KR840003644A - 0가 닉켈 착화물의 제조방법 - Google Patents

0가 닉켈 착화물의 제조방법 Download PDF

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Publication number
KR840003644A
KR840003644A KR1019830000734A KR830000734A KR840003644A KR 840003644 A KR840003644 A KR 840003644A KR 1019830000734 A KR1019830000734 A KR 1019830000734A KR 830000734 A KR830000734 A KR 830000734A KR 840003644 A KR840003644 A KR 840003644A
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range
nickel
maintained
carbon atoms
concentration
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KR1019830000734A
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KR900003458B1 (ko
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조셉 오스테르마이어 죤
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에이.에.리디
이.아이.듀퐁 드 네모아 앤드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0257—Phosphorus acids or phosphorus acid esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

0가 닉켈 착화물의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 표면적이 닉켈 1g당 약 800㎠ 이상의 원소 닉켈을, 반응 매질중의 액체 중량에 대하여 50중량% 이상의 L, 2중량% 이상의 탄소원자수 4 내지 20개를 갖는 유기 니트릴 및 유기 클로리다이트로서 100ppm 이상의 Cl로 조성되는 반응 매질중에서 반응온도를 102-0.375×(% L)와 동일한 최저온도 내지 58.3+0.725×(%L)와 동일한 최대온도의 범위 이내로 유지하면서 연속 접촉시킴을 특징으로 하는 하기 일반식으로 표시되는 0가 닉켈 착화합물의 연속 제조방법.
    Ni(L)4
    상기 식에서,
    L은 일반식 P(Z)3로 표시되는 중성 리간드이고, Z는 R 또는 OR이며, R는 탄소원자수 18개 이하의 알킬또는 아릴기이다.
  2. 제 1 항에 있어서, L의 농도가 65 내지 90% 범위로 유지되는 방법.
  3. 제 2 항에 있어서, 유기 니트릴의 농도가 6 내지 12% 범위로 유지되는 방법.
  4. 제 1, 2 또는 3 항에 있어서, 닉켈분말의 표면적이 닉켈 1g당 800 내지 2, 000㎠ 범위로 유지되고, 클로리다이트의 농도가 150 내지 300ppm Cl 범위로 유지되는 방법.
  5. 제 1 항에 있어서, L이 일반식 P(OAr)3(Ar는 탄소원자수 18개 이하의 아릴기임)로 표시되는 리간드인 방법.
  6. 제 4 항에 있어서, L이 일반식 P(OAr)3(Ar는 탄소원자수 18개 이하의 아릴기임)로 표시되는 리간드인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830000734A 1982-02-23 1983-02-23 0가 닉켈 착화합물의 제조방법 KR900003458B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/351,421 US4416825A (en) 1982-02-23 1982-02-23 Preparation of zerovalent nickel complexes
US351421 1982-02-23

Publications (2)

Publication Number Publication Date
KR840003644A true KR840003644A (ko) 1984-09-15
KR900003458B1 KR900003458B1 (ko) 1990-05-19

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KR1019830000734A KR900003458B1 (ko) 1982-02-23 1983-02-23 0가 닉켈 착화합물의 제조방법

Country Status (11)

