KR840003644A - 0가 닉켈 착화물의 제조방법 - Google Patents

0가 닉켈 착화물의 제조방법 Download PDF

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Publication number
KR840003644A
KR840003644A KR1019830000734A KR830000734A KR840003644A KR 840003644 A KR840003644 A KR 840003644A KR 1019830000734 A KR1019830000734 A KR 1019830000734A KR 830000734 A KR830000734 A KR 830000734A KR 840003644 A KR840003644 A KR 840003644A
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range
nickel
maintained
carbon atoms
concentration
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KR1019830000734A
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KR900003458B1 (ko
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조셉 오스테르마이어 죤
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에이.에.리디
이.아이.듀퐁 드 네모아 앤드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0257—Phosphorus acids or phosphorus acid esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

내용 없음

Description

0가 닉켈 착화물의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 표면적이 닉켈 1g당 약 800㎠ 이상의 원소 닉켈을, 반응 매질중의 액체 중량에 대하여 50중량% 이상의 L, 2중량% 이상의 탄소원자수 4 내지 20개를 갖는 유기 니트릴 및 유기 클로리다이트로서 100ppm 이상의 Cl로 조성되는 반응 매질중에서 반응온도를 102-0.375×(% L)와 동일한 최저온도 내지 58.3+0.725×(%L)와 동일한 최대온도의 범위 이내로 유지하면서 연속 접촉시킴을 특징으로 하는 하기 일반식으로 표시되는 0가 닉켈 착화합물의 연속 제조방법.
    Ni(L)4
    상기 식에서,
    L은 일반식 P(Z)3로 표시되는 중성 리간드이고, Z는 R 또는 OR이며, R는 탄소원자수 18개 이하의 알킬또는 아릴기이다.
  2. 제 1 항에 있어서, L의 농도가 65 내지 90% 범위로 유지되는 방법.
  3. 제 2 항에 있어서, 유기 니트릴의 농도가 6 내지 12% 범위로 유지되는 방법.
  4. 제 1, 2 또는 3 항에 있어서, 닉켈분말의 표면적이 닉켈 1g당 800 내지 2, 000㎠ 범위로 유지되고, 클로리다이트의 농도가 150 내지 300ppm Cl 범위로 유지되는 방법.
  5. 제 1 항에 있어서, L이 일반식 P(OAr)3(Ar는 탄소원자수 18개 이하의 아릴기임)로 표시되는 리간드인 방법.
  6. 제 4 항에 있어서, L이 일반식 P(OAr)3(Ar는 탄소원자수 18개 이하의 아릴기임)로 표시되는 리간드인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830000734A 1982-02-23 1983-02-23 0가 닉켈 착화합물의 제조방법 KR900003458B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/351,421 US4416825A (en) 1982-02-23 1982-02-23 Preparation of zerovalent nickel complexes
US351421 1982-02-23

Publications (2)

Publication Number Publication Date
KR840003644A true KR840003644A (ko) 1984-09-15
KR900003458B1 KR900003458B1 (ko) 1990-05-19

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KR1019830000734A KR900003458B1 (ko) 1982-02-23 1983-02-23 0가 닉켈 착화합물의 제조방법

Country Status (11)

