분해 시키거나; 일반식(VII)의 페녹시 프로피온산 유도체의 R에 난티오머를 산 수용체 존재하 및 필요에 따라 희석제 존재하에서 일반식(VIII)의 할로겐 화합물과 반응시킨 후 생성된 일반식(VI)의 디페닐 에테르 유도체의 R에난티오머를, 필요에 따라 촉매 존재하 및 필요에 따라 희석제 존재하에서, 니트로화제와 반응시키고, 필요에 따라 형성된 에스테르를 희석제 존재하에서 가수분해시킴을 특징으로하여, 다음 일반식(I)의 페녹시프로피오네이트의 R에난티오머를 제조하는 방법.상기 일반식에서, X는 수소 또는 할로겐이고, R1은 수소 또는 알킬이고, Y는 트리알킬실릴, 알콕시알킬 또는 라디칼-COOR2(여기서 R2는 수소, 알킬 또는 알콕시알킬이다)이고, Y1은 트리알킬실릴, 알콕시알킬 또는 라디칼-COOR3(여기서 R3는 알킬 또는 알콕시알킬이다)이고, Z는 토실레이트 또는 메실레이트이고, Hal은 염소 또는 브롬이다.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19833319289 DE3319289A1 (de) | 1983-05-27 | 1983-05-27 | Optisch aktive phenoxypropionsaeure-ester |
| DEP3319289.8 | 1983-05-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR850000028A true KR850000028A (ko) | 1985-02-25 |
Family
ID=6200050
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019840002935A KR850000028A (ko) | 1983-05-27 | 1984-05-26 | 광학적 활성 페녹시프로피오네이트의 제조방법 |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0128381A1 (ko) |
| JP (1) | JPS59222447A (ko) |
| KR (1) | KR850000028A (ko) |
| AU (1) | AU2846984A (ko) |
| BR (1) | BR8402529A (ko) |
| DE (1) | DE3319289A1 (ko) |
| DK (1) | DK260384A (ko) |
| IL (1) | IL71918A0 (ko) |
| ZA (1) | ZA843991B (ko) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100399102B1 (ko) * | 2000-12-22 | 2003-09-22 | 용강호 | 액자장식용 수용성 전사액의 조성물 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4221581A (en) * | 1977-10-25 | 1980-09-09 | Ciba-Geigy Corporation | Phenoxyphenoxyalkanecarboxylic acid esters |
| CH650493A5 (en) * | 1977-12-24 | 1985-07-31 | Hoechst Ag | D-(+)-alpha-phenoxypropionic acid derivatives |
| DE2906087A1 (de) * | 1979-02-17 | 1980-09-04 | Bayer Ag | Phenoxycarbonsaeure-carbonylalkylester, verfahren zu ihrer herstellung und ihre verwendung als herbizide |
| DE3141860A1 (de) * | 1981-10-22 | 1983-05-05 | Bayer Ag, 5090 Leverkusen | Trifluormethyl-phenoxy-phenyl-silicium-derivate, verfahren zu ihrer herstellung und ihre verwendung als herbizide und pflanzenwuchsregulatoren |
| EP0095115A1 (de) * | 1982-05-26 | 1983-11-30 | Bayer Ag | Substituierte Diphenylether |
-
1983
- 1983-05-27 DE DE19833319289 patent/DE3319289A1/de not_active Withdrawn
-
1984
- 1984-05-14 EP EP84105433A patent/EP0128381A1/de not_active Withdrawn
- 1984-05-22 AU AU28469/84A patent/AU2846984A/en not_active Abandoned
- 1984-05-23 JP JP59102750A patent/JPS59222447A/ja active Pending
- 1984-05-24 IL IL71918A patent/IL71918A0/xx unknown
- 1984-05-25 DK DK260384A patent/DK260384A/da not_active Application Discontinuation
- 1984-05-25 ZA ZA843991A patent/ZA843991B/xx unknown
- 1984-05-26 KR KR1019840002935A patent/KR850000028A/ko not_active Application Discontinuation
- 1984-11-27 BR BR8402529A patent/BR8402529A/pt unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100399102B1 (ko) * | 2000-12-22 | 2003-09-22 | 용강호 | 액자장식용 수용성 전사액의 조성물 |
Also Published As
| Publication number | Publication date |
|---|---|
| BR8402529A (pt) | 1985-04-02 |
| DK260384D0 (da) | 1984-05-25 |
| JPS59222447A (ja) | 1984-12-14 |
| IL71918A0 (en) | 1984-09-30 |
| ZA843991B (en) | 1985-01-30 |
| AU2846984A (en) | 1984-11-29 |
| DK260384A (da) | 1984-11-28 |
| EP0128381A1 (de) | 1984-12-19 |
| DE3319289A1 (de) | 1984-11-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |