KR880000360A - 방향족 화합물의 아실화방법 - Google Patents

방향족 화합물의 아실화방법 Download PDF

Info

Publication number
KR880000360A
KR880000360A KR870005701A KR870005701A KR880000360A KR 880000360 A KR880000360 A KR 880000360A KR 870005701 A KR870005701 A KR 870005701A KR 870005701 A KR870005701 A KR 870005701A KR 880000360 A KR880000360 A KR 880000360A
Authority
KR
South Korea
Prior art keywords
metal
process according
aluminum
halide
alkyl
Prior art date
Application number
KR870005701A
Other languages
English (en)
Inventor
에게르스도르퍼 만프레트
지이겔 하르도
슈마허 알프레트
그로쉬 발터
헨켈만 요헴
Original Assignee
마티아스 · 바르쯔
바스프 악티엔게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19863619169 external-priority patent/DE3619169A1/de
Priority claimed from DE19863642329 external-priority patent/DE3642329A1/de
Application filed by 마티아스 · 바르쯔, 바스프 악티엔게젤샤프트 filed Critical 마티아스 · 바르쯔
Publication of KR880000360A publication Critical patent/KR880000360A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C07B37/02—Addition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/373—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in doubly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/46—Friedel-Crafts reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Fats And Perfumes (AREA)

Abstract

내용 없음

Description

방향족 화합물의 아실화방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 아실하반응이 주기율표상의 주족 2내지 5의 금속 또는 반금속 및/또는 아족 2 또는 4의 금속의 금속알킬 또는 할로겐화 금속알킬의 존재하에 수행됨을 특징으로 하는 프리델-크라프츠 방법에 의한 방향족화합물의 아실화방법.
  2. 제 1 항에 있어서, 할로겐화 카르보닐 또는 카르복실산 무수물을 알킬방향족화합물과 반응시켜 알킬치환된 방향족 케톤을 얻음을 특징으로 하는 방법.
  3. 제 1 항 및 2 항에 있어서, 알루미늄, 마그네슘, 붕소, 주석, 아연 또는 티탄의 금속알킬 또는 할로겐화 금속알킬을 사용함을 특징으로 하는 방법.
  4. 제 1 항 및 2 항에 있어서, 다음식(Ia)의 트리알킬 알루미늄 또는 할로겐화 알킬알루미늄 또는 식(Ia)의 2개의 화합물의 혼합물을 사용함을 특징으로 하는 방법 :
    RnAIX3-n(Ia)
    상기식에서, R은 같거나 또는 다르고, C1내지 C12알킬기이고, X는 할로겐원자이고, n은 1,2 또는 3이다.
  5. 제 1 내지 4 항중 어느 한항에 있어서, 사용된 할로겐화 금속알킬이 염화 또는 브롬화 금속알킬임을 특징으로 하는 방법.
  6. 제 1 내지 5 항중 어느 한항에 있어서, 사용된 프리델-크라프츠 촉매가 염화 또는 브롬합 알루미늄임을 특징으로 하는 방법.
  7. 제 1 내지 6 항중 어느 한항에 있어서, 사용된 방향족화합물이 알킬벤젠임을 특징으로 하는 방법.
  8. 제 2 내지 7 항중 어느 한항에 있어서, 프리델-크라프츠 촉매와 트리알킬알루미늄 또는 할로겐화 알킬알루미늄의 혼합물이 할로겐하 아실 1 당량당 1 내지 1.5몰의 양으로 사용되거나 또는 무수물의 1 당량당 2내지 2.5몰의 양으로 사용됨을 특징으로 하는 방법.
  9. 제 2 내지 7 항중 어느 한항에 있어서, 이할로겐화 알킬알루미늄 0.1 내지 약 1 몰 또는 트리알킬 알루미늄 0.03 내지 약 0.33몰이 할로겐화아실 또는 무수물의 1 당량당 사용됨을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR870005701A 1986-06-06 1987-06-05 방향족 화합물의 아실화방법 KR880000360A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE19863619169 DE3619169A1 (de) 1986-06-06 1986-06-06 Verfahren zur acylierung von aromaten
DEP3619169.8 1986-06-06
DEP3642329.7 1986-12-11
DE19863642329 DE3642329A1 (de) 1986-12-11 1986-12-11 Verfahren zur acylierung von aromaten

Publications (1)

Publication Number Publication Date
KR880000360A true KR880000360A (ko) 1988-03-25

Family

ID=25844428

Family Applications (1)

Application Number Title Priority Date Filing Date
KR870005701A KR880000360A (ko) 1986-06-06 1987-06-05 방향족 화합물의 아실화방법

Country Status (10)

Country Link
US (1) US4895984A (ko)
EP (1) EP0248423B1 (ko)
JP (1) JP2535018B2 (ko)
KR (1) KR880000360A (ko)
AU (1) AU601191B2 (ko)
CA (1) CA1305723C (ko)
DE (1) DE3760505D1 (ko)
ES (1) ES2010203B3 (ko)
FI (1) FI88914C (ko)
NO (1) NO165392C (ko)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3732015A1 (de) * 1987-09-23 1989-04-06 Basf Ag 2-neopentylanthrachinon, verfahren zur herstellung von 2-neopentylanthrachinon und dessen verwendung als katalysator bei der h(pfeil abwaerts)2(pfeil abwaerts)o(pfeil abwaerts)2(pfeil abwaerts)-herstellung
DE4011916A1 (de) * 1990-04-12 1991-10-17 Basf Ag Verfahren zur acylierung von alkylaromaten
DE69025185T2 (de) * 1990-04-18 1996-06-20 Chinoin Gyogyszer Es Vegyeszet Verbesserter prozess zur darstellung von keton-verbindungen
US5532416A (en) * 1994-07-20 1996-07-02 Monsanto Company Benzoyl derivatives and synthesis thereof
DE4233387A1 (de) * 1992-10-05 1994-04-07 Basf Ag Neue 2-tert.-Amylverbindungen
US5880290A (en) * 1994-01-31 1999-03-09 Monsanto Company Preparation of substituted 3-aryl-5-haloalkyl-pyrazoles having herbicidal activity
US5869688A (en) * 1994-07-20 1999-02-09 Monsanto Company Preparation of substituted 3-aryl-5-haloalkyl-pyrazoles having herbicidal activity
US5698708A (en) * 1996-06-20 1997-12-16 Monsanto Company Preparation of substituted 3-aryl-5-haloalkyl-pyrazoles having herbicidal activity
FR2760744B1 (fr) * 1997-03-12 1999-04-23 Rhodia Chimie Sa Procede d'acylation d'un compose aromatique
US6700036B2 (en) 2000-09-22 2004-03-02 Tredegar Film Products Corporation Acquisition distribution layer having void volumes for an absorbent article
US6610904B1 (en) 2000-09-22 2003-08-26 Tredegar Film Products Corporation Acquisition distribution layer having void volumes for an absorbent article
GB0123597D0 (en) 2001-10-02 2001-11-21 Univ Belfast Friedal-crafts reactions
WO2013040311A1 (en) * 2011-09-14 2013-03-21 Los Alamos National Security, Llc Compounds and methods for the production of long chain hydrocarbons from biological sources
TWI496739B (zh) * 2011-11-30 2015-08-21 Univ Chang Gung Chemically modified graphene and its preparation method
CN103524336A (zh) * 2013-09-18 2014-01-22 北京石油化工学院 高叔仲比的2-（4-戊基苯甲酰）苯甲酸的制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2004069A (en) * 1931-05-14 1935-06-04 Rohm & Haas Process for preparing alkylated aromatic ketones and product
US2587540A (en) * 1950-03-22 1952-02-26 Goodrich Co B F Method for the preparation of alpha-beta unsaturated ketones and aralkyl carboxylic acids
US3154585A (en) * 1961-07-21 1964-10-27 Continental Oil Co Method of producing ketones and alochols
DE1288584B (de) * 1966-01-31 1969-02-06 Akad Wissenschaften Ddr Verfahren zur Herstellung von Ketocarbonsaeuren mit ª†- oder ª€-staendigen Ketogruppen und bzw. oder der entsprechenden ungesaettigten und gesaettigten Lactone
AT351019B (de) * 1976-05-10 1979-07-10 Yamamoto Kagaku Gosei Kk Verfahren zur herstellung von 2-(p-amylbenzoyl) -benzoesaeure
EP0012850B1 (de) * 1978-11-28 1981-11-25 Hoechst Aktiengesellschaft Verfahren zur Herstellung von Ketonen durch Umsetzung von Carbonsäurehalogeniden mit Alkylaluminiumverbindungen
DE2851371C2 (de) * 1978-11-28 1981-01-29 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von Ketonen
JPS55113735A (en) * 1979-02-23 1980-09-02 Agency Of Ind Science & Technol Preparation of aromatic ketone
DE2928944A1 (de) * 1979-07-18 1981-02-12 Basf Ag Verbessertes verfahren zur herstellung von hoeheren ungesaettigten ketonen

Also Published As

Publication number Publication date
NO165392C (no) 1991-02-06
NO165392B (no) 1990-10-29
AU7389387A (en) 1987-12-10
ES2010203B3 (es) 1989-11-01
FI88914B (fi) 1993-04-15
FI88914C (fi) 1993-07-26
DE3760505D1 (en) 1989-10-05
AU601191B2 (en) 1990-09-06
EP0248423B1 (de) 1989-08-30
JPS62298538A (ja) 1987-12-25
US4895984A (en) 1990-01-23
JP2535018B2 (ja) 1996-09-18
EP0248423A1 (de) 1987-12-09
NO872383L (no) 1987-12-07
NO872383D0 (no) 1987-06-05
CA1305723C (en) 1992-07-28
FI872515A (fi) 1987-12-07
FI872515A0 (fi) 1987-06-04

Similar Documents

Publication Publication Date Title
KR880000360A (ko) 방향족 화합물의 아실화방법
KR880000507A (ko) 올레핀 중합 촉매 조성물 및 그 제조방법
IT1195953B (it) Componenti e catalizzatori per la polimerizzazione di olefine
KR890005018A (ko) 벤젠환이 염소화된 트리시클로 8.2.2.2 헥사데카 4,6,10,12,13,15헥산의 제조방법
SE8401555D0 (sv) Acetofenoner
GB1364141A (en) 2-mercapto-pyridine-n-oxyde metal salts
GB1242432A (en) CHLORINATION OF ALKYL AND ARALKYL omega-CYANOPERFLUOROALKANOATES AND ETHER ALKANOATES
FI895703A (fi) -olefiinien polymerointiin tarkoitettu prokatalyyttikompositio, sen valmistus ja käyttö
ES415100A1 (es) Procedimiento de obtencion de catalizadores solidos aplica-bles a la polimerizacion de olefinas.
GB1228615A (ko)
NO832808L (no) Alkenpolymeriseringskatalysator og anvendelse av denne
GB1037064A (en) Sulphur- and halogen-containing olefin polymers
KR910014333A (ko) 펜타플루오로디클로로프로판의 제조방법
KR850002569A (ko) 올레핀중합 촉매성분 및 중합법
KR840002767A (ko) 디페닐 벤조산염의 제조방법
US5345018A (en) Method for preparing 1-chloro-1-iodoethane
PT75328A (fr) Procede de preparation d'un catalyseur homogene comprenant un metal de transition et du magnesium utilisable dans la polimerisation de l'ethylene
KR920700190A (ko) 브롬화 중간체의 제조방법
KR940006986A (ko) 치환된 스티렌
KR880011058A (ko) 카르복실산 또는 카르복실산 할로겐화물 그룹을 트리할로메틸 그룹으로 전환시키는 방법
KR890009986A (ko) 알파-올레핀의 중합법과 이 중합에 사용할수 있는 고체 촉매착물 및 이의 제조방법
KR940701380A (ko) 5-(3-부티르일-2,4,6-트리메틸)-2-(1-(에톡시이미노)프로필)-3-하이드록시싸이클로헥스-2-엔-1-온 제조방법
GB1228810A (ko)
JPS5645910A (en) Polymerization of olefin
GB1297351A (ko)

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E601 Decision to refuse application