KR840006354A - 발포 및 경화성 조성물 - Google Patents

발포 및 경화성 조성물 Download PDF

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Publication number
KR840006354A
KR840006354A KR1019830004410A KR830004410A KR840006354A KR 840006354 A KR840006354 A KR 840006354A KR 1019830004410 A KR1019830004410 A KR 1019830004410A KR 830004410 A KR830004410 A KR 830004410A KR 840006354 A KR840006354 A KR 840006354A
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KR
South Korea
Prior art keywords
composition
parts
blowing agent
peroxide
promoter
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Application number
KR1019830004410A
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English (en)
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KR910006956B1 (ko
Inventor
루돌프 카멘즈 에르니스트
Original Assignee
베라 엠. 바이른
펜 월트 코포레이션
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Publication of KR840006354A publication Critical patent/KR840006354A/ko
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Publication of KR910006956B1 publication Critical patent/KR910006956B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/104—Hydrazines; Hydrazides; Semicarbazides; Semicarbazones; Hydrazones; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2333/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Sewage (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Forms Removed On Construction Sites Or Auxiliary Members Thereof (AREA)
  • Joining Of Building Structures In Genera (AREA)

Abstract

내용 없음

Description

발포 및 경화성 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 자유라디칼 개시에 의해 중합될 수 있고/있거나 가교결합될 수 있는 매질, 과산화물, 금속중 적어도 하나가 철 및 구리로부터 선택된 적어도 하나의 전이금속염 촉진제, 및 t-알킬 히드라지니움염 발포제의 혼합물을 함유함을 특징으로 하는 발포 및 경화성 조성물.
  2. 제1항에 있어서, 매질의 농도가 100부, 과산화물이 약 0.2내지 약 20부, 촉진제가 약 0.01내지 약 2.0부 및 발포제가 약 0.2내지 약 10부인 조성물.
  3. 제2항에 있어서, 과산화물의 농도가 약 0.5내지 10부, 촉진제가 약 0.05내지 약 1.0부 및 발포제가 약 0.2내지 약 5부인 조성물.
  4. 제1항에 있어서, 적당한 계면 활성제가 조성물내에 함유된 조성물.
  5. 제1항에 있어서, 언급된 매질이 불포화 폴리에스터 수지인 조성물.
  6. 제1항에 있어서, 언급된 과산화물이 과산화수소, 하이드로퍼옥사이드, 디아실퍼옥사이드, 퍼옥시 디카보네이트 및 케톤퍼옥사이드 그룹으로부터 선택된 조성물.
  7. 제1항에 있어서, 촉진제가 염화제2철, 염화제1철염화제1구리, 염화제2구리, 및 나프텐산구리 그룹으로부터 선택된 조성물.
  8. 주위온도에서 발포 및 경화가 완수될 때까지, 자유라디칼 개시에 의해 중합될 수 있고/있거나 가교 결합될 수 있는 매질, 과산화물, 금속중 적어도 하나가 철 및 구리로부터 선택된 적어도 하나의 전이금속염 촉진제 및, t-알킬히드라지니움염 발포제의 혼합물을 함유하는 발포 및 경화성 조성물을 반응시켜 발포 및 경화된 수지를 제조하는 방법.
  9. 제8항에 있어서, 먼저 금속염을 수지반응 혼합물에 가하여 완전히 혼합하고, 다음으로 발포제를 첨가하여 완전히 혼합하고, 마지막으로 과산화물을 첨가하여 완전히 혼합하는 방법.
  10. 제8항에 있어서, 수지가 불포화 폴리에스터수지인 제조방법.
  11. 제8항에 있어서, 발포제 및 금속염 촉진제를 조절함으로써 발포 및 경화된 수지의 밀도를 조절하는 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830004410A 1982-09-30 1983-09-20 발포 및 경화성 조성물 KR910006956B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US431,545 1982-09-30
US06/431,545 US4393148A (en) 1982-09-30 1982-09-30 Reaction of t-alkylhydrazinium salts and ogranic peroxides to foam unsaturated polyester resins

Publications (2)

Publication Number Publication Date
KR840006354A true KR840006354A (ko) 1984-11-29
KR910006956B1 KR910006956B1 (ko) 1991-09-14

Family

ID=23712412

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019830004410A KR910006956B1 (ko) 1982-09-30 1983-09-20 발포 및 경화성 조성물

Country Status (16)