Country Link
US (1) US4416825A (ko)
JP (1) JPS58157795A (ko)
KR (1) KR900003458B1 (ko)
BE (1) BE895990A (ko)
CA (1) CA1204119A (ko)
DE (1) DE3306311A1 (ko)
FR (1) FR2523974B1 (ko)
GB (1) GB2115421B (ko)
IT (1) IT1164587B (ko)
LU (1) LU84656A1 (ko)
NL (1) NL8300658A (ko)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4537982A (en) * 1982-08-03 1985-08-27 Bayer Aktiengesellschaft Production of organic nickel compounds
US4539302A (en) * 1984-04-30 1985-09-03 E. I. Du Pont De Nemours And Company Recovery of zerovalent nickel complexes
US6139445A (en) * 1998-08-14 2000-10-31 Frank D. Werner Golf club face surface shape
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854892B1 (fr) 2003-05-12 2005-06-24 Rhodia Polyamide Intermediates Procede de fabrication de dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
EP1948591A1 (en) 2005-10-18 2008-07-30 INVISTA Technologies S.à.r.l. Process of making 3-aminopentanenitrile
US7629484B2 (en) 2006-03-17 2009-12-08 Invista North America S.A.R.L. Method for the purification of triorganophosphites by treatment with a basic additive
US7709674B2 (en) 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US7880028B2 (en) 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
WO2009075692A2 (en) 2007-05-14 2009-06-18 Invista Technologies S.A.R.L. High efficiency reactor and process
WO2008157218A1 (en) 2007-06-13 2008-12-24 Invista Technologies S.A.R.L. Process for improving adiponitrile quality
CN101918356B (zh) 2008-01-15 2013-09-25 因温斯特技术公司 戊烯腈的氢氰化
US7977502B2 (en) 2008-01-15 2011-07-12 Invista North America S.A R.L. Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
FR2926816B1 (fr) 2008-01-25 2010-05-14 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2932477B1 (fr) 2008-06-17 2013-01-18 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
US8247621B2 (en) 2008-10-14 2012-08-21 Invista North America S.A.R.L. Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols
FR2937321B1 (fr) 2008-10-21 2010-10-22 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2941455B1 (fr) 2009-01-29 2011-02-11 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
KR20120047251A (ko) 2009-08-07 2012-05-11 인비스타 테크놀러지스 에스.에이.알.엘. 디에스테르를 형성하기 위한 수소화 및 에스테르화
US8815186B2 (en) 2009-12-18 2014-08-26 Invista North America S.A.R.L. Nickel compositions for preparing nickel metal and nickel complexes
WO2012005916A1 (en) 2010-07-07 2012-01-12 Invista Technologies S.A.R.L. Process for making nitriles
EP2614070B1 (en) * 2010-09-07 2017-07-26 Invista Technologies S.à r.l. Nickel compositions for preparing nickel metal and nickel complexes
KR20140039268A (ko) 2011-06-10 2014-04-01 인비스타 테크놀러지스 에스.에이 알.엘. 유동층 반응기를 포함하는 하소 및 환원 방법
CN103732323B (zh) 2011-06-10 2016-09-14 因温斯特技术公司 用于催化镍-配体配合物的制备的镍形式
JP2014530221A (ja) 2011-10-07 2014-11-17 インヴィスタテクノロジーズ エスアエルエル ニトリルの作製方法
CN109999913A (zh) 2012-12-07 2019-07-12 英威达纺织（英国）有限公司 用于改善镍-配体的溶解性的组合物
EP2928597B1 (en) 2012-12-07 2019-07-17 INVISTA Textiles (U.K.) Limited Improved process for producing pentenenitriles
CN107082752B (zh) 2013-07-17 2021-06-15 英威达纺织（英国）有限公司 通过蒸馏将溶剂与镍催化剂分离

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US3668086A (en) * 1970-07-28 1972-06-06 Phillips Petroleum Co Electrochemical generation of soluble nickel(o) catalysts
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Also Published As

Publication number Publication date
JPH0369915B2 (ko) 1991-11-05
US4416825A (en) 1983-11-22
FR2523974B1 (fr) 1986-09-12
GB2115421B (en) 1985-09-25
LU84656A1 (fr) 1983-09-08
NL8300658A (nl) 1983-09-16
BE895990A (fr) 1983-08-23
FR2523974A1 (fr) 1983-09-30
GB8304943D0 (en) 1983-03-23
KR900003458B1 (ko) 1990-05-19
GB2115421A (en) 1983-09-07
CA1204119A (en) 1986-05-06
IT1164587B (it) 1987-04-15
DE3306311A1 (de) 1983-09-01
IT8347749A0 (it) 1983-02-22
DE3306311C2 (ko) 1991-08-01
JPS58157795A (ja) 1983-09-19

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