Country Link
US (1) US4416825A (ko)
JP (1) JPS58157795A (ko)
KR (1) KR900003458B1 (ko)
BE (1) BE895990A (ko)
CA (1) CA1204119A (ko)
DE (1) DE3306311A1 (ko)
FR (1) FR2523974B1 (ko)
GB (1) GB2115421B (ko)
IT (1) IT1164587B (ko)
LU (1) LU84656A1 (ko)
NL (1) NL8300658A (ko)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4537982A (en) * 1982-08-03 1985-08-27 Bayer Aktiengesellschaft Production of organic nickel compounds
US4539302A (en) * 1984-04-30 1985-09-03 E. I. Du Pont De Nemours And Company Recovery of zerovalent nickel complexes
US6139445A (en) * 1998-08-14 2000-10-31 Frank D. Werner Golf club face surface shape
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854892B1 (fr) 2003-05-12 2005-06-24 Rhodia Polyamide Intermediates Procede de fabrication de dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
WO2007046799A1 (en) 2005-10-18 2007-04-26 Invista Technologies S.A R.L. Process of making 3-aminopentanenitrile
EP2395010B1 (en) 2006-03-17 2016-07-13 Invista Technologies S.à.r.l. Method for the purification of triorganophosphites by treatment with a basic additive
US7880028B2 (en) 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US7709674B2 (en) 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
CN101687658B (zh) 2007-05-14 2013-07-24 因温斯特技术公司 高效反应器和方法
WO2008157218A1 (en) 2007-06-13 2008-12-24 Invista Technologies S.A.R.L. Process for improving adiponitrile quality
CN101910119B (zh) 2008-01-15 2013-05-29 因温斯特技术公司 用于制备和精制3-戊烯腈，和用于精制2-甲基-3-丁烯腈的方法
CN101918356B (zh) 2008-01-15 2013-09-25 因温斯特技术公司 戊烯腈的氢氰化
FR2926816B1 (fr) 2008-01-25 2010-05-14 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2932477B1 (fr) 2008-06-17 2013-01-18 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
CN102177122B (zh) 2008-10-14 2013-12-11 因温斯特技术公司 用于制备2-仲烷基-4，5-二-(正烷基)苯酚的方法
FR2937321B1 (fr) 2008-10-21 2010-10-22 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2941455B1 (fr) 2009-01-29 2011-02-11 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
WO2011017543A1 (en) 2009-08-07 2011-02-10 Invista Technologies S.A. R.L. Hydrogenation and esterification to form diesters
EP2512673B1 (en) * 2009-12-18 2016-09-28 Invista Technologies S.à.r.l. Nickel metal compositions and nickel complexes derived from basic nickel carbonates
WO2012005917A1 (en) 2010-07-07 2012-01-12 Invista Technologies S.A.R.L. Process for making nitriles
WO2012033556A1 (en) 2010-09-07 2012-03-15 Invista Technologies S.A R.L. Preparing a nickel phosphorus ligand complex
JP2014523481A (ja) 2011-06-10 2014-09-11 インヴィスタ テクノロジーズ エスアエルエル 流動床反応器を含む焼成プロセス及び還元プロセス
CN107020150B (zh) 2011-06-10 2019-11-29 英威达纺织（英国）有限公司 镍金属配体催化剂形成上的改进
WO2013052610A1 (en) 2011-10-07 2013-04-11 Invista Technologies S.A R.L. Process for making nitriles
US9932298B2 (en) 2012-12-07 2018-04-03 Invista North America S.A R.L. Process for producing pentenenitriles
EP3593902A1 (en) 2012-12-07 2020-01-15 INVISTA Textiles (U.K.) Limited Composition for improved nickel-ligand solubility
EP3022172B1 (en) 2013-07-17 2018-10-17 INVISTA Textiles (U.K.) Limited Separating a solvent from a nickel catalyst by distillation

Family Cites Families (10)

* Cited by examiner, † Cited by third party
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NL266664A (ko) * 1960-07-07 1900-01-01
BE606408A (ko) * 1960-07-22
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US3152158A (en) * 1961-01-23 1964-10-06 Cities Service Res & Dev Co Method of preparing tetrakis (triorganophosphite) nickel compounds
US3631191A (en) * 1970-04-08 1971-12-28 Du Pont Synthesis of zero valent nickel-tetrakis triaryl phosphite complexes
US3668086A (en) * 1970-07-28 1972-06-06 Phillips Petroleum Co Electrochemical generation of soluble nickel(o) catalysts
US3671560A (en) * 1970-09-29 1972-06-20 Phillips Petroleum Co Manufacture of palladium or platinum-containing compounds
US3859327A (en) * 1972-10-25 1975-01-07 Du Pont Process for recovery of nickel from a deactivated hydrocyanation catalyst
US3903120A (en) * 1973-06-19 1975-09-02 Du Pont Preparation of zerovalent nickel complexes from elemental nickel
US4055582A (en) * 1976-05-10 1977-10-25 Phillips Petroleum Company Synthesis of nickel and palladium organophosphorus complexes

Also Published As

Publication number Publication date
BE895990A (fr) 1983-08-23
NL8300658A (nl) 1983-09-16
DE3306311C2 (ko) 1991-08-01
JPH0369915B2 (ko) 1991-11-05
GB2115421B (en) 1985-09-25
GB8304943D0 (en) 1983-03-23
IT8347749A0 (it) 1983-02-22
JPS58157795A (ja) 1983-09-19
FR2523974A1 (fr) 1983-09-30
FR2523974B1 (fr) 1986-09-12
CA1204119A (en) 1986-05-06
KR900003458B1 (ko) 1990-05-19
LU84656A1 (fr) 1983-09-08
DE3306311A1 (de) 1983-09-01
GB2115421A (en) 1983-09-07
IT1164587B (it) 1987-04-15
US4416825A (en) 1983-11-22

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