KR840007235A - 폴리우레탄 촉매 조성물 - Google Patents
폴리우레탄 촉매 조성물 Download PDFInfo
- Publication number
- KR840007235A KR840007235A KR1019830005964A KR830005964A KR840007235A KR 840007235 A KR840007235 A KR 840007235A KR 1019830005964 A KR1019830005964 A KR 1019830005964A KR 830005964 A KR830005964 A KR 830005964A KR 840007235 A KR840007235 A KR 840007235A
- Authority
- KR
- South Korea
- Prior art keywords
- composition
- dicarboxylic acid
- acid dialkyl
- dialkyl tin
- alkyl
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims 9
- 239000003054 catalyst Substances 0.000 title claims 3
- 229920002635 polyurethane Polymers 0.000 title 1
- 239000004814 polyurethane Substances 0.000 title 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 6
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims 5
- 239000012948 isocyanate Substances 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 239000011541 reaction mixture Substances 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 150000007824 aliphatic compounds Chemical class 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- -1 isocyanate compounds Chemical group 0.000 claims 2
- ZRWNRAJCPNLYAK-UHFFFAOYSA-N 4-bromobenzamide Chemical compound NC(=O)C1=CC=C(Br)C=C1 ZRWNRAJCPNLYAK-UHFFFAOYSA-N 0.000 claims 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000012975 dibutyltin dilaurate Substances 0.000 claims 1
- 150000002513 isocyanates Chemical group 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2120/00—Compositions for reaction injection moulding processes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (9)
- 중량비가 약 25:75 내지 약 75:25인 타프탈렌산 납과 디카르복실산 디알킬 주석을 함유하며, 하이드록실을 함유하는 지방족 화합물과 저지된 지방족 2급 및(혹은)3급 이소시아네이트 화합물과의 반응에 촉매로 사용되기 위한 조성물.
- 제1항에 있어서, 상기 중량비가 약 25:75 내지 약 75:25인 나프탈렌산 납과 디카르복실산 디알킬 주석을 필수성분으로 하여 구성되는 조성물.
- 제1항에 있어서, 상기 중량비가 약 25:75 내지 약 75:25인 나프탈렌산 납과 디카르복실산 디알킬 주석으로 구성되는 조성물.
- 제1항에 있어서, 상기 디카르복실산 디알킬 주석이 다음과 같은 구조식을 갖는 조성물.상기 식에서, R은 C1~C8알킬이며, R'는 C1~C18알킬이다.
- 제1항에 있어서, 상기 디카르복실산 디알킬 주석이 디라우린산 디메틸 주석과 디라우린산 디부틸 주석으로부터 선택된 조성물.
- 제1항에 있어서, 나프탈렌산 납과 디카르복실산 디알킬 주석의 중량비가 약 50:50인 조성물.
- 제1항에서 정의된 바와 같은 촉매조성물 약 0.05 내지 약 5중량%를 반응혼합물내에 혼입(混入)시키는 것으로 구성되는, 하이드록실을 함유하는 지방족 화합물과 저지된 지방족 2급 및 (혹은) 3급 이소시아네이트 화합물과의 혼합물에 대한 촉매화방법.
- 제7항에 있어서, 상기 반응혼합물이 다음구조식의 이소시아네이트 화합물을 함유하는 방법.상기 식에서, R1은 수소 혹은 C1~C4알킬이며, R2는 수소 혹은 C1~C4알킬이다.
- 제7항에 있어서, 상기 반응혼합물이 1,8-디아소시아네이토-0-멘탄을 함유하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45062682A | 1982-12-17 | 1982-12-17 | |
| US450,626 | 1982-12-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR840007235A true KR840007235A (ko) | 1984-12-06 |
| KR920002770B1 KR920002770B1 (ko) | 1992-04-03 |
Family
ID=23788860
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019830005964A KR920002770B1 (ko) | 1982-12-17 | 1983-12-16 | 개량된 폴리우레탄 촉매조성물 |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0111681B1 (ko) |
| JP (1) | JPS59115320A (ko) |
| KR (1) | KR920002770B1 (ko) |
| AT (1) | ATE37553T1 (ko) |
| BR (1) | BR8306594A (ko) |
| CA (1) | CA1219576A (ko) |
| DE (1) | DE3378122D1 (ko) |
| MX (1) | MX163655B (ko) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4548919A (en) * | 1982-12-17 | 1985-10-22 | American Cyanamid Company | Catalyst compositions for polyaliphatic isocyanate-based polyurethanes |
| NL1003263C2 (nl) * | 1996-06-04 | 1997-12-10 | Dsm Nv | Katalysator voor de reactie tussen een verbinding die met isocyanaat- groepen kan reageren en een verbinding die twee of meer isocyanaat- groepen met verschillende reaktiviteiten bevat. |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3385807A (en) * | 1964-11-30 | 1968-05-28 | Allied Chem | Cellular urethanes and process for preparing same wherein a combination of stannous and lead salts are employed |
| SE7400301L (ko) * | 1973-10-31 | 1975-05-02 | M & T Chemicals Inc |
-
1983
- 1983-10-22 AT AT83110577T patent/ATE37553T1/de not_active IP Right Cessation
- 1983-10-22 DE DE8383110577T patent/DE3378122D1/de not_active Expired
- 1983-10-22 EP EP83110577A patent/EP0111681B1/en not_active Expired
- 1983-11-30 BR BR8306594A patent/BR8306594A/pt not_active IP Right Cessation
- 1983-12-14 JP JP58234441A patent/JPS59115320A/ja active Granted
- 1983-12-14 MX MX199739A patent/MX163655B/es unknown
- 1983-12-15 CA CA000443430A patent/CA1219576A/en not_active Expired
- 1983-12-16 KR KR1019830005964A patent/KR920002770B1/ko not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE3378122D1 (en) | 1988-11-03 |
| MX163655B (es) | 1992-06-10 |
| JPH0410893B2 (ko) | 1992-02-26 |
| BR8306594A (pt) | 1984-07-31 |
| CA1219576A (en) | 1987-03-24 |
| JPS59115320A (ja) | 1984-07-03 |
| EP0111681B1 (en) | 1988-09-28 |
| EP0111681A2 (en) | 1984-06-27 |
| KR920002770B1 (ko) | 1992-04-03 |
| EP0111681A3 (en) | 1985-07-31 |
| ATE37553T1 (de) | 1988-10-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| G160 | Decision to publish patent application | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 19970331 Year of fee payment: 6 |
|
| LAPS | Lapse due to unpaid annual fee |