Country Link
US (1) US4393148A (ko)
EP (1) EP0106938B1 (ko)
JP (1) JPS5981346A (ko)
KR (1) KR910006956B1 (ko)
AT (2) ATE36546T1 (ko)
AU (1) AU567542B2 (ko)
BR (1) BR8303409A (ko)
CA (1) CA1211900A (ko)
DE (1) DE3377718D1 (ko)
DK (1) DK161335C (ko)
ES (1) ES523708A0 (ko)
IL (1) IL68547A0 (ko)
IN (1) IN159539B (ko)
MX (1) MX162787A (ko)
PH (1) PH17609A (ko)
ZA (1) ZA833372B (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4692269A (en) * 1985-09-25 1987-09-08 Pennwalt Corporation Gas-releasing composition for tailoring gas evolution of system
US4607059A (en) * 1985-09-25 1986-08-19 Pennwalt Corporation Gas-releasing composition for tailoring gas evolution of system IR 2811
EP0220751A3 (en) * 1985-09-26 1988-08-17 Pennwalt Corporation Foamable and cross-linkable unsaturated polyester composition
US4636528A (en) * 1985-09-26 1987-01-13 Pennwalt Corporation Foaming of unsaturated polyester resin at elevated temperatures
US4607060A (en) * 1985-09-30 1986-08-19 Pennwalt Corporation Foaming and crosslinking of elastomeric and/or thermoplastic polymers
US4588752A (en) * 1985-09-30 1986-05-13 Pennwalt Corporation Foaming and vulcanizing of elastomeric polymers
US8530534B2 (en) 2006-05-04 2013-09-10 Air Products And Chemicals, Inc. Trimerization catalysts from sterically hindered salts
CN102633913B (zh) * 2012-04-19 2016-05-04 武汉市科达云石护理材料有限公司 引发剂组合物

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3993609A (en) * 1974-03-21 1976-11-23 Pennwalt Corporation Process for preparing foamed structures
US3920591A (en) * 1974-07-18 1975-11-18 Stepan Chemical Co Low-density polyester resin foams and method of preparation
US3920590A (en) * 1974-07-18 1975-11-18 Stepan Chemical Co Low-density polyester resin foams and method of preparation
US3920589A (en) * 1974-07-18 1975-11-18 Stepan Chemical Co Low-density polyester resin foams and method of preparation
US4101464A (en) * 1975-02-11 1978-07-18 Pennwalt Corporation Process for preparing foamed solids using two or more azo compounds
US4029615A (en) * 1975-02-11 1977-06-14 Pennwalt Corporation Polymeric cellular structures
US4309511A (en) * 1979-06-04 1982-01-05 Air Products And Chemicals, Inc. Process for promoting the low temperature cure of polyester resins
US4322502A (en) * 1980-09-11 1982-03-30 Uniroyal, Inc. Simultaneous expansion and cure of polyester resin composition
US4327196A (en) * 1980-12-22 1982-04-27 Uniroyal, Inc. Method for producing expanded and cured polyester resin
US4435525A (en) * 1982-09-30 1984-03-06 Pennwalt Corporation Reaction of carbonylhydrazines and organic peroxides to foam unsaturated polyester resins
CA1209300A (en) * 1983-12-12 1986-08-05 Thomas M. Burton Method of producing polyester foams using borohydride blowing agents
CA1208850A (en) * 1983-12-12 1986-07-29 Fiberglas Canada Inc. Blowing agents and their use in preparations of polyester foams

Also Published As

Publication number Publication date
JPS5981346A (ja) 1984-05-11
BR8303409A (pt) 1984-06-12
PH17609A (en) 1984-10-05
US4393148A (en) 1983-07-12
DK161335C (da) 1991-12-02
DK161335B (da) 1991-06-24
ZA833372B (en) 1984-01-25
KR910006956B1 (ko) 1991-09-14
EP0106938A3 (en) 1984-11-28
IL68547A0 (en) 1983-09-30
EP0106938A2 (en) 1984-05-02
ES8500975A1 (es) 1984-11-01
ATA279383A (de) 1987-11-15
MX162787A (es) 1991-06-26
ES523708A0 (es) 1984-11-01
DE3377718D1 (en) 1988-09-22
ATE36546T1 (de) 1988-09-15
DK446083A (da) 1984-03-31
AU2469584A (en) 1985-08-22
CA1211900A (en) 1986-09-23
DK446083D0 (da) 1983-09-29
EP0106938B1 (en) 1988-08-17
AU567542B2 (en) 1987-11-26
IN159539B (ko) 1987-05-23
JPH0358377B2 (ko) 1991-09-05